Masters of Science / Located on the western offshore on the Atlantic Ocean margin of Southern Africa, the Orange Basin is the youngest and largest of the South Africa’s seven sedimentary basins. This passive margin basin in known for its hydrocarbon potential and therefore is the focus of attraction of several oil exploration companies. The study area lies near the continental margin in which four exploratory wells were drilled. An attempt has been made in this work to understand the depositional settings of these reservoirs and their biostratigraphy. Distribution of important planktonic index foraminifera helps in dating the reservoir sections. Paleoecological studies of benthic foraminifera were used for understanding the prevailing environment during the Cretaceous period. The study indicates that most of the reservoirs are distributed in the Albian (Early Cretaceous) and a few in the Cenomanian age sediments. Relatively shallow shelf sedimentation prevailed in the Late Aptian to middle part of Albian with deposition of arenaceous units. There were periodic localised deepening as well as very shallow depositional condition leading to exposure (diastem) as indicated by lithology and faunal composition. Gradual rise in sea level started in Late Albian and the entire area was under bathyal environment till the end of Cenomanian stage. This is indicated by deposition of claystone rich units and the associated fossil benthics indicates deposition in slope area. The few relatively minor argillaceous sandstone and siltstone units are with poor reservoir quality.

>Magister Scientiae - MSc / Wetlands are unique ecosystems that are acknowledged among the world’s most productive and valuable ecosystems. They are recognized as being essential to sustainable development and human welfare due to their unique environmental and socio-economic value. These highly productive ecosystems provide functions such as recycling of nutrients, watershed protection and flood control as well as grazing resources. Wetlands provide the basis for human livelihoods in Africa through ecosystem services. However, these ecosystems are affected by internal and external factors within and outside their catchments, hence the importance of monitoring those changes around these wetlands.

Wetlands are considered a last line of defence against poor water quality. Despite the natural capabilities of wetlands to remove a variety of contaminants from surface water, the track record for wetland conservation leaves much to be desired. In the northern parts of the City of Tshwane, 84% of wetlands have been degraded. When viewed against the poor bacteriological quality of river water in the study area, the lack of wetland conservation efforts is of particular concern. Given the large number of wetlands in the Tshwane area in need of rehabilitation, this study aimed to devise a methodology to prioritise these wetlands for rehabilitation. No blueprint for such a prioritisation process exists, as studies are adapted to take into account the availability of data and the unique requirements of the study area. The methodology for this study is based on the prioritisation of a specific river basin, based on expected maximum faecal bacterial load originating from various sources of pollution. Four river basins were compared with each other in a series of screening processes. Screening was done on a landscape level using a Geographic Information System (GIS) to generate various composite layers as part of the screening process. The screening processes relied on the application of several weighted criteria. Weights for criteria are based on scientific literature. Weights are also allocated in line with the “worst case scenario”, as the study is in essence an assessment of the various pollution sources and their maximum possible contribution to deteriorating surface water quality. A Simple Additive Weighting technique was used to assess the total pollution loads and total numbers of users at risk from contaminated surface water in each of the river basins. It is important to note that the objective is to only rate the pollution sources, whilst exact pollution loads were not calculated. Diffuse, areal and point sources of pollution were rated using the estimated contributions to faecal coliform loads. The river basin with the highest score was selected for the selection of candidate wetlands for rehabilitation purposes. The Apies River Basin scored highest for most of the criteria, with the exception of the number of households at risk from contaminated surface water. Despite the 0.60 weight allocated to households at risk, the extent of pollution sources in this river basin allowed it to be singled out as the basin in which a wetland for rehabilitation is most urgent in order to attenuate bacterial load. Two wetlands were short listed, based on their high need for rehabilitation, their hydrogeomorphic location (valley bottom with a channel), and given that they are larger than 1ha in size and within a minimum distance from the households at risk. Site level assessments are required for a final selection between the two, taking into account the nature of the current disturbances, the possibility of risk due to back-flooding, the projected costs associated with rehabilitation, the nature of the vegetation associated with the wetlands and the general conservation value of each of the wetlands.

Eco-geomorphic interactions occur across a range of spatial and temporal scales from the level of the entire watershed to an individual geomorphic unit within a stream channel. Predicting the mechanisms, rates and timing of sediment production and storage in the landscape are fundamental problems in the watershed sciences. This is of particular concern given that excess sedimentation is considered a major pollutant to aquatic ecosystems. Rates of sediment delivery to stream networks are characteristically unsteady and non-uniform. Because of this, conventional approaches for predicting sediment yield provide incomplete and often inaccurate information. Terrestrial cosmogenic nuclides (TCNs) provide an estimate of spatially averaged rates of sediment yield from 101 to 104 km2 and temporally integrated from 103 to 105 years. Here, I used TCNs to constrain unsteadiness and non-uniformity of sediment yield within specific catchments of the Columbia River Basin (CRB). This is in combination with GIS analysis optically stimulated luminescence (OSL), Carbon-14 (C14) dating of fluvial deposits, and rapid geomorphic assessments. Results showed an order of magnitude spatial variability in the rates of millennial-scale sediment yield at the scale of the entire CRB. At the broadest scale long-term rates of sediment yield generally are poorly predicted from topographic and environmental parameters. A notable exception is the observed positive correlation between mean annual precipitation and sediment yield. Where functional relationships exist, the nature of those relationships are scale and situation-dependent. In addition to the broadest scale, each smaller watershed (e.g., ~ 10 – 2,000 km2) has a distinct geologic, geomorphic, and disturbance history that sets the template for the modern sediment dynamics and the physical aspects of aquatic habitat. Chapter 2 presents results of broad-scale trends while Chapter 3 is comprised of case studies from smaller watersheds. Finally, Chapter 4 explores the relationship between long-term sediment yield and modern channel form.

Colorado River cutthroat trout, Oncorhyncus clarki pleuriticus , occupy less than 12% of their historic range. Restoration and conservation of this species are currently under way across the upper Colorado River basin, but guidance to inform management decisions related to the impacts of climate change on cutthroat is lacking. Shifts in the thermal distribution of freshwater fish have been documented, and will continue to occur as cold water habitat is threatened by warming water temperatures. Coupled air and water temperature data allow for an estimation of potential resistance and resilience to warming, determining the effect that local air has on stream temperature. The United States Forest Service, cooperating with federal agencies, state agencies and private landowners, placed temperature loggers in the water and two air locations at 50 sites. To select a representative subset of sites, six habitat characteristics of each Colorado River cutthroat trout core conservation population were considered. These characteristics include solar input, elevation, watershed area, riparian vegetation, groundwater input, and the 30-year mean maximum July air temperature. Results from coupled temperature loggers indicate that the relationship between air and water temperature in the upper Colorado River basin is neither linear, nor one-to-one. Using Mohseni's (2003) equation, the relationship between air and water temperature was fit to a nonlinear regression curve. Analysis shows that the median rise in daily maximum water temperature is only 0.41°C for a 1.0°C increase in the median daily maximum air temperature. Air temperature exerts the most influence over water temperature; however, these results indicate that there are other characteristics that influence stream temperature. To determine these characteristics, analysis of the six habitat characteristics used for site selection in addition to aspect, slope, and latitude were used to model multiple temperature metrics. The best model, nonlinear water to air temperature relationship, had an R2 between actual and predicted values of 0.71. It also became clear that using multi-metric analysis would provide a much more robust indicator of resistance. This work will allow managers to consider potential climate change resistance or resilience in project prioritization, by understanding potential habitat characteristics to buffer stream warming.

>Magister Scientiae - MSc / Many countries in sub-Sahara African region are characterised by crystalline basement aquifers where groundwater explorations are often described as complex. This is because groundwater availability in such aquifers is largely a consequence of the interaction of several processes related to groundwater process [recharge-flow-discharge process], underlying geological features and fracture connectivity of the aquifer rock matrix. At a local scale, crystalline basement aquifers are heterogeneous and anisotropic due to fractures, geological structures and discontinuities including varying hydraulic characteristics which need to be understood. The lack of detailed investigations of site-specific conditions to assess influence on groundwater recharge process limits implementation of initiatives for groundwater abstraction that supports environment and socio-economic projects. / 2023

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第18565号 / 工博第3926号 / 新制||工||1603(附属図書館) / 31465 / 京都大学大学院工学研究科社会基盤工学専攻 / (主査)教授 寶 馨, 教授 堀 智晴, 准教授 KIM Sunmin / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19409号 / 工博第4125号 / 新制||工||1636(附属図書館) / 32434 / 京都大学大学院工学研究科社会基盤工学専攻 / (主査)教授 寶 馨, 教授 立川 康人, 准教授 佐山 敬洋 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

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Mercury (Hg) in rivers and streams of the Mackenzie River Basin (MRB) presents a risk to fish, aquatic mammals, and humans. This thesis makes use of newly-released water quality data, including total mercury (THg) and dissolved mercury (DHg), gathered through the NWT-Wide Community-based Water Quality Monitoring (CBM) program. Landscape metrics extracted from geospatial datasets (e.g. vegetation type cover and ground ice presence), along with the water quality parameters were transformed, as needed, and then assessed for relationships with Hg concentration in rivers using principle component analysis, correlation and linear regression. Transformed turbidity, total phosphate, total sulfate, and the 1st principle component representing total metals were positively correlated with log10 THg and log10 particulate Hg (PHg) (p < 0.05) in major tributaries on the MRB. Major tributaries had a greater proportion of THg as PHg. Dissolved organic carbon and total organic carbon were positivity correlated to log10 DHg in minor tributaries (p < 0.05) of the MRB. Logit-transformed ground ice presence was positively correlated with median log10 PHg and log10 THg (PHg; p < 0.05, THg; p < 0.05). Median log10 DHg was positively correlated with logit-transformed landcover metric mixed forest (R2 = 0.67), and negativity correlated with logit-transformed landcover metric sub-polar taiga needleleaf forest (R2 = 0.64) (p < 0.05). This suggests suspended particles, derived potentially from suspended mineral matter, kerogens, and/ or weathering of sulfides could be a control on PHg in major tributaries of the MRB, while thicker, organic soils, potentially in forested areas, releasing TOC and DOC, could control export of DHg to minor tributaries in the MRB.