Graduation date: 1998

The Hanford nuclear reservation in Washington state was initially created during World War II for the production of plutonium to be used in atomic bombs. A perceived need for a large increase in the number of nuclear weapons spurred expansions in production facilities at Hanford through the 1960's, and production was continued through the mid 1980's. The production process included irradiation of uranium fuel in reactors followed by chemical separation of the plutonium from the other fuel constituents, and finally transformation of plutonium nitrate to plutonium metal. The various steps in the process produced large amounts of radioactive as well as chemical hazardous waste. Some of this waste was released to the environment either through deliberate disposal methods or by leaks in transfer and storage systems. As a result, the soil at many areas of Hanford is contaminated to a point at which it would be unsafe for human contact for more than a short period of time. The current focus of efforts at Hanford is cleanup of the environment as well as decommissioning of the facilities. As part of the cleanup process, future land use must be determined which will then affect the scale of the remediation effort. The proposed land use will determine the residual contamination which will be left after all remediation is complete and access is allowed to the site. This document details the process for determining the residual contamination levels associated with various land use options. Some possible land use options are explained in the form of exposure scenarios. These scenarios give data in the form of exposure factors which describe the possible exposure level of an individual to contaminated media. Once the exposure factors are determined, they can be used in the equations outlined in the Hanford Site Risk Assessment Methodology to calculate preliminary remediation goals. These goals are presented as contaminant concentrations in environmental media which are the maximum allowable in order to meet regulatory limits. The limits are expressed either as a risk for carcinogens, or as a hazard quotient for non-carcinogens. / Graduation date: 1997

Thesis (M.A.)--Oregon State University, 2007. / Printout. Includes bibliographical references (leaves 81-87). Also available on the World Wide Web.

The use of nano zerovalent iron (nZVI) for environmental remediation is a promising new technique for in situ remediation. Due to its high surface area and high reactivity, nZVI is able to dechlorinate organic contaminants and render them harmless. Limited mobility, due to fast aggregation and sedimentation of nZVI, limits the capability for source and plume remediation. Carbo-Iron is a newly developed material consisting of activated carbon particles (d50 = 0,8 µm) that are plated with nZVI particles. These particles combine the mobility of activated carbon and the reactivity of nZVI. This paper presents the rst results of the transport experiments. / Der Einsatz von elementarem Nanoeisen ist eine vielversprechende Technik zur Sanierung von Altlastenschadensfällen. Aufgrund der hohen Oberäche und der hohen Reaktivität kannn ZVI chlororganische Schadstoffe dechlorieren und zu harmlosen Substanzen umwandeln. Der Einsatz von Nanoeisen zur Quellen- und Fahnensanierung wird jedoch durch mangelnde Mobilität im Boden im eingeschränkt. Carbo-Iron ist ein neu entwickeltes Material, das aus Aktivkohlepartikeln (d50 = 0,8 µm) und nZVI besteht. Diese Partikel kombinieren die Mobilit ät von Aktivkohle mit der Reaktivität von nZVI. Dieser Artikel beschreibt erste Ergebnisse von Transportuntersuchungen.

The concept of the photographic truth has had a special status for almost 200 years. Yet with the emerge of digital technology and especially digital photography there has been a loss of the particular connection photography has had in reference to reality. The aim of this study is to see in what ways digitalization has affected the credibility of photography from the perspective of professionals in the field of photography. The digital technology that has enabled the large-scale manipulation of photographies is not, however, the main reason for the decreased credibility of photography. The ongoing discussion about the available possibilities concerning digital imagery and manipulation has had a far more powerful effect on the concept of the photographic truth. Along with these possibilities a post-photographic photograph has seen the light of day. We discuss further some credibility problems caused by this new phenomenon; i.e. the post-photographic photographies can’t be considered to have the same status as the traditional photographies when it comes to presenting reality truthfully. We approached the subject through theory studies and methodically through personal interviews. Key words: credibility, digitalization, manipulation, remediation, reality, noeme, and the post-photographic era.

The purpose of this study is to determine the most suitable remediation techniques via engineering geological assessment of the landslide that occurred during the construction of Artvin-Savsat Junction - Meydancik Provincial Road at Km: 12+200 in an active landslide area. For this purpose, the geotechnical parameters of the mobilized geological material which is colluvium along the sliding surface were determined by back analyses of the landslide at three geological sections. The landslide were then modeled along the most representative section of the study area by considering the landslide mechanism, the parameters determined from the geotechnical investigations, the size of the landslide and the location of the slip circle. In addition, pseudostatic stability analyses were performed comprising the earthquake potential of the site. The most suitable slope remediation technique was determined to be a combination of surface and subsurface conditions. A static analysis of the landslide shall also be performed through utilizing finite element analyses. The static analyses were compared with the inclinometer readings in the field to verify the direction of the movement. Consequently, shear strength parameters were specified as c = 0 kPa and f = 10&deg / for the landslide material and pre-stressed anchoring and rock buttressing were considered as a remediation method.

Progressive spatial segregation of Whites from other ethnic races in South Africa started in 1886. Apartheid rulers evicted three and a half million Blacks, Coloureds and Indians from white urban and residential areas between 1904 and 1994. Apartheid planners used natural, mining, industrial, and infrastructural buffer zones to spatially enforce segregation. They based their apartheid spatial governance on separation and control and not on urban development. Today remnants of apartheid remain deeply embedded in the urban framework, where large buffer zones continue to enforce segregation and disrupt economic growth. Victims of apartheid legislation believed the eradication of apartheid in 1994 meant the right to live in the city and the end of forced evictions. Since then the post-Apartheid government has conducted 2 million evictions, reminiscent of the 3.5 million evictions during the apartheid years. In an attempt to make Johannesburg a `world class city`, the municipality forcefully removed the poor from the city, and relocated them to rural locations where their livelihoods are severely challenged. To many, a new ``apartheid` has been born; one that segregates the rich and the poor. The government has released several strategies to provide land for the poor near the city, but the high cost of land in urban areas has disrupted implementation. The thesis proposes a three-fold strategic design intervention to provide land for the poor near the city and dissolve the apartheid-designed buffer zone between Soweto and Johannesburg. The site, a landmark from the apartheid spatial legacy and part of the Witwatersrand gold mining belt, separates Soweto, home to four million Blacks, from the city of Johannesburg. About one and a half million people commute to the city each day passing by the 14 km stretch of this toxic mining land. The thesis proposes three urban design strategies to transform the site into a community, which the local people would build: Remediation strategies to address the toxic mining landscape, infrastructural strategies to provide basic services and economic strategies to promote economic growth. These strategies operate in a codependent structure. Co-op centres implement these strategies, transfering strategy technologies to the local community.

<p><p>Clean water is a critical natural resource. We do not have much available: only 2.5% of water on Earth is freshwater and of that only 31% is in liquid form. 96% of the liquid fresh water is groundwater. Unfortunately that resource is subject to contamination by hazardous materials accidentally or illicitly spilled, leaked, or deposited in or on the ground. Among the methods to remediate these disasters, pump-and-treat (P&T) is the most common. The vertical circulation well (VCW) is a P&T configuration with extraction and injection sites within the same well. It can be adapted to many remediation techniques and has been gaining popularity since the 1990s and is often a better alternative to conventional P&T. Conventional P&T and VCWs are typically run with steady flow.</p></p><p><p>The major bottleneck to steady flow remediation is that contaminants become trapped in dead-end pores. In an aquifer there are two types of pores: <it>pass-through</it> pores and <it>dead-end</it> pores. The flow in former completely sweeps through the pore space while the flow does not enter the later; however, the flow through the <it>pass-through</it> pore induces a vortex in the <it>dead-end</it> pore. Under steady flow the only mechanism for contaminants to escape the <it>dead-end</it> pores is molecular diffusion.</p></p><p><p>A similar problem is encountered in the removal of surfactants in the manufacture of semiconductor and the removal of oil residue build-up in small ducts. Manufacturers discovered that pulsed flow would accelerate the mass transfer between the cavities and grooves on these surfaces and the external flow. This was because the unsteady ramp-up in flow rate initiated a deep sweep of the cavities. The unsteady ramp-down in flow rate initiated a vortex ejection where the sequestered vortex is no longer constrained and protrudes from the cavity.</p></p><p><p>We hypothesized that just as pulsed flow improves cleaning of grooved surfaces in several manufacturing procedures, rapidly pulsed pumping (with a period on the order of a second rather than weeks or months) in pump-and-treat groundwater remediation would boost the diffusion-limited removal of contaminants trapped in dead-end pores by generating transient deep sweeps and vortex ejections in these pores. These processes have not yet been exploited in groundwater remediation to any significant degree.</p></p><p><p>We tested our hypothesis in a series of numerical and laboratory experiments. We considered unwashed and washed media. For unwashed media (Chapter 1) we used as a square pore in the numerical domain and crushed glass (for its negligible sorption capacity) in laboratory column studies. For washed media (Chapter 2) we used a smooth dead-end pore constructed with two tangential quarter circles as the pore in the numerical domain and glass spheres in the laboratory column studies. In all our laboratory experiments we used a fluorescent dye, Fluorescein, as a conservative tracer. We used the same parameters in our numerical experiments. However, in some we also considered immiscible contaminants such as NAPLs (Chapter 4).</p></p><p><p>All numerical experiments were conducted with the computational fluid dynamics software, FIDAP. In numerical experiments we studied the contaminant removal from interacting dead-end pores connected to both a straight pass-through pore and a divergent pass-through pore. The latter with the flow somewhat analogous to the radial spreading encountered around a around a well in field applications (Chapter 5).</p></p><p><p>To elucidate the dead-end pore dynamics (Chapter 3), we performed numerical experiments and used a physical model to obtain a relationship between the rapidly pulsed flow frequency and length of the pore. Our dimensional analysis pointed to the change in pressure as the key component in the initiation of transient deep sweeps and vortex ejections, two new pore-cleaning mechanisms.</p></p><p><p>We conclude that the rapidly pulsed flow improves the recovery of contaminants from unwashed, or rough, porous media. In numerical experiments with a pore system consisting of just a single square dead-end pore and a single pass-through pore, at 100 pore volumes pumped the rapidly pulsed flow improved cleanup of the dead-end pore alone by approximately 40%. This translates into a 10% improvement of the cleanup of the pore system (dead-end and pass-through pore). Since the dead-end pore is the bottleneck of the current groundwater remediation, it the first measure that is relevant.</p></p><p><p>In corresponding laboratory column experiments with crushed glass, the dead-end pore volume alone is not known. The cleanup of the whole pore space was improved by roughly 10% with the rapidly pulsed pumping, which corresponds nicely to our numerical results.</p></p><p><p>Our numerical experiments demonstrate that there exists an optimal pulsed pumping frequency that is a function of the local flow velocity and the pore geometry (size and morphology).</p></p><p><p>The contaminant recovery from washed, or rounded, media was not as pronounced in the laboratory experiments and the numerical experiments showed no improvement. While both rapidly pulsed and steady flow recovered all of the contaminant in the laboratory column tests, the difference in the time between the two pumping schemes was approximately 0.9 pore volumes pumped. This improvement is likely to be amplified with sorbing contaminants.</p></p><p><p>Many contaminants are non-aqueous phase liquids (NAPLs), which do not readily dissolve in water. We showed in numerical experiments that rapidly pulsed flow can recover NAPLs with viscosity lower than water, but is not as effective with higher viscosity materials; however, these results were based on a model that did not account for interfacial tension and wetting; therefore we will require additional numerical and laboratory experiments.</p></p><p><p>In practice, a flow through porous media is significantly more complex than the one-directional dominated flows considered in our numerical and laboratory column experiments. Around a well the flow is typically three-dimensional and largely radially dominated. We constructed two numerical domains to study the interactions between the cleanup of three square pores: one in a straight channel and one in a divergent channel to study the radial spread that would be experienced around a well. For a series of three dead-end pores, there was a 35% improvement by rapidly pulsed flow over steady flow in the straight channel and a 33% improvement in the divergent domain. The optimal frequency was different in the divergent flow even though the pores were the same size as in the previous study. Since the divergent channel reduced the flow velocity, the pulses reached the pores at a decreasing rate. Due to this divergence and the range of pore-sizes in a natural aquifer, implementation of rapidly pulsed flow should likely include a range of frequencies.</p></p><p><p>We concluded that the rapidly pulsed flow on the time scale of one-second would greatly enhance the cleanup of contaminated aquifers by P&T or VCW approaches. We measured significant improvements in the time to recovery. For our preliminary VCW experiment showed that rapidly pulsed pumping recovers 50% of the contaminant four times faster than steady pumping. P&T and VCW remediation typically use a steady flow; there are some methods that change the flow rate in P&T and other configurations, such as the VCW. These periodic changes in rate are on the scale of months to years. Some VCWs and air sparging technologies pulse oxygen, surfactants, and/or nutrients into the aquifer to oxidize, mobilize, or bioremediate the contaminants. As reviewed in chapter 6 in detail, all pulsing so far applied in remediation is on the time scale of a day or longer. Such low pulsing frequency does not produce sufficiently many deep sweeps to make a significant difference in cleaning dead-end pores.</p></p><p><p>Implementation of rapidly pulsed technology will utilize the same extraction and injection wells currently used in pump-and-treat remediation but will require replacement or significant modification of the pumps.</p></p><p><p>There are public health and financial implications of this research. In the dissertation conclusions section we reinterpret our numerical experiments with the multiple interacting dead-end pores and a divergent pass-through pore and laboratory experiments with a vertical circulation well chamber by calculating and plotting the ratio of times needed to reach a specified fraction recovered (specified cleanup level) in the steady and rapidly pulsed pumping modes, \tau_{s} / \tau_{p}. This ratio represents the speedup factor, i.e., the factor by which the time needed to reach the specified cleanup level with the conventional remediation (with steady pumping) would be reduced. From our experiments it appears that with the increasing level of targeted cleanup (contaminant fraction recovered), the speedup factor increases and may even exceed an order of magnitude. As we demonstrate in the dissertation conclusions section, this could translate into tens of billions of dollars in savings. Whether or not the laboratory speedup factors would hold in the field cannot be established without field-scale experiments.</p></p> / Dissertation

Little is known about the enzyme-substrate interactions occurring during the dechlorination of chloroform (CF) and 1,1,1-trichloroethane (1,1,1-TCA) by the enrichment culture containing Dehalobacters, hereafter called DHB-CF/MEL. Compound specific isotope analysis (CSIA) is used to investigate the factors which may affect the isotope fractionation observed for CF and 1,1,1-TCA dechlorination. This thesis reports the first isotope enrichment factors observed for CF biodegradation at -27.5‰ ± 0.9‰, thus providing fundamental information for comparing isotope enrichment factors observed during trichlorinated alkane degradation by DHB-CF/MEL. The thesis also reports how the presence of CF and 1,1,1-TCA influences isotope fractionation and explores the possible influence of substrate inhibition on isotope fractionation during 1,1,1-TCA dechlorination. The data suggests that substrate inhibition during 1,1,1-TCA dechlorination by DHB-CF/MEL may not affect carbon isotope fractionation. The results suggest that CSIA is a promising monitoring tool even for the simultaneous biodegradation of CF and 1,1,1-TCA at different 1,1,1-TCA starting concentration.

Sewer trenches usually contain material with a higher hydraulic conductivity then the adjacent soil. Thus they can serve as paths of preferential flow in a polluted area. Wastewater from factories can also leak from wastewater pipes and pollute the soil in the sewer trenches. The purpose of this project was to investigate pollutions in sewer trenches and in sewer pipes in the industrial area of Köpmanholmen, 20 km south of Örnsköldsvik in the north of Sweden. To make an estimation concerning the potential of transport of pollutions in sewer trenches, hydrological calculations were performed. Leakage to any greater extent did not seem to be a problem in the area. This is the case both for the concrete and the wooden pipes that have served as factory wastewater pipes. A large transport in the lengthwise direction of the sewer trenches was not shown to exist. Instead the greatest risk of transport from a polluted area seems to come from infiltration into wastewater pipes, where the pollutants can flow readily to the recipient or wastewater treatment plant. / Rörgravar innehåller ofta grövre material med högre hydraulisk konduktivitet än omgivande jord och kan därför tjäna som spridningsvägar från förorenade områden. Avloppsvatten från fabriksområden kan också misstänkas ge upphov till föroreningar i rörgravar via läckage från avloppsrören. Detta arbete har haft som mål att utreda föroreningssituationen i ledningsgravar och avloppsledningar på Köpmanholmens industriområde, ca 2 mil söder om Örnsköldsvik. För att bedöma ledningsgravarnas potential att sprida föroreningar har också hydrologiska beräkningar har gjorts. Läckage i någon större omfattning från avloppsledningar har inte kunnat påvisas. Detta gäller både betongledningar och den trätub som har utgjort fabriksavlopp på området. Inte heller har någon föroreningsspridning kunnat påvisas i ledningsgravarnas längdriktning. Den största risken för spridning av föroreningar verkar istället vara via infiltration till avloppsledningarna. Detta ger en snabb transport från förorenade områden till recipient eller reningsverk.