Initial studies to determine the thermodynamic solubility product (Ksp) of gypsum and CaCO3 were conducted. The influence of different electrolyte salts at different concentrations upon the solubility of gypsum and CaCO3 was then tested. Analytical data was utilized in conjunction with a computer to calculate the activity of CaCO3 and gypsum, the ion pair concentration and the solubility product. Indifferent salts increased the solubility of gypsum and CaCO3, and salts with a common ion decreased the solubility of gypsum and CaCO3. Lithium was found to be the dominant monovalent cation present in these marine derived soils. In most cases the lithium concentration was greater than the sodium plus potassium (Na++K+) concentrations. All soils were found to be high in calcium and sulfate and the 1:1 soil water suspensions were saturated with respect to the constituent mineral gypsum. Salt release from Mancos shale is controlled by the parabolic diffusion law. Two diffusion controlled reactions occur: (a) a fast surface reaction and (b) a slow mineral weathering reaction. The fast reaction, accounting for 80-90 percent of the total salt production is due to the dissolution of salt from the surface of the mineral particles and to the dissolution of the fine (<.10 mm) mineral fraction. This reaction occurred in less than 2 minutes. The slow reaction accounting for 10-20 percent of the salt production is due to the dissolution of the larger more resistant mineral fraction, and proceeds for several days. Chemical equilibrium was reached in less than 72 hours for the small natural occurring size fraction (<.10 mm), while 7 to 9 days was required for equilibrium in the larger (>.25 to >1.0 mm) size fractions, respectively. Soil columns were leached with deionized water to allow the calculation of potential to produce 3.15 tons of salt per acre inch, and the salt accounted for 1.89 percent of the soil's total mass.

Areally expansive, persistent and recurring blooms frequently dominated by cyanobacteria have developed primarily in the north-central region of Florida Bay since approximately 1991. This part of the bay has a history of the following: periodic hypersalinity, high sediment-derived turbidity, P limitation, N limitation, light limitation and long water residence time. Clonal isolates of selected dominant bloom species of cyanobacteria (Synechococcus cf. elongatus and Synechocystis sp.) and diatoms (Chaetoceros cf. salsugineus and Thalassiosira cf. oceanica) from Florida Bay were examined in an effort to explain their relative dominance of the phytoplankton community. The following physiological characteristics and nutrient strategies of the study species were examined: (1) salinity-growth response; (2) light-growth response; (3) phosphorus-dependent growth kinetics; (4) ERC-theory phosphorus competitiveness; (5) cellular quotas and luxury storage capabilities of N and P; (6) optimal N:P ratios; (7) P and N-limited competitiveness under various salinities, N:P ratios, forms of N and P, and rates of nutrient delivery; (8) aerobic nitrogen fixation; (9) production of allelochemic compounds, and (10) response to resuspended sediment. This study identified salinity and nutrient limitation as the factors having the greatest potential to regulate the development of cyanobacteria and diatom bloom dominance in Florida Bay. The results strongly suggest that the frequent dominance of Synechococcus cf. elongatus, and Synechocystis sp. in the recurring phytoplankton blooms of the north-central region of Florida Bay can be attributed to their superior P-competitiveness and to a lesser degree to their greater salinity tolerance limits.

Dryland salinity occurs extensively throughout the Spicers Creek Catchment in central west New South Wales, Australia. The extent of dryland salinity in the Spicers Creek Catchment has severely altered the landscape, having major environmental implication. Large area of the catchments has experienced soil erosion resulting from the saline groundwater in the surface soil causing the destruction of clay and soil structure. The objective of this study was to use seismic refraction methods to map in detail a shear zone, which was associated with an area of major dryland salination. In particular, both the width of shear zone and the rock fabric within it were to be mapped with two both compressional (P) and shear (S) waves using a three-dimensional (3D) array of three- component (3C) receivers. The seismic data was recorded across a shear zone which is associated with salination in the Spicers Creek Catchment using the Australian National Seismic Imaging Resources (ANSIR) 360-trace system. Three-component (3C) geophones were used to record shear waves as well as compressional wave. An IVI minivibrator T-15000 was used as the main source of energy for the seismic survey. The results of the three-dimensional three-component seismic refraction surveys at the Spicers Creek Catchment show that the shear zone exhibit the seismic geophysical anomaly of a shear zone, existing as a narrow region with low seismic velocities and increased depth of weathering. A detailed analysis of the refractor seismic velocities and amplitude show a number of linear features parallel to and cross-cutting the shear zone. Linear features cut the shear zones at each site. They have been interpreted as a series of recent faults which act as discharge zone bringing saline groundwater to the surface.

Soil is the world’s largest terrestrial carbon (C) sink, and is estimated to contain approximately 1600 Pg of carbon to a depth of one metre. The distribution of soil organic C (SOC) largely follows gradients similar to biomass accumulation, increasing with increasing precipitation and decreasing temperature. As a result, SOC levels are a function of inputs, dominated by plant litter contributions and rhizodeposition, and losses such as leaching, erosion and heterotrophic respiration. Therefore, changes in biomass inputs, or organic matter accumulation, will most likely also alter these levels in soils. Although the soil microbial biomass (SMB) only comprises 1-5% of soil organic matter (SOM), it is critical in organic matter decomposition and can provide an early indicator of SOM dynamics as a whole due to its faster turnover time, and hence, can be used to determine soil C dynamics under changing environmental conditions.¶ Approximately 932 million ha of land worldwide are degraded due to salinity and sodicity, usually coinciding with land available for agriculture, with salinity affecting 23% of arable land while saline-sodic soils affect a further 10%. Soils affected by salinity, that is, those soils high in soluble salts, are characterised by rising watertables and waterlogging of lower-lying areas in the landscape. Sodic soils are high in exchangeable sodium, and slake and disperse upon wetting to form massive hardsetting structures. Upon drying, sodic soils suffer from poor soil-water relations largely related to decreased permeability, low infiltration capacity and the formation of surface crusts. In these degraded areas, SOC levels are likely to be affected by declining vegetation health and hence, decreasing biomass inputs and concomitant lower levels of organic matter accumulation. Moreover, potential SOC losses can also be affected from dispersed aggregates due to sodicity and solubilisation of SOM due to salinity. However, few studies are available that unambiguously demonstrate the effect of increasing salinity and sodicity on C dynamics. This thesis describes a range of laboratory and field investigations on the effects of salinity and sodicity on SOC dynamics.¶ In this research, the effects of a range of salinity and sodicity levels on C dynamics were determined by subjecting a vegetated soil from Bevendale, New South Wales (NSW) to one of six treatments. A low, mid or high salinity solution (EC 0.5, 10 or 30 dS/m) combined with a low or high sodicity solution (SAR 1 or 30) in a factorial design was leached through a non-degraded soil in a controlled environment. Soil respiration and the SMB were measured over a 12-week experimental period. The greatest increases in SMB occurred in treatments of high-salinity high-sodicity, and high-salinity low-sodicity. This was attributed to solubilisation of SOM which provided additional substrate for decomposition for the microbial population. Thus, as salinity and sodicity increase in the field, soil C is likely to be rapidly lost as a result of increased mineralisation.¶ Gypsum is the most commonly-used ameliorant in the rehabilitation of sodic and saline-sodic soils affected by adverse soil environmental conditions. When soils were sampled from two sodic profiles in salt-scalded areas at Bevendale and Young, SMB levels and soil respiration rates measured in the laboratory were found to be low in the sodic soil compared to normal non-degraded soils. When the sodic soils were treated with gypsum, there was no change in the SMB and respiration rates. The low levels of SMB and respiration rates were due to low SOC levels as a result of little or no C input into the soils of these highly degraded landscapes, as the high salinity and high sodicity levels have resulted in vegetation death. However, following the addition of organic material to the scalded soils, in the form of coarsely-ground kangaroo grass, SMB levels and respiration rates increased to levels greater than those found in the non-degraded soil. The addition of gypsum (with organic material) gave no additional increases in the SMB.¶ The level of SOC stocks in salt-scalded, vegetated and revegetated profiles was also determined, so that the amount of SOC lost due to salinisation and sodication, and the increase in SOC following revegetation relative to the amount of SOC in a vegetated profile could be ascertained. Results showed up to three times less SOC in salt-scalded profiles compared to vegetated profiles under native pasture, while revegetation of formerly scalded areas with introduced pasture displayed SOC levels comparable to those under native pasture to a depth of 30 cm. However, SOC stocks can be underestimated in saline and sodic landscapes by setting the lower boundary at 30 cm due to the presence of waterlogging, which commonly occurs at a depth greater than 30 cm in saline and sodic landscapes as a result of the presence of high or perched watertables. These results indicate that successful revegetation of scalded areas has the potential to accumulate SOC stocks similar to those found prior to degradation.¶ The experimental results from this project indicate that in salt-affected landscapes, initial increases in salinity and sodicity result in rapid C mineralisation. Biomass inputs also decrease due to declining vegetation health, followed by further losses as a result of leaching and erosion. The remaining native SOM is then mineralised, until very low SOC stocks remain. However, the C sequestration potential in these degraded areas is high, particularly if rehabilitation efforts are successful in reducing salinity and sodicity. Soil ecosystem functions can then be restored if organic material is available as C stock and for decomposition in the form of either added organic material or inputs from vegetation when these salt-affected landscapes are revegetated.

At no point in history have we demanded so much from our agricultural land whilst simultaneously leaving so little room for management error. Of the many possible environmental impacts from agriculture, soil and water salinisation has some of the most long-lived and deleterious effects. Despite its importance, however, land managers are often unable to make informed decisions of how to manage the risk of salinisation due to a lack of data. Furthermore, there remains no universally agreed method for salinity risk mapping. This thesis addresses these issues by investigating new methods for producing high-resolution predictions of soil salinity, soil physical properties and groundwater depth using a variety of traditional and emerging ancillary data sources. The results show that the methodologies produce accurate predictions yielding natural resource information at a scale and resolution not previously possible. Further to this, a new methodology using fuzzy logic is developed that exploits this information to produce high-resolution salinity risk maps designed to aid both agricultural and natural resource management decisions. The methodology developed represents a new and effective way of presenting salinity risk and has numerous advantages over conventional risk models. The incorporation of fuzzy logic provides a meaningful continuum of salinity risk and allows for the incorporation of uncertainty. The method also allows salinity risk to be calculated relative to any vegetation community and shows where the risk is coming from (root-zone or groundwater) allowing more appropriate management decisions to be made. The development of this methodology takes us a step closer to closing what some have called our greatest gap in agricultural knowledge. That is, our ability to manage the salinity risk at the subcatchment scale.

Spicers Creek catchment is located approximately 400 km west of Sydney in the Central West region of New South Wales, Australia. Dryland salinity has been recognised as a major environmental issue impacting soil and water resources in the Central West region of NSW for over 70 years. Due to the geological complexity of the catchment and the presence of high salt loads contained within the soils, groundwater and surface waters, the Spicers Creek catchment was identified as a large contributor of salinity to the Macquarie River catchment. Over fifty-two dryland salinity occurrences have been identified in the Spicers Creek catchment and it appears that dryland salinity is controlled by the presence of geological structures and permeability contrasts in the shallow aquifer system. Combinations of climatic, geological and agricultural factors are escalating salinity problems in the catchment. The main aim of this thesis was to identify the factors affecting salinisation processes in the Spicers Creek catchment. These include the role of geological structures, the source(s) of salts to the groundwater system and the geochemical processes influencing seepage zone development. To achieve these aims a multidisciplinary approach was untaken to understand the soils, geology, hydrogeology and hydrogeochemistry of the catchment. Investigative techniques employed in this project include the use of geophysics, soil chemistry, soil spectroscopy, hydrogeochemistry and environmental isotopes. Evaluation of high-resolution airborne magnetics data showed a major north-east to south-west trending shear zone. This structure dissects the catchment and several other minor faults were observed to be splays off this major structure. These structures were found to be conducive to groundwater flow and are influencing the groundwater chemistry in the fractured aquifer system. Two distinctive groundwater chemical types were identified in the catchment; the saline Na(Mg)-Cl-rich groundwaters associated with the fractured Oakdale Formation and the Na-HCO3-rich groundwaters associated with the intermediate groundwater system. The groundwater chemistry of other deep groundwaters in the catchment appears to be due to mixing between these end-member groundwaters within the fractured bedrock system. The spatial distribution of electrical conductivity, Cl-, Sr2+ and 87Sr/86Sr isotopic ratios showed the correlation between saline groundwaters and the location of faults. Elevated salinities were associated with the location of two crosscutting fault zones. The spatial distribution of HCO3-, K+, Li+ and ?????3CDIC highlighted the extent of Na-HCO3-rich groundwaters in the catchment and showed that these groundwaters are mixing further east than previously envisaged. These findings show that Na(Mg)-Cl-rich groundwaters are geochemically distinctive and have evolved due to extensive water-rock interaction processes within the fracture zones of the Oakdale Formation. These saline groundwaters contain elevated concentrations of trace elements such as As, V and Se, which pose a potential risk for water resources in the area. 87Sr/86Sr isotopic ratios indicated that the source of salinity to the Na(Mg)-Cl-rich groundwaters was not purely from marine or aerosol input. Salt is most likely contributed from various allochthonous and autochthonous sources. This research found that the main mechanism controlling the formation of dryland salinity seepage zones in the Spicers Creek catchment is due to the presence of geological structures. These groundwater seepage zones act as mixing zones for rainfall recharge and deeper groundwaters. The main sources of salt to the seepage zones are from deeper Na(Mg)-Cl-rich groundwaters and rainfall accession. The major importance of this research highlights the need for an integrated approach for the use of various geoscientific techniques in dryland salinity research within geologically complex environments.

The thesis summary is included in the 01front.pdf

This study examines the seasonal variability in temperature and salinity of the nearshore waters off Oregon and Northern California. Specifically, temperature and salinity variations during summer and winter were ana1yzed from data gathered at shore stations along the coast and from hydrographic data collected within 25 nautical miles of shore. At each of five shore stations a modal cell technique was used to establish the temperature-salinity characteristics of the "normal" water type existing at each station during summer and winter. A classification scheme was employed to determine what local processes were influential in altering the "normal" T-S characteristics at each station. In summer mixing with Columbia River plume water was found to be the major modifying process along the Northern Oregon coast. Off Central and Southern Oregon local heating and mixing with water from the shelf/slope region were found to be most influential. In winter dilution due to precipitation and subsequent runoff is the major modifying factor along the entire coast except off Northern Oregon where mixing with shelf/slope waters is slightly more influential. The temperature and salinity structure of the near surface waters (< 200 meters) was examined for four latitudinal zones off the Oregon- Northern California coast. Within each zone profiles were constructed at 5, 15, and 25 nautical miles offshore. Surface waters are warmer and more saline in summer than in winter. Surface temperatures increase seaward in both seasons. Surface salinities increase seaward only during winter; in summer the increase is shoreward. Offshore gradients of temperature and salinity are one to two orders of magnitude greater than longshore gradients. A strong thermocline to 30 meters and a strong halocline to 75 meters is present in summer. In winter the water is isothermal to 50 meters while a strong halocline is present to 100 meters. Below these levels temperatures and salinities continue to slowly decrease and increase, respectively, until at 200 meters they become constant throughout the study area. Variability with distance from shore is significant only in summer and is constrained to the upper 150 meters of the water column. / Graduation date: 1972

Graduation date: 1963

The work of this Master of Science thesis project is an analysis of salinity effects on nearshore epifauna along the western shore of Biscayne Bay in southeast Florida, USA. Field collection surveys have found a high probability of occurrence of bigeye mojarra (Eucinostomus havana) in salinities near 25 ppt. In a salinity gradient observation experiment test subjects of the same species and size class were also observed more frequently at 24 ppt. In this analysis presence and abundance patterns found in field surveys were compared with behavioral results obtained in the observation tank. This apparatus provided insight into distribution patterns of the bigeye mojarra (Eucinostomus havana) and possible changes in distribution that may result from habitat changes in the future. Historically, the western shore of Biscayne Bay was more freshwater marsh than the mangrove dominated marine environment that prevails today. Changes to fresh water inputs into the Bay are planned through projects of the Comprehensive Everglades Restoration Plan (CERP). CERP is a joint Florida state and U.S. federal effort to redesign surface water flow through the canal system of South Florida, replenish the Everglades ecosystem, and restore a more natural quantity, timing, and distribution of flow into Biscayne and Florida Bays. Approved by the U.S. Congress as part of the Water Resources Development Act of 2000, CERP will be implemented by the South Florida Water Management District (SFWMD) and the U.S. Army Corps of Engineers (USACE). This plan is designed to restore the ecosystem from its freshwater core to the coastal wetlands recreating a condition close to that existing before the current system of flood control drainage canals was begun in 1903 and continued by the federal Central and Southern Florida Project in 1948 (www.evergladesplan.org). Changes are planned to divert a portion of canal flows to Biscayne Bay into coastal wetlands as sheet flow and surface runoff. Planned changes to freshwater delivery may change the habitat along the shoreline and thus the distribution of prey organisms living in this habitat. This may in turn affect predator fish important to local recreational and commercial fisheries as well as other predators such as wading birds. The analysis and prediction provided in this thesis work is important for better understanding the effects of restoration efforts on the Bay nearshore habitat and its condition as essential fish habitat, which is federally regulated by the Magnuson-Stevens Fishery Conservation and Management Act (Magnuson-Stevens, 1996). The distribution of small fish and invertebrate inhabitants of the nearshore environment and habitat environmental qualities have been recorded over the past five years from throw-trap surveys of the western shoreline of Biscayne Bay as part of a CERP-sponsored monitoring program. This pattern is correlated with salinity, but there may be other factors affecting the distribution of this species.