L’intérêt croissant de l’industrie pour les matériaux composites thermoplastiques est motivé par leurs propriétés de thermoformabilité, de recyclabilité ainsi que leurs capacités de cadences de production élevées. Le développement de matériaux pré-imprégnés thermoplastiques, apparus dès les années 1980, s’est imposé comme un moyen efficace de contourner les fortes viscosités des polymères utilisés en réduisant la distance d’écoulement des polymères à l’état « fondu ». Cette étude s’est plus particulièrement intéressée au développement de composites à base de tissus de verre et de carbone pré-imprégnés par un latex acrylique, le TPREG I. En outre, les propriétés mécaniques élevées des matrices acryliques, alliées à un coût relativement faible, en font un matériau intéressant, de nature à permettre un saut technologique dans la conception et la fabrication de composites structuraux à matrice organique. Notre étude s’est concentrée sur la mesure de l’adhésion à l’interface fibre/matrice acrylique car cette région est au cœur du transfert de charge de la matrice vers les fibres et conditionne donc les propriétés mécaniques du composite. Nous avons choisi d’évaluer l’adhésion interfaciale en combinant des analyses de mouilllage avec des tests mécaniques aux échelles microscopique et macroscopique. Le test micromécanique de la microgoutte permet de mettre en évidence le rôle central de l’ensimage des fibres sur la contrainte de cisaillement interfaciale. L’adhésion thermodynamique, déterminé par des mesures d’énergie de surface, est en accord avec la contrainte de cisaillement et souligne l’influence de la polarité de l’ensimage. A l’échelle macroscopique, les essais de traction hors-axe sur composites unidirectionnels permettant de solliciter l’interface en cisaillement quasi-plan ont mis en exergue une corrélation entre les échelles micro et macro. L’étude a également permis de dégager une forte augmentation de l’adhésion grâce à une modification de la matrice acrylique, ainsi qu’une dégradation des propriétés interfaciales à l’échelle micro par vieillissement hydrolytique. Cette étude constitue une première base de données concernant les propriétés interfaciales de composites thermoplastiques acryliques et démontre l’importance d’une étude multi-échelles dans la conception de nouveaux composites. / The present study was initiated by the development of a new processing route, i.e. latex-dip impregnation, for thermoplastic (TP) acrylic semi-finished materials. The composites resulting from thermocompression of TPREG I plies were studied by focusing of interfacial adhesion. Indeed the fiber/matrix interface governs the stress transfer from matrix to fibers. Thus, a multi-scale analysis of acrylic matrix/fiber interfaces was conducted by considering microcomposites, as models for fiber-based composites, and unidirectional (UD)macro-composites. The study displayed various types of sized glass and carbon fibers. On one hand, the correlation between thermodynamic adhesion and practical adhesion, resulting from micromechanical testing, is discussed by highlighting the role of the physico-chemistry of the created interphase. Wetting and thermodynamical adhesion are driven by the polarity of the film former of the sizing. On the other hand, in-plane shear modulus values from off-axis tensile test results on UD composites are consistent with the quantitative analyses of the interfacial shear strength obtained from microcomposites. More specifically, both tests have enabled a differentiation of interface properties based on the fiber sizing nature for glass and carbon fiber-reinforced (micro-)composites. The study of overall mechanical and interface properties of glass and carbon fiber/acrylic composites revealed the need for tailoring interfacial adhesion. Modifications of the matrix led to successful increases of interfacial adhesion in glass fiber/acrylic composites. An additional hygrothermal ageing study evidenced a significant loss of interfacial shear strength at micro-scale which was not observed for UD composites. The results of this study are a first step towards a database of relevant interface properties of structural TP composites. Finally, the analyses of interfaces/phases at different scales demonstrate the importance of a multi-scale approach to tailor the final properties of composite parts.

This thesis has a theoretical and a practical part. The first part contains theoretical introduction to the phenomenon of increased stiffness at very small strains and possibilities of its practical applications. The available methods for evaluating initial shear modulus tests are described below. Increased attention is paid to the method of evaluation of test data in the frequency domain using the Fourier transform. The last chapter in this part describes an algorithm designed for automatic evaluation of measurements in the frequency domain. The practical part deals with measurement and evaluation of initial shear modulus for Brno clay as a function of vertical stress in oedometric test. Firstly, a device is presented that allows the extension of the oedometric test with sensors for measuring initial shear modulus of soil. This device was designed for the test in this thesis. Subsequently, the test plan is described including description of all soil samples. In this thesis, several types of soil samples from a single site were tested. Next, the results of the individual tests are evaluated by the selected methods. Examples are used for showing the differences in evaluation of the same data by other methods. At the end, the results of the individual tests for all sample types are compared with each other and with data from literature.

Subject of this diploma thesis is to describe the effect of adding different amount of aged binder recovered from RAP on the change of properties of polymer modified bitumen. The RAP containing unmodified bitumen and the RAP where we can expect bitumen modification are used to recover binder. The binder obtained from RAP is dosed into the virgin binder in amount of 15 %, 30 % and 50 %. The methods of recycling of flexible pavements, extraction and regeneration of asphalt binders, rejuvenating of their properties and methods of empirical and functional laboratory tests are described in the theoretical part. The practical part deals with evaluating and comparison of the results mixed binders properties.

Byggbranschens utsläpp av växthusgaser utgör en stor andel av Sveriges totala utsläpp. För att minska de byggrelaterade utsläppen är det på många fronter som byggbranschen behöver förändras och effektiviseras. De senaste åren har en succesiv ökning av byggandet i trä skett vilket är gynnsamt då trä alternativet är mer klimatvänligt än stål och betong. De tuffa klimatmålen vi nu står framför innebär dock att mer behöver göras än att endast öka andelen träbyggnader. Pappersmassaindustrin är lätt att bortse ifrån, då den hittills inte varit relevant för byggbranschen och för att återanvändning är relativt framträdande inom den branschen. Ifrån sågverken som sönderdelar trästockar till virke fraktas flis som blir över till pappersbruk. Av flisen görs sedan bland annat diverse pappförpackningar som går att återvinna. Problemet är att dessa förpackningar endast går att återvinna ett visst antal gånger innan fibrerna blir obrukbara och istället används som biobränsle. Om byggmaterial skulle gå att producera baserat på dessa fibrer, skulle detta innebära en mer långlivad användning av dem. Ett byggmaterial som uppfunnits, gjort på fibrer från pappersmassabruk är core-materialet ”Greenwood”. Eftersom materialet är nytt och egenskaperna till stor del är okända krävs det att diverse studier görs som undersöker materialets olika egenskaper som är relevanta för en eventuell tillämpning inom byggbranschen. Denna studie avser att undersöka skjuvstyvhet, böjstyvhet och bärförmåga hos sandwichelement uppbyggda av core-materialet Greenwood och ytskikt av papp. Detta genom att först  dynamiskt och statiskt testa de ingående materialens egenskaper, följt av böjprovning av nio sandwichbalkar med varierande tjocklek på ytskikten. Samtliga balkar testades även dynamiskt. Core-materialet Greenwood som ingick i sandwichelementen var endast den begränsande faktorn en gång av tio böjprov. När core-materialets skjuvstyvhet togs fram både dynamiskt och statiskt och när den omvandlades till en skjuvmodul visade det sig att Greenwood har en mer än dubbelt så stor styvhet som EPS-cellplast vid liknande densitet. Detta är intressant då denna cellplast ofta agerar som ett core-material i sandwichelement ute i byggbranschen. Testerna visar även på att balkarna har en relativt liten spridning vilket innebär att resultaten har god tillförlitlighet. Slutligen, kan det konstateras att dessa sandwichelement uppvisar sega egenskaper med en viss kvarvarande lastkapacitet även efter brott. Samtliga nämnda egenskaper ovan talar för en viss potential för tillämpning av dessa sandwichelement inom byggbranschen. Fortsatta studier av fukt- och krypegenskaper vid långtidsbelastning rekommenderas, vilket är viktigt för användning inom byggandet. De omfattande resultaten från föreliggande studie utgör dock ett bra underlag för fortsatta undersökningar och värdering av möjliga tillämpningar. / The construction industry`s greenhouse emissions, makes up for a large portion of Sweden’s total emissions. In order to reduce construction related emissions, a fair amount of fronts within the construction industry needs to be changed and streamlined. In the last couple of years, there has been a successive increase in the number of structures that are built from wood amongst other things, which is beneficial because the wood alternative is more climate friendly than steel and concrete. The current tough climate goals entails that more has to be done than just increasing the amount of wood constructions. The pulp industry is easy to write off because so far, it has not been relevant to the construction industry and because recycling is relatively prominent within that industry. From the sawmills that dismember wooden logs to lumber, leftover wood chips are transported to paper mills. Among other things, different cardboard packages that can be recycled are then made from those wood chips. The problem with these packages is that they can only be recycled a certain number of times before the fibers become unusable and instead, are used as biofuel. If building materials were to be able to be produced with these fibers, that would be a more long-lived use of them. A building material, recently invented, made of fiber from paper mills is the core-material “Greenwood”. Because the material is new and its properties for the most part are unknown, this requires that various studies are conducted that examines the different properties the material possesses that are relevant for a contingent enforcement within the construction industry. This study intends to examine the shear rigidity, flexural rigidity and maximum capacity for sandwich panels made from the core-material Greenwood and faces of paperboard. This was achieved by first dynamically and statically test the properties of the two different materials, followed by flexure testing nine sandwich beams with varying face thicknesses. Every beam was also tested dynamically. The core-material Greenwood which was a part of the sandwich panels, was only the limiting factor 1 time out of 10 flexure tests. When the shear rigidity of the core-material was calculated both statically and dynamically and when it was converted to a shear modulus it was shown that Greenwood has a rigidity of more than double that of EPS cellular plastic at similar density. This is interesting because this type of cellular plastic often acts as a core-material in sandwich structures found in the construction industry. The tests also show that the beams have a relatively small spread which means that the results have good reliability. Finally, it can be concluded that these  sandwich panels exhibit ductile properties with a certain lasting load capacity even after ultimate load has been reached. Every property mentioned above indicates that there is a certain potential for applicability of these sandwich panels within the construction industry. Continued studies of moisture properties and creep properties during long-term loading is recommended, which is important for a possible use within construction. The extensive results from this study constitutes a good basis for continued research and assessment of possible applications.

The presentation describes partial results from an industrial project in which a transmission test bench from ZF Prüfsysteme was decoupled from the foundation in terms of vibration using commercial PU foam material ('Sylomer' SR220 from Getzner). The presentation shows how this material was extensively tested by the manufacturer and characterized in numerous data sheets in order to enable the engineer to perform a simple, operating point-dependent dynamic design using clear diagrams and the classic equation for a single-mass oscillator. However, if a more complex analysis is to be carried out using the finite element method, e.g. to determine all 6 rigid body shapes and natural frequencies of the dynamically decoupled test rig and not just the purely vertical natural shape/frequency, the apparent elasticity and shear moduli specified in the manufacturer's data sheets must be converted into true values for the corresponding operating points, which can then be used in a linear FE calculation. For this purpose, FEM models of the elastomer test specimens are generated for different shape factors. The conversion of the apparent to the true characteristic values is then carried out using the optimizer available in the PTC software “Creo Simulate” in a so-called 'feasibility study' and the results are discussed. It can be seen that the true moduli of elasticity and transverse strain coefficients are only slightly or no longer dependent on the form factor. Depending on the density of the PU foam, the transverse strain coefficient is also significantly lower than 0.5. The true shear modulus is practically identical to the measured shear modulus, as a pure biaxial stress and strain state occurs in the shear specimens, in which strain restraints due to transverse strain plays no role - quite unlike in the specimens loaded in the normal (compression) direction, in which triaxial compression stress states occur due to transverse strain restraints. Finally, the true material properties determined in this way are used for an exemplary modal analysis of the entire, idealized test rig on the strip foundation using the finite element method. The error is evaluated if the apparent modulus of elasticity and a Poisson ratio of zero is used instead, so that a simple evaluation and error estimation of analysis results is possible in practical applications. / Der Vortrag beschreibt Teilergebnisse aus einem industriellen Projekt, in dem ein Getriebeprüfstand der ZF Prüfsysteme schwingungstechnisch über kommerzielles PU- Schaummaterial („Sylomer“ SR220 der Firma Getzner) vom Fundament abgekoppelt wurde. Der Vortrag stellt dar, wie dieser Werkstoff vom Hersteller umfangreich getestet und in zahlreichen Datenblättern charakterisiert wurde, um dem Ingenieur schließlich eine einfache, betriebspunktabhängige dynamische Auslegung mittels übersichtlicher Diagramme und der klassischen Gleichung für einen Einmassenschwinger zu ermöglichen. Soll jedoch eine aufwendigere Analyse mittels der Methode der Finiten Elemente durchgeführt werden, z.B. um alle 6 Starrkörperformen und Eigenfrequenzen des dynamisch abgekoppelten Prüfstandes zu bestimmen und nicht nur die rein vertikale Eigenform/Eigenfrequenz, müssen die in den Herstellerdatenblättern angegeben formzahlabhängigen scheinbaren Elastizitäts- und Schubmoduli in wahre Werte für die entsprechenden Betriebspunkte umgerechnet werden, die dann in einer linearen FE-Rechnung verwendet werden können. Dafür werden FEM-Modelle der Elastomer-Probekörper für verschiedene Formfaktoren erzeugt. Die Umrechnung der scheinbaren in die wahren Kennwerte wird anschließend mittels des in der PTC-Software „Creo Simulate“ vorhandenen Optimierers in einer sogenannten „Machbarkeitsstudie“ durchgeführt und die Ergebnisse diskutiert. Es zeigt sich, dass die wahren E-Moduli und Querdehnzahlen nur noch gering bzw. nicht mehr vom Formfaktor abhängen. Je nach Dichte des PU-Schaums stellt sich auch eine Querdehnzahl von deutlich kleiner als 0,5 ein. Der wahre Schubmodul ist praktisch identisch wie der gemessene Schubmodul, da in den Schubproben ein reiner zweiachsiger Spannungs- und Dehnungszustand auftritt, in dem Dehnungsbehinderung durch Querdehnung keine Rolle spielt – ganz anders als in den in Normalenrichtung (Druck-) belasteten Proben, in denen durch die Querdehnungs- behinderung dreiachsige Spannungszustände auftreten. Schließlich werden die so bestimmten wahren Werkstoffkennwerte für eine exemplarische Modalanalyse des gesamten, idealisierten Prüfstandes auf den Streifenfundamenten mittels der Methode der Finiten Elemente verwendet. Der Fehler wird bewertet, wenn man stattdessen den scheinbaren E-Modul und eine Querdehnzahl von Null verwendet, so dass in der Anwendungspraxis eine einfache Bewertung und Fehlerabschätzung von Analyseergebnissen möglich ist.

Seafloor compliance is a non-intrusive geophysical method sensitive to the shear modulus of the sediments below the seafloor. A compliance analysis requires the computation of the frequency dependent transfer function between the vertical stress, produced at the seafloor by the ultra low frequency passive source-infra-gravity waves, and the resulting displacement, related to velocity through the frequency. The displacement of the ocean floor is dependent on the elastic structure of the sediments and the compliance function is tuned to different depths, i.e., a change in the elastic parameters at a given depth is sensed by the compliance function at a particular frequency. In a gas hydrate system, the magnitude of the stiffness is a measure of the quantity of gas hydrates present. Gas hydrates contain immense stores of greenhouse gases making them relevant to climate change science, and represent an important potential alternative source of energy. Bullseye Vent is a gas hydrate system located in an area that has been intensively studied for over 2 decades and research results suggest that this system is evolving over time. A partnership with NEPTUNE Canada allowed for the investigation of this possible evolution. This thesis describes a compliance experiment configured for NEPTUNE Canada’s seafloor observatory and its failure. It also describes the use of 203 days of simultaneously logged pressure and velocity time-series data, measured by a Scripps differential pressure gauge, and a Güralp CMG-1T broadband seismometer on NEPTUNE Canada’s seismic station, respectively, to evaluate variations in sediment stiffness near Bullseye. The evaluation resulted in a (- 4.49 x10-3± 3.52 x 10-3) % change of the transfer function of 3rd October, 2010 and represents a 2.88% decrease in the stiffness of the sediments over the period. This thesis also outlines a new algorithm for calculating the static compliance of isotropic layered sediments.

Seafloor compliance is a non-intrusive geophysical method sensitive to the shear modulus of the sediments below the seafloor. A compliance analysis requires the computation of the frequency dependent transfer function between the vertical stress, produced at the seafloor by the ultra low frequency passive source-infra-gravity waves, and the resulting displacement, related to velocity through the frequency. The displacement of the ocean floor is dependent on the elastic structure of the sediments and the compliance function is tuned to different depths, i.e., a change in the elastic parameters at a given depth is sensed by the compliance function at a particular frequency. In a gas hydrate system, the magnitude of the stiffness is a measure of the quantity of gas hydrates present. Gas hydrates contain immense stores of greenhouse gases making them relevant to climate change science, and represent an important potential alternative source of energy. Bullseye Vent is a gas hydrate system located in an area that has been intensively studied for over 2 decades and research results suggest that this system is evolving over time. A partnership with NEPTUNE Canada allowed for the investigation of this possible evolution. This thesis describes a compliance experiment configured for NEPTUNE Canada’s seafloor observatory and its failure. It also describes the use of 203 days of simultaneously logged pressure and velocity time-series data, measured by a Scripps differential pressure gauge, and a Güralp CMG-1T broadband seismometer on NEPTUNE Canada’s seismic station, respectively, to evaluate variations in sediment stiffness near Bullseye. The evaluation resulted in a (- 4.49 x10-3± 3.52 x 10-3) % change of the transfer function of 3rd October, 2010 and represents a 2.88% decrease in the stiffness of the sediments over the period. This thesis also outlines a new algorithm for calculating the static compliance of isotropic layered sediments.