Thesis (Ph.D.)--University of Adelaide, Dept. of Chemical Engineering, 2000? / Bibliography: leaves 182-198.

The low-rate trickling filter is the most common biological treatment process used in small and medium sized sewage works in the UK. It produces an inconsistent effluent quality, which has traditionally been related to seasonal changes in solids accumulation, grazing activity and sloughing of microbial film. The final effluent solids and, organic matter content is then too high for discharge or reuse. Given the increasingly stringent effluent standards, both in terms of quality and consistency, tertiary treatment is often required. This study was designed to investigate the key parameters affecting the performance of low-rate trickling filters and the characteristics of their effluents in terms of contaminant size, which might influence the efficiency of crossflow filtration as a tertiary treatment for the trickling filter.

Clean and spiked sediment formulations of various silt sand and clay sand ratios were tested for toxicity using a bioassay that utilizes bioluminescent bacteria Measured toxicities of clean and copper sulfate–spiked sediments were negatively but nonlinearly related with percent silt and percent clay, but no significant relationship existed between measured toxicity and sediment composition for methyl parathion–spiked formulations Results suggest that solid phase sediment bioassays using bioluminescent bacteria may be useful for testing the toxicities of single contaminants in formulated artificial sediments of known particle size composition, and for repeated samples collected from the same site However, extreme caution must be taken when testing sediments of varying composition or which may be differentially contaminated or contain a suite of contaminants.

The study investigates the surface controls of major dust emissions and determines the patial distribution of major dust source in South Africa. This study follows a multi-disciplinary approach where primary and secondary data were used. The main objective of the study is to determine the spatial distribution of South Africa's Major Dust Sources. Meteosat Second Generation (MSG) satellite imagery, land use and land cover maps were used to achieve the first and the second objectives of the study. Primary data involved sampling 30 soil samples in the field in order to achieve the third objective of the study. The crust, soil moisture, soil texture and grain size are all controls of dust emission. This investigation is however focused predominantly on grain size characteristics. GIS methods were also used to determine soil type from the African soil map. Soil samples in both provinces were then collected to assess the Particle Size Distribution (PSD) of the soils. The particle size was determined based on a sieve analysis for grain sizes that were greater than 2mm and laser diffractometry, MasterSizer (Malvern) was used to achieve this. The results from the Malvern were later put to R Statistics where they were clustered into eight clusters to determine similarities and difference of the grain size. Because there is no uniqueness in the soil types found in the study area, there were no solid conclusions made based in them. The results show that the soil types are found across South Africa but not the same amount of dust activity was detected in the other parts of the country. Previous studies show that global significant dust sources are natural sources such as lakes, pans and depressions. However, results demonstrate that South African dust sources are anthropogenic sources resulting from commercial agriculture in semi-arid regions. This study has demonstrated that surface sediments suitable for dust production are a mixture of fine material, silt (50µm) and coarse material, sand (2000µm) and it appears that all clusters in this study all contained both mixtures and all have potential to emit dust.

<p> The purpose of this research paper is to empirically examine the evolution of the Canadian urban system throughout the past century. This task is completed with the use of the rank-size rule and the parameters that emanate from its logarithmic distribution. This process entails the creation of a historical data set from the inception of the urban areas of each one of the twenty-four CMAs that are used in this study. The collection of the evolving slope and yintercept parameters during the study's fourteen rank-size distribution periods, shows how policy decisions are manifested in the empirical changes of the rank-size rule's slope. Confederation and expansion of the railroad into the prairie frontier are distictly evident in the evolving parameters. It was also found that Canada's geographical distribution of CMAs apparently limits the rank-size rule constant to a value of -1.1 . This distribution is steeper than the optimal market efficiency slope of -1.0 as presented in Zipf's explanation of the forces of attraction and dispersion of economic activity. The statistical results of this paper can be used to· compare different national systems or take a more regional approach in comparing Canadian CMA sub-systems. </p> / Thesis / Bachelor of Arts (BA)

As part of a risk assessment study of the Leading Creek Watershed in Ohio, a prior Virginia Tech researcher collected pavement and subpavement sediment samples at 17 sites using the hybrid areal sampling technique with a clay adhesive. The watershed, which is heavily impacted by mining and agricultural activities, suffers from low pH, high concentrations of metals and sediment in the water column, and excessively silted streambeds. The current work presents the results of the particle size analyses performed on the hybrid samples in the context of evaluating the effectiveness of the technique itself and as a tool in future watershed/ecological studies, as well as examining possible relationships between siltation and indicators of ecological health in Leading Creek. By combining clay grid and adhesive sampling methods, the hybrid technique consistently achieved an effective particle size sampling range of 0.05 mm (1.97 x 10-3 in) to over 300 mm (11.8 in), thereby reducing the common problem of trunction. However, the overlap of the clay adhesive and natural sediment distributions and atypical sediment loading from surrounding abandoned and reclaimed mine lands obscured expected trends such as downstream fining and hindered the analysis of materials finer than 0.125 mm (4.93 x 10-3 in). Volumetric conversion of areal samples using the Modified Cube Model with a traditional exponent of -1 for clay was complicated by the large amount of fines in the Leading Creek samples. Further investigation into a more appropriate conversion technique for the evaluation of fine sediment samples is warranted. / Master of Science

No description available.

Thesis advisor: Douglas A. Edmonds / Delta morphology is traditionally explained by differences in fluvial energy and wave and tidal energy. However, deltas influenced by similar ratios of river to marine energy can display strikingly different morphologies. Other variables, such as grain size of the sediment load delivered to the delta, influence delta morphology, but these models are largely qualitative leaving many questions unanswered. To better understand how grain size modifies deltaic processes and morphologies I conducted 33 numerical modeling experiments and quantified the effects produced by different grain sizes. In these 33 runs I change the median (0.01 - 1 mm), standard deviation (0.1 - 3 φ), and skewness (-0.7 - 0.7) of the incoming grain-size distribution. The model setup includes a river carrying constant discharge entering a standing body of water devoid of tides, waves, and sea-level change. The results show that delta morphology undergoes a transition as median grain size and standard deviation increase while changing skewness has little effect. At small median grain size and standard deviation, deltas have elongate planform morphologies with sinuous shorelines characterized by shallow topset gradients ranging from 1 x 10<super>-4</super> to 3 x 10<super>-4</super>, and by 1 - 8 stable active channels. At large median grain size and standard deviation, deltas transition to semi-circular planform morphologies with smooth shorelines characterized by steeper topset gradients ranging from 1 x 10<super>-3</super> to 2 x 10<super>-3</super>, and by 14 - 16 mobile channels. The change in delta morphology can be morphodynamically linked to changes in grain size. As grain size increases delta morphology transitions from elongate to semi-circular because the average topset gradient increases. For a given set of flow conditions, larger grain sizes require a steeper topset gradient to mobilize and transport. The average topset gradient reaches a dynamic equilibrium through time. This requires that, per unit length of seaward progradation, deltas with steeper gradients have higher vertical sedimentation rates. Higher sedimentation rates, in turn, perch the channel above the surrounding floodplain (so-called `super-elevation'), resulting in unstable channels that frequently avulse and create periods of overbank flow. The overbank flow is more erosive because the steeper gradient causes higher shear stresses on the floodplain, which creates more channels. More channels reduce the average water and sediment discharge at a given channel mouth, which creates time scales for mouth bar formation in coarse-grained deltas that are longer than the avulsion time scale. This effectively suppresses the process of bifurcation around river mouth bars in coarse-grained deltas, which in turn creates semi-circular morphologies with smooth shorelines as channels avulse across the topset. On the other hand, the finest-grained (i.e. mud) deltas have low topset gradients and fewer channels. The high water and sediment discharge per channel, coupled with the slow settling velocity of mud, advects the sediment far from channel mouths, which in turn creates mouth bar growth and avulsion time scales that are longer than the delta life. This creates an elongate delta as stable channels prograde basinward. Deltas with intermediate grain sizes have nearly equal avulsion and bifurcation time scales, creating roughly semi-circular shapes but with significant shoreline roughness where mouth bars form. / Thesis (MS) — Boston College, 2013. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

O desempenho final das argamassas depende das matérias-primas e de suas proporções na formulação, pois estas determinam o comportamento do material na etapa de aplicação e a microestrutura final do material endurecido. Entre as patologias de revestimentos, a falha de aderência é um dos fenômenos mais freqüentes, sendo originada pela incompatibilidade entre o comportamento reológico da argamassa e a energia de lançamento utilizada, resultando em defeitos na interface argamassa substrato. A adequação das características reológicas das argamassas às solicitações envolvidas na aplicação fornece condições de processamento mais favoráveis para a obtenção das máximas propriedades finais do revestimento. Assim, o objetivo do trabalho é desenvolver critérios de formulação, baseados nas características das matérias-primas, nos modelos de empacotamento de partículas e nos comportamentos reológicos, de modo a obter um método de formulação de argamassas. O método de squeeze-flow foi desenvolvido com sucesso para avaliação reológica de argamassas, sendo as principais variáveis experimentais foram estudadas, assim como o efeito do tipo de mistura no comportamento reológico. Procedimento para quantificação da segregação pasta-agregado foi criado, tendo em vista o intenso efeito que este fenômeno exerce sobre o comportamento reológico em squeeze-flow, especialmente em baixas velocidades. Foi ainda comprovado que o squeeze-flow tem boa relação com a percepção do pedreiro, principalmente, nas etapas de lançamento e aperto. Diversas argamassas nacionais e européias foram caracterizadas, resultando em um mapeamento das características de formulação, do comportamento reológico e das propriedades no estado endurecido. Através da aplicação de conceitos de empacotamento e distância de separação de partículas, foi verificado que a otimização do empacotamento de agregados permite um melhor aproveitamento da pasta para promover argamassas com comportamento reológico mais adequado à aplicação ou com menor consumo de finos e água. As correlações estabelecidas entre as características no estado fluido e as propriedades no estado endurecido permitem prever o comportamento das propriedades no estado endurecido com boa confiabilidade. Por fim, são descritas diretrizes sistemáticas para a formulação de argamassas considerando requisitos de desempenho tanto no estado fresco quanto no endurecido. / The in-use performance of rendering mortars depends on the raw materials features and their content in the formulation, since they have major influence on the material behavior during emplacement, as well as, on its final properties. Adherence failure is one of the most frequent problems of this class of building materials, caused by the incompatibility between rheological behavior and the application process, generating mortar/substrate interface flaws. A rheological behavior more suitable to the application demands, provides appropriate conditions to obtain maximum final rendering properties. Therefore, the main goal of this work is to develop mix-design parameters based on raw materials features, particle packing models and rheological behavior, in order to create a mix-design method for mortars. Squeeze-flow technique was successfully adapted for the rheological evaluation of rendering mortars, and the most important experimental parameters were studied. The method is sensitive enough to measure rheological changes as a function of the mixing process applied. Considering that phase segregation plays an important role on the rheological behavior of concentrated suspensions especially at low speeds, a method was developed to measure paste-aggregate segregation. It was also established that the squeeze-flow agrees well with the workers perception during manual emplacement. Several Brazilian and European products were evaluated, and significant differences were determined on the formulation features, rheological behavior and hardened properties. Using models of particle packing and particle distance, it was verified that optimized packing of aggregates enhances rheological behavior and can also allow the reduction of water and fine particles consumption. The experimental relationships established between fresh characteristics, rheological behavior and final properties can be used to predict hardened features and properties with fair confidence. Lastly, mix-design suggestions are made considering both fresh and hardened performance.

Why some countries are so much richer than others is a question of central interest in economics. Low aggregate income per worker in poor countries is mostly accounted for by low labor productivity and high employment in agriculture. This thesis attempts to understand cross-country income difference through examining productivity differences at the sector level - in agriculture and in non-agriculture. Between rich and poor countries, there is a 45-fold difference in agricultural output per worker and a 34-fold difference in mean farm size. In the first chapter, I argue farmer's skill as a plausible explanation for these differences. The model features heterogeneity in innate agricultural skill, on-the-job skill accumulation, and span-of-control in agricultural production. I show that low total factor productivity (TFP) in poor countries not only induces more individuals with low innate skill to choose farming, but also reduces the incentive to accumulate skill. Between rich and poor countries, the model generates substantial difference in farmer's skill, which translates into differences in agricultural productivity and farm size distribution. Quantitatively, the calibrated model explains half of the cross-country differences in agricultural output per worker, and successfully replicates the size distribution of farms in both rich and poor countries. Cross-country productivity differences are asymmetric across sectors. The labor productivity gap between rich and poor countries in agriculture is twice as large as that in the aggregate, and ten times larger than that in non-agriculture. The second chapter shows that these sectoral productivity differences can arise solely from difference in aggregate TFP. I extend the framework in the first chapter to allow for different skill in non-agricultural production as well. Low TFP distorts the allocation of skills across sectors and discourages skill accumulation on the job. To discipline the initial skill distribution and skill accumulation, the model is calibrated to match earnings distribution and age-earnings profiles in both agriculture and non-agriculture in the U.S. The model's implications are then examined using a sample of 70 countries that covers a wide range of development. Between rich and poor countries, the model accounts for most of the productivity differences at the sector level - productivity difference in agriculture in the model is 1.8 times larger than those in the aggregate and 6 times larger than those in non-agriculture. As in the data, the share of farmer in the labor force in the model declines from 85 percent in the poorest countries to less than 2 percent in the richest countries. These results suggest that policy aiming at improving overall efficiency should be prioritized.