This study aimed to contribute to baseline knowledge of permafrost geochemistry within the uppermost 3-4 m of permafrost at 8 sites on the Peel Plateau and east of the Mackenzie Delta, NWT (67-68oN). The following variables were measured: gravimetric water content (GWC), pore water conductivity (PWC), leachate conductivity (LC), dissolved ions by ICP-AES (i.e. Ca, SO4, Mg, Fe, K, Na, Mn, Cl), organic carbon content (calculated by linear regression from organic matter content), as well as inorganic carbon content (obtained from loss on ignition analysis). PWC was positively correlated to GWC and values were generally at least 5 times less than LC values, likely underestimating total dissolved solutes using the former method. LC increased with depth to reach maximum values below the paleo thaw unconformity (>10 mS/cm). Carbon content typically remained low throughout the cores with the exception of samples associated to the shallow-rooted vegetation cover at the ground surface. Results showed that the active layer, relict active layer and the permafrost below the thaw unconformity can be divided into three statistically significant layers. PCA results indicated some spatial patterns with increasing LC values at greater depth, suggesting that layer geochemical profiles reflect varying degrees of soil chemical weathering processes since the early Holocene.

Thawing permafrost – in the form of shoreline retrogressive thaw slump events – influence adjacent arctic tundra lake systems near Inuvik, NT. Slump-affected lakes demonstrated lower organic matter and key nutrients such as phosphorus (P), as well as greater water clarity. Key terrestrial permafrost soil indicators such as U, Sr, and Li, were identified to be elevated in slump-affected lakes, while other more biologically important metals (e.g. Fe, Mn) were significantly lower in affected lakes. These physical-chemical changes led to increasing P-limitation for both phytoplankton and periphyton, resulting in lower phytoplankton biomass (Chl-a). Using P as covariate in ANCOVA analysis, slump-affected lakes were also lower in phytoplankton biomass (Chl-a) relative to other study landscapes across the Canadian low-Arctic. Slump-affected lakes also exhibited lower organic matter leading to lower overall Hg concentrations within slump-affected lakes. However, this same reduction in dissolved organic carbon (DOC) has also led to an increase in bioavailable Hg, and increased bioaccumulation of Hg in both periphyton as well as macroinvertebrate species in our most disturbed lakes with DOC concentrations less than 6 and 9 mg DOC/L, respectively. A negative correlation between Hg bioaccumulation and DOC above these concentrations was also observed, and is the typical condition within reference lakes. The legacy impacts of mining were also observed in lakes within 25 km of the Giant Mine roaster stack in the Yellowknife region. Increases in both arsenic (As) and methyl mercury were measured in lakes nearer to the mine, with As concentrations well above water quality guidelines in lakes within 17 km of the roaster stack. This research highlights the necessity of baseline environmental monitoring prior to resource development, as well as the potential for compounded influences of such development within sensitive permafrost regions exposed to thawing.

Permafrost temperatures were measured by the Geological Survey of Canada (GSC) in 1977-1981 at boreholes along a proposed pipeline route in the southern Yukon. Analysis of climate station records indicate that mean annual air temperatures in the region have since increased by 0.5-1.0˚C. Renewed interest in the pipeline and the need to develop adaptation strategies for existing highway infrastructure have meant that information on permafrost and geotechnical conditions must be updated. To accomplish this goal, a total of eight GSC boreholes ranging in depth from 5-9 m were located, unblocked of ice and instrumented with thermistor cables and data-loggers to permit renewed ground temperature monitoring. Manual temperature measurements were also taken at four other shallow boreholes. Electrical resistivity tomography (ERT) surveys were conducted at each site. MAGTs below 1 m at permafrost sites in the study area range from -0.2˚C to -1.5˚C with permafrost depths greater than 25 m. The permafrost at the study sites can be classified as sporadic discontinuous and extensive discontinuous. Ground temperatures indicate that permafrost can persist under warmer climatic conditions as long as it remains protected by its ecosystem properties. Thermal monitoring for 2011-2012 shows an average increase of 0.5-1.0˚C when compared to the original 1978-1981 ground temperatures. This slow rate of ground warming is mainly attributed to a combination of limited climate change, especially in the south of the study area, ground temperatures close to 0˚C, and the possible disturbance of sites from the removal of vegetation prior to the original measurements being made. ERT surveys conducted at most borehole sites show deeper thaw or taliks where the cleared cut-line used for geophysical work in the 1970s is crossed. These results indicate the impacts of climate change and environmental change in the study area over the past three decades. They appear to match the relatively slow rates of ground warming observed elsewhere in northern Canada where permafrost temperatures are close to 0˚C and where warming also requires changes in latent heat due to internal thaw. TTOP equilibrium modelling suggests that if climate change is responsible for the ground warming, most of the change can be attributed to the step-like MAAT increase that occurred between 1975-1976.

This study investigates the runoff process and groundwater behavior in a subarctic watershed called Wolf Creek Research Basin, in Whitehorse, Yukon Territory, Canada. This basin is underlain by discontinuous permafrost that is typical of high latitude watersheds. Goundwater supports the stream flow year round and dominated the hydrology in most of the study period as baseflow. The baseflow was concentrated in dissolved ions. However, the baseflow was diluted during the melt season in May and June of 2012. Multiple chemical and isotopic tracers were used to develop a robust three-component (groundwater, soilwater and precipitation) mixing model for runoff generation. The concentrations of weathering ions decreased with the increased discharge during the melt. Soilwater was responsible for about 60% of the streamwater on the hydrograph in the melt season. The infiltration of the meltwater from the snowpack and the thawed water from the seasonal frost to the baseflow existed. The tritium concentrations indicated that there was fast moving hydrogeological system within the basin. The baseflow was also characterized as relatively enriched in both 13C and 14C, and concentrated in DIC. DIC was the major loss of carbon in Wolf Creek Research Basin.Le pergélisol est grandement sous-jacent dans les bassins-versants à haute latitude. Cette étude examine le processus de ruissellement et le comportement des eaux souterraines dans un bassin-versant subarctique de Wolf Creek, à Whitehorse, territoire du Yukon au Canada. Les eaux souterraines soutenaient l’écoulement fluvial et dominaient l’hydrographe comme débit de base durant la majorité de la période d’étude. Le débit de base était concentré d’ions dissipés. Par contre, le débit de base était dilué durant la saison des fontes au mois de mai et juin 2012. Plusieurs traceurs chimiques et isotopiques étaient utilisé afin de développer un modèle de trois composants (eau souterraine, eau interstitielle de sol et précipitation) de ruissellement. Les concentrations de la déségrégation des ions diminuaient avec l’augmentation du débit durant la fonte. Les eaux interstitielles des sols étaient responsables de 60% de l’eau de ruisseau sur l’hydrographe durant la saison de fontes. L’infiltration de l’eau de fonte du manteau neigeux et l’eau du gel du débit de base existaient. Les concentrations de tritium indiquent qu’il y avait un système hydrogéologique qui se déplaçait à grande vitesse dans les limites du bassin. Le débit de base était aussi caractérisé comme étant enrichi en 13C et 14C, avec des concentrations en carbone inorganique dissous.

This thesis applies a novel method of change detection, the Landsat Image Stack Trend Analysis method to the monitoring of retrogressive thaw slumps in the Richardson Mountains, NWT. This method represents a significant improvement upon previous methods of thaw slump monitoring, which utilized air photos and high-resolution satellite imagery. This method applies Tasseled Cap brightness, wetness and greenness indices to Landsat TM/ETM images acquired between 1985 and 2011 and analyzes the temporal change of each pixel for the different indices values. This method is useful in retrogressive thaw slump monitoring in two ways. First, by creating a map showing the linear change over time from 1985 to 2011, retrogressive thaw slumps can be easily identified, as they are more dynamic than the surrounding tundra. In total, 251 thaw slumps were identified within an area of roughly 18 000km2. Second, thaw slump activity, from initiation, growth and stabilization can be studied by plotting the annual vegetation index pixel values of adjacent pixels in a thaw slump. This method allows for the efficient extraction of annual thaw slump headwall retreat rates, provided the availability of cloud-free imagery. The retreat rates of 16 slumps were extracted, which were found to have an average annual retreat rate of 11.8 m yr-1.

Permafrost thaw slumping along lakeshores in lakes of the Mackenzie Delta Uplands, NT is known to alter water chemistry significantly. Its impact on benthic communities and persistent organic pollutant (POP) behaviour in lakes is not known. Benthic invertebrate communities responded to slumps through changes to community composition and size spectra. Larger taxa tended to dominate in lakes with slumps. Variability in biomass size spectra was related to total dissolved nitrogen concentration and slump size. Concentrations of POPs in Gammarus were negatively correlated with total phosphorus and positively correlated with the percentage of the catchment slumped. Lakes with slumps generally had higher mean concentrations of POPs in Gammarus (ex. ΣPCBsDisturbed = 27.54 ng/g lipid, ΣPCBsUndisturbed = 16.97 ng/g lipid; ΣDDT Disturbed =18.47 ng/g lipid and ΣDDTUndisturbed =10.86 ng/g lipid). Benthic invertebrate biomass was also negatively correlated with concentrations of contaminants in Gammarus, supporting the biomass dilution hypothesis. Thaw slumps have large enough impacts on the physico-chemical characteristics of lakes that they alter benthic invertebrate community composition and size-structure, and contaminant concentrations in Gammarus.

Organic matter (OM) in arctic permafrost ground contains about twice as much carbon (C) as is currently present in the atmosphere. Climate change is particularly strong in the Arctic, and could cause a considerable part of the OM in permafrost to thaw out, decompose, and be released as greenhouse gases; further enhancing global warming. The exact size of the northern circumpolar C pool remains unclear, and processes that control decomposition and mineralization rates are even more uncertain. Superimposed on the long-term release of C through microbial decomposition of OM in the gradually deepening active layer, is the rapid release of currently sequestered OM through geomorphological processes. This thesis considers the quantity, quality, and availability of permafrost C, and explores interactions and common controls. To better understand the potential effects of thawing permafrost, it is vital to: i) obtain more accurate size and distribution estimates of permafrost C stocks, and develop methods to accurately and efficiently implement these in models, ii) identify OM characteristics that control decomposition, specifically for permafrost material, and iii) determine and quantify key geomorphological processes that cause large amounts of OM to become available for rapid decomposition. Detailed C quantifications are valuable to increase our fundamental understanding of permafrost soil processes and C sequestration, but including high levels of heterogeneity in models is challenging. Simple upscaling tools based on e.g. elevation parameters (Paper I) can help to bridge the gap between detailed field studies and global C models. Permafrost OM quality is controlled by different factors than those commonly observed in temperate soils (without permafrost). We observed an unexpected (significant) correlation in upper permafrost samples, where material that is generally considered more recalcitrant showed the highest CO2 production rates per g C, indicating high lability (Paper II). In ancient Pleistocene permafrost, labile samples related significantly to OM that was enriched in decomposed microbial remains, whereas less-decomposed plant material was more stable (Paper III). Investigation of multiple incubation datasets revealed that the unusual relationship between %C and CO2 production occurred in contrasting field sites throughout the Arctic, indicating important permafrost-specific controls over OM quality (Paper IV). We discuss several possible explanations for the observed high lability of permafrost OM, such as a pool of labile dissolved organic C in the upper permafrost, or increased lability caused by past decomposition. In order to conclusively identify causal relationships, and to answer the question whether or not the same mechanisms control OM quality in different environments, further investigation of permafrost-specific OM quality is required. Geomorphology plays a key role in C reworking and OM decomposition. Vast amounts of OM can be released abruptly (e.g. in thaw slumps and thermokarst lakes, Paper II), resulting in C turnover that will likely outweigh decomposition through gradual active layer deepening. Climate change could enhance this rapid release of C, and changes in surface hydrology and increased fire activity are expected to become the largest contributors to C loss from permafrost regions. Together with C quantity and quality, availability through gradual and abrupt processes must be parameterized and included in models in order to accurately assess the potential permafrost C climate feedback. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 1: Manuscript. Paper 3: Manuscript. Paper 4: Manuscript.</p>

At this moment there is a gap in information regarding the affect roots might have on 210Pb distribution in peat cores and in turn the obtained chronologies by 210Pb dating. Therefore, four peat cores were collected from the snow manipulation study site within the mire complex Storflaket (68°20048″N, 18°58016″E). Two cores from snow fence plots, which has experienced root growth due to permafrost thaw, and 2 cores from control plots. 210Pb distribution and the provided 210Pb chronologies were then compared with root content within and between the cores. In two of the cores (C5 and SF2) did subsurface peaks in the 210Pb activity profile follow the distribution profile of the dwarf shrub roots. The same pattern was not seen with Eriophorum roots. This indicates that presence of dwarf root with their shallow and horizontally growth can affect the 210Pb profile by horizontal translocation of 210Pb. The chronologies obtained by the CF:CS and CRS dating models could not be validated for the C5 core which suggest that dwarf shrub roots also can affect the 21oPb dating.

Rapid warming in northern latitudes will lead to permafrost thaw and subsequent carbon remobilisa­tion and release to the atmosphere. To incorporate the permafrost carbon climate feedback in globalEarth System Models, it is of importance to know the carbon stored in the circum­Arctic permafrostregion as accurate and precise as possible. Whereas soil, Yedoma and delta carbon stocks are alreadyquantified, deep carbon stocks for vast areas of the current permafrost region are still unaccountedfor. The aim of this Master thesis project is to estimate the deep carbon stock (&gt;3m) for Quaternarydeposits outside the known reservoirs. Therefore, 363 boreholes and exposures were compiled fromthe scientific literature. 244 sites provide profile descriptions (depositional environment, depth andthickness) and another 119 sites contain data to calculate carbon densities (ground ice content, coarsefraction (&gt;1cm and/or &gt;2mm), bulk density and total organic carbon). Data gaps were filled usinglocal, regional and global average facies values from the compiled dataset. For spatial upscaling,key regions are defined using the permafrost zone, overburden thickness and ice content. The fielddata compiled here shows disagreements with the Circum­Arctic Map of Permafrost and Ground­Iceconditions (Brown et al. 2002), which should be updated especially in thin and ice­poor regions. Atotal C stock of 1698 ±255 PgC is estimated for 3­25m in Quaternary deposits of the circum­Arcitcpermafrost region, next to the Yedoma domain (327 ­ 466 PgC, Strauss et al. 2017) and deltas (41 ­151 PgC, Hugelius et al. 2014). About 70% of the carbon is stored within 3­10m (1200 ±238 PgC).Due to a publication bias towards thick and organic­rich sediments in the literature, C stocks calcualtedhere might be overestimated. Additional to the Yedoma domain, 309 ±99 PgC are stored in ice­richdeposits of the continuous permafrost zone, a regions especially prone to thermokarst and deep carbonremobilisation. Thermokarst, thermo­fluvial erosion along rivers and coasts as well as carbon releasethrough inland water systems presents possible release mechanisms for stored carbon. The permafrostcarbon estimate determined here doubles the known carbon reservoir in the permafrost region and em­phasises the importance for possible deep carbon release with future permafrost thawing.

At this moment there is a gap in information regarding the affect roots might have on 210Pb distribution in peat cores and in turn the obtained chronologies by 210Pb dating. Therefore, four peat cores were collected from the snow manipulation study site within the mire complex Storflaket (68°20048″N, 18°58016″E). Two cores from snow fence plots, which has experienced root growth due to permafrost thaw, and 2 cores from control plots. 210Pb distribution and the provided 210Pb chronologies were then compared with root content within and between the cores. In two of the cores (C5 and SF2) did subsurface peaks in the 210Pb activity profile follow the distribution profile of the dwarf shrub roots. The same pattern was not seen with Eriophorum roots. This indicates that presence of dwarf root with their shallow and horizontally growth can affect the 210Pb profile by horizontal translocation of 210Pb. The chronologies obtained by the CF:CS and CRS dating models could not be validated for the C5 core which suggest that dwarf shrub roots also can affect the 21oPb dating.