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Abstract Sleep Apnea (SA) is a common disorder that affects approximately 2% of middle-aged women and 4% of middle-aged men. It is characterized by repetitive cessation of breathing during sleep. SA has significant health and social consequences such as daytime sleepiness, impaired quality of life, and in the worst case, myocardial infarction and sudden cardiac death. It has been estimated that approximately 80% of individuals with moderate to severe SA syndrome have not been diagnosed. The lack of patient sleep histories has caused low identification of SA and referral rates, especially in primary care facilities. Moreover, due to the inadequate prevalence of overnight polysomnography (PSG) as a standard clinical test of SA, patients suspected of having this sleep disorder have to wait several months for diagnosis and treatment. The costly and time-consuming nature of PSG and the lack of sleep clinics have created a demand for suitable home-based health monitoring devices. Over the years, several devices have been developed to monitor sleep unobtrusively, while an individual is lying in bed. However, most of these devices would either disrupt the sleep of the patient or be disrupted by the patient during routine bed sheet changes. Pressure measurement using a Pressure Sensitive Mat (PSM) enables a non-contact approach for monitoring patient vital signs such as respiration rate. The PSM has the potential to replace obtrusive breathing sensors in the sleep lab and to be used as a pre-screening tool for patients suspected of having sleep apnea. This thesis proposes multiple algorithms applicable to PSM in order to assess sleep quality. First, fusion techniques are proposed to extract a breathing signal from PSM. Second, a wide range of machine learning approaches including a simple threshold-based algorithm, a linear support vector machine (SVM) and two deep learning methods (i.e., a temporal convolutional network (TCN) and a bidirectional long short-term memory (BiLSTM) network) are compared to find a good- iii performing method for automatically detecting central sleep apnea (CSA) events from PSM signals. The results show that the accuracy of the model with the best performance is 95.1% and it is achieved by the BiLSTM network. Finally, by applying SVM, personalized systems are optimized to investigate long-term sleep pattern changes such as central apnea index (CAI), bed occupancy (BO), day-clock, and night-clock from previously recorded data.

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This thesis investigates the effect of reaction media on the efficiency of grafting hydrophobic polymers from cellulose nanocrystals (CNCs) via surface-initiated atom transfer radical polymerization (SI-ATRP), with the goal of producing highly-modified CNCs for incorporation into latex-based pressure sensitive adhesives (PSAs). A latex is a dispersion of polymer particles in water made by emulsion polymerization; latexes are commonly used in paints, coatings, elastomers, inks/toners, household products, cosmetics, and adhesives. However, latex-based PSAs often underperform compared to their organic solvent-polymerized counterparts due to a lack of cohesive strength in the cast latex films. The environmental benefit of using latex-based PSAs synthesized in water is significant, but the development of strategies to improve their performance are required. CNCs are hydrophilic rod-shaped nanoparticles with high mechanical strength. Adding CNCs to latex-based PSAs has been shown to improve both adhesive (i.e., tack and peel strength) and cohesive (i.e., shear strength) properties and offers a degree of sustainability because CNCs are derived from natural cellulose sources such as wood pulp. However, their hydrophilicity, particularly relative to the hydrophobic polymers used in PSAs, has constrained CNCs to the continuous (i.e., water) phase of the latex. To improve CNC compatibility with the dispersed (i.e., polymer) phase and improve their distribution in cast latex films, hydrophobic polymers can be grafted from CNCs. However, CNCs with a high polymer graft density are required to ensure their compatibility with monomers/polymers during latex synthesis. To begin, grafting poly(butyl acrylate) (PBA) from CNCs using SI-ATRP in polar dimethylformamide (DMF) versus non-polar toluene was directly compared. The enhanced colloidal stability of initiator-modified CNCs in DMF led to improved accessibility to surface initiator groups during polymer grafting. As such, PBA-grafted CNCs produced in DMF had up to 30 times more grafted polymer chains than PBA-grafted CNCs produced in toluene. The PBA-grafted CNCs produced in DMF showed high contact angles when cast in a film and formed stable suspensions in toluene. This work highlights that optimizing CNC colloidal stability in a given solvent prior to polymer grafting is a more crucial consideration than solvent–polymer compatibility in the context of obtaining high graft densities and thus hydrophobic CNCs via SI-ATRP. The improved polymer grafting method in DMF was then used to produce PBA and poly(methyl methacrylate) (PMMA)-grafted CNCs at two polymer chain lengths. Polymer grafted CNCs were incorporated in situ during a seeded semi-batch emulsion polymerization to produce PBA latex nanocomposite PSAs. Viscosity measurements revealed significant differences between latexes prepared with CNCs versus polymer-grafted CNCs, with the lower viscosities of the latter suggesting their incorporation inside the polymer particles. When CNCs with short polymer grafts were introduced into PSAs at 1 wt. % loading, they exhibited comparable tack and improved peel strength compared to unmodified CNCs (and all properties improved relative to the base latex without any CNCs). This is attributed to their improved distribution throughout the PSA, the enhanced wettability of the substrate with the CNC containing latex, and the increased polymer chain mobility achieved based on the low molecular weight of the grafts. CNCs with long polymer grafts aggregated in the latex and did not improve PSA properties. PMMA-grafted CNCs slightly outperformed PBA-grafted CNCs likely due to the higher glass transition temperature of PMMA. These results provide insight into future optimization of more sustainable latex-based PSA formulations as well as new commercial CNC-latex products, where the presence of low molecular weight grafts on CNC surfaces could improve polymer mobility and tack and peel strength. / Thesis / Master of Applied Science (MASc) / When the adhesives used in tapes, labels or sticky notes are produced using water-based reactions, they normally underperform compared to conventional adhesives produced using toxic solvents. To improve such water-based adhesives, adding nanocellulose (tiny particles derived from wood pulp) during synthesis has been shown to be an asset. Nanocellulose can be chemically modified to improve its compatibility with adhesive ingredients, and thus change the role of nanocellulose during adhesive manufacturing. In this thesis, modified nanocelluloses were added to water-based adhesives to evaluate their effect on performance (i.e., strength and stickiness). It was found that the reaction conditions during nanocellulose modification were crucial for obtaining highly modified particles that are compatible with adhesive ingredients. This work aims to provide insight for future production of less environmentally taxing adhesives made in water and expand the use of nanocellulose in new commercial products.

In this study, novel lamination techniques are introduced for the coating of fabrics in order to enhance their ballistic/needle penetration resistance properties. Pressure sensitive adhesive (PSA) was used to create flexible ballistic composite panels with ultra-high molecular weight polyethylene (UHMWPE) fabric. An increase in processing pressure from 0.1 to 8 MPa significantly improved the ballistic performance against 9 mm FMJ ammunition of UHMWPE composite. The number of layers required to stop the bullet were reduced from 45 to 22 layers after lamination without a significant increase in stiffness. The backface signature (BFS) was reduced from 19.2 mm for the 45 layer neat samples to 11.7 mm for the 25 layer laminated samples pressed at 8 MPa. The second lamination technique used patterned thermoplastic hot film to create flexible UHMWPE composite laminates. Hexagonal patterns were cut through a heat transfer vinyl carrier sheet using a vinyl cutter and was used as a mask between the UHMWPE fabric and hot film during heat treatment in order to have the fabric coated only on those regions. The patterns had a nominal diameter of 27.9 mm with a 1 mm gap between each region. A significant improvement in the ballistic performance of UHMWPE fabric is observed after coating each individual layer with patterned hot film and 25 layers of laminated fabric were sufficient to stop a .357 magnum FMJ ammunition compared to unlaminated neat fabric which required 45 layers to stop the bullet. Patterning of the hot film did not negatively affect the ballistic performance of the composite laminates whilst increasing their flexibility in relation to using plain hot film with no patterning involved. It resulted in a 21% increase in bending angle of the 25 layer samples v and 9.5% reduction in bending length of the single plies which both relate to greater flexibility because a higher bending angle and lower bending length correlates to more flexibility. The same technique of patterning of hot film is used in the lamination of woven cotton fabric to enhance needle penetration resistance properties whilst maintaining the flexibility. Patterns used in this study were either hexagonal or a combination of hexagons and triangles and the nominal diameter ranged from 2.6-13.5 mm. The lamination significantly improved the 25G hypodermic needle penetration resistance of the fabric. By increasing the number of laminated fabric plies from 1 to 2, the needle resistance force increased by up to 150%. However, in comparison to just one layer, the flexibility decreased by about 12% to 26% for two and three layers, respectively. It was observed that reducing the sizes of the patterns improved the flexibility of the samples by up to 30% without compromising the needle penetration resistance. / Thesis / Master of Applied Science (MASc)

Pressure sensitive insoles are an emerging and promising technology that has always been interesting for gait and planar pressure related applications. This technology can be especially valuable for monitoring, movement, and rehabilitation purposes where the pressure sensing insoles could be utilized to assess for abnormalities in order to treat or prevent complications. This thesis project explores the use of graphene coated resistive textiles based smart insoles with the purpose of constructing a functional, easy to fabricate prototype that is viable for plantar pressure and gait cycle applications. This project follows a double diamond, co-productive approach with multiple stakeholders involved during the discovery, definition, development, and delivery of the project to co-create knowledge of value for society. The results of the thesis project present three functional prototypes with 3, 4 and 6 pressure sensors with the 4-sensor prototype indicating to be the most feasible out of the three. The highlight of the prototypes features is that it is capable of detecting and measuring pressure, operates with durable and thin properties and low accuracy. Through proper calibration with an ADC tool, the prototype was able to detect and measure movement during testing. Furthermore, several areas with a room for improvement have been identified with potential for further automating the production process as well as unlocking barriers for certain applications with a cost effective approach. In conclusion, this thesis project contributes to the advancement of smart insoles by presenting a functional, easy to fabricate method for the production of smart insoles for low accuracy gait cycle and plantar pressure applications.

This thesis aims to improve the performance of latex-based pressure-sensitive adhesives (PSAs). PSA performance is usually evaluated by tack, peel strength and shear strength. Tack and peel strength characterize a PSA’s bonding strength to a substrate while shear strength reflects a PSA’s capability to resist shear deformation. In general, increasing shear strength leads to a decrease in tack and peel strength. While there are several commercial PSA synthesis methods, the two most important methods consist of either solvent-based or latex-based techniques. While latex-based PSAs are more environmentally compliant than solvent-based PSAs, they tend to have much lower shear strength, at similar tack and peel strength levels. Therefore, the goal in this thesis was to greatly improve the shear strength of latex-based PSAs at little to no sacrifice to tack and peel strength. In this study, controlling the polymer microstructure of latexes or their corresponding PSA films was used as the main method for improving the PSA performance. The research was sub-divided into four parts. First, the influence of chain transfer agent (CTA) and cross-linker on latex polymer microstructure was studied via seeded semi-batch emulsion polymerization of butyl acrylate (BA) and methyl methacrylate (MMA). Three techniques were used to produce the latexes: (1) adding CTA only, (2) adding cross-linker only, and (3) adding both CTA and cross-linker. It was found that using CTA and cross-linker simultaneously allows one to expand the range of latex microstructural possibilities. For example, latexes with similar gel contents but different Mc (molecular weight between cross-links) and Mw (molecular weight of sol polymers) could be produced if CTA and cross-linker concentration are both increased. However, for the corresponding PSAs with similar gel contents, the relationship between their polymer microstructure and performance was difficult to establish as almost all of the medium and high gel content PSAs showed very low tack and peel strength as well as extremely large shear strength readings. In the second part of this thesis, in order to improve the tack and peel strength of medium and high gel content PSAs, the monomer composition and emulsifier concentration were varied. It was found that changing the monomer mixture from BA/MMA to BA/acrylic acid (AA)/2-hydroxyethyl methacrylate (HEMA) while simultaneously decreasing emulsifier concentration dramatically improved the corresponding PSAs’ shear strength as well as tack and peel strength. The addition of polar groups to the PSA increased its cohesive strength due to the presence of strong hydrogen bonding; meanwhile, PSA films’ surface tension increased. In the third part, two series of BA/AA/HEMA latexes were generated by varying the amounts of CTA either in the absence or presence of cross-linker. The latexes produced in the absence of cross-linker exhibited significantly larger Mc and Mw compared to their counterparts with similar gel contents prepared with cross-linker. The PSAs with the larger Mc and Mw showed much larger shear strengths due to improved entanglements between the polymer chains. In the final part of the thesis, the performance of the BA/AA/HEMA PSAs was further improved by post-heating. Compared with original latex-based PSAs with similar gel contents, heat-treated PSAs showed not only significantly improved shear strengths, but also much larger tack and peel strengths. The different shear strengths were related to the PSAs’ gel structures, which were discrete in the original PSAs but continuous in the heat-treated PSAs. The improved tack and peel strengths were related to the PSA films’ surface smoothness. During the post-heating process, the PSA polymer flowed, resulting in much smoother surfaces than the original PSA films. In addition, the effect of post-heating was related to the polymer microstructure of the untreated PSAs. Decreasing the amount of very small or very big polymers or simultaneously increasing Mc and Mw could lead to post-treated PSAs with significantly better performance. Moreover, it was found that by optimizing the polymer microstructure of the original latex-based PSAs, it was possible to obtain a treated PSA with similar or even better performance than a solvent-based PSA with similar polymer microstructure. Our original objective was surpassed: in two cases, not only was shear strength greatly improved, but so were tack and peel strength due to the simultaneous modification of PSA bulk and surface properties.

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