The diploma thesis aimed to changes of mechanical properties in the influence the use of geometry reinforcement, time delay between cure and measurement. Mechanical properties of model dental bridge observed effect of hydrothermal stress. Dental bridges were reinforced two types of Fiber Reinforced Composites. The first reinforcement had straight unidirectional orientation. The second reinforcement had multidirectional orientation. Mechanical testing was realized in the dependence at the force to deformation model of the dental bridge. Conversion was counted pursuant photo DSC measurement. The character of break was observed at SEM pictures and macro photos. Type of material and reinforcement fibers and their combination had important role at the mechanical properties.

The deformation on cylindrical surfaces of holes in tensile loaded laminated composite specimens was measured using new moire interferometry techniques. These new techniques were developed and evaluated using a 7075-T6 aluminum control specimen. Grating replication techniques were developed for replicating high quality diffraction gratings onto the cylindrical surfaces of holes. Replicas of the cylindrical specimen gratings (undeformed and deformed) were fabricated onto circular steel sectors. Narrow angular regions of these sector gratings were directly evaluated in a moire interferometer. This moire interferometry approach eliminated potential sources of error associated with other moire interferometry approaches. Two composite tensile specimens, fabricated from IM7/5250-4 pre-preg with ply layups of [0₄/90₄]_3s and [+30₂/-30₂/90₄]_3s, were examined using the newly developed moire interferometry techniques. Circumferential and thickness direction displacement fringe patterns (each 3 degrees wide) were assembled into 90 degrees wide mosaics around the hole periphery for both composite specimens. Distributions of strain were calculated with high confidence on a sub-ply basis at select angular locations. Measured strain behavior was complex and displayed ply-by-ply trends. Large ply related variations in the circumferential strain were observed at certain angular locations around the periphery of the holes in both composites. Extremely large ply-by-ply variations of the shear strain were also documented in both composites. Peak values of shear strain approached 30 times the applied far-field axial strain. Post-loaded viscoelastic shearing strains were recorded that were associated with the regions of large load-induced shearing strains. Large ply-grouping related variations in the thickness direction strain were observed in the [+30₂/-30₂/90₄]_3s specimen. An important large-scale trend was observed where the thickness direction strain tended to be more tensile near the outside faces of the laminate than near the mid-ply region. The measured strains were compared with the three-dimensional analysis technique known as Spline Variational Elastic Laminate Technology (SVELT), resulting in a very close match and corroborating the usefulness of SVELT. / Ph. D.

Fiber-reinforced composites (FRCs) offer a stronger and lighter weight alternative to traditional materials used in engineering components such as wind turbine blades and rotorcraft structures. Composites for these applications are often fabricated using liquid molding techniques, such as injection molding or resin transfer molding. One significant issue during these processing methods is void formation due to incomplete wet-out of the resin within the fiber preform, resulting in discontinuous material properties and localized failure zones in the material. A fundamental understanding of the resin evolution during processing is essential to designing processing conditions for void-free filling, which is the first objective of the dissertation. Secondly, FRCs used in rotorcraft experience severe vibrational loads during service, and improved damping characteristics of the composite structure are desirable. To this end, a second goal is to explore the use of matrix-embedded nanoscale reinforcements to augment the inherent damping capabilities in FRCs. The first objective is addressed through a computational modeling and simulation of the infiltrating dual-scale resin flow through the micro-architectures of woven fibrous preforms, accounting for the capillary effects within the fiber bundles. An analytical model is developed for the longitudinal permeability of flow through fibrous bundles and applied to simulations which provide detailed predictions of local air entrapment locations as the resin permeates the preform. Generalized design plots are presented for predicting the void content and processing time in terms of the Capillary and Reynolds Numbers governing the molding process. The second portion of the research investigates the damping enhancement provided to FRC's in static and rotational configurations by different types and weight fractions of matrix-embedded carbon nanotubes (CNTs) in high fiber volume fraction composites. The damping is measured using dynamic mechanical analysis (DMA) and modal analysis techniques, and the results show that the addition of CNTs can increase the material damping by up to 130%. Numerical simulations are conducted to explore the CNT vibration damping effects in rotating composite structures, and demonstrate that the vibration settling times and the maximum displacement amplitudes of the different structures may be reduced by up to 72% and 50%, respectively, with the addition of CNTs. / Ph. D.

<p>When a composite laminate is transversely impacted by a projectile at the ballistic limit, its failure mode transits from global conical deformation to localized perforation. This Ph.D. dissertation aims to reveal the fundamental material failure mechanism at the ballistic limit to control perforation. First, transverse impact experiments were designed on composite strips to isolate the interaction between plies and tows. Three failure modes were identified, divided by no, partial, and complete failure before the transverse wave deformed the entire composite strip. The failure phenomenon and critical velocity region can differ with the fiber type and projectile nose geometry and dimension. In most impact events, the composite strips all failed in tension in the front of the projectiles, although they failed at different positions as the projectile nose geometry and fiber type changed. A special failure phenomenon was uncovered when the composite strips were impacted onto razor blades above the upper limit of the critical velocity region: the composite strips seemed to be cut through completely by the razor blades. To further investigate the failure by razor blade, a microscopic method was developed to cut a single fiber extracted from the composite strip and simultaneously image the failure process inside a Scanning Electron Microscope (SEM). The experiments revealed that the razor blade cannot cut through the inorganic S-2 glass fibers while can partially incision the aramid Kevlar^®KM2 Plus fibers and completely shear through the ultra-high-molecular-weight polyethylene (UHMWPE) Dyneema^® SK76 fibers. Further investigations on the fiber’s failure under dynamic cut revealed that there was no variation in the failure mode when the cut speed was increased from 1.67 μm/s to ~5.34 m/s. To record the local dynamic failure inside the composite strips and single fibers at high-velocity impact, an advanced imaging technique, high-speed synchrotron X-ray phase-contrast imaging, was introduced, which allows to capture the composite’s internal failure with a resolution of up to 1.6 μm/pixel and at a time interval 0.1 μs. Integrated with a reverse impact technique, such an advanced imaging technique is believed to be capable of revealing the mechanism involved in the impact-induced cut in single fibers, yarns, and composite strips. The relevant studies will be the extended work of this Ph.D. dissertation and published in the future.</p>

Thermal protection systems, which are commonly used to protect spacecraft during atmospheric entry, have traditionally been made of materials which are traditionally high in manufacturing costs for both the materials needed and the manufacturing complexity, such as carbon-carbon composites and aerogels. [1] In addition to their manufacturing costs, these materials are also limited in their strength, such as PICA, in a way that necessitate the use of tiles as opposed to single structures because they are not capable of supporting larger structures. [2] The limitations of polymer reinforced composites have limited their entry into these applications, except for pyrolyzed composite materials, such as carbon-carbon and ceramic composites. These materials have been successfully demonstrated their utility in extreme environments, such as spacecraft heat shields, but their high costs and the difficulty to manufacture them have limited their use to similarly high performance applications where the costs are justifiable. Previous work by others with “fuzzy fiber” composites have shown that aligned carbon nanotubes (CNTs) grown on fibers can improve their thermal conductivity and wettability. To this end vertically aligned CNTs were studied for their potential use, but found to be difficult to process with current conventional techniques. A composite material comprised of basalt, a relatively new reinforcing fiber, and phenolic, which has been used in high-temperature applications with great success was made to attempt to create a new material for these applications. To further improve upon the favorable properties of the resulting composite, the composite was pyrolyzed to produce a basalt-carbon composite with a higher thermal stability than its pristine state. While testing the effects of pyrolysis on the thermal stability, a novel iv technique was also developed to promote in-situ carbon nanotube growth of the resulting basaltcarbon composite without using a monolithic piece of cured phenolic resin in place of the standard aromatic hydrocarbon-catalyst precursor. [3, 4] The in-situ growth of carbon nanotubes (CNTs) was explored as their thermal stability [5] and effectiveness in improving performance has been previously demonstrated when used as a resin additive [6]. The specimens were examined with SEM, EDS, and TGA to determine the effects of both pyrolysis and CNT growth during pyrolysis of the basalt phenolic composites. These tests would confirm the presence of CNTs/CNFs directly grown in the composite by pyrolysis, and confirm their composition by EDS and Raman spectroscopy. EDS would additionally confirm that the surface of the basalt fibers possess a composition suitable for CNT growth, similar to the parameters of CVD processing. Additional testing would also show that the growth behavior of the CNTs/CNFs is dependent on temperature as opposed to composition, indicating that there is a threshold temperature necessary to facilitate the availability of catalysts from within the basalt fibers. The thermal stability shown by TGA indicates that the process of pyrolysis leaves the newly formed composite with a high degree of thermal stability, making the new materials potentially usable in applications such as turbines, in addition to large-scale thermal protection systems.

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Three different void content calculation techniques using optical microscopy werecompared in multiple-user trials. The three methods studied comprised of a selection,thresholding, and semi-automatic machine learning method. The techniques wereapplied to micrographs of three carbon fiber-epoxy composite plates manufacturedin-house, where one plate had reduced void content by means of debulking priorto curing. The users performed the techniques on the sets of micrographs and thestandard deviation between the users void content results were measured.The advantages of the three methods were discussed and their practical applications wereproposed. The trials showed agreement between users on what are voids and not as well asshowing that uncertainties in void content are specimen-specific and not attributed todifferent users or methods applied. All three methods showed satisfying precision incalculating void content compared to void content quality levels provided by literature.It was found that thresholding, which is the current standard method of void contentcalculation using microscopy, inhabits an unscientific bias which compromises the legitimacyof the method. The study formulates a manual selection-based method usingedge-detection selection tools intended to benchmark void content in images, as wellas proposing a route to the automation of void content analysis using microscopy. / Tre olika beräkningstekniker för kavitetshalter med hjälp av mikroskopi jämfördes genom fleranvändar-tester. De tre metoderna innefattade en selektions-metod, tröskelvärdesmetod, och en övervakad maskininlärningsmetod. Metoderna applicerades på mikrografer av tre kolfiber-epoxi kompositplattor tillverkade internt, varav en platta hade reducerad kavitetshalt genom en avbulkningsprocess innan härdning. Användarna genomförde metoderna på mikrograferna och standardavvikelsen mellan användarnas resulterande kavitetshalter mättes. För- och nackdelarna hos de tre metoderna diskuterades och deras praktiska applikationer föreslogs. Testerna visade en överensstämmelse mellan användare om vad som omfattar kaviteter och inte, samt en påvisning på att osäkerheter kring kavitetshalter är provbitberoende och inte användar- eller metodberoende. Alla tre metoder uppvisade en tillfredsställande precision i kavitethaltsberäkning jämfört med kvalitetsnivåer av kavitethalter erhållna från litteratur. Det konstaterades att tröskelvärdesmetoden, vilket är nuvarande standardmetoden för kavitethaltsberäkning med mikroskopi, innehar en bias som sätter validiteten av metoden i fråga. Studien formulerar även en manuell selektions-metod som använder selektions-verktyg för randdetektering, ämnad för att hitta referensvärden för kavitetshalter. Förslag ges även kring tillvägagångssättet till att uppnå automatiserade metoder för kavitethaltsberäkning.

Analytic methods of elastic wave scattering in fiber-reinforced composite materials are investigated in this study to calculate the effective static stiffness (axial shear modulus, m) and wave properties (axially shear wave speed, B and attenuation, Y) in composites. For simplicity only out-of-plane shear waves are modeled propagating in a plane transverse to the fiber axis. Statistical averaging of a spatially random distribution of fibers is performed and a simultaneous system of linear equations are obtained from which the effective global wave numbers are numerically calculated. The wave numbers, K=Re(K)+iIm(K), are complex numbers where the real parts are used to compute the effective axial shear static stiffness and wave speed; the imaginary parts are used to compute the effective axial shear wave attenuation in composites. Three major parts of this study are presented. The first part is the discussion of multiple scattering phenomena in a successive-events scattering approach. The successive-events scattering approach is proven to be mathematically exact by comparing the results obtained by the many-bodies-single-event approach. Scattering cross-section is computed and comparison of the first five scattering orders is made. Furthermore, the ubiquitous quasi-crystalline approximation theorem is given a justifiable foundation in the fiber-matrix composite context. The second part is to calculate m, B and Y for fiber-reinforced composites with interfacial layers between fibers and matrix. The material properties of the layers are assumed to be either linearly or exponentially distributed between the fibers and matrix. A concise formula is obtained where parameters can be computed using a computationally easy-to-program determinant of a square matrix. The numerical computations show, among other things, that the smoother (more divisional layers), or thinner, the interfacial region the less damped are the composite materials. Additionally composites with exponential order distribution of the interfacial region are more damped than the linear distribution ones. The third part is to calculate m, B and Y for fiber-reinforced composites with interfacial cracks. The procedures and computational techniques are similar to those in the second part except that the singularity near the crack tip needs the Chebychev function as a series expansion to be adopted in the computation. Both the interfacial layers and interfacial crack cases are analyzed in the low frequency range. The analytic results show that waves in both cases are attenuated and non-dispersive in the low frequency range. The composites with interfacial layers are transversely isotropic, while composites with interfacial cracks are generally transversely anisotropic. / Ph. D.

In the past few years a new class of layered piezoceramic and piezoceramic-composite actuators, known as RAINBOW and GRAPHBOW, respectively, that are capable of achieving 100 times greater out-of-plane displacements than previously available has been developed. Prior to the development of RAINBOW and GRAPHBOW, large stacks of piezoelectric actuators, requiring complicated electronic drive circuits, were necessary to achieve the displacement now possible through the use of a single RAINBOW actuator. The major issues with both RAINBOW and GRAPHBOW are the prediction of their room-temperature shapes after processing, and their deformation response under application of electric field. In this research, a methodology for predicting the manufactured shapes of rectangular and disk-style RAINBOW and GRAPHBOW is developed. All of the predictive analyses developed are based on finding approximate displacement responses that minimize the total potential energy of the devices through the use of variational methods and the Rayleigh-Ritz technique. These analyses are based on classical layered plate theory and assumed the various layers exhibited linear elastic, temperature-independent behavior. Geometric nonlinearities are important and are included in the strain-displacement relations. Stability of the predicted shapes is determined by examining the second variation of the total potential energy. These models are easily modified to account for the deformations induced by actuation of the piezoceramic. The results indicate that for a given set of material properties, rectangular RAINBOW can have critical values of sidelength-to-thickness ratio (Lx/H or Ly/H) below which RAINBOW exhibits unique, or single-valued, spherical or domed shapes when cooled from the processing temperature to room temperature. For values of sidelength-to-thickness ratio greater than the critical value, RAINBOW exhibits multiple room-temperature shapes. Two of the shapes are stable and are, in general, near-cylindrical. The third shape is spherical and is unstable. Similarly, disk-style RAINBOW can have critical values of radius-to-thickness ratios (R/H) below which RAINBOW exhibits axisymmetric room-temperature shapes. For values of R/H greater than the critical value, disk-style RAINBOW exhibits two stable near-cylindrical shapes and one unstable axisymmetric shape. Moreover, it is found that for the set of material properties used in this study, the optimal reduced layer thickness would be at 55%, since the maximum change in curvature is achieved under the application of an electric field, while the relationship between the change in curvatures and the electric field is kept very close to being linear. In general, good agreement is found for comparisons between the predicted and manufactured shapes of RAINBOW. A multi-step thermoelastic analysis is developed to model the addition of the fiber-reinforced composite layer to RAINBOW to make GRAPHBOW. Results obtained for rectangular RAINBOW indicate that if the bifurcation temperature in the temperature-curvature relation is lower than the composite cure temperature, then a unique stable GRAPHBOW shape can be obtained. If the RAINBOW bifurcation temperature is above the composite cure temperature, multiple room-temperature GRAPHBOW shapes are obtained and saddle-node bifurcations can be encountered during the cooling to room temperature of [0°/RAINBOW], [RAINBOW/0o], and [0o2/RAINBOW]. Rectangular [RAINBOW/0o/90o] seems to be less likely to encounter saddle-node bifurcations. Furthermore, the unstable spherical RAINBOW configuration is converted to a stable near-cylindrical configuration. For the case considered of disk-style GRAPHBOW, three stable room-temperature shapes are obtained and the unstable axisymmetric RAINBOW configuration is also converted to a stable near-cylindrical configuration. For both rectangular and disk-style GRAPHBOW, the relationship between the major curvature and the electric field is shown to be very close to being linear. This characteristic would aid any dynamic analysis of RAINBOW or GRAPHBOW. / Ph. D.

Yes / Composites have clinical application for their ability to mimic the hierarchical structure of human tissues. In tissue engineering applications the use of degradable biopolymer matrices reinforced by bioactive ceramics is seen as a viable process to increase osteoconductivity and accelerate tissue regeneration, and technologies such as additive manufacturing provide the design freedom needed to create patient-specific implants with complex shapes and controlled porous structures. In this study a medical grade poly(l-lactide) (PLLA) was used as matrix while apatite-wollastonite (AW) was used as reinforcement (5 wt% loading). Premade rods of composite were pelletized and processed to create a filament with an average diameter of 1.6 mm, using a twin-screw extruder. The resultant filament was 3D printed into three types of porous woodpile samples: PLLA, PLLA reinforced with AW particles, and PLLA with short AW fibres. None of the samples degraded in phosphate buffered solution over a period of 8 weeks, and an average effective modulus of 0.8 GPa, 1 GPa and 1.5 GPa was obtained for the polymer, particle and fibre composites, respectively. Composite samples immersed in simulated body fluid exhibited bioactivity, producing a surface apatite layer. Furthermore, cell viability and differentiation were demonstrated for human mesenchymal stromal cells for all sample types, with mineralisation detected solely for biocomposites. It is concluded that both composites have potential for use in critical size bone defects, with the AW fibre composite showing greater levels of ion release, stimulating more rapid cell proliferation and greater levels of mineralisation. / The research was funded in part by the UK EPSRC Centre for Doctoral Training in Additive Manufacturing and 3D Printing (EP/L01534X/1), the UK EPSRC Centre for Innovative Manufacture in Medical Devices (EP/K029592/1), and Glass Technology Services Ltd., Sheffield, UK.