O presente projeto tem como objetivo contribuir para o desenvolvimento de dispositivos para monitoração de pressão dinâmica do ar. Para isso, foram produzidos filmes sensíveis a pressão baseados na detecção de concentração de oxigênio por meio de processos de emissão fotoluminescente das moléculas de Azul de Metileno (MB) e Platina Octaetilporfirina (PtOEP). Nesse sentido, foi estudado o comportamento da emissão fotoluminescente dessas moléculas em interação com o gás de oxigênio. A concentração de oxigênio (do ar) sobre superfície sensível depende da pressão dinâmica de superfície. Desta forma, monitorando a fotoluminescência dos dispositivos submetidos a diferentes concentrações de oxigênio, pode-se determinar uma relação entre a pressão pontual da superfície analisada e a intensidade de emissão fotoluminescente do filme. Os dispositivos de monitoração de pressão dinâmica são constituídos de um filme de estado sólido contendo as moléculas sensíveis. Foram utilizados como substratos hospedeiros para o Azul de Metileno e para a Octaetilporfirina de Platina, os filmes de silício poroso oxidado e Poliestireno, respectivamente. É proposto um arranjo experimental que utiliza um fluorímetro para caracterizar as amostras produzidas e uma câmara de fluxo de gases. Os dispositivos apresentaram elevada sensibilidade e evidenciaram o potencial para desenvolvimento e integração de sensores baseados no silício poroso à microeletrônica. / This project aims to contribute to the development of devices for monitoring dynamic pressure of the air. In this sense, films were produced based on pressure-sensitive detection of oxygen concentration through processes of photoluminescence emission from the molecules of methylene blue (MB) and platinum octaethylporphyrin (PtOEP). Accordingly, it was studied the behavior of the photoluminescence emission of these molecules in interaction with the oxygen gas. The concentration of oxygen (of the air composition) on the sensitive surface depends on the surface dynamic pressure. Thus, monitoring the photoluminescence of the devices under different oxygen concentrations, it can be determined a relationship between the punctual pressure of the tested surface and the photoluminescence emission intensity of the film. The devices for monitoring dynamic pressure are made of a solid state film containing the sensitive molecules. Oxidized porous silicon and polystyrene films were used as hosts for the Methylene Blue and for the Platinum Octaethylporphyrin, respectively. It was proposed an experimental setup that uses a spectrofluorophotometer and a gas flow chamber to characterize the produced samples. The devices showed high sensitivity and potential for development and integration of the sensors based on porous silicon for microelectronics.

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No. of bitstreams: 1 TA Régis Sá - Versão final.pdf: 1389017 bytes, checksum: 97c7377b6be8f6a5b880fad7cad49613 (MD5) Previous issue date: 2018-09-27 / Este Trabalho Aplicado examina como se dá a incorporação de sustentabilidade na agenda de inovação do segmento de rótulos autoadesivos, através do estudo de caso da Novelprint, importante player do segmento no Brasil. Traz revisão da literatura sobre a conexão entre sustentabilidade e inovação no contexto das organizações, culminando no conceito de Sustainability-Oriented Innovation (SOI). A análise da incorporação de sustentabilidade na agenda de inovação, unidade de análise do estudo de caso, se dá por meio de modelos de SOI. Utiliza a metodologia de estudo de caso único, com dados coletados em entrevistas semi-estruturadas com profissionais do setor e da empresa estudada e analisados sob a ótica dos modelos SOI apresentados na revisão de literatura. O caso apresenta um modelo de negócio atípico no segmento por integrar verticalmente todas as etapas produtivas de autoadesivos: laminação, conversão e equipamentos de aplicação. A empresa estudada detém mais de cem patentes e possui em seu portfólio produtos com importantes atributos de sustentabilidade. Para contexto há uma análise setorial sobre o segmento de rótulos autoadesivos no Brasil, sua cadeia de fornecimento e perfil das empresas laminadoras e convertedoras destes materiais, além de estudar temas da sustentabilidade neste segmento. A análise revela não haver incorporação da sustentabilidade na agenda de inovação do segmento, ainda que existam ações de ecoeficiência, inerentes ao setor de embalagens. Não foram identificadas demandas externas explícitas como pressões de clientes e empresas usuárias, tão presentes em compromissos empresariais relacionados à sustentabilidade no setor de bens de consumo, ou mesmo de regulação, fazendo com que o tema da sustentabilidade esteja distante, não apenas da agenda de inovação, mas também à estratégia de sustentabilidade de forma mais ampla. O estudo revela ainda que, apesar de contar com produtos que apresentam vantagens em atributos sustentáveis, a empresa examinada não utiliza corretamente este diferencial em seu mercado de atuação, algo que é objeto de recomendações ao final do trabalho. Considerando-se o limitado poder de generalização deste estudo, o protagonismo da empresa no setor e seu perfil inovador, seria válido examinar se os achados deste estudo também se aplicam a outros players do segmento no país. / This paper examines the incorporation of sustainability aspects in the innovation’s agenda in the Brazilian pressure sensitive labels (PSL) market throw case study methodology, focused on Novelprint, an important player in this segment. Presents a literature review related to the connection between sustainability and innovation in organizations contexts, leading to the examination of the SustainabilityOriented Innovation (SOI) concept. The analysis of the incorporation of sustainability aspects in the innovation’s agenda, the analysis focus in the case study, occurs through SOI models. It uses the single case study methodology, with the data collected in semistructured interviews with professionals of the sector and the company and analyzed by the SOI models presented in the literature review. The case presents an atypical vertically business model, integrating all the structures of the PSL segment: coating & lamination, converting and label application machinery, owner of more than one hundred patents and with important attributes of sustainability in its products portfolio. To context this understanding, this present paper includes a PSL sectorial analysis in Brazil, their supply chain and the profile of coating & lamination and converting companies, besides studying the theme of sustainability in this segment. The analysis reveals that there’s no incorporation of sustainability in the innovation agenda, even though there are ecoefficiency actions inherent to the packaging sector. No external demands have been identified, as pressures from customers and end-user companies, so present in sustainable corporate commitments in the consumer goods sector, or even regulation, making the subject of sustainability far away, not only in relation to the innovation agenda, but also to the sustainability strategy in general. The study also reveals that, despite products with advantages in sustainable attributes in its portfolio, the company doesn’t use this differential correctly in its market, something that is object of recommendations at the end of the work. Considering the limited generalization power of this study, the company's role in the industry and its innovative profile, it would be worth exam if the findings of this study also apply to other players in the Brazilian PSL market.

Indiana University-Purdue University Indianapolis (IUPUI) / Paper spray - mass spectrometry (PS-MS) has been developed as a rapid and direct ionization method for qualitative and quantitative analysis of complex samples at trace levels. In this work, different sampling devices for PS-MS were investigated to improve the assay’s simplicity and sensitivity over traditional approaches. In particular, chapter two characterizes an alternate paper substrate to enhance drug detection on surfaces like asphalt, cloth, concrete, aluminum, and glass. Analysis occurs on a single spray ticket coated with pressure-sensitive adhesive (PSA), also known as Post-it notes to detect and quantify drug residues. A PS-MS method utilizing PSA paper was developed to detect a mixture of ten drugs off of various surfaces to evaluate the qualitative and quantitative capabilities of the aforementioned substrate. After the method development on a conventional linear ion trap mass spectrometer, the assay was translated for use on a portable mass spectrometer to evaluate the suitability of the pressure-sensitive adhesive paper substrate in the field in chapter three. Chapter four introduces a sampling device combined with a snap-in solid-phase extraction (SPE) column. The new cartridge design not only inherits the functions from the first iteration SPE cartridge, including extraction and preconcentration from complex samples, but also exhibits greater flexibility in volume control and ease of use for on-site sample collection.

When performing a biomechanical analysis of human movement, knowledge about the ground reaction force (GRF) is necessary to compute forces and moments within joints. This is important when analysing a movement and its effect on the human body. To obtain knowledge about the GRF, the gold standard is to use force plates which directly measure all three components of the GRF (mediolateral, anteroposterior and normal). However, force plates are heavy, clunky and expensive, setting constraints on possible experimental setups, which make it desirable to exclude them and instead use a predictive method to obtain the full GRF. Several predictive methods exist. The node model is a GRF predictive method included in a musculoskeletal modeling software. The tool use motion capture and virtual actuators to predict all three GRF components. However, this model has not yet been validated during weighted leg press and weighted squat. Furthermore, the normal component of the GRF can be measured continuously during the activity with pressure sensitive insoles (PSIs), which might provide better accuracy of the GRF prediction. The objectives of this thesis were to investigate whether force plates can be exluded during weighted leg press and weighted squat and to investigate whether PSIs can improve the GRF prediction. To investigate this, the node model and a developed shear model was validated. The shear model computes the two shear GRF components based on data from PSIs, an external load acting upon the body and data from a motion capture system. Both the node model and the shear model were analysed with two test subjects performing two successive repetitions of both weighted squat and weighted leg press in a flywheel exercise device. During the leg press exercise, the node model had a mean coeffcient of correlation (Pearson's) ranging from 0.70 to 0.98 for all three directions with a mean root mean square error ranging between 8 % to 20 % of the test person's body weight. The developed shear model had a coeffcient of correlation (Pearson's) between 0.64 to 0.99 and a mean root mean square error between 3 % and 21 % of the test person's body weight. This indicates that it is possible to exclude force plates and instead predict the GRF during weighted leg press. During squat, neither the node model nor the shear model provided accurate results regarding the mediolateral and anteroposterior components of the GRF, suggesting that force plates can not yet be excluded to obtain the full GRF during weighted squat. The results of the normal component during leg press was somewhat improved with the shear model compared to the node model, indicating that using PSIs can improve the results to some extent.

High fidelity measurements are necessary to validate existing and future turbulence models for the purpose of producing the next generation of more efficient gas turbines. The objective of the present study is to conduct several different measurements of multi-row film cooling arrays in order to better understand the physics involved with injection of coolant through multiple rows of discrete holes into a flat plate turbulent boundary layer. Adiabatic effectiveness distributions are measured for several multi-row film cooling geometries. The geometries are designed with two different hole spacings and two different hole types to yield four total geometries. One of the four geometries tested for adiabatic effectiveness was selected for flowfield measurements. The wall and flowfield are studied with several testing techniques, including: particle image velocimetry, hot wire anemometry, pressure sensitive paint and discrete gas sampling.

No description available.

<p>Multilayer polymer decorative films are showing a growing presence in the automotive industry, substituting conventional paint applications while maintaining similar aesthetic appeal. However for certain film constructions that have distinct layer properties, the polymer film laminates have shown to form wrinkles on application of heat during thermoforming. In this study, attempts were made to identify the factors influencing wrinkling and to predict the variation in the wrinkle parameters under changing forming conditions using existing theoretical models. A new modified thermoforming technique is proposed for producing thermoformed parts without wrinkles and thereby achieving a <em>Class A</em> finished surface.</p> / Master of Applied Science (MASc)

Autohesion is defined as the resistance to separation of two bonded identical films that have been joined together for a period of time under a given temperature and pressure. Studies on the autohesion phenomenon can provide fundamental insights into the physical processes of adhesive bond and failure, as well as the practical engineering issues such as crack healing, elastomer tack, polymer fusion, self-healing, and polymer welding. In the first part of this dissertation work, four ethylene/1-octene (EO) copolymers were used in the present study consisting of molecules with linear polyethylene backbone to which hexyl groups are attached at random intervals. These copolymers have similar number-average molecular weight (Mn) and polydispersity, but different 1-octene content. These hexyl groups act as the short branches and hinder the crystallization, reduce density to some extent in the solid state, lower the melting temperature, and decrease the stiffness of the bulk materials. A full understanding of the autohesion behavior of the ethylene/1-octene copolymers involves investigations at three different length scales: 1) the molecular scale which controls the interfacial structure; 2) the mesoscopic or microscopic scale which can provide information on the formation of interfaces and on how the energy is dissipated during a fracture process; and 3) the macroscopic scale at which the mechanical properties such as fracture energy can be obtained for a particular test geometry. In the present study, the effects of the branch content on the formation and fracture of the interface of these ethylene/1-octene assemblies were evaluated at the bonding temperatures (Tb) and bonding times (tb). The correlation among these three length scales was also investigated and modeled. The adhesion strength of these symmetric interfaces of EO copolymers was investigated by T-peel fracture tests. The fracture of the interface is an irreversible entropy creating process which involved a substantial amount of energy dissipation. The results of such mechanical tests with respect to the bonding temperature (Tb), bonding time (tb) and peel rate indicated this energy dissipation is the result of a complicated interplay between the ability of the interface to transfer stress and its plastic and viscoelastic deformation properties. When Tb is much higher than the characteristic temperature (Tc), the interfaces were completely healed and cohesive failure was observed in T-peel tests. In this case, the fracture strength decreased with increasing branch content. In contrast, when Tb is very close to Tc, the fracture strength showed an increase with the branch content with either interfacial failure or cohesive failure being observed depending on the branch content and Tb. At higher peel rates, it is observed that higher peel energies are required to fracture the surfaces. Transmission electron microscopy (TEM) showed that the interfacial/interphase structure changed from amorphous to crystalline with an increase in the Tb. The results from the bonding time effect studies showed that the peel energy is proportional to tb1/2 regardless of Tb. But the branch content and the Tb play an important role on the seal rate. Thus, higher seal rate was found for higher Tb and higher branch content. These results also suggest that the autohesion of ethylene/1-octene copolymers are strongly associated with the interactions of melted chains. The chain compositions of these Zeigler-Natta EO copolymers are highly heterogeneous with the branches concentrated in the lower molecular weight portion. Long linear chain segments could form large, well-ordered crystals that provide strong anchors for the tie molecules and therefore determine the density of inter-crystalline links. Short chains with lots of branches could behave as protrusions along the chain to obstruct chain disentanglement and limit a chain from sliding through a crystal. Due to these reasons, the short chains with branches would contribute much less than the long linear chains to the full peel strength after complete sealing. However, higher peel strengths could be obtained only at the higher temperatures or longer bonding times at which the long linear chains begin to melt and diffuse across the interface. On the other hand, the higher branch content samples have the lower crystallinity and could obtain the higher chain mobility at the lower bonding temperatures and with shorter bonding times. Therefore, higher seal strength was observed for the higher branch content samples at lower Tb. Following T-peel fracture tests of ethylene/1-octene copolymer assemblies which showed interfacial failures, the fractured surfaces were investigated by using Atomic Force Microscopy (AFM) and characterized by fractal analysis together with the original films. The AFM images showed strong dependence on the peel rate and branch content. Quantitatively, the fractal analyses demonstrated fractal characteristics at the different finite scales. Two regimes showing fractal features were identified for each surface. In regime I (low magnifications) the fracture test did not change the fractal dimensions much. But there were significant changes in regime II before welding and after T-peel fracture tests. The length scale that separated these two regimes is very close to the size of lamellar structures. The characteristic sizes at which the fractal characteristics emerge were shown to appear at larger scales for surfaces fractured at higher peel rates. This suggests that the appearance of fractal behavior at larger scales requires higher fracture energies. The characteristic sizes and fractal dimensions were shown to depend on the molecular structure. Because the fractal analysis suggests at least some crystalline lamellae on the surfaces still existed during T-peel fracture tests, a "Stitch-welding" has been therefore proposed as the autohesion mechanism in which only chains in the amorphous portions could inter-diffuse. In the second part of this dissertation work, a multi-layer lap-shear geometry has been designed and proven as a reliable testing method in evaluation of the dynamical mechanical properties of polyacrylic pressure sensitive adhesive (PSA) in paper lamination for postage stamp applications. In-situ testing of four different PSA stamp laminates constructed by laminating water-based polyacrylic PSAs to the stamp face papers were carried out using a dynamic mechanical analyzer (DMA) in the temperature range from -50 to 60 oC at frequencies 0.1, 1, 10, and 100 Hz. This geometry requires the tension mode on the DMA, but the results which were recorded as tensile properties were converted to shearing properties of the PSA layers in the laminate. The effect of the thickness (layers of laminates) on the dynamical mechanical properties has been studied and the results suggested that a multi-layer geometry with 5-10 layers could be an appropriate structure to produce enhanced responses. Therefore, the geometry with 8-layer laminates was used for frequency sweep/isothermal temperature and frequency sweep/temperature step tests. The results showed three relaxation responses that is, glassy, transition, and flow regions with respect to the frequencies and temperatures. These results also implied the viscoelastic characteristics of these PSA products. The tensile properties of the face papers were also tested using the same parameters as those of the multi-layer geometry. Significant differences were found between the shearing behaviors of the multi-layer geometry and the tensile behaviors of the elastic face paper. This suggests that the tensile deformation of the face paper in the multi-layer geometry could be ignored and the elastic paper did not contribute to the shearing properties of the PSA layers. Time-temperature superposition curves have been produced with reference temperature set at 23 oC, which can be used to predict the long term and short term performances of these samples at this temperature. This method can be utilized as a standard testing method on the PSA adhesives in the laminate form. In addition to the dynamic mechanical properties, it can also be developed to be a general standard method on testing the rheological properties of adhesives, polymer melts and other viscous materials. / Ph. D.

The interaction of a shock wave with a boundary layer is a classic viscous/inviscid interaction problem that occurs over a wide range of high speed aerodynamic flows. For example, on transonic wings, in supersonic air intakes, in propelling nozzles at offdesign conditions and on deflected controls at supersonic/transonic speeds, to name a few. The transonic interaction takes place at Mach numbers typically between 1.1 and 1.5. On an aerofoil, its existence can cause problems that range from a mild increase in section drag to flow separation and buffeting. In the absence of separation the drag increase is predominantly due to wave drag, caused by a rise in entropy through the interaction. The control of the turbulent interaction as applied to a transonic aerofoil is addressed in this thesis. However, the work can equally be applied to the control of interaction for numerous other occurrences where a shock meets a turbulent boundary layer. It is assumed that, for both swept normal shock and unswept normal shock interactions, as long as the Mach number normal to the shock is the same, then the interaction, and therefore its control, should be the same. Numerous schemes have been suggested to control such interaction. However, they have generally been marred by the drag reduction obtained being negated by the additional drag due to the power requirements, for example the pumping power in the case of mass transfer and the drag of the devices in the case of vortex generators. A system of piezoelectrically controlled flaps is presented for the control of the interaction. The flaps would aeroelastically deflect due to the pressure difference created by the pressure rise across the shock and by piezoelectrically induced strains. The amount of deflection, and hence the mass flow through the plenum chamber, would control the interaction. It is proposed that the flaps will delay separation of the boundary layer whilst reducing wave drag and overcome the disadvantages of previous control methods. Active control can be utilised to optimise the effects of the boundary layer shock wave interaction as it would allow the ability to control the position of the control region around the original shock position, mass transfer rate and distribution. A number of design options were considered for the integration of the piezoelectric ceramic into the flap structure. These included the use of unimorphs, bimorphs and polymorphs, with the latter capable of being directly employed as the flap. Unimorphs, with an aluminium substrate, produce less deflection than bimorphs and multimorphs. However, they can withstand and overcome the pressure loads associated with SBLI control. For the current experiments, it was found that near optimal control of the swept and unswept shock wave boundary layer interactions was attained with flap deflections between 1mm and 3mm. However, to obtain the deflection required for optimal performance in a full scale situation, a more powerful piezoelectric actuator material is required than currently available. A theoretical model is developed to predict the effect of unimorph flap deflection on the displacement thickness growth angles, the leading shock angle and the triple point height. It is shown that optimal deflection for SBLI control is a trade-off between reducing the total pressure losses, which is implied with increasing the triple point height, and minimising the frictional losses.

The interaction of a shock wave with a boundary layer is a classic viscous/inviscid interaction problem that occurs over a wide range of high speed aerodynamic flows. For example, on transonic wings, in supersonic air intakes, in propelling nozzles at offdesign conditions and on deflected controls at supersonic/transonic speeds, to name a few. The transonic interaction takes place at Mach numbers typically between 1.1 and 1.5. On an aerofoil, its existence can cause problems that range from a mild increase in section drag to flow separation and buffeting. In the absence of separation the drag increase is predominantly due to wave drag, caused by a rise in entropy through the interaction. The control of the turbulent interaction as applied to a transonic aerofoil is addressed in this thesis. However, the work can equally be applied to the control of interaction for numerous other occurrences where a shock meets a turbulent boundary layer. It is assumed that, for both swept normal shock and unswept normal shock interactions, as long as the Mach number normal to the shock is the same, then the interaction, and therefore its control, should be the same. Numerous schemes have been suggested to control such interaction. However, they have generally been marred by the drag reduction obtained being negated by the additional drag due to the power requirements, for example the pumping power in the case of mass transfer and the drag of the devices in the case of vortex generators. A system of piezoelectrically controlled flaps is presented for the control of the interaction. The flaps would aeroelastically deflect due to the pressure difference created by the pressure rise across the shock and by piezoelectrically induced strains. The amount of deflection, and hence the mass flow through the plenum chamber, would control the interaction. It is proposed that the flaps will delay separation of the boundary layer whilst reducing wave drag and overcome the disadvantages of previous control methods. Active control can be utilised to optimise the effects of the boundary layer shock wave interaction as it would allow the ability to control the position of the control region around the original shock position, mass transfer rate and distribution. A number of design options were considered for the integration of the piezoelectric ceramic into the flap structure. These included the use of unimorphs, bimorphs and polymorphs, with the latter capable of being directly employed as the flap. Unimorphs, with an aluminium substrate, produce less deflection than bimorphs and multimorphs. However, they can withstand and overcome the pressure loads associated with SBLI control. For the current experiments, it was found that near optimal control of the swept and unswept shock wave boundary layer interactions was attained with flap deflections between 1mm and 3mm. However, to obtain the deflection required for optimal performance in a full scale situation, a more powerful piezoelectric actuator material is required than currently available. A theoretical model is developed to predict the effect of unimorph flap deflection on the displacement thickness growth angles, the leading shock angle and the triple point height. It is shown that optimal deflection for SBLI control is a trade-off between reducing the total pressure losses, which is implied with increasing the triple point height, and minimising the frictional losses.