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The Global ETD Search service is a free service for researchers
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Synthesis And Environmental Applications Of Polyaniline And Its NanocompositesMahanta, Debajyoti 01 1900 (has links) (PDF)
The present thesis is focused on the synthesis and environmental applications of polyaniline and its nanocomposites. It is organized in six chapters and brief discussions of the contents of the individual chapters are given below. Chapter 1 reviews two important water purification methods: adsorption and photocatalysis, which are widely discussed in literature. A general introduction to conducting polymers has been given and their photocatalytic activity has been described. Chapter 2 reports the application of polyaniline emeraldine salt for the removal of anionic dyes from aqueous solutions by adsorption. A possible mechanism for the anionic dye adsorption by PANI emeraldine salt has been proposed. The electrostatic interaction between the positively charged PANI backbone and dye anions is responsible for significant dye adsorption. The kinetic parameters for the adsorption of anionic dyes on PANI have also been determined. In Chapter 3, we investigate the adsorption and desorption of anionic dyes from aqueous solution by PANI doped with different protonic acids. PANI with three dopants, namely p-toluene sulfonic acid (PTSA), camphor sulfonic acid (CSA) and dodecyl benzene sulfonic acid (DBSA) were used to adsorb various dyes. The adsorbed dyes were desorbed from the polymer by using a basic aqueous solution. It was found that the adsorption of dye is dependent on the size and nature of the dopant acids. The influence of different dopants on the adsorption and desorption kinetic parameters was also examined. In chapter 4, the inherent property of PANI to adsorb dyes has been explored for the detection of dyes by electrochemical method. The changes in the CV of PANI film coated on Pt electrodes on addition of dye have been employed for detection of dye in aqueous solution. Furthermore, PANI coated stainless steel (SS) electrodes show a change in current intensity of Fe2+/Fe3+ redox peaks due to addition of dye in the electrolyte solution. Chapter 5 describes the synthesis and characterization of polyaniline-grafted-chitosan (CPANI) with different grafting ratios. The mechanical properties and the crystallinity of CPANI were investigated by means of nanoindentation and X-ray diffraction experiments, respectively. CPANI has been further self-assembled into multilayer thin film via versatile and simple layer-by-layer (LbL) approach. Negatively charged hyaluronic acid (HUA) was used as complementary polyelectrolyte for the self-assembly. LbL growth of the multilayer thin films has been monitored with UV-vis spectral analysis as well as by AFM. The formation of thin film has been further characterized by SEM. The pH responsive behavior of CPANI/HUA multilayer thin film has been investigated. Reusability of this thin film has been investigated by repeating the pH responsive experiments for 10 cycles. Chapter 6 is focused on the preparation of nanocomposite thin films of CPANI/PSS/TiO2 via LbL approach. LbL growth of this self-assembly was monitored by UV-vis spectral analysis and porous nature was observed from SEM images. Poly (styrene sulfonate) (PSS) was used as bridging layer between TiO2 nanoparticles and CPANI for the multilayer self-assembly. Incorporation of CPANI within this LbL self-assembly enhanced the dye degradation ability of the thin film by increasing the availability of dye molecules around the TiO2 nanoparticles. Furthermore, CPANI may act as a sensitizer to enhance the photocatalytic activity of TiO2. The effects of surface area of the multilayer thin film and amount of catalysts (TiO2 nanoparticles) incorporated in the self-assembly were described based on the kinetics of the dye degradation reactions. The same multilayer thin film can be efficiently used for dye degradation several times. The work presented in this thesis utilizes unique dye adsorption properties of PANI and its copolymers. The change in conductivity of PANI after dye adsorption and the electrochemical dye detection in aqueous medium promise the potential of PANI as a dye sensing material in waste water at very low concentration. The nanocomposites of CPANI/PSS/TiO2 present a novel material for photocatalysis.
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La politique extérieure de l'Inde en Afrique / The Indian foreign policy in AfricaMonnet, Rodolphe 12 June 2018 (has links)
Depuis 2001 et la recomposition des équilibres de puissance, l'Inde s'affirme comme l'un des acteurs qui compte dans un espace international de plus en plus multipolaire. Les mouvements de fond actuels provoquent une redistribution de cette puissance imposant de nouvelles alliances et de nouveaux jeux de pouvoirs. L'Inde n'est pas étrangère à cette tendance et encore plus depuis l'arrivée au pouvoir, en 2014, de l'actuel Premier ministre, Narendra Modi. Ce dernier conduit une politique extérieure ambitieuse pour que son pays accède à un statut de puissance mondiale. C'est dans ce cadre que se pose notre problématique qui est de savoir dans quelle mesure la place de l'Afrique dans la politique étrangère indienne permet-elle justement à l'Inde de parvenir à se hisser à ce statut de puissance. Pour y répondre, cette thèse investigue trois directions. D'abord, la place de l'océan Indien dans la relation indo-africaine doit rendre compte du rôle de l'Afrique dans la volonté indienne de faire de cet océan un espace pacifique et sécurisé sur lequel l'Inde puisse être un acteur incontournable face à des acteurs politiques puissants et hétérogènes. Ensuite, cette thèse s'attache à déterminer le rôle que l'Afrique joue dans la volonté de l'Inde d'être une puissance ayant une capacité d'influence politique sur la scène internationale au travers des instances internationales, de ses relations bilatérales avec les États africains et de la diaspora indienne installée dans ces pays. Enfin, cette recherche de statut passe par le champ économique et la nécessaire évaluation de l'empreinte économique que l'Inde souhaite imprimer en Afrique pour mieux asseoir ses capacités d'influence. Cette étude doit permettre de donner un éclairage sur la politique extérieure indienne à l'heure où les États-Unis réévaluent leur implication dans l'océan Indien, où la Chine met en place la « One Belt, One Road » et où l'Inde et le Japon viennent de s'unir pour proposer un nouveau partenariat à l'Afrique. / Since 2001 and the reshuffling of the balance of power, India has become one of the influential actors in an increasingly multipolar international context. The current groundswells are reshuffling powers between Nations in shaping new alliances and new power games. India is, more than ever, involved in this trend since the current Prime Minister, Narendra Modi, came to power in 2014. He conducts an ambitious foreign policy as a means to make his country a global and respected power. The context of the issue detailed in this document is: to what extent does Africa's place in India's foreign policy enables India to reach this status of power? This thesis investigates the following three themes: Firstly, the Indian Ocean's place in the Indo-African relationship should reflect Africa's role in India's will to make the Indian Ocean region a peaceful and secured space in which India is a decisive player in front of powerful and heterogeneous political actors. Secondly, this thesis focuses on assessing Africa's role in India's initiatives to be an influential player on politics on the international agenda through international bodies, its bilateral relations with African states and the Indian diaspora settled down in these countries. Thirdly, India's search for that particular status goes through the economic area and the assessment of India's economic footprint in Africa to better establish its influence on that Continent. This study tries to shed the light on India's foreign policy while the United States are reassessing their involvement in the Indian Ocean, and while China is setting up its "One Belt, One Road" and India and Japan have just come together to propose a new partnership to Africa.
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Charge Transfer and Capacitive Properties of Polyaniline/ Polyamide Thin FilmsAbrahams, Dhielnawaaz January 2018 (has links)
Magister Scientiae - MSc (Chemistry) / Blending polymers together offers researchers the ability to create novel materials that
have a combination of desired properties of the individual polymers for a variety of
functions as well as improving specific properties. The behaviour of the resulting
blended polymer or blend is determined by the interactions between the two polymers.
The resultant synergy from blending an intrinsically conducting polymer like polyaniline
(PANI), is that it possesses the electrical, electronic, magnetic and optical properties
of a metal while retaining the poor mechanical properties, solubility and processibility
commonly associated with a conventional polymer. Aromatic polyamic acid has
outstanding thermal, mechanical, electrical, and solvent resistance properties that can
overcome the poor mechanical properties and instability of the conventional
conducting polymers, such as polyaniline.
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Corrosion Protection Performance and Spectroscopic Investigations of Soluble Conducting Polyaniline-Dodecylbenzenesulfonate Synthesized via Inverse Emulsion ProcedureShreepathi, Subrahmanya, Hoang, Hung Van, Holze, Rudolf 09 May 2009 (has links)
Corrosion protection performance of a completely soluble polyaniline-dodecylbenzenesulfonic acid salt (PANI-DBSA) on C45 steel has been studied with electrochemical impedance and potentiodynamic measurements. Chloroform is the most suitable solvent to process the pristine PANI-DBSA because of negligible interaction of the solvent with the polyaniline (PANI) backbone. An anodic shift in the corrosion potential (<img src="http://scitation.aip.org/stockgif3/Dgr.gif" alt="Delta" align="bottom" border="0"><i>E</i>=~70 mV), a decrease in the corrosion current and a significant increase in the charge transfer resistance indicate a significant anti-corrosion performance of the soluble PANI deposited on the protected steel surface. Corrosion protection follows the mechanism of formation of a passive oxide layer on the surface of C45 steel. In situ UV-Vis spectroscopy was used to investigate the differences in permeability of aqueous anions into PANI-DBSA. Preliminary results of electron diffraction studies show that PANI-DBSA possesses an orthorhombic type of crystal structure. An increase in the feed ratio of DBSA to aniline increases the tendency of aggregation of spherical particles of PANI obvious in transmission electron microscopy. PANI-DBSA slowly loses its electrochemical activity in acid free electrolyte without undergoing degradation.
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