Funktionskläder utgör idag en stor marknad över hela världen med stigande efterfrågan där syntetiska material står för en betydande andel av de producerade textilierna. Ett plaggs totala miljöpåverkan kan till stor del härledas till materialvalet. Materialkompositionen i underställ består ofta av blandningar av textila fibrer, vilket komplicerar återvinningsprocessen och gör den nästintill omöjlig. För att kunna 'sluta cirkeln' måste innovativa textila lösningar tas fram för att styra textilindustrin i rätt riktning. Studien undersöker alternativa fibrer och jämför dem med de konventionella för textilier till underställ där man vill uppnå god fukttransport och värmeisolering. Vidare kartläggs materialens användningsområden för att skapa ett mångsidigt funktionsplagg och därmed möjliggöra en klimatsmartare garderob. Studien identifierar och jämför de termofysiologiska egenskaperna hos materialen bambuviskos, merinoull, Tencel, PCM och Coolmax. Textilprover stickades i hundraprocentiga materialkompositioner med en utvald trikåbindning i en rundsticksmaskin. Textilprovets termofysiologiska egenskaper utvärderades med hjälp av testutrustningarna Hudmodellen och WickView för att bestämma värmemotstånd och fukttransport. Därefter analyserades resultaten på materialens termofysiologiska komfort för att sedan kartlägga deras användningsområde baserat på aktivitetsnivå och omgivningsfaktorer. Resultaten från studien indikerar att merinoull och Coolmax kan rekommenderas för användning i underställ där både värmeisolering och fukttransport är viktiga, där merinoull är mest lämplig för kalla klimat. Vidare kan bambuviskos och Tencel vara lämpliga alternativ för användning i underställ vid aktiviteter av måttlig intensitet i varierande klimatförhållanden. PCM, med sitt låga värmemotstånd och medelhöga fukttransport, gör materialet mindre lämpligt för underställ. Testresultaten från studien ger insikt i materialens termofysiologiska komfort, men bör inte ses som en heltäckande bild av denna komfort. För att erhålla en mer valid slutsats krävs ytterligare tester och beaktande av fler faktorer. / Functional clothing represents a significant global market with rising demand today, where synthetic materials account for a considerable proportion of the textiles produced. A garment's total environmental impact can largely be traced back to the choice of material. The material composition of base layers often consists of mixtures of textile fibers, which complicates the recycling process and makes it almost impossible. To 'close the loop', innovative textile solutions must be developed to steer the textile industry in the right direction. The study investigates alternative fibers and compares them with conventional ones for textiles in base layers where effective moisture transport and heat insulation are sought. Furthermore, the areas of use for these materials are mapped out to create a versatile functional garment, thereby enabling a more climate-smart wardrobe. The study identifies and compares the thermophysiological properties of the materials bamboo viscose, merino wool, Tencel, PCM, and Coolmax. Textile samples were knitted in 100% material compositions using a selected tricot stitch on a circular knitting machine. The thermophysiological properties of the textile samples were evaluated using the Skin Model and WickView testing equipment to determine heat resistance and moisture transport. Afterwards, the results on the materials' thermophysiological comfort were analyzed, and their areas of use were mapped out based on activity level and environmental factors. The results from the study indicate that merino wool and Coolmax can be recommended for use in base layers where both heat insulation and moisture transport are important, with merino wool being most suitable for cold climates. Furthermore, bamboo viscose and Tencel could be suitable alternatives for use in base layers for activities of moderate intensity in varying climate conditions. PCM, with its low heat resistance and medium-high moisture transport, makes the material less suitable for base layers. The test results from the study provide insight into the materials' thermophysiological comfort but should not be seen as a comprehensive picture of this comfort. To obtain a more valid conclusion, additional tests and consideration of more factors are required.

Utilizing Phase Change Materials (PCM) for Latent Thermal Energy Storage (LTES) applications have previously been extensively researched as a measure to reduce greenhouse gas emissions from energy consumption. In order to make use of the waste heat from industrial processes for LTES purposes, a new demand emerged for PCMs capable of phase change in mid-temperature ranges of 100 °C - 200 °C. This higher temperature requirement made most of the previously studied material inapplicable as they had much lower melting and solidification temperatures. With this in mind, a new generation of PCMs consisting of Sugar Alcohols (SA) has been proposed. Erythritol is seen as an especially promising SA with good thermophysical properties for LTES purposes. However, it has been shown to suffer from severe supercooling, which makes it unreliable in real applications. To eradicate this issue, two additives, Graphene Oxide (GO) and Polyvinylpyrrolidone (PVP) at varying mass fractions were mixed with pure erythritol to form a composite which was studied using the Temperature-history (T-history) method to determine its effectiveness in reducing supercooling. Results show that at its most effective mass fraction, GO reduces supercooling by 28 o C and a 31 o C reduction is seen by the addition of PVP. The impacts on the duration of crystallization was also documented and analyzed using the same method. It was observed that the duration of crystallization was increased with increasing mass fractions of the additives. Other important properties of the composites were also studied in order to determine the overall feasibility for industrial applications. It includes analysis of the storage capacity through latent heat, changes in viscosity along with impacts on thermal diffusivity of the composites. / Att använda fasändringsmaterial (PCM) för termisk energilagring i form av latent värme (LTES) har tidigare extensivt forskats och undersökts som en lösning för att minska utsläppen av växthusgaser från energiförbrukning. För att utnyttja spillvärme från industriella processer för LTES-ändamål uppstod en efterfrågan på PCM som ändrar fas i temperaturer mellan 100 °C - 200 °C. Detta krav på högre temperatur gjorde att de flesta av de tidigare aktuella materialen inte kunde tillämpas eftersom de hade mycket lägre smält- och kristalliseringstemperaturer. Med detta i åtanke har en ny generation av PCM bestående av sockeralkoholer (SA) föreslagits. Erytritol ses som ett särskilt lovande SA med goda egenskaper för LTES-ändamål. Den har dock visat sig drabbas av svår underkylning, vilket gör den opålitligt i verkliga tillämpningar. För att utrota detta problem blandades två tillsatser, Graphene Oxide (GO) och Polyvinylpyrrolidone (PVP) vid olika massfraktioner med ren erytritol för att bilda en komposit som studerades med metoden Temperature-history (T-history) för att bestämma dess effektivitet på att minska underkylningen. Resultaten visar att GO på sin mest effektiva massfraktion minskar underkylningen med 28 o C och tillsats av PVP lyckats minska den med som mest 31 o C. Påverkningarna på varaktighet av kristallisering dokumenterades och analyserades med samma metod. Det var observerad att varaktigheten av kristallisering ökades med ökande massfraktioner av tillsatserna. Även andra viktiga egenskaper hos kompositerna studerades för att avgöra rimligheten att använda dessa för industriella tillämpningar. Det inkluderar analys av lagringskapaciteten genom latent värme, förändringar i viskositet tillsammans med påverkan på kompositernas termiska diffusivitet.

Utilizing Phase Change Materials (PCM) for Latent Thermal Energy Storage (LTES) applications have previously been extensively researched as a measure to reduce greenhouse gas emissions from energy consumption. In order to make use of the waste heat from industrial processes for LTES purposes, a new demand emerged for PCMs capable of phase change in mid-temperature ranges of 100 °C - 200 °C. This higher temperature requirement made most of the previously studied material inapplicable as they had much lower melting and solidification temperatures. With this in mind, a new generation of PCMs consisting of Sugar Alcohols (SA) has been proposed. Erythritol is seen as an especially promising SA with good thermophysical properties for LTES purposes. However, it has been shown to suffer from severe supercooling, which makes it unreliable in real applications. To eradicate this issue, two additives, Graphene Oxide (GO) and Polyvinylpyrrolidone (PVP) at varying mass fractions were mixed with pure erythritol to form a composite which was studied using the Temperature-history (T-history) method to determine its effectiveness in reducing supercooling. Results show that at its most effective mass fraction, GO reduces supercooling by 28 oC and a 31 oC reduction is seen by the addition of PVP. The impacts on the duration of crystallization was also documented and analyzed using the same method. It was observed that the duration of crystallization was increased with increasing mass fractions of the additives. Other important properties of the composites were also studied in order to determine the overall feasibility for industrial applications. It includes analysis of the storage capacity through latent heat, changes in viscosity along with impacts on thermal diffusivity of the composites. / Att använda fasändringsmaterial (PCM) för termisk energilagring i form av latent värme (LTES) har tidigare extensivt forskats och undersökts som en lösning för att minska utsläppen av växthusgaser från energiförbrukning. För att utnyttja spillvärme från industriella processer för LTES-ändamål uppstod en efterfrågan på PCM som ändrar fas i temperaturer mellan 100 °C - 200 °C. Detta krav på högre temperatur gjorde att de flesta av de tidigare aktuella materialen inte kunde tillämpas eftersom de hade mycket lägre smält- och kristalliseringstemperaturer. Med detta i åtanke har en ny generation av PCM bestående av sockeralkoholer (SA) föreslagits. Erytritol ses som ett särskilt lovande SA med goda egenskaper för LTES-ändamål. Den har dock visat sig drabbas av svår underkylning, vilket gör den opålitligt i verkliga tillämpningar. För att utrota detta problem blandades två tillsatser, Graphene Oxide (GO) och Polyvinylpyrrolidone (PVP) vid olika massfraktioner med ren erytritol för att bilda en komposit som studerades med metoden Temperature-history (T-history) för att bestämma dess effektivitet på att minska underkylningen. Resultaten visar att GO på sin mest effektiva massfraktion minskar underkylningen med 28 oC och tillsats av PVP lyckats minska den med som mest 31 oC. Påverkningarna på varaktighet av kristallisering dokumenterades och analyserades med samma metod. Det var observerad att varaktigheten av kristallisering ökades med ökande massfraktioner av tillsatserna. Även andra viktiga egenskaper hos kompositerna studerades för att avgöra rimligheten att använda dessa för industriella tillämpningar. Det inkluderar analys av lagringskapaciteten genom latent värme, förändringar i viskositet tillsammans med påverkan på kompositernas termiska diffusivitet.

<p dir="ltr">Smart windows, dynamically adjusting optical transmittance, face global adoption challenges due to climatic and economic variability. Aiming these issues, we synthesized a methyl cellulose (MC) salt system with high tunability for intrinsic optical transmittance (89.3%), which can be applied globally to various locations. Specifically, the MC window has superior heat shielding potential below transition temperatures while turning opaque at temperatures above the Lower Critical Solution Temperature (LCST), reducing the solar heat gain by 55%. Such optical tunability is attributable to the particle size change triggered by the temperature-induced reversible coil-to-globular transition. This leads to effective refractive index and scattering modulation, making them prospective solutions for light management systems, an application ahead of intelligent fenestration systems. MC-based windows demonstrated a 9°C temperature decrease compared to double-pane windows on sunny days and a 5°C increase during winters in field tests, while simulations predict an 11% energy savings.</p><p dir="ltr">Incorporating MC-based phase change materials in passive solar panels indicated optimized energy efficiency, offering a sustainable alternative. Real-time simulations validate practical applicability in large-scale solar panels. Furthermore, a temperature-responsive sorbent with a dark layer demonstrates an optimal optical and water uptake performance. Transitioning between radiative cooling and solar heating, the sorbent exhibits high water harvesting efficiency in lab and field tests. With an adjustable LCST at 38 ℃, the cellulose-based sorbent presents a potential solution for atmospheric water harvesting, combining optical switching and temperature responsiveness for sustainable water access. Furthermore, the ubiquitous availability of materials, low cost, and ease-of-manufacturing will provide technological equity and foster our ambition towards net-zero buildings and sustainable future.</p>

The Phase change materials (PCM) have the ability to absorb and release heat as the temperature changes from high to low temperature and vice versa. The use of phase change materials has increased in the construction sector due to the established environmental requirements and the various application benefits, especially in the thermal comfort of building applications and construction of sustainable infrastructure around the world (Berardi and Gallardo, 2019). Over the past decade, many studies have been conducted on the thermal properties of PCM (phase change material), however, few studies have focused on the study effect of PCM on mechanical and physical properties, although of great importance. In this work, three different microencapsulated types of phase change material (PCM) have been studied, while its effect on the mechanical and hydration properties of the cement paste with regard to constant ratio of water to cement ratio has been taken into account. The PCMs that have been studied are the following: Microencapsulated PCM, which is Nextek 24 D, Nextek 57D (Microtek Laboratories) and Croda Therm ME29P (Croda). In this study, various tests were performed on cementitious paste mixed with different doses of PCM to test the effect that PCM has on the cement hydration (under semi-adiabatic and isothermal conditions), the physical properties (setting time, slump flow, density) and the mechanical properties ( compressive strength). The results of this study indicated that both the melting point of the PCM and its amount have a decisive effect on the properties of the cement paste. Finally, the following conclusions have been drawn: • Additions of different dosage levels of the 24D and Croda PCM types showed that an increase in the dosage resulted in impaired mechanical and physical properties such as compressive strength of the cement paste (mechanical) decreased, and the density and random flow decreased (physical). While Nextek 57D did not show a great effect on cement paste according to density and random flow, which gives reduced negative impact on cement paste workability (physical). According to the mechanical properties, Nextek57D PCM with different levels of levels showed immediate positive effect on cement paste compressive strength compared to reference paste (no addition of PCM), and other cement pastes with other PCM types used in this study. • Mikrotek 57D PCM also gives a positive effect at different dose levels compared to two other types of Nextek 24D and Croda PCM regarding the effect of heat flow, which gives rise to hydration heat during the cement hydration process. However, other types of Nextek 24D and Croda in all quantities showed negligible effect on the heat flow during the cement hydration process.

Die vorliegende Arbeit untersucht die Leistungsfähigkeit von PV-Modulen in verschiedenen Fassadensystemen und beschreibt die Entwicklung eines Fassadenpaneels für Pfosten-Riegel-Fassaden, bei welchem die Modultemperatur durch die Integration von Phasenwechselmaterialien (PCM) reguliert wird, um einen höheren Wirkungsgrad zu erzielen.

Tato diplomová práce je zaměřena na sestavení přehledu konstrukcí a teplených cest kosmických lodí a kosmických vozidel, které se v současné době používají. Na základě specifických požadavků a standardů jsou vypracovány koncepční návrhy zástavby tepelného spínače do konstrukce družice. V jednotlivých kapitolách jsou popsány určité členy, které se na vedení tepla podílí a jsou důležité pro navrhované koncepty z pohledu konstrukce. Diplomová práce popisuje postupy výpočtu tepelných vodivostí a rozložení působící tíhové síly do míst uchycení pro jednotlivé koncepty. Na závěr provádí hodnocení a výběr potenciálně nejvhodnějšího návrhu.

La gestion thermique des batteries Li-ion pour le véhicule électrique est essentielle, pour assurer une autonomie et une durée de vie optimales de ces batteries. Habituellement, des circuits d'air ou de liquide de refroidissement sont utilisés comme systèmes de gestion thermique. Cependant, ces systèmes sont coûteux en termes d'investissement et d'exploitation et doivent être dimensionnés sur la puissance maximale à extraire. L'utilisation de matériaux à changement de phase (MCP) pour l’absorption sous forme de chaleur latente de la chaleur à dissiper peut représenter une alternative moins coûteuse et plus facile à utiliser. En effet, les MCP peuvent stocker passivement la chaleur excédentaire produite et être utilisés en tant que systèmes passifs. Cependant, les MCP présentent de nombreux inconvénients comme la difficulté de décharger l’énergie thermique stockée, ce qui limite l’aptitude du système au cyclage, ou encore leur conductivité thermique peu élevée qui limite les capacités d’échange. Pour résoudre le problème de la régénération des MCP, un système actif supplémentaire peut être ajouté, dimensionné sur une puissance modérée; l'ensemble devient alors un système semi-passif. Dans cette étude, un système de gestion thermique composé d'un MCP et d’air en convection forcée est évalué. Ce système permet de coupler les avantages de ces deux techniques. Une modélisation du système est développée pour une cellule de batterie. Une comparaison avec de l’air uniquement, en convection forcée, montre l'utilité du MCP. Pour augmenter la capacité d’échange du MCP, un matériau à haute conductivité thermique peut être ajouté au MCP, ce qui permet d’obtenir un composite ayant une conductivité thermique plus élevée. Des composites basés sur les MCP étudiés et des nanostructures de carbone sont élaborés, leur conductivité thermique est mesurée. Ensuite, un système expérimental simulant la dissipation d’une cellule de batterie est construit et utilisé pour évaluer le MCP seul, le MCP inclus dans une mousse métallique et le meilleur composite obtenu. Enfin, pour se rapprocher des conditions réelles, un modèle représentant un stack entier de batterie est développé, des simulations sont produites et les résultats obtenus sont commentés. / Li-ion battery thermal management is essential for electric vehicles (EVs), to ensure an optimal autonomy and lifespan of those batteries. Usually, air or coolant circuits are employed as thermal management systems. However, those systems are expensive in terms of investment and operating costs and must be dimensioned on the maximal power to be extracted. The use of phase change materials (PCMs) as latent heat storage medium allowing the absorption of the heat to be dissipated as latent heat may represent an alternative cheaper and easier to operate. In fact, PCMs can passively store the excess heat produced by a device and be used as passive systems. However, PCMs have several drawbacks like the difficulty to discharge the stored thermal load which limits the system’s cyclability or their low thermal conductivity which limits their heat transfer capacity. To solve the problem of the PCM regeneration, an additional active system can be added, dimensioned on a moderate power; the whole becomes a semi-passive system. In this study, a thermal management system composed of a PCM and forced air convection is evaluated. This system permits to combine the respective advantages of the two techniques. A model of the system is developed for one battery cell. A comparison with forced air convection only points out the usefulness of the PCM. To overcome the PCM low thermal conductivity, a highly conductive material can be added to the PCM permitting to obtain a composite with a higher thermal conductivity. Composites based on the PCMs studied and carbon nanostructures are elaborated, and their thermal conductivity is measured. Then, an experimental system permitting to simulate the dissipation of a battery cell is build and used to evaluate the PCM alone, the PCM embedded in metal foam and the better obtained composite. Finally, to be closer to the real conditions, a model representing an entire battery stack is developed, simulations are produced and the obtained results are discussed.

The work is focused on the development of an environmentally friendly external thermal insulation composite system in terms of product composition and composition of the whole system. The intention is to develop an alternative to standard external thermal insulation composite systems. Undoubtely, standard systems have a contribution to energy savings (primary role), but their actual production and composition is also a burden on the environment. The research is focused onthe development of adhesive and leveling substance and plaster using progressive material with phase transformation and energy by-product (fly ash). Furthermore, it is focused on the selection of insulation from renewable sources. Therefore, there is paid attention to the overall composition of the thermal insulation system in order to achieve the most effective impact with respect to the environment. The goal is to achieve secondary energy and resource savings due to the composition of components and also the composition of the entire system.

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