Le géothermomètre Δ47 est basé sur la relation entre l’abondance des liaisons 13C–18O des carbonates et la température de calcification. Ce proxy contourne potentiellement les limites des autres thermomètres (δ18O, Mg/Ca) pour reconstruire les paléo-températures des océans, expliquant son développement exponentiel depuis dix ans. Cette thèse teste pour la première fois le potentiel et les limites de la thermométrie Δ47 sur les coccolithes, des nannofossiles calcaires produits par des organismes calcifiants dans la zone photique. Ces biominéraux calcitiques et ubiquistes constituent une part importante de l’archive sédimentaire. Des cultures in vitro nous ont permis d’établir que trois espèces de coccolithes actuelles enregistrent la même relation Δ47 – T que la calcite inorganique, alors qu'elles présentent de très larges effets vitaux en δ18O (±5‰). Nous concluons que ces espèces de coccolithes d'importance géologique ne présentent pas d’effets vitaux en Δ47. Nous avons ensuite appliqué le Δ47 à l’étude des sédiments enregistrant l’événement d’anoxie océanique du Toarcien (–183 Ma) au cours duquel les reconstructions de températures restent encore ambigües, notamment du fait de la méconnaissance de la composition isotopique en oxygène de l’eau de mer. Sur la base des données Δ47 acquises, nous proposons des températures élevées (de l’ordre de 36°C), mais restant relativement stables sur l'intervalle d'étude. En couplant ces températures aux données de δ18O des carbonates, nous suggérons une variation importante du δ18O de l'eau de mer dans le Bassin de Paris lors de la mise en place des faciès black shales. Enfin, sur des sédiments pélagiques subactuels, l’une des espèces étudiées présente des déséquilibres isotopiques en Δ47 non observés en culture et explicables par d’autres paramètres environnementaux comme l’intensité lumineuse. Cette thèse illustre le potentiel du thermomètre Δ47 des coccolithes en différents contextes, ouvrant un vaste champ d’application de reconstruction des paléo-environnements sur le Méso-Cénozoïque / The Δ47 geothermometer relies on the relationship between the 13C–18O abundance in carbonateand temperature of calcification. This proxy has the potential to overcome limitations of other thermometers(δ18O, Mg/Ca) to reconstruct oceanic paleotemperatures. This thesis evaluates for the first time the potentialand the limitations of the Δ47 thermometry of the coccoliths, the calcareous nannofossils produced byorganisms calcifying in the photic zone. These calcitic and ubiquitous biominerals represent an importantpart of the sedimentary archive. In vitro cultures allow us to establish that three modern coccoliths speciesrecord the same Δ47–T relation than inorganic calcite, although exhibiting substantial δ18O vital effects(±5‰). We conclude that these coccoliths species do not present any Δ47 vital effect. We subsequentlyapplied the Δ47 proxy to sediments from the Toarcian oceanic anoxic events (–183 Ma) during which thetemperatures reconstructions are still elusive, mainly due to the unknown oxygen isotopic composition ofseawater. On the basis of our Δ47 data, we infer relatively high, yet steady temperatures (around 36°C) duringthe examined interval. By combining these Δ47-derived temperatures to carbonate δ18O data, we can suggestdrastic change in the seawater δ18O composition in the Paris Basin at the onset of black shale deposition. Acore top calibration of Δ47 of coccoliths revealed that one of the studied cultured species exhibits Δ47disequilibrium that is accountable by other environmental parameters, such as light irradiance in the naturalenvironment. Thus, this thesis illustrates the potential of the coccolith Δ47 thermometer in different settings,opening a wide range of application to reconstruct the palaeoenvironments over the Meso-Cenozoic Eras

Made available in DSpace on 2014-08-20T14:25:45Z (GMT). No. of bitstreams: 1 dissertacao_catia_cristina_braga_rodrigues.pdf: 1202246 bytes, checksum: 0067166e90de2215d4ec858dba3e1ba5 (MD5) Previous issue date: 2012-04-18 / The periods of large variations in rainfall in the Mato Grosso do Sul State (centralwest region, Brazil), in particular the great floods or droughts, generate large economic losses to the state. The summer drought may further compromise the winter period, which often short rains occur. The main objective of this research is to verify bimonthly rainfall variation in the state of Mato Grosso do Sul during the summer (maximum variation) and the winter (minor variations) and their relationships with the bimonthly SST anomalies combined of the South Pacific and South Atlantic oceans. The combined anomalies were represented by Principal Oscillation Patterns (POPs), which represent the predominant patterns of ocean circulation. Monthly precipitation data from January to December (from 1981 to 2009) and monthly data of Sea Surface Temperature (SST) were used. From the rainfall climatology of the marking periods were selected two periods: December/January (rainier) and July/August (dry season). Homogeneous regions were generated by the K-means Method, three for December/January period and two for the July/August period. The regional accumulated rainfall presented no significant trend at 5% probability. The regional accumulated precipitation anomalies of two-month periods showed no significant correlations with SST anomalies in the Central Pacific (Niño 3.4) along the studied period. During the two months December/January, the largest excess precipitation in the region occurred with a predominance of strong El Nino events and droughts in major events La Niña and neutral. In regions 2 and 3 there is not a predominant sign of some events. During the July/ August period, the greatest excesses of precipitation occurred in the region with a predominance of La Niña events, with less relation respect region 2, both regions in a coherent signal (Neutral and La Niña). In cases of severe dry period, both regions have low relation with the events signals. The settings of multiple regressions of bi-monthly precipitation accumulated in homogeneous regions with the scores of the first six patterns of SST showed significant increase in both studied marking periods. The correlation coefficient between the bimonthly observed accumulated precipitation and regional estimates were significant at 1% probability in all regions. This occur especially in the region that represents the northwest quarter of the state in December/January and in the region that represents the major portion of Mato Grosso do Sul State in the July/August period. / Os períodos de grandes variações da precipitação no Mato Grosso do Sul, em especial as grandes cheias ou grandes estiagens, trazem grandes prejuízos financeiros ao Estado. As estiagens de verão podem comprometer ainda mais o período de inverno, no qual já é normal ocorrer poucas chuvas. Esta pesquisa tem por proposta principal verificar as variações bimensais da precipitação no estado de Mato Grosso do Sul nos períodos de verão (variações máximas) e inverno (variações mínimas) e suas relações com as anomalias bimensais de TSM combinadas dos oceanos Pacífico Sul e Atlântico Sul. As anomalias combinadas foram representadas pelos Padrões de Oscilação Principal (POP), os quais representam os padrões predominantes de circulação oceânica. Foram usados dados de precipitação mensal de janeiro a dezembro, período de 1981 a 2009 e dados médios mensais de Temperatura na Superfície do Mar (TSM). A partir da climatologia da precipitação foi selecionado os bimestres dezembro/janeiro (mais chuvoso) e julho/agosto (menos chuvoso) e geradas pelo método K-means regiões homogêneas, sendo três para o bimestre dezembro/janeiro e duas para o bimestre julho/agosto. As precipitações acumuladas regionais não apresentaram tendência temporal significativas a 5% de probabilidade. As anomalias de precipitação acumulada regionais dos bimestres não apresentaram correlações significativas com as anomalias de TSM na região do Pacífico Central (Niño 3.4) ao longo do período estudado, mas durante o bimestre dezembro/janeiro, os maiores excessos de precipitação da região 1 ocorreram com forte predomínio de eventos El Niño fortes e a maiores estiagens em Eventos La Niña e Neutros. Nas regiões 2 e 3 não existem um sinal predominante de alguns dos eventos. Durante o bimestre julho/agosto, os maiores excessos de precipitação ocorreram na região 1 com predomínio de eventos La Niña, com menor relação na região 2, mas ambas regiões com coerência do sinal (Neutro e La Niña). Nos casos de fortes estiagens, ambas as regiões apresentam baixa relação com os sinais dos eventos. Os ajustes das regressões múltiplas das precipitações acumuladas bimestrais nas regiões homogêneas com os escores dos seis primeiros padrões de TSM apresentaram aumento de significância em ambos bimestres estudados. O coeficiente de correlação entre as precipitações acumuladas regionais bimestrais observadas e estimadas foram significativas a 1% de probabilidade em todas as regiões, especialmente na região que representa o noroeste do Estado no bimestre dezembro/janeiro e a região que representa a maior parte do estado do Mato Grosso do Sul no bimestre julho/agosto.

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In this thesis we examine intra-seasonal oscillations (ISO) in the aqua-planet setup of the Community Atmospheric Model (CAM) version 5.1, mainly based on July and January climatological sea surface temperature (SST). We investigate mainly two questions -what should be the SST distribution for the existence of (a) northward moving ISO in summer, and (b) eastward moving MJO-like modes in winter. In the first part of the thesis we discuss the northward propagation. A series of experiments were performed with zonally symmetric and asymmetric SST distributions. The basic lower boundary condition is specified from zonally averaged observed July and January SST. The zonally symmetric July SST experiment produced an inter tropical convergence zone (ITCZ) on both sides of the equator. Poleward movement is not clear, and it is confined to the region between the double ITCZ. In July, the Bay of Bengal (BOB) and West Pacific SST is high compared to the rest of the northern tropics. When we impose a zonally asymmetric SST structure with warm SST spanning about 80 of longitude, the model shows a monsoon-like circulation, and some northward propagating convective events. Analysis of these events shows that two adjacent cells with cyclonic and anticyclonic vorticity are created over the warm SST anomaly and to the west. The propagation occurs due to the convective region drawn north in the convergence zone between these vortices. Zonally propagating Madden-Julian oscillations (MJO) are discussed in the second part of the thesis. All the experiments in this part are based on the zonally symmetric SST. The zonally symmetric January SST configuration gives an MJO-like mode, with zonal wave number 1 and a period of 40-90 days. The SST structure has a nearly meridionally symmetric structure, with local SST maxima on either side of the equator, and a small dip in the equatorial region. If we replace this dip with an SST maximum, the time-scale of MJO becomes significantly smaller (20-40 days). The implication is that an SST maximum in the equatorial region reduces the strength of MJO, and a flat SST profile in the equatorial region is required for more energetic of MJO. This result was tested and found to be valid in a series of further experiments.

Exchange of mass (water vapor), momentum, and energy between atmosphere andocean has profound influence on weather and climate. This exchange takes place at the air-sea interface, which is part of the marine atmospheric boundary layer. Various empirical relations are being used for estimating these fluxes in numericalweather and climate models but their accuracies are not sufficiently verified or tested over the Indian Ocean. The main difficulty is that vast areas of open oceans are not easily accessible. The marine environment is very corrosive and unattended long term and accurate measurements are extremely expensive. India has research ships that spend most of their time over the seas around India but that opportunity is yet to be exploited. To address this, an air-sea flux measurement system for operation on board research ships was planned. The system was tested on board Indian Research Vessels ORV SagarKanya during its cruise SK-296 in the Bay of Bengal (BoB) in July-August 2012, and NIO ship Sindhu Sadhana in June-July 2016. The complete set included instruments for measuring wind velocity, windspeed and direction, air and water temperature, humidity, pressure, all components of radiation and rainfall. In addition, ship motion was recorded at required sampling rate to correct for wind velocity. The set up facilitates the direct computation of sensible and latent heat fluxes using the eddy covariance method. In this thesis, design and installation of meteorological and ship motion sensors onboard research ships, data collection and quality control, computation of fluxes of heat, moisture and momentum using eddy covariance method and their comparison with those derived from bulk method are described. A set of sensors (hereafter, flux measuring system) were mounted on a retractable boom, ~7 m long forward of the bow to minimize the flow disturbance caused by the ship superstructures. The wind observed in the ship frame was corrected for ship motion contaminations. During the CTCZ cruise period true mean wind speed was over 10 m/s and true wind direction was South/South-Westerly. True windspeedis computed combiningdata from the anemometer a compass connected to AWS and a GPS. Turbulent fluxes were computed from motion-corrected time-series of high frequency velocity, water vapor, and air temperature data. Covariance latent heat flux, sensible heat flux, and wind stress were obtained by cross-correlating the motion-corrected vertical velocity with fast humidity fluctuations measured with anIR hygrometer, temperate fluctuation from sonic anemometer and motion-corrected horizontal windfluctuations from sonic anemometer, respectively. During the first attempt made in July-August 2012 as part of a cruise of CTCZ monsoonresearch program, observations were mainly taken in the North Bay of Bengal. The mean air-temperature and surface pressure were ~28 Deg C and ~998 hPa, respectively. Relative humidity was ~80%. Average wind speed varied in the range 4-12 m/s. The mean latent heat flux was 145 W/m2 , sensible heat flux was ~3 W/m2 and average sea-air temperature difference was ~ 0.7°C. The Bay of Bengal boundary layer experiment (BoBBLE) was conducted during June-July 2016 and the NIO research ship Sindhu Sadhana was deployed. The same suite of sensors installed during CTCZ were used during BoBBLE. During daytime, peaks of hourly net heat fluxes (Qnet ) were around 600 Wm-2(positive if into the sea), whereas, night time values were around -250 W m-2. Sea surface temperature was always >28°C and maximum air temperature exceeded 29°C. During the experimental period the mean Qnet was around -24 Wm-2 from both eddy covariance and conventional bulk methods, but there are significant differences on individual days.The new flux system gives fluxes which are superior to what was available before.