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Die für technische Anwendungen attraktivsten Eigenschaften der Hochtemperatur-Supraleiter beruhen auf der Wechselwirkung der Materialien mit einem externen Magnetfeld. Für hochleistungsfähige Supraleiteranwendungen werden großvolumige Funktionselemente mit eindomänigem Magnetisierungsverhalten benötigt. Zur Vergrößerung der magnetischen Domäne schmelztexturierter YBa2Cu3O7-δ-Kompaktsupraleiter wurde anhand der Multi-Seeding-Technik, die Rekristallisation unter Verwendung mehrerer SmBa2Cu3O7-δ-Keimpräparate untersucht. Als Schlüsseltechnologie zur Herstellung anwendungsorientierter Supraleitererzeugnisse wurde zu Beginn der Arbeit die Keimkristallherstellung optimiert. Gemäß den Zielvorgaben stehen zukünftig quasi-einkristalline Keimkörper definierter Form und Orientierung in hoher Stückzahl zur Verfügung. Die Supraleiter betreffend ist es gelungen, für den wechselseitigen Abstand und die Ausrichtung der Keimpräparate ein Optimum zu finden sowie tolerierbare Winkel der Verschwenkung angrenzender Kristalle zu ermitteln. Es wurde festgestellt, dass das Auftreten isolierender Korngrenzeneinschlüsse mit den magnetischen Materialeigenschaften korreliert und vom Keimabstand und der Korngrenzenorientierung abhängig ist. Mit Einsatz von bis zu 16 Keimkristallen gelang es, eindomänige Supraleiterhalbzeuge mit Höchstmaßen von (79 x 39 x 20) mm3 und Remanenzflussdichten von bis zu 1,3 T zu erzeugen. Im Chargenprozess konnten abschließend Multi-Seeding-Funktionselemente mit anwendungskonformen geometrischen und magnetischen Materialeigenschaften zum Aufbau eines hochdynamischen Supraleitermotors reproduzierbar gefertigt werden. In Leistungstests wurde für die Dynamik des Motors mit 200.000 rpm/s ein Rekordwert erzielt – nun können die Motoren in der Anwendung erprobt werden.

No description available.

Die für technische Anwendungen attraktivsten Eigenschaften der Hochtemperatur-Supraleiter beruhen auf der Wechselwirkung der Materialien mit einem externen Magnetfeld. Für hochleistungsfähige Supraleiteranwendungen werden großvolumige Funktionselemente mit eindomänigem Magnetisierungsverhalten benötigt. Zur Vergrößerung der magnetischen Domäne schmelztexturierter YBa2Cu3O7-δ-Kompaktsupraleiter wurde anhand der Multi-Seeding-Technik, die Rekristallisation unter Verwendung mehrerer SmBa2Cu3O7-δ-Keimpräparate untersucht. Als Schlüsseltechnologie zur Herstellung anwendungsorientierter Supraleitererzeugnisse wurde zu Beginn der Arbeit die Keimkristallherstellung optimiert. Gemäß den Zielvorgaben stehen zukünftig quasi-einkristalline Keimkörper definierter Form und Orientierung in hoher Stückzahl zur Verfügung. Die Supraleiter betreffend ist es gelungen, für den wechselseitigen Abstand und die Ausrichtung der Keimpräparate ein Optimum zu finden sowie tolerierbare Winkel der Verschwenkung angrenzender Kristalle zu ermitteln. Es wurde festgestellt, dass das Auftreten isolierender Korngrenzeneinschlüsse mit den magnetischen Materialeigenschaften korreliert und vom Keimabstand und der Korngrenzenorientierung abhängig ist. Mit Einsatz von bis zu 16 Keimkristallen gelang es, eindomänige Supraleiterhalbzeuge mit Höchstmaßen von (79 x 39 x 20) mm3 und Remanenzflussdichten von bis zu 1,3 T zu erzeugen. Im Chargenprozess konnten abschließend Multi-Seeding-Funktionselemente mit anwendungskonformen geometrischen und magnetischen Materialeigenschaften zum Aufbau eines hochdynamischen Supraleitermotors reproduzierbar gefertigt werden. In Leistungstests wurde für die Dynamik des Motors mit 200.000 rpm/s ein Rekordwert erzielt – nun können die Motoren in der Anwendung erprobt werden.

Chionochloa, a genus of snow tussock grasses native to New Zealand, exhibits pronounced mast seeding. Chionochloa suffers very high levels of pre-dispersal flower and seed predation by three main insects: Eucalyptodiplosis chionochloae, a cecidomyiid midge, which is formally described here; Megacraspedus calamogonus, a gelechiid moth and Diplotoxa similis, a chloropid fly. Seven species of parasitoids that attack these seed predators were discovered. Four species parasitize M. calamogonus (one tachinid fly and three hymenopteran wasps), one parasitizes D. similis (Hymenoptera: Eulophidae) and two parasitize E. chionochloae, (a pteromalid wasp Gastrancistrus sp. and a platygastrid wasp Zelostemma chionochloae, which is given a formal description here). The abundance, predation levels by each of the insect species, and interactions between all the organisms in the community were studied across three elevations at Mount Hutt over three summer seasons. M. calamogonus was most abundant at 450 m altitude during all three seasons. D. similis was most common at 1070 m altitude, while its predation levels peaked in low flowering seasons and decreased in high seasons. E. chionochloae was abundant in all three altitudes and increased its predation levels with increasing flowering intensity. E. chionochloae was confirmed to use prolonged diapause of at least three years. Prolonged diapause was also confirmed in its two parasitoids. Chionochloa plants were manipulated with various treatments to test the effect on diapause in E. chionochloae and its two parasitoids. Treatments included plant warming, root pruning, gibberellic acid sprayed on the plants and combinations of these treatments. All three insects changed their emergence in response to some treatments and therefore it was suggested that combined with risk-spreading diapause, they may use some predicting to emerge from prolonged diapause. E. chionochloae control their diapause following some of the cues that Chionochloa use for flowering, while Z. chionochloae and Gastrancistrus in some cases follow their host’s cues and in others use similar cues as Chionochloa plants. Emergence or diapause predictions differed across elevations and plant species in all three insect seed/flower predators. E. chionochloae had female-biased sex ratios in different populations even after prolonged diapause. There was week evidence that both parasitoid species are female-biased in the first emergence year and male-biased after more than one year in diapause. Therefore it was suggested that diapause is not more costly for females of E. chionochloae and its parasitoid than for males. Females of all three species were not found to be better predictors (i.e, more likely to respond to treatments by not entering extended diapause) than males. The complex interactions of all the organisms in this web are thought to be sensitive to climate, and it was suggested that the global climate change may alter this sensitive system.

Articular cartilage has a low propensity for self-repair, due to which 27 million people are affected by osteoarthritis every year in North America. The current repair techniques used for cartilage defects possess flaws that reduce long-term clinical success. Tissue engineering carries with it the promise of engineering hyaline-like cartilage with physical and biochemical properties, similar to that of native cartilage. This being said, the primary objective of my project was to engineer clinically relevant sized articular cartilage constructs. To achieve my objective, first, I investigated the effect of continuous culture on cartilaginous tissue growth. Constructs grown under continuous media flow significantly accumulated more collagen and glycosaminoglycan, and displayed a stratified morphology, similar to that found in native cartilage. The second goal was to further increase chondrocyte proliferation, and extracellular matrix (ECM) accumulation. To achieve this, constructs were grown in a bioreactor with media supplemented with 14 mM sodium bicarbonate (NaHCO3). Constructs cultivated in the bioreactor with NaHCO3 supplementation exhibited a significant (p<0.05) increase in ECM accumulation (a 98-fold increase in glycosaminoglycans and a 25-fold increase in collagen content), cell proliferation (a 13-fold increase), and thickness (a 28-fold increase) compared to all other conditions (static and reactor without NaHCO3 supplementation). The third goal was to engineer cartilage constructs with as little cells as possible, reducing donor site morbidity. From the results obtained, it was evident that the monolayer constructs outperformed all the other constructs (pellet, biopsy, and minced). The final goal was to understand the underlying reason for the increased proliferation. First, I investigated if there were any differences present in intracellular pH (pHi) and intracellular buffering capacity. Second, I determined the role of extracellular pH (pHe) on cell proliferation. In an effort to accurately achieve this, I, for the first time, have reported on measuring pHi of chondrocytes while still in culture (2D and 3D cultures) using a confocal microscope. This study demonstrated the importance of extracellular environments, such as pHe, extracellular buffering capacity, and the presence of carbon dioxide and bicarbonate ions for chondrocyte proliferation. / Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2012-10-30 19:19:32.026

O cultivo de plantas de cobertura como cultura de inverno para produzir palha e proteger o solo após a colheita da cultura de verão, na região do Cerrado brasileiro, tem sido um dos maiores desafios para os produtores que optaram pela adoção do sistema semeadura direta. Outra dificuldade inerente ao sistema semeadura direta, com peculiaridade para o Cerrado, refere-se ao manejo do nitrogênio (N) na cultura do milho, já que o ciclo deste nutriente é extremamente dependente das condições climáticas, apresentando, por isto, comportamento diferente da região Sul do país. Nesta situação, a aplicação de N na semeadura da cultura de cobertura de solo com o objetivo de aumentar a produção de palha ou em pré-semeadura da cultura principal, buscando otimizar tempo, pode ser uma estratégia que apresente a mesma eficiência da fertilização na cobertura no milho em sucessão à soja. Os objetivos do estudo foram avaliar a produção de massa de matéria seca de culturas de cobertura de solo e de espécies espontâneas; determinar a influência das épocas da fertilização nitrogenada nos caracteres fenológicos, na produtividade de grãos e de massa de matéria seca da cultura do milho cultivado após 2 anos de soja e, também, quantificar a eficiência da adubação nitrogenada, utilizando a técnica da diluição isotópica (15N). Foram desenvolvidos dois experimentos na região do Triângulo Mineiro, no Estado de Minas Gerais, avaliando-se doses, fontes e épocas de aplicação de N. As doses de N foram: 110 kg ha-1 no experimento em solo de textura média e 70 kg ha-1 no experimento em solo de textura muito argilosa, como dose suplementar à adubação de semeadura. As culturas de cobertura de solo, cultivadas após a colheita da cultura de verão, não foram eficientes na produção de palha; a adubação nitrogenada aplicada na semeadura da cultura de cobertura de solo também não resultou em produção de palha. No experimento em solo de textura média houve resposta à aplicação de N em relação à testemunha e beneficio do parcelamento em diferentes épocas, em relação à aplicação de maiores doses em uma única aplicação. Neste experimento, não houve diferença na produtividade de grãos na fertilização de cobertura do milho, usando uréia ou sulfato de amônio. Em solo de textura muito argilosa não houve resposta na produtividade de grãos do milho quando se aplicou N suplementar à adubação de semeadura, independente da época de aplicação. A eficiência da adubação nitrogenada variou de 26 a 70% para as diferentes épocas de aplicação, sendo que a média de aproveitamento foi de 50%. A aplicação antecipada não se mostrou eficiente em relação à recuperação do fertilizante, sendo recomendada adubação em cobertura, principalmente em solos mais arenosos / Cultivation of soil cover crops as second crop willing to produce straw and protect the soil after the harvest of the summer crop at the Brazilian Cerrados region had been one of the biggest challenges faced by farmers that decided for the no tillage system. Another problem inherent to the no tillage system in the Cerrados in relation with the nitrogen management (N) for corn crops is due to the cycle of this nutrient is extremely dependent on climatic conditions and for this reason, a totally different activity in comparison with Southern region of Brazil must be considered. In this situation, N supply whether in the seeding time of the soil cover crops in order to increase the straw production or before the of main cultivation (pre-seeding) looking to optimize time, it might be a strategy that demonstrates the same efficiency offered by the topdressing of the corn in soybean succession. The objectives of the study were to evaluate dry matter production in the soil cover crops and spontaneous species; to determine the influence of different timing of N-fertilizer supply in the phenology characters, yield and dry matter of corn after 2 years of soybean cultivation and, also, to quantify the efficiency of the nitrogen supply using the isotopic dilution technique (15N). Two experiments were carried out at the Triângulo Mineiro region, Minas Gerais State, Brazil, where rates, sources and timing of N applications were evaluated. The rates of N were: 110 kg ha-1 for the sandy clay loam soil experiment and 70 kg ha-1 for the very clayed soil experiment, besides the nitrogen supplied at the corn crop seeding. The cultivation of the soil cover crops after the harvest of the summer crop was not efficient for cover straw production; the nitrogen supplied at the seeding time of the cover crops also did not result in cover straw production. On the sandy clay loam experiment there was response to nitrogen regarding to the control treatment and also pointed benefit using split time application in relation with higher dose n a unique application. Also there was no difference in the corn yield whether by using urea fertilization or ammonium sulfate topdressing. For the very clayed soil experiment, there was no response on corn yield when nitrogen was supplied at the seeding independent of application timing. The efficiency of the nitrogen fertilization ranged from 26 to 70% among the different application timing and the average efficiency was 50%. The anticipated application did not demonstrate efficient with regard to the fertilizer recovery, being recommended topdressing applications, especially in sandy soils

Nas topologias de redes WDM-PON (Wavelength Division Multiplexed Passive Optical Network) baseadas em transmissores colorless, isto é, transmissores que possam operar em uma grande gama de comprimentos de onda, que empreguem técnica de auto-alimentação e reuso de comprimento de onda, tem despertado grande interesse devido a sua comprovada eficiência, granularidade e custo reduzido em relação às alternativas. Entretanto, o alcance destas redes é limitado pelo emprego de remodulação, devido a dependência existente com a qualidade dos sinais a serem remodulados. Neste cenário, mantendo-se uma melhor relação custo-benefício, taxas de operação típicas são da ordem de 1,25, e 2,5 Gb/s (20 quilômetros). Neste trabalho é investigada uma nova topologia que combina as técnicas de auto-alimentação e reuso de comprimento de onda, bem como, utiliza um circuito de dupla cavidade óptica, possibilitando um reforço no apagamento óptico e manutenção do estado da polarização no percurso de recirculação da cavidade externa, objetivando uma melhora na qualidade dos sinais a serem remodulados, possibilitando altas taxas de transmissão e um maior alcance da rede. Nesta topologia, amplificadores ópticos semicondutores refletivos são utilizados como transmissores colorless, por meio da emissão espontânea amplificada, garantido assim uma redução no custo da rede óptica de acesso. Como metodologia adotada, inicialmente foram realizadas caracterizações ópticas no ambiente de simulação, validação da palheta configurada no simulador com resultados experimentais e avaliações da topologia em taxas simétricas de 1,25 Gb/s. Ademais, são conduzidas análises comparativas entre a topologia proposta frente a topologias disponíveis na literatura no estado da arte. Com os resultados obtidos, acredita-se que essa proposta atende aos requisitos de capacidade agregada e custo reduzido, podendo alcançar taxas de transmissão de até 10 Gb/s utilizando transmissores de baixa complexidade, características essenciais para impulsionar a implementação de redes de acesso óptico. / WDM-PON topologies based on colorless transmitters employing self-seeding and wavelength-reuse techniques have attracted a great deal of interest because of its well known efficiency, granularity and reduced cost, when compared to other alternatives in the literature. Nevertheless, the network reach is limited by the use of remodulation scheme. Maintaining an adequate cost-benefit relation requires typical operating rates of the order of 1.25 Gb/s to 2.5 Gb/s over 20 km of SSMF. In the above framework, we investigate a new topology which combines self-seeding and wavelength-reuse techniques, but also employs a scheme to reinforce the data erasure in the optical carrier, simultaneously providing state of polarization (SOP) maintenance in the external cavity recirculation path. The proposed configuration improves the quality of the signals to be remodulated, thus allowing high rate and broader reach. Specifically, in our work, reflective semiconductor optical amplifiers are employed as colorless transmitters, by using their own amplified spontaneous emission as a seed to provide the optical carrier. Optical analysis were performed in a simulation environment, including self-seeding layout validation by comparison to experimental results at the symmetric transmission rate of 1.25 Gb/s. Next, comparative analysis are conducted between the topology proposed in this work and topologies in the state of the art, found in the literature. According to the results, we believed that the proposal meets the requirements of aggregate capacity and reduced cost, being able to reach transmission rates of up to 10 Gb/s by using transmitters of low complexity, essential features to drive optical access networks implementation.

Thesis (M.Sc. (Environmental Science and Management)--North-West University, Potchefstroom Campus, 2008.