Bow shocks and related density enhancements produced by the winds of massive stars moving through the interstellar medium provide important information regarding the motions of the stars, the properties of their stellar winds, and the characteristics of the local medium. Since bow-shock nebulae are aspherical structures, light scattering within them produces a net polarization signal even if the region is spatially unresolved. Scattering opacity arising from free electrons and dust leads to a distribution of polarized intensity across the bow-shock structure. That polarization encodes information about the shape, composition, opacity, density, and ionization state of the material within the structure. In this paper, we use the Monte Carlo radiative transfer code SLIP to investigate the polarization created when photons scatter in a bow-shock-shaped region of enhanced density surrounding a stellar source. We present results for electron scattering, and investigate the polarization behaviour as a function of optical depth, temperature, and source of photons for two different cases: pure scattering and scattering with absorption. In both regimes, we consider resolved and unresolved cases. We discuss the implications of these results as well as their possible use along with observational data to constrain the properties of observed bow-shock systems. In different situations and under certain assumptions, our simulations can constrain viewing angle, optical depth and temperature of the

Recombination line profile shapes are derived for ionized spherical stellar winds at radio wavelengths. It is assumed that the wind is optically thick owing to free-free opacity. Emission lines of arbitrary optical depth are obtained assuming that the free-free photosphere forms in the outer, constant expansion portion of the wind. Previous works have derived analytic results for isothermal winds when the line and continuum source functions are equal. Here, semi-analytic results are derived for unequal source functions to reveal that line shapes can be asymmetric about line center. A parameter study is presented and applications discussed.

Les Noyaux actifs de galaxie (AGN) incluent les sources quasi stables les plus énergétiques connues dans l'univers jusqu'à aujourd’hui. Du fait de leur distance, de leur haute luminosité et de leur petite taille, leurs régions intérieures ne sont pas directement résolvables avec les télescopes actuels. C’est pour ces raisons que nous avons besoin de techniques d’observation indirectes et de modèles théoriques pour discerner leur structure. Dans cette optique, le rôle de la polarimétrie est crucial. Elle a été ces dernières années la méthode clé qui a permis de développer le modèle unifié des AGN et pourrait, à l’avenir, nous offrir des nouveaux éléments pour sonder les régions des AGN irrésolues. Dans cette thèse, j’ai conduit des simulations sur les transferts radiatifs relatifs aux rayonnements continus émis des différentes régions intérieures des AGN en utilisant la nouvelle technique de cartographie de réverbération polarimétrique. Ce travail a été inspiré par les recherches de Gaskell et al. (2012). Le but de cette recherche est de fournir des modèles théoriques sur les différents composants des AGN en considérant le rayonnement polarisé en fonction du temps. La polarisation induite par la diffusion a été modélisée et différentes géométries de poussières circumnucléaires ont été testées. Les résultats incluent les effets de l’agrégation des poussières et différentes compositions de poussière. Pour étendre le modèle, les effets complémentaires des vents ionisés s’étirant en direction des pôles ont également été étudiés ainsi que ceux de l’anneau de diffusion équatorial théorique, avec pour postulat qu'il explique l’angle de polarisation observé dans les pôles des AGN. Les simulations ont été exécutées en utilisant une version du code STOKES incluant la dépendance temporelle. Il sera possible d'étendre ce travail à l'avenir. Les prochaines étapes suggérées incluront des raies d'émission aux modélisations ainsi que plus de complexité concernant la géométrie et la distribution de la poussière et/ou des électrons dans les régions de diffusion. Ce travail sera important pour profiter de futures données observationnelles systématiques avec un bon échantillonnage temporel. / Active galactic nuclei (AGN) include the most powerful quasi-steady sources of energy known to date in the universe. Due to their distance, high brightness and small size, their inner regions are not directly resolvable with current telescopes. This is the reason why indirect techniques and theoretical models are needed to discern their structure. In this scenario the role of polarimetry is crucial. In the past it was the key method that led to the development of the Unified Model of AGN and in the future, it may give us new clues to probe unresolved AGN regions. In this thesis, I conducted radiative transfer simulations for continuous radiation of different inner regions of the AGN using the new technique of polarimetric reverberation mapping. This work has been inspired by the work of Gaskell et al. (2012). The goal of this research is to provide theoretical models of the different components of the AGN considering time-dependent polarized radiation. Scattering induced polarization has been modeled and different circumnuclear dust geometries have been explored. The results include the effects of clumpiness and different dust compositions. To further extend the model, the effects of additional extended ionized winds along the polar direction have also been explored as well as the putative equatorial scattering ring postulated to explain the polarization angle observed in pole-on AGN. The simulations were run using a time-dependent version of the STOKES code. It will be possible to extend this work in the future. Suggested future steps are including emission lines in the models, as well as more complexity in the geometry and distribution of dust and/or electrons in the scattering regions. This work will be important for taking advantage of systematic future observational data with good temporal sampling.

Les domaines millimétrique et submillimétrique sont des domaines qui permettent de caractériser la physico-chimie des atmosphères <br />planétaires par l'observation des molécules qui les composent. Le télescope spatial Herschel et l'interféromètre ALMA, qui <br />entreront prochainement en service, permettront d'améliorer considérablement notre connaissance des atmosphères planétaires.<br /><br />L'un des principaux objectifs de cette thèse est de développer un modèle d'analyse des observations millimétriques et submillimètriques qui seront effectuées avec Herschel et ALMA. C'est en ce sens que nous détaillons un modèle qui tient compte de la géométrie sphérique des corps observés et des spécificités instrumentales propres aux télescopes utilisés. <br /><br />Dans un premier temps, ce qui a permis notamment de valider notre modèle de transfert radiatif, nous avons étudié l'origine des <br />composés oxygénés dans les atmosphères des planètes géantes. Nous présentons l'analyse d'observations de Saturne et d'Uranus, effectuées avec les télescopes de l'IRAM et du JCMT, pour contraindre les sources de monoxyde de carbone dans ces atmosphères. Nous améliorons ainsi les limites supérieures précédemment publiées et réalisons la première observation du monoxyde de carbone dans l'atmosphère de Saturne dans <br />le domaine submillimètrique. Cette observation prouve l'existence d'une source externe pour ce composé. Nous analysons également des observations récentes de Jupiter, effectuées par le télescope spatial Odin, pour contraindre l'origine externe de l'eau dans la stratosphère de cette planète. Les observations confirment que la chute de la comète Shoemaker-Levy~9 est vraisemblablement la source principale d'eau. <br /><br />Dans un second temps, nous avons appliqué notre modèle à l'étude de la structure thermique et la dynamique de l'atmosphère de Mars, à partir d'observations du monoxyde de carbone. Ces observations sont comparées aux prédictions d'un modèle de circulation générale, ce qui permet de vérifier la validité de ses prédictions et de fournir de nouvelles contraintes observationnelles pour ce type de modélisations.<br /><br />Enfin, nous avons appliqué notre modèle à l'étude des planètes géantes avec le télescope spatial Herschel, dans le cadre du programme-clé de temps garanti du télescope spatial Herschel "Water and related chemistry in the Solar System''. Nous avons également identifié les améliorations à apporter à notre modèle pour analyser des observations ALMA.

<p>Comets are the most primordial and least evolved bodies in the Solar System. As such, they are unique sources of information regarding the early history of the Solar System. However, little is known about cometary nuclei since they are very difficult to observe due to the obscuring coma. Indirect methods are therefore often used to extract knowledge about nucleus parameters such as size, shape, density, material strength, and rotational properties. For example, tidal and non-tidal splitting of cometary nuclei can provide important information about nuclear densities and material strengths, but only if the criteria for mechanical stability are well known. Masses and densities of cometary nuclei can also be obtained by studying orbital modifications due to non-gravitational forces, but only if the thermophysics of comets can be modelled accurately. </p><p>A detailed investigation is made regarding the mechanical stability of small Solar System bodies. New expressions for the Roche distance are derived, as functions of the size, shape, density, material strength, rotational period, and spin axis orientation of a body. The critical rotational period for centrifugal breakup in free space is also considered, and the resulting formulae are applied to comets for which the size, shape and rotational period have been estimated observationally, in order to place constraints on their densities and material strengths. </p><p>A new thermophysical model of cometary nuclei is developed, focusing on two rarely studied features - layer absorption of solar energy, and parallel modelling of the nucleus and innermost coma. Sophisticated modelling of radiative transfer processes and the kinetics of gas in thermodynamic non-equilibrium form the basis for this work. The new model is applied to Comet 19P/Borrelly, and its density is estimated by reproducing the non-gravitational changes of its orbit.</p>

<p>This thesis is a detailed observational study of the accretion processes in T Tauri stars (TTS). The interaction between the central star, the circumstellar disk and the magnetic field gives rise to a wide range of features in the spectra of TTS. The current picture of TTS is based on rather simple models assuming that accretion is a homogeneous and axisymmetric process. Although these models have been successful in explaining some observational signatures of TTS such as the shape of emission lines, the static nature of these models makes them unsuitable for describing the strong variability of the veiling spectrum and emission lines of TTS. An improved understanding of this variability is of key importance to study the dynamic processes related to the accretion flow and the winds.</p><p>This study is based on a set of high-quality spectroscopic observations with the UVES spectrograph at the 8-m VLT in 2000 and 2002. These spectra, with exposure times as short as 10-15 minutes, have high spectral resolution and high signal-to-noise ratios and cover a large part of the optical wavelength range. From this dataset we determine the basic physical parameters of several TTS and model their photospheres. These models then serve as a basis for a detailed investigation of variations of the veiling continuum and line emission. We confirm that the level of veiling correlates with some of the strongest emission lines and that coherent changes in accretion occur on a timescale of a few hours, comparable to the free-fall time from the disk to the star. From the properties of the emission lines formed close to the central star and in the stellar wind we derive restrictions on the geometry of the observed systems.</p><p>Because the intrinsic axial symmetry of a single star makes it almost impossible to disentangle rotational modulation from inhomogeneity and axial asymmetry of the accretion flow, we study a series of spectra of a close spectroscopic binary at different orbital phases and derive the 3D structure of flows between the disk and the star. Finally, we calculate the profiles of hydrogen emission lines by iteratively solving 3D NLTE radiative transfer in a state-of-the-art magnetospheric model.</p>

Stellar winds play an important role for the evolution of massive stars and their cosmic environment. Multiple lines of evidence, coming from spectroscopy, polarimetry, variability, stellar ejecta, and hydrodynamic modeling, suggest that stellar winds are non-stationary and inhomogeneous. This is referred to as 'wind clumping'. The urgent need to understand this phenomenon is boosted by its far-reaching implications. Most importantly, all techniques to derive empirical mass-loss rates are more or less corrupted by wind clumping. Consequently, mass-loss rates are extremely uncertain. Within their range of uncertainty, completely different scenarios for the evolution of massive stars are obtained. Settling these questions for Galactic OB, LBV and Wolf-Rayet stars is prerequisite to understanding stellar clusters and galaxies, or predicting the properties of first-generation stars. In order to develop a consistent picture and understanding of clumped stellar winds, an international workshop on 'Clumping in Hot Star Winds' was held in Potsdam, Germany, from 18. - 22. June 2007. About 60 participants, comprising almost all leading experts in the field, gathered for one week of extensive exchange and discussion. The Scientific Organizing Committee (SOC) included John Brown (Glasgow), Joseph Cassinelli (Madison), Paul Crowther (Sheffield), Alex Fullerton (Baltimore), Wolf-Rainer Hamann (Potsdam, chair), Anthony Moffat (Montreal), Stan Owocki (Newark), and Joachim Puls (Munich). These proceedings contain the invited and contributed talks presented at the workshop, and document the extensive discussions.

This thesis is a detailed observational study of the accretion processes in T Tauri stars (TTS). The interaction between the central star, the circumstellar disk and the magnetic field gives rise to a wide range of features in the spectra of TTS. The current picture of TTS is based on rather simple models assuming that accretion is a homogeneous and axisymmetric process. Although these models have been successful in explaining some observational signatures of TTS such as the shape of emission lines, the static nature of these models makes them unsuitable for describing the strong variability of the veiling spectrum and emission lines of TTS. An improved understanding of this variability is of key importance to study the dynamic processes related to the accretion flow and the winds. This study is based on a set of high-quality spectroscopic observations with the UVES spectrograph at the 8-m VLT in 2000 and 2002. These spectra, with exposure times as short as 10-15 minutes, have high spectral resolution and high signal-to-noise ratios and cover a large part of the optical wavelength range. From this dataset we determine the basic physical parameters of several TTS and model their photospheres. These models then serve as a basis for a detailed investigation of variations of the veiling continuum and line emission. We confirm that the level of veiling correlates with some of the strongest emission lines and that coherent changes in accretion occur on a timescale of a few hours, comparable to the free-fall time from the disk to the star. From the properties of the emission lines formed close to the central star and in the stellar wind we derive restrictions on the geometry of the observed systems. Because the intrinsic axial symmetry of a single star makes it almost impossible to disentangle rotational modulation from inhomogeneity and axial asymmetry of the accretion flow, we study a series of spectra of a close spectroscopic binary at different orbital phases and derive the 3D structure of flows between the disk and the star. Finally, we calculate the profiles of hydrogen emission lines by iteratively solving 3D NLTE radiative transfer in a state-of-the-art magnetospheric model.

This thesis is about modelling and predicting the perceived whiteness of plain paper from the paper composition, including fluorescent whitening agents. This involves psychophysical modelling of perceived whiteness from measurable light reflectance properties, and physical modelling of light scattering and fluorescence from the paper composition. Existing models are first tested and improvements are suggested and evaluated. A colour appearance model including simultaneous contrast effects (CIECAM02-m2), earlier tested on coloured surfaces, is successfully applied to perceived whiteness. An extension of the Kubelka-Munk light scattering model including fluorescence for turbid media of finite thickness is successfully tested for the first time on real papers. It is extended to layered constructions with different layer optical properties and modified to enable parameter estimation with conventional d/0° spectrophotometers used in the paper industry. Lateral light scattering is studied to enable simulating the spatially resolved radiance factor from layered constructions, and angle-resolved radiance factor simulations are performed to study angular variation of whiteness. It is shown that the linear CIE whiteness equation fails to predict the perceived whiteness of highly white papers with distinct bluish tint. This equation is applicable only in a defined region of the colour space, a condition that is shown to be not fulfilled by many commercial office papers, although they appear white to most observers. The proposed non-linear whiteness equations give to these papers a whiteness value that correlates with their perceived whiteness, while application of the CIE whiteness equation outside its region of validity overestimates perceived whiteness. It is shown that the fluorescence efficiency of FWA is essentially dependent only on the ability of the FWA to absorb light in its absorption band. Increased FWA concentration leads accordingly to increased whiteness. However, since FWA absorbs light in the violet-blue region of the electromagnetic spectrum, the reflectance factor decreases in that region with increasing FWA amount. This violet-blue absorption tends to give a greener shade to the paper and explains most of the observed greening and whiteness saturation at larger FWA concentrations. A red-ward shift of the quantum efficiency is observed with increasing FWA concentration, but this is shown to have a negligible effect on the whiteness value. The results are directly applicable to industrial applications for better instrumental measurement of whiteness and thereby optimising the use of FWA with the goal to improve the perceived whiteness. / PaperOpt

Comets are the most primordial and least evolved bodies in the Solar System. As such, they are unique sources of information regarding the early history of the Solar System. However, little is known about cometary nuclei since they are very difficult to observe due to the obscuring coma. Indirect methods are therefore often used to extract knowledge about nucleus parameters such as size, shape, density, material strength, and rotational properties. For example, tidal and non-tidal splitting of cometary nuclei can provide important information about nuclear densities and material strengths, but only if the criteria for mechanical stability are well known. Masses and densities of cometary nuclei can also be obtained by studying orbital modifications due to non-gravitational forces, but only if the thermophysics of comets can be modelled accurately. A detailed investigation is made regarding the mechanical stability of small Solar System bodies. New expressions for the Roche distance are derived, as functions of the size, shape, density, material strength, rotational period, and spin axis orientation of a body. The critical rotational period for centrifugal breakup in free space is also considered, and the resulting formulae are applied to comets for which the size, shape and rotational period have been estimated observationally, in order to place constraints on their densities and material strengths. A new thermophysical model of cometary nuclei is developed, focusing on two rarely studied features - layer absorption of solar energy, and parallel modelling of the nucleus and innermost coma. Sophisticated modelling of radiative transfer processes and the kinetics of gas in thermodynamic non-equilibrium form the basis for this work. The new model is applied to Comet 19P/Borrelly, and its density is estimated by reproducing the non-gravitational changes of its orbit.