A Quaternary perspective on the paleoceanographic evolution of the central Arctic Ocean has been obtained in this PhD thesis by studying sediment cores from all of the Arctic’s major submarine ridges and plateaus. The included cores were mainly recovered during the Healy-Oden Trans-Arctic expedition in 2005 and the Lomonosov Ridge off Greenland expedition in 2007. One of the main thesis objectives is to establish whether different sediment depositional regimes prevailed in different parts of the central Arctic Ocean during the Quaternary and, if so, establish general sedimentation rates for these regimes. This was approached by dating key cores using the decay of the cosmogenic isotopes 10Be and 14C, and through stratigraphic core-to-core correlation using sediment physical properties. However, the Arctic Ocean sea ice complicated the use of 10Be for dating because a solid sea ice cover prevents the 10Be isotopes from reaching the seafloor, resulting in too old ages. Dating using 14C is also complicated due to uncertain marine reservoir age corrections in the central Arctic Ocean. The core-to-core correlations show five areas with different depositional regimes; the northern Mendeleev Ridge and Alpha Ridge, southern Mendeleev Ridge, Morris Jesup Rise, Lomonosov Ridge and Yermak Plateau, listed in the order of increasing sedimentation rates from ~0.5cm/ka to ~4.8 cm/ka. A detailed study of the relationship between sediment bulk density and grain sizes suggests a strong link between variations in clay abundance and bulk density. Grain size analysis of a Lomonosov Ridge core show that fine silt and clay dominates the interglacials, possibly due to increased suspension freezing of these size fractions into sea ice and/or nepheloid transport. Sediments younger than the marine isotope stage (MIS) 7 generally contain more coarse silt, attributed to a regime shift during the Quaternary with increased iceberg transport into the central Arctic Ocean from MIS 6 and onwards. / At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: In progress. Paper 4: In progress. Paper 5: In progress. Paper 6: In progress.

The primary objective of this study is to provide a greater understanding of the tectonic evolution of the Warburton, Cooper, Eromanga and Lake Eyre Basins in central Australia. However, this study additionally attempts to provide a greater understanding of lineaments. This study compares lineament data with a traditional tectonic analysis in order to evaluate lineaments and to best understand the tectonic evolution of the region.

The sedimentary rocks of the Karoo Supergroup in the Tuli Basin (South Africa) consist of various terrigenous clastic and chemical deposits (parabreccias, conglo-breccias, conglomerates, sandstones, fine-grained sediments, calcretes and silc~etes). Four stratigraphic units were identified: the Basal, Middle and· Upper Units, and the CI~rens Formation. The palaeo-environmental reconstructions of the four stratigraphic units are based on evidence provided by primary sedimentary structures, palaeo-flow measurements, clast size/shape analysis, petrographic studies, palaeontological findings, borehole data and stratigraphic relations. The facies associations of the Basal Unit are interpreted as colluvial fan and low sinuosity, braid~d river channel with coal-bearing overbank and thaw-lake deposits. The interpreted depositional environment implies a cold climate, non-glacial subarctic fluvio-Iacustrine system. The current indicators of the palaeo-river system suggest flow direction from ENE to WSW. The lithologies of the Basal Unit are very similar to the deposits of the fluvial interval in the Vryheid Formation (Ecca Group) of the main Karoo Basin. There is no indubitable evidence for glacial activity (e.g. striated pavements or clasts, varvites, etc.), therefore the presence of unequivocal Dwyka Group correlatives in the Tuli Basin remains uncertain. The sedimentary structures and palaeo-current analysis indicate that the beds of the Middle Unit were deposited by an ancient river system flowing in a north-northwesterly direction. A lack of good quality exposures did not allow the reconstruction of the fluvial style, but the available data indicate a high-energy, perhaps braided fluvial system. The lack of bio- and chronostr~~igraphic control hampers precise correlation and enables only the lithocorrelation of the Middle Unit with other braided river systems either in the Beaufort Group or in the Molteno Formation of the main Karoo Basin. The depositional environment of the Upper Unit is interpreted as a low-sinuosity, ephemeral stream system with calcretes and silcretes in the dinosaur-inhabited overbank area. During the deposition of the unit, the climate was semi-arid with sparse precipitation resulting -iFlhighmagnitude, low-frequency devastating flash floods. The sediments were built out from a distant northwesterly source to the southeast. The unambiguous correspondence between the Upper Unit and the Elliot Formation (main Karoo Basin) is provided by lithological similarities and prosauropod dinosaurs remains. The palaeo-geographic picture of the Clarens Fonnation indicates a westerly windsdominated erg environment with migrating transverse dune types. The ephemeral stream deposits, fossil wood and trace fossils are only present in the lower part of the Formation, indicating that the wet-desert conditions were progressively replaced by dry-desert conditions. Based on lithological and palaeontological evidence, the Formation correlates with the Clarens Formation in the main Karoo Basin. At this stage, it remains difficult to establish the exact cause of the regional palaeo-slope changes during the deposition of the Karoo Supergroup in the Tuli Basin. It is probable that foreland system tectonics, which affected the lower part of the Supergroup (Basal Unit and Middle Unit?), were replaced by incipient continental extension and rift related tectonic movements in the Middle and Upper Units, and Clarens Formation.

Arctic climate variability over the Holocene has been both extensive and, at times, abrupt. Current understanding of these changes is still quite limited with few high-resolution paleoclimate records available for this period. In order to place observed and predicted 21st century climate change in perspective, reliable and highly resolved paleo-reconstructions of Arctic climate are essential. Using an 8.5 m sediment core from Nanerersarpik Lake, this project will characterize climate changes during the Holocene, including the deglacial transition, the rapid changes that are known to have occurred around 8,200 years ago, the transition from Holocene thermal maximum (HTM) to the colder Neoglacial period, and intervals of abrupt climate change during the late Holocene such as the Medieval Warm Period and Little Ice Age. The 8.5 m sediment core from Nanerersarpik contains a dense gray clay in the lower 0.5m. The upper 8.0m of sediment is light brown and organic-rich with centimeter to half-centimeter laminations, interrupted by mass-movement events. Paleoenvironmental conditions have been interpreted using magnetic susceptibility, grain size, biogenic silica, TOC, C/N, organic lipid biomarkers, and δ13Corg, as well as with high-resolution spectral reflectance and scanning XRF profiles. These parameters allow us to interpret changes in autochthonous productivity and clastic input throughout the Holocene. A chronology for the record has been established using 7 radiocarbon dates. The age-model indicates Nanerersarpik Lake contains an ~8,500-yr sediment record with a linear age/depth relationship and a sedimentation rate of 0.1cm/yr, allowing for potentially decadal scale resolution of environmental changes. An abrupt transition from dense glacial clay to laminated organic rich sediment occurs near the base of the core. This is interpreted as marking the retreat of glacial ice from the catchment around 8,250 cal yr BP. High frequency variations dominate the spectral, scanning XRF, and magnetic susceptibility data and indicate some correlation with Holocene climate intervals. Biogenic silica and TOC analysis indicate broad scale changes in primary productivity generally consistent with known Holocene climatic intervals: the deglacial period, the Holocene Thermal Maximum, and the Neoglacial, with high variability during the late Holocene. High resolution biogenic silica data over the past 1500 cal yr BP show some correspondence to Greenland Ice Core paleotemperature reconstructions, suggesting biogenic silica may be responding to temperature on short timescales and should be used as a paleo-environmental proxy in future studies. Alkenones and glycerol dialkyl glycerol tetraethers were present in Nanerersarpik sediments, suggesting this location or others in SE Greenland might be suitable for future high-resolution paleotemperature studies using biomarkers.

During the latter half of the 20th century until present day there has been an unprecedented rise in global annual mean temperatures accompanied by rising sea levels and a decrease in Northern Hemisphere snow cover, which if it continues will lead to widespread disruption of climate patterns, ecosystems, and present-day landscapes. It is therefore of critical importance to establish an expanded network of paleoclimate records across the globe in order to better assesses how the global climate system has changed in the past, that we may create a metric by which to address modern change. Herein is presented a7,700 years record of Holocene climatic and environmental variability in Sermilik Valley, located on Ammassalik Island, SE Greenland. This objective of this study is to determine the timing of major Holocene climate transitions as expressed in the physical, elemental, and geochemical parameters preserved in the 484 cm sediment record of Lower Sermilik Lake. Major transitions observed in this study include the deglaciation of Sermilik Valley, the onset and termination of the Holocene Climatic Optimum, the transition into neoglacial conditions, and the Little Ice Age.

Southwestern Alaska is a critically understudied region of Beringia, highlighted by the lack of paleoenvironmental reconstructions of the Yukon-Kuskokwim Delta (YK Delta). This sub-arctic region is a joint deltaic coastal lowland environment, home to 50 Yup’ik and Cup’ik communities. Anthropogenic climate change dramatically impacts the landscape. Increases in the intensity and occurrence of coastal flooding, the thaw of permafrost and tundra wildfire events have directly affected community resilience and their subsistence way of life. The YK Delta also contributes to the global atmospheric carbon budget as the region’s discontinuous permafrost thaws releasing stored carbon. These issues necessitate the filling of the regional paleoenvironmental knowledge to properly inform native populations and predict future changes to the landscape. Working with two communities on the outer YK Delta, namely, Kongiganak and Mekoryuk, this thesis presents initial paleoenvironmental studies which contribute to our understanding of the impacts of climate change on this region. The first effort documents the development of a loess plateau on the YK Delta during the Last Glacial Period (115,000 – 11,700 years ago), specifically during Marine Isotope Stage III (60,000 – 25,000 years ago), described in Chapter 2. This topic was developed from exposures at Kongiganak and Mekoryuk, and helps to refine the relative sea level history and aeolian processes of the YK Delta. Other efforts on Nunivak Island consist of preliminary results from the first late Holocene lacustrine reconstruction and the first attempt to provide context to coastal dune geomorphology, highlighted in Chapter 3. These efforts help to establish regional paleoenvironmental conditions in the late Holocene, methodology for future sampling, and provide important estimates of long-term coastal erosion.

<p>Urban expansion and agricultural growth are placing significant stresses on existing groundwater reserves hosted within Quaternary sediments in southern Ontario. Preserving the quality and quantity of groundwater resources requires a detailed knowledge of the three-dimensional distribution of subsurface geologic units. In this study, integrated analysis of surficial sediment exposures, geophysical and remotely-sensed data, and fully-cored boreholes in the Alliston region of southern Ontario has allowed for the identification of landform-sediment associations, or landsystems, which can be used to predict the nature of subsurface sediment types and to assist with the reconstruction of paleoenvironmental change in the region. The landsystems identified in the Alliston region can also be used as a foundation for the development of a stratigraphic framework for hydrogeological investigations.</p> <p>Nine landsystems were identified in the study area and include: i) bedrock escarpment, ii) gravel bench, iii) V-shaped valleys and fills, iv) streamlined uplands, v) low-relief uplands, vi) upland plains and scarps, vii) erosional amphitheatres, viii) hummocky terrain, and ix) lowland plains. These landsystems record the changing distribution of glacial, ice-marginal, glaciofluvial, glaciolacustrine, and post-glacial depositional systems that affected the region during the late Quaternary. The landsystems analysis approach provides a useful framework for discerning the spatiotemporal relationship of a complex suite of depositional systems. Analysis of the distribution and internal composition of landsystems in the study area has allowed the development of a preliminary risk assessment map for aquifer vulnerability in the region.</p> <p>Detailed analysis of 56 outcrop exposures in cutbanks along the Nottawasaga River within the former Lake Algonquin plain has led to the identification of six lithofacies associations (FA 1–6) that present a detailed record of environmental change during the deglacial period. The stratigraphy is floored by the Late Wisconsin Newmarket Till (FA 1) which is locally overlain by ice-proximal debris flows (FA 2). These glacial sediments are overlain by glaciolacustrine silt rhythmites (FA 3) that pass upwards into deltaic sand (FA 4) and channelized fluviodeltaic sand and gravel (FA 5). Lying above the fluvial deposits and capping the succession are widespread sand and silt rhythmites (FA 6), which coarsen up-section. These six facies associations provide a record of changing environmental conditions that existed during deglaciation of the region and give valuable insights into the nature of the evolution of glacial lakes Schomberg, Algonquin, and Nipissing. The deglacial environmental changes described from southern Simcoe County may be valuable analogues for the interpretation of regional-scale events that occurred in extensive lake basins in other formerly glaciated regions.</p> <p>Qualitative observations of groundwater discharge from sediment facies at outcrop faces along the Nottawasaga River have yielded important data on the internal heterogeneity of subsurface units. These data can be used to identify possible preferential groundwater flow pathways through both aquifer and aquitard units in the region. Understanding the geometry and interconnectedness of these subsurface sediments is essential for planning future water supply for growing urban communities and agricultural irrigation needs in the region and for the prediction of contaminant migration pathways.</p> / Master of Science (MSc)

Αντικείμενο της παρούσας μελέτης αποτελεί ο μεγαλύτερος ποταμός της Πελοποννήσου, ο Αλφειός και ο παραπόταμός του Ερύμανθος. Ο Αλφειός πηγάζει από τους ασβεστολιθικούς όγκους της ορεινής Αρκαδίας που ανήκουν στη γεωτεκτονική ζώνη Γαβρόβου – Τριπόλεως ενώ ο Ερύμανθος πηγάζει από την ορεινή Αχαΐα (και το ομώνυμο όρος Ερύμανθος) που ανήκει γεωτεκτονικά στη ζώνη Ωλονού - Πίνδου. Το υδρογραφικό δίκτυο του Αλφειού καλύπτει μια ευρεία περιοχή που εκτείνεται από την ορεινή Αχαΐα, Αρκαδία και Μεσσηνία και διαρρέοντας ένα μεγάλο μέρος της κεντρικής Πελοποννήσου συνεχίζει στο Νομό Ηλείας εκβάλλοντας στο Ιόνιο Πέλαγος. Στο πρώτο κεφάλαιο πραγματοποιείται μια περιγραφή της περιοχής μελέτης με κάποια γενικά στοιχεία και δίνεται μια εικόνα χρήσεων γης της περιοχής. Στο δεύτερο κεφάλαιο παρουσιάζονται τα γεωμορφολογικά στοιχεία, γίνεται ανάλυση του υδρογραφικού δικτύου και του ανάγλυφου. Στο τρίτο κεφάλαιο αναλύεται η γενική γεωλογική δομή της περιοχής μελέτης. Πραγματοποιείται ανάλυση της στρωματογραφίας αλλά και της τεκτονικής Στο τέταρτο κεφάλαιο περιλαμβάνονται οι αναλύσεις και τα συμπεράσματα από την περιοχή μελέτης. Σημειώνεται ότι η περιοχή μελέτης χωρίστηκε σε δύο τμήματα που αποτελούν χωριστές διπλωματικές εργασίες. Η παρούσα αναφέρεται στο κομμάτι του Ερύμανθου ποταμού πριν την ένωση με τον κηρίο πόταμο τον Αλφειό. Η αναφορά που φαίνεται στους πίνακες και για τα στοιχεία των αναλύσεων για τον Αλφειό γίνεται για να μπορέσει να γίνει σύγκριση μεταξύ των δυο διπλωματικών. Στο πέμπτο κεφάλαιο ιζηματολογική λιθογραφική μελέτη Στο τελευταίο κεφάλαιο έχουμε Συζήτηση Συμπεράσματα Τέλος, θα πρέπει να αναφέρω ότι οι εργασίες πεδίου έγιναν συγχρόνως και στα δύο τμήματα του Αλφειού όμως η παρουσίαση γίνεται χωριστά για να αναδειχτούν οι διαφορές μεταξύ των δύο τμημάτων. / Purpose of this study is the largest river in the Peloponnese, Alpheus and tributary Erymanthos.

The Mississippian Barnett Formation is a prolific shale-gas reservoir that was deposited in the Fort Worth Basin, Texas. Many previous studies of the Barnett Formation have been conducted in the main production area; few studies have been made of the Barnett Formation in the southern part of the basin, which is a less productive area. In the present research, several cores from the Barnett Formation in Hamilton County, southeast Fort Worth Basin, are studied in detail. Two vertical, continuous cores from Hamilton County, Texas, were studied to delineate the depositional setting, lithofacies, pore types, and reservoir quality of the Barnett Formation in the area. Five lithofacies were defined by analysis of the two cores: (1) laminated clay-rich silty and skeletal peloidal siliceous mudstone; 2) laminated skeletal silty peloidal siliceous mudstone; 3) nonlaminated silty peloidal calcareous mudstone; 4) laminated and nonlaminated skeletal calcareous mudstone; and 5) skeletal phosphatic packstone to grainstone. As indicated from this study, the dominant organic matter type is a mixture of Type II (major) and Type III (minor) kerogen having a mean TOC content of approximately 4%. Analysis of Rock Eval data shows that most of the interval is within the oil window; calculated Ro is approximately 0.9%. Organic geochemistry shows that the hydrocarbon generation potential of the abundant oil-prone kerogen was excellent. Mineralogical analysis reveals that the two types of siliceous mudstone, which are similar in composition to the siliceous mudstone in the main producing area in the northern Fort Worth Basin, are good for hydraulic fracturing and production, but they are also limited by their marginal thickness. Organic matter pores, which are the dominant pore types in these two cores, are consistent with pore types found in currently producing wells in the Newark East Field. This research also suggests that the deposition of Barnett Formation was controlled largely by basinal geometry, suspension settling, and slope-originated gravity-flow events. Skeletal deposits and carbonate-silt starved ripples suggest gravity-flow deposits and bottom-current reworking during deposition. Redox-sensitive elements and degree of pyritization both indicate anoxic/euxinic conditions during the deposition of the Barnett Formation. / text

This thesis presents the findings of a combined geomorphological, sedimentological and geochronological investigation into the glacial history of the Clearwater Basin, Mid Canterbury, New Zealand. The study demonstrates that a thick wedge of glacial and paraglacial sediments are preserved in the valley. These are >100m thick and preserve evidence of at least 3 glacial phases (>180ka). The study presents a new and detailed geomorphology map for the Clearwater valley and adjacent areas and has added 17 new recessional positions to the local glacial record. Surface Exposure Dating (SED) has been used to directly date the moraines of the Clearwater Basin providing the first detailed chronology for glacial moraine in this area. In total 31 cosmogenic ages from 9 separate moraines are presented. The results demonstrate that the LGM advance is the Trinity moraine of Mabin (1980) and not the Hakatere moraine as previously assumed and that the LGM was achieved at or about 23ka. The Clearwater glacier receded up valley between 23 and 13ka with some indication of accelerated retreat after c.16ka. The correlation to the adjacent Lake Heron Valley is also revised.