Orientador: José Roberto Sanches Mantovani / Resumo: O problema de alocação ótima de banco de capacitores em sistema de distribuição radiais consiste em definir as barras onde devem ser alocados os bancos de capacitores, além de determinar os tipos, potência nominal e em quais fases eles devem ser alocados, atendendo a restrições físicas e operacionais das redes elétricas, juntamente com os padrões da qualidade de fornecimento normatizados pelas agências reguladoras do setor. Também deve-se definir o esquema de controle, ou seja, quando os bancos capacitivos variáveis devem operar em diferentes níveis de carregamentos. A alocação de bancos de capacitores em sistemas de distribuição é um problema de programação não-linear inteiro misto, não convexo, de difícil solução através de técnicas clássicas de otimização, pela sua natureza combinatória, devido o aumento no número de variáveis inteiras envolvidas na solução de problemas de médio e grande porte. Neste trabalho, propõe-se para a sua solução a meta-heurística de Evolução Diferencial (ED), que deve fornecer a localização e dimensionamento dos bancos de capacitores fixos e chaveados ao longo dos alimentadores primários, em sistemas de distribuição radiais trifásicos e desbalanceados. A alocação deve atender aos critérios de mínimo custo de investimento e operação do sistema, dados pela soma do custo de aquisição, instalação e manutenção dos bancos de capacitores, mais o custo de perdas ativas no sistema além de melhorar o fator de potência. São apresentados neste trabalho, resu... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The optimal allocation problem of capacitor bank in radial distribution systems is to define the bus where the capacitor banks must be allocated, furthermore determine the types, nominal power and which phase they must be allocated as they attended the physical and the operational constraints of power systems in conjunction with the supplier quality standards normalized by the sector regulatory agencies. Moreover, you must define the check schema, in the words, when the variable capacitor banks must operate at different load levels. The allocation of capacitor banks in distribution systems it's a not convex mixed integer nonlinear programming problem with a difficult solution through classical optimization techniques due to the increase of integer variables involved in the solution of large and medium-size problems. This works proposes for the solution, a metaheuristic based on Differential Evolution (DE) which provide the location and the sizing of fixed capacitor banks, switched over the primary feeders in unbalanced three-phase radial distribution systems, with the aim of minimizing the total investment and the system operation cost, given by sum of acquisition cost, installation and maintenance of capacitor banks, plus the cost of active losses in the system and to im-prove the power factor. Results for a 135-bus unbalanced three-phase system are presented. / Mestre

Made available in DSpace on 2016-06-02T20:36:37Z (GMT). No. of bitstreams: 1 4277.pdf: 1447497 bytes, checksum: 188cbf0751a74eaadec5a15e0a55c7e7 (MD5) Previous issue date: 2012-02-27 / Financiadora de Estudos e Projetos / The effects on the reduction of space on the structural properties of two liquids and a mixture thereof were analyzed with a definition of nanoscale confinement, based on carbon nanotubes. The methodology involves the use of the Monte Carlo Method at isobaric-isothermal assembly, ������ , and Radial Distribution Functions for structural analysis. The results showed that in confinement conditions presents formation and distortion of structural patterns in the correlation functions for the studied liquids, water and methanol. The variations in these functions are presented as dependent on the description of the nanotubes. / Os efeitos na redução do espaço sobre as propriedades estruturais de dois líquidos e uma mistura dos mesmos foram analisados com uma definição de condição de confinamento em escala nanométrica, a partir de nanotubos de carbono. A metodologia empregada utiliza para os cálculos o método Monte Carlo no ensemble isotérmico-isobárico, ������, e a função de distribuição radial de pares para a análise estrutural. Os resultados obtidos mostraram que em condição de confinamento apresenta-se formação e distorção de padrões estruturais nas funções de correlação para os líquidos estudados, água e metanol. As variações nestas funções apresentam-se como dependentes da descrição dos nanotubos.

No description available.

Duplex stainless steels (DSSs) are important engineering materials due to their combination of good mechanical properties and corrosion resistance. However, as a consequence of their ferrite content, DSSs are sensitive to the so-called ‘475°C embrittlement’, which is induced by phase separation, namely, the ferrite decomposed into Fe-rich ferrite (α) and Cr-rich ferrite (α'), respectively. The phase separation is accompanied with a severe loss of toughness. Thus, the ‘475°C embrittlement’ phenomenon limits DSSs’ upper service temperature to around 250°C. In the present work, Fe-Cr binary model alloys and commercial DSSs from weldments were investigated for the study of phase separation in ferrite. Different techniques were employed to study the phase separation in model alloys and commercial DSSs, including atom probe tomography, transmission electron microscopy and micro-hardness test. Three different model alloys, Fe-25Cr, Fe-30Cr and Fe-35Cr (wt. %) were analyzed by atom probe tomography after different aging times. A new method based on radial distribution function was developed to evaluate the wavelength and amplitude of phase separation in these Fe-Cr binary alloys. The results were compared with the wavelengths obtained from 1D auto-correlation function and amplitudes from Langer-Bar-On-Miller method. It was found that the wavelengths from 1D auto-correlation function cannot reflect the 3D nano-scaled structures as accurate as those obtained by radial distribution function. Furthermore, the Langer-Bar-On-Miller method underestimates the amplitudes of phase separation. Commercial DSSs of SAF2205, 2304, 2507 and 25.10.4L were employed to investigate the connections between phase separation and mechanical properties from different microstructures (base metal, heat-affected-zone and welding bead) in welding. Moreover, the effect of external tensile stress during aging on phase separation of ferrite was also investigated. It was found that atom probe tomography is very useful for the analysis of phase separation in ferrite and the radial distribution function (RDF) is an effective method to compare the extent of phase separation at the very early stages. RDF is even more sensitive than frequency diagrams. In addition, the results indicate that the mechanical properties are highly connected with the phase separation in ferrite and other phenomena, such as Ni-Mn-Si-Cu clusters, that can also deteriorate the mechanical properties. / <p>QC 20130308</p>

Mémoire numérisé par la Division de la gestion de documents et des archives de l'Université de Montréal.

Mémoire numérisé par la Division de la gestion de documents et des archives de l'Université de Montréal

Die fortwährende Verkleinerung der Strukturbreiten in der Mikroelektronik erfordert es, herkömmliche SiO2 Dielektrika durch Materialien mit kleinerer Dielektrizitätskonstante zu ersetzen. Dafür sind verschiedene „low-k Materialien“ entwickelt worden. Unter diesen sind die Organosilikatgläser, die aus SiO2 Netzwerken mit eingelagerten Methylgruppen bestehen wegen ihrer ausgezeichneten Eigenschaften besonders interessant als Dielektrika zwischen metallischen Leiterbahnen. In dieser Arbeit sind fünf verschiedene dieser „low-k Materialien“ untersucht worden: ein dichtes und vier poröse Materialien, die alle durch plasmagestützte chemische Gasphasenabscheidung hergestellt wurden. Die strukturellen, chemischen und dielektrischen Eigenschaften der Materialien wurden mit Hilfe der analytischen Durchstrahlungselektronenmikroskopie unter Verwendung eines abbildenden GATAN-Energiespektrometers untersucht. Die Bestimmung der radialen Verteilungsfunktion (RDF) zur Charakterisierung der atomaren Nahordnung ermöglicht uns die Ermittlung mittlerer Bindungslängen und – winkel sowie der mikroskopischen Dichte des Materials. Gegenüber SiO2 wurden in den untersuchten „low-k Materialien“ stark veränderte mittlere Si-O, O-O und Si-Si Bindungslängen gefunden. Dieses wirkt sich natürlich auch auf die mittleren Si-O-Si bzw. O-Si-O Bindungswinkel aus, und wie erwartet war auch die mikroskopische Dichte der „low-k Materialien“ kleiner als die Dichte des SiO2. Elektronen Energieverlustspektroskopie (EELS) und Photoelektronenspektroskopie (XPS) wurden zur Charakterisierung der chemischen Umgebung der Atome in den „low-k Materialien“ herangezogen. Die Energien von Ionisationskanten und die Bindungsenergien der Silizium-2p und Sauerstoff-1s Elektronen waren in den „low-k Materialien“ größer als im SiO2. Die Kohlenstoffatome kamen in den „low-k Materialien“ sowohl sp2 als auch sp3 hybridisiert vor. sp2-Hybridisierung liegt vor, wenn Bindungen wie Si=CH2 und C=C im Netzwerk vorkommen, während sp3 Hybridisierung z.B. dann vorkommt, wenn freie Si-Bindungen durch –CH3 Gruppen abgesättigt werden. Die Anteile an sp2- bzw. sp3-hybridisierten Kohlenstoffatome wurden aus der Feinstruktur der K-Energieverlustkanten des Kohlenstoffs abgeschätzt. Das ergab, daß die meisten Kohlenstoffatome in den „low-k Materialien“ sp2-hybridisiert sind. Die dielektrischen Eigenschaften wurden durch Kramers-Kronig-Transformation einer Energieverlustfunktion ermittelt, die aus dem Niedrigverlust-EELS-Spektrum im Bereich der Plasmonenanregungen gewonnen wurde. Die Bandlücke des SiO2 beträgt ungefähr 9 eV während dichte „low-k Materialien“ aufgrund der Unregelmäßigkeiten in ihrem SiO2-Netzwerk zusätzliche Zustandsdichten innerhalb der Bandlücke aufweisen. Die Erzeugung von Poren im „low-k Material“ vermindert offenbar die Zustandsdichte im Bereich der Bandlücke und erweitert diese im Vergleich zum SiO2. Eine Modellrechnung mit der Dichtefunktionaltheorie für ein Strukturmodell, das den „low-k Materialien“ nahe kommt, ist zum Vergleich mit der experimentell gefundenen kombinierten Zustandsdichte herangezogen worden und zeigt eine gute Übereinstimmung. Die im Standard-Herstellungsprozeß vorkommenden Verfahren des Plasmaätzens und der Plasmaveraschung können die Struktur des „low-k Materials“ z.B. an den Seitenwänden von Ätzgräben verändern. Die gestörten Bereiche wurden mit der energiegefilterten Elektronenmikroskopie untersucht. Dabei wurde gefunden, daß sich die Strukturveränderungen der Seitenwände bis zu einer Tiefe in der Größenordnung von ungefähr 10 Nanometern erstrecken. Diese Bereiche sind verarmt an Kohlenstoff und ähneln folglich mehr einem SiO2-Dielektrikum. Die Kohlenstoffverarmung erstreckt sich in die „low-k Schicht“ in Form eines gaussartigen Profils mit maximaler Kohlenstoffkonzentration in der Mitte der Schicht. Die Sauerstoffkonzentration und die mikroskopische Dichte steigen in der Nähe der Seitenwände.

Power losses are always a cause of worry for any power grid. In India, the situation is even worse. Though recent reports by Ministry of Power shows that Aggregate Technical and Commercial losses (AT &C losses) have come down from 36.64% in 2002-03 to 27% in 2011-12, yet they are much higher than the losses seen in many of the developed nations. The reduction shown in power loss is because of the Electricity Act, 2003 and the amendments made to it in 2007 which controlled the commercial losses rather than the technical losses. According to Ministry of Power, technical losses (Transmission & Distribution losses or T&D losses) in India are reported to be 23.65% in 2011-12. However, according to the study done by EPRI, for systems deployed in developed countries, these losses are estimated to be in the range of 7-15.5%. T & D losses occur in four system components namely step-up transformers and high voltage transmission (0.5-1%), step down to in intermediate voltage, transmission and step down to sub transmission voltage level (1.5-3%), sub-transmission system and step down to low voltage for distribution (2-4.5%), and distribution lines (3-7%). 1% of power loss is approximately equivalent to annual loss of Rs 600 million for a single state. Hence, in a year, loss in distribution line alone causes approximate loss of Rs 1.8-4.2 billion per state. Understanding and reducing power losses in distribution lines which contribute nearly 50% of the total T&D losses assume significance and has formed the motivation for the work reported in the thesis. In recent years, the trend has been to encourage users to generate solar power predominantly at residential complexes and captive power plants at industrial complexes. It has been suggested in the literature that Distributed Generation (DG) can not only reduce the load demanded from the power grid but also the power loss. In this thesis, it has been shown that by the choice of proper size and location of DG, the power loss can be reduced substantially as compared to unplanned deployment of DGs. The objective of the thesis is to design strategy for location of distributed user generated power to maximize the reduction in power loss. The thesis begins with a study of distributed generation in primary distribution networks and proceeds to problem formulation, with the aim being to develop an algorithm that can find out the optimal locations for DG allocation in a network. A greedy approximation algorithm, named OPLODER (i.e. Optimal Locations for Distributed Energy Resources), is proposed for the same and its performance on a benchmark data set is observed, which is found to be satisfactory. The thesis then moves on to describe the actual data of 101,881 commercial, residential and industrial consumers of Bangalore metropolitan area. A loss model is discussed and is used to calculate the line losses in LV part of the grid and loss is estimated for the said actual data. The detailed analysis of the losses in the distribution network shows that in most cases the losses are correlated with the sanctioned load. However there are also some outliers indicating otherwise. The analysis concludes that the distributed generated sources need to be optimally located in order to benefit fully. Also presented thereafter is a study about the impact of electrical properties and the structure of the network on power loss. In the second part of the thesis, OPLODER was again used to process the BESCOM data of 101,881 consumers by modeling them to be connected in three topologies namely Bus (i.e. linear structure), Star (i.e. directly connected) and Hybrid (i.e. tree structure). In case of Bus topology, when DG capacity available is 5% of the demand in substation, OPLODER reduced the loss from 14.65% to 10.75%, from 11.63% to 7.71% and from 13.33% to 9.24% for IISc, Brindavan, and Gokula substations respectively. Similarly, for the same amount of DG in case of star topology, OPLODER reduced loss from 1.75% to 1.26%, from 3.39% to 2.59% and from 2.96% to 1.99% for IISc, Brindavan, and Gokula substations respectively. Thereafter, the available real world data is re-modeled as a tree-type structure which is closer to the real world distribution network and OPLODER is run on it. The results obtained are similar to those presented above and are highly encouraging. When applied to the three substations viz. IISc, Brindavan and Gokula, the power loss dips from 9.95% to 7.42%, from 6.01% to 4.44% and from 8.07% to 5.95%, in case of DG used is 5% of the demand in substation. For the optimal strategies worked out in the thesis, additional overheads will be present. These overheads are studied and it has been found that the present infrastructure and technologies will be sufficient to handle the smart distribution network and the optimal strategy for distributed sources.

An in-depth knowledge of the structure formation process and the resulting dependency of the morphology on the reaction mechanism is a key requirement in order to design application-oriented materials. For twin polymerization, the basic idea of the reaction process is established, and important structural properties of the final nanoporous hybrid materials are known. However, the effects of changing the reaction mechanism parameters on the final morphology is still an open issue. In this work, the dependence of the morphology on the reaction mechanism is investigated based on a previously introduced lattice-based Monte Carlo method, the reactive bond fluctuation model. We analyze the effects of the model parameters, such as movability, attraction, or reaction probabilities on structural properties, like the specific surface area, the radial distribution function, the local porosity distribution, or the total fraction of percolating elements. From these examinations, we can identify key factors to adapt structural properties to fulfill desired requirements for possible applications. Hereby, we point out which implications theses parameter changes have on the underlying chemical structure.

Thesis (M.Sc. (Physics)) -- University of Limpopo, 2022 / The gas sensing performance of two-dimensional (2D) hexagonal boron nitride nanosheets (h-BNNSs) has being studied by means of computational and experimental methods. The structural, stability and vacancies properties of both defect free and defected 2D h-BNNSs were studied using the classical molecular dynamics (MD) approach. The calculations were performed in the NVT Evans and NPT hoover ensembles using the Tersoff potentials with the Verlet leapfrog algorithm to obtain reliable structural properties and energies for defect free, boron (B) and nitrogen (N) vacancies. B and N defect energies were calculated relative to the bulk defect free total energies, and the results suggest that N vacancy is the most stable vacancy as compared to the B vacancy. The radial distribution functions and structure factors were used to predict the most probable structural form. Mean square displacements suggests the mobility of B and N atoms in the system is increasing with an increase in the surface area of the nanosheets. Results obtained are compared with the bulk defect free h-BNNSs. Experimentally, 2D h-BNNSs were synthesised using the wet chemical reaction method through chemical vapour deposition (CVD) catalyst free approach. The X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR), Raman Spectroscopy (RM), UV-visible Spectroscopy (UV-VIS), dynamic light scattering (DLS), Energy Dispersion Spectroscopy (EDS) and Brunauer-Emmett Teller (BET) were adopted to attain the structural properties of the nanosheets. Each spectroscopic technique affirmed unique features about the surface morphology of h BNNSs. The crystallinity of the nanosheets with the stacking of the B and N vii honeycomb lattice was validated by the XRD, while the TEM disclosed the specimen orientations and chemical compositions of phases with the number of layers of a planar honeycomb BN sheet, the EDS express the atoms present in the samples and BET validated the surface area of the materials. The FTIR, RM, DLS and the UV-vis expressed the formation of the in-plane, out-of-plane h-BN vibrations and, the nature of the surface with the thickness, particles stability together with the optical properties of the nanosheets. From TEM, FTIR, RS and BET the material fabricated at 800°C showed different morphologies, large number of disordering together with high surface area, which enhances the sensing properties of the nanosheets. However, with an increase in temperature the sensitivity of the nanosheets was found to decrease. Additionally, the UV-vis results, confirmed a lower energy band gap of 4.79, 4.55 and 4.70 eV for materials fabricated at 800, 900 and 1000 °C, that improved the semiconducting properties of the materials, which in return enhanced the sensing properties of the nanosheets. The gas sensing properties of the 2D h BNNSs were also investigated on hydrogen sulphide (H2S) and carbon monoxide (CO). The fabricated sensor based on 800 – 900 °C h-BNNSs showed good sensitivity towards ppm of H2S at 250 °C. The excellent gas sensing properties could be attributed to high surface area, small crystallite size, defect/disordering of h BNNSs. Overall, the h-BNNSs were found to be more sensitive to H2S over CO. / University of Limpopo (UL) Mintek Council for Scientific and Industrial Research (CSIR) Center for High Performance Computing (CHPC)