Induced strain actuators have been integrated with conventional structural materials to serve as energy input devices or actuating elements in many engineering applications implementing intelligent material systems and structures concepts. In order to use the actuation mechanism produced by the integrated induced strain actuators efficiently, the mechanics of the mechanical interaction between the actuator and the host substructure must be understood and modeled accurately. A refined analytical model has been developed based on the plane stress formulation of the theory of elasticity for a surfacebonded induced strain actuator/beam substructure system. Closed-form solutions of the induced stress field were obtained in an approximate manner using the principle of stationary complementary energy. The model has also been extended to include the presence of adhesive bonding layers and applied external loads. The results of the current model were compared with those obtained by finite element analysis and the pin-force and Euler-Bernoulli models. It was shown that the current model is capable of describing the edge effects of the actuator on actuation force/moment transfer and interfacial shear and peeling stress distributions that the existing analytical models fail to describe. Good agreement was obtained between the current model and the finite element analysis in terms of predicting actuation force/moment transfer. The interfacial shear stress distribution obtained by the current model satisfies stress-free boundary conditions at the ends of the actuator, which the finite element model is not able to satisfy. The current model correctly describes the transfer of the actuation mechanism and the resulting interfacial stress distributions; thus, it can be used in designing integrated induced strain actuator/substructure systems. Moreover, a new induced strain actuator configuration, which includes inactive edges on the ends of the actuators, has been proposed to alleviate the intensity of the interfacial stresses. The effectiveness of the actuator on the interfacial stress alleviation was verified by the current analytical model and finite element analysis. It was shown that the proposed actuator configuration can significantly alleviate intensive interfacial shear and peeling stresses without sacrificing the effectiveness of the actuation mechanism. The chances of interfacial failure of the integrated structural system, fatigue failure in particular, can thus be reduced. / Ph. D.

Yes / A novel fluorescent monomer was synthesized to probe the state of CO2-responsive cross-linked polymeric particles. The fluorescent emission of this aminobromomaleimide-bearing monomer, being sensitive to protic environments, can provide information on the core hydrophilicity of the particles and therefore indicates the swollen state and size of the particles. The particles’ core, synthesized from DEAEMA (N,N-diethylaminoethyl methacrylate), is responsive to CO2 through protonation of the tertiary amines of DEAEMA. The response is reversible and the fluorescence emission can be recovered by simply bubbling nitrogen into the particle solution. Alternate purges of CO2 and N2 into the particles’ solution allow several ON/OFF fluorescence emission cycles and simultaneous particle swelling/shrinking cycles. / British Petroleum Company (BP), Engineering and Physical Sciences Research Council (EPSRC)

Yes / Molecularly Imprinted Polymers (MIPs) are a class of polymeric materials that exhibit highly specific recognition properties towards a chosen target. These “smart materials” offer robustness to work in extreme environmental conditions and cost effectiveness; and have shown themselves capable of the affinities/specificities observed of their biomolecular counterparts. Despite this, in many MIP systems heterogeneity generated in the polymerisation process is known to affect the performance. Microwave reactors have been extensively studied in organic chemistry because they can afford fast and well-controlled reactions, and have been used for polymerisation reactions; however, their use for creating MIPs is limited. Here we report a case study of a model MIP system imprinted for caffeine, using microwave initiation. Experimental parameters such as polymerisation time, temperature and applied microwave power have been investigated and compared with polymers prepared by oven and UV irradiation. MIPs have been characterised by BET, SEM, DSC, TGA, NMR, and HPLC for their physical properties and analyte recognition performance. The results suggest that the performance of these polymers correlates to their physical characteristics. These characteristics were significantly influenced by changes in the experimental polymerisation parameters, and the complexity of the component mixture. A series of trends were observed as each parameter was altered, suggesting that the performance of a generated polymer could be possible to predict. As expected, component selection is shown to be a major factor in the success of an imprint using this method, but this also has a significant effect on the quality of resultant polymers suggesting that only certain types of MIPs can be made using microwave irradiation. This work also indicates that the controlled polymerisation conditions offered by microwave reactors could open a promising future in the development of MIPs with more predictable analyte recognition performance, assuming material selection lends itself to this type of initiation. / DMU School of Pharmacy undergraduate project scheme for financial support.

In the last decades, additive manufacturing (AM), also called three-dimensional (3D) printing, has advanced micro/nano-fabrication technologies, especially in applications like lightweight engineering, optics, energy, and biomedicine. Among these 3D printing technologies, two-photon polymerization (TPP) offers the highest resolution (even at the nanometric scale), reproducibility and the possibility to create monolithically 3D complex structures with a variety of materials (e.g. organic and inorganic, passive and active). Such active materials change their shape upon an applied stimulus or degrade over time at certain conditions making them dynamic and reconfigurable (also called 4D printing). This is particularly interesting in the field of medical microrobotics as complex functions such as gentle interactions with biological samples, adaptability when moving in small capillaries, controlled cargo-release profiles, and protection of the encapsulated cargoes, are required. Here we review the physics, chemistry and engineering principles of TPP, with some innovations that include the use of micromolding and microfluidics, and explain how this fabrication schemes provide the microrobots with additional features and application opportunities. The possibility to create microrobots using smart materials, nano- and biomaterials, for in situ chemical reactions, biofunctionalization, or imaging is also put into perspective. We categorize the microrobots based on their motility mechanisms, function, and architecture, and finally discuss the future directions of this field of research.

Magnetic shape memory alloys are active materials which deform under the application of a magnetic field or an external stress. Due to their internal friction, recognizable from the strain-stress hysteresis, this new material technology allows the design of multistable actuators. This paper describes and characterizes an innovative airflow control valve whose aperture is proportional to the deformation of the active material and thus controllable by the input voltage. The multistability of the material is partially exploited within an airflow control loop to reduce the energy losses of the valve when a specific airflow value must be hold.

Thesis (MSc (Chemistry and Polymer Science))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: The use of various ‘smart materials’ (briefly meaning materials that respond to a change in their environment) is currently of interest to both academics and industry. The primary aim of the current study was to entrap photochromic (PC) dyes in miniemulsions, as a means to improve their fatigue resistance, thus synthesizing smart nanoparticles. In the coatings industry the use of aqueous systems is becoming a common requirement for health and environmental reasons. Miniemulsion entrapment allows the direct dispersion of PC dyes into aqueous systems while allowing for the opportunity to tailor-make the host matrix in order to obtain a suitable PC response and improved fatigue resistance. The optimal instrument set-up required to establish the PC response of films of the so-called smart nanoparticles (i.e. PC miniemulsions) was determined. A UV-Vis instrument with a chip-type UV LED mounted inside for activation of the samples provided PC response results. A tungsten lamp with filter provided deactivation of the samples. A stable butyl methacrylate (BMA) miniemulsion formulation was established by conducting a design of experiments. A chromene and spironapthoxazine (SNO) PC dye were entrapped in the BMA miniemulsion. A hindered amine light stabiliser (HALS) was also entrapped with the SNO dye in the BMA miniemulsion to further improve the fatigue resistance. The following PC properties of the smart nanoparticles films were evaluated: colourability, thermal decay rate, half-life and fatigue resistance. To compare results with conventional systems, a BMA solution polymer was prepared. The SNO dye and different concentrations of the HALS were mixed with the BMA solution polymer. In comparison to the SNO smart nanoparticles the chromene smart nanoparticles films had lower colourability, but better fatigue resistance. Incorporating HALS at levels of 0.5–2% in the BMA miniemulsion with PC dye did not lead to any significant improvement in fatigue resistance, yet films of the BMA solution polymer showed some improvement. SNO dye incorporated at 1% gave similar colourability in both miniemulsion and in solution polymer, yet the fatigue resistance of the films of the PC miniemulsions was much better. / AFRIKAANSE OPSOMMING: Die gebruik van verskeie “slim materiale’ (kortliks beskryf as materiale wat reageer op `n verandering in hul omgewing) is tans van belang vir beide akademici en die industrie. Die hoofdoel van hierdie studie was om miniemulsietegnologie te gebruik om fotochromiese (FC) kleurstowwe vas te vang, vir die sintese van slim nanopartikels, om sodoende die weerstand teen afgematheid te verbeter. In die verfindustrie word die gebruik van waterbasissisteme meer algemeen weens gesondheids- en omgewingsredes. Die gebruik van miniemulsie sisteme om materiale vas te vang maak dit moontlik om FC kleurstowwe direk in waterbasissisteme te meng. Die sintese van `n unieke gasheer matriks word benodig om die optimum FC verandering te toon en weerstand teen afgematheid te verbeter. Om die FC verandering van die sogenaamde slim nanopartikel films (d.w.s. FC miniemulsies) te ondersoek was `n gepaste instrumentele opstelling nodig. Dit is vasgestel dat `n UV-Vis instrument waarin `n skyfie-tipe UV LED gemonteer is vir aktivering van die monsters, reproduseerbare resultate gegee het. Die monsters is gedeaktiveer deur gebruik te maak van `n tungsten lig met ‘n filter. `n Eksperimentele ontwerp is toegepas om `n stabiele butielmetakrielaat (BMA) miniemulsie formulasie te verkry. `n ‘Chromene’ en ‘spironapthoxazine’ (SNO) FC kleurstof is in die BMA miniemulsie vasgevang tesame met `n verhinderde amien ligstabiliseerder (VALS) om die weerstand teen afgematheid verder te verbeter. Die volgende FC eienskappe van die slim nanopartikels is gemeet: kleurintensiteit, tempo van termiese verwering, half-lewe en weerstand teen afgematheid. `n BMA polimeeroplossing is berei om resultate mee te vergelyk. Die SNO kleurstof en verskillende konsentrasies van die VALS is met die BMA polimeeroplossing gemeng. In vergelyking met die slim SNO nanopartikels het die intelligente chromene nanopartikelfilms `n swakker kleurintensiteit gehad, maar `n hoër weerstand teen afgematheid. Die gebruik van 0.5–2% VALS in die BMA miniemulsie met FC kleurstof het minimale verbetering in weerstand teen afgematheid getoon, maar daar was wel `n beduidende verbetering in die geval van films met FC kleurstof in `n BMA polimeeroplossing. Byvoeging van 1% SNO kleurstof in `n BMA miniemulsie of polimeeroplossing het dieselfde kleurintensiteit gelewer, maar die weerstand teen afgematheid van die FC miniemulsie was baie beter.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The successful design, implementation and testing of a feedback control system for tab-deflection control of a shape memory alloy (SMA) based control surface actuator is presented. The research is performed as part of the Control Surfaces in Confined Spaces (CoSICS) research project conducted at Stellenbosch University. The research group investigates ways to provide control surface actuation in size-restricted spaces in commercial aircraft such as the Airbus A320 and A330. This is achieved by investigating the concept of trailing edge tabs to reduce the required torque load, resulting in reduced actuator requirements enabling the use of smaller actuators. This thesis contributes to the project by investigating the possibility of using SMA-based actuators in reduced hinge moment requirement applications. An SMA-based tab actuator demonstrator design is presented. Mathematical models are derived for the SMA material, thermodynamics and actuator geometry. The models are combined to formulate an SMA-based control surface actuator model. The model is utilised in four tracking feedback controller designs; two based on linear and two based on non-linear control techniques. The manufactured prototype is presented along with the incorporated hardware for controller implementation. System identification follows and validates the three mathematical models. Practical verification of the model and two of the controllers is conducted. The unimplemented controllers are implemented through a validated model simulation. Controller evaluation, based on the dynamic controller performance, is conducted. The results validate the concept of using an SMA actuator for tab-deflection control and indicate important limitations for the intended application. / AFRIKAANSE OPSOMMING: Die tesis behels die ontwerp, implementering en toetsing van ’n terugvoer beheerstelsel vir hulpvlak defleksie beheer van ’n vorm-geheue allooi (SMA) gebaseerde aktueerder. Die navorsing vorm deel van die Beheervlakke in Begrensde Ruimtes (CoSICS) navorsingsprojek by Stellenbosch Universiteit. Die CoSICS navorsing behels ’n ondersoek na beheervlak aktueering in beknopte spasies in kommersiële vliegtuie soos die Airbus A320 en A330. Die probleem word aangespreek deur ’n ondersoek na aerodinamiese hulpvlakke wat ’n vermindering in skarnier moment tot gevolg het en sodoende die aktueerder vereistes verminder. Hierdie tesis dra by tot die projek deur die moontlikheid van die gebruik van SMAgebaseerde aktueerders in verminderde skarnier moment vereiste toepassings te ondersoek. ‘n SMA gebaseerde hulpvlak demonstrasie aktueerder ontwerp word voorgelê. Wiskundige modelle vir die SMA materiaal, termodinamika en prototipe geometrie is geformuleer en gekombineer om ‘n SMA gebaseerde beheervlak aktueerder model te ontwikkel. Die model word in vier beheerder ontwerpe toegepas. Twee ontwerpe is op liniëre en twee op nie-liniëre beheer tegnieke gebaseer. Die prototipe en nodige hardeware vir beheerder implementasie is voorgedra. Stelsel identifikasie is toegepas en verifieer die drie wiskundige modelle. Praktiese verifikasie van die model en twee beheerders is gedoen. Die ongeïmplementeerde beheerders is deur die geverifieerde aktueerder model gesimuleer. ‘n Beheerder evaluasie gebaseer op die dinamiese beheerder gedrag word toegepas. Die evaluasie beklemtoon kritiese aspekte en beperkinge in verband met SMA aktueering. Die resultate regverdig die gebruik van ‘n SMA aktueerder vir hulpvlak defleksie beheer en beklemtoon belangrike beperkinge ten opsigte van die voorgestelde toepassing.

Submitted by Angela Maria de Oliveira (amolivei@uepg.br) on 2019-03-12T14:31:37Z No. of bitstreams: 2 license_rdf: 811 bytes, checksum: e39d27027a6cc9cb039ad269a5db8e34 (MD5) Luis Henrique da Silveira Lacerda.pdf: 5893257 bytes, checksum: a2df90c95fd70919cf9b3cefa1fedec8 (MD5) / Made available in DSpace on 2019-03-12T14:31:37Z (GMT). No. of bitstreams: 2 license_rdf: 811 bytes, checksum: e39d27027a6cc9cb039ad269a5db8e34 (MD5) Luis Henrique da Silveira Lacerda.pdf: 5893257 bytes, checksum: a2df90c95fd70919cf9b3cefa1fedec8 (MD5) Previous issue date: 2019-02-18 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / O desenvolvimento de materiais para aplicação tecnológica tem sido foco de inúmeros trabalhos científicos e, dentre a gama extremamente variada de materiais investigados, encontram-se os materiais multiferróicos, considerados a próxima geração de materiais para desenvolvimento de dispositivos inteligentes. O multiferroísmo consiste na existência simultânea de ordenamento magnético e propriedades ferroelétricas ou ferroelásticas em uma mesma fase cristalina do material. O tipo mais comum de material multiferróico apresenta um acoplamento entre as propriedades ferroelétricas e magnéticas, também chamado de acoplamento magnetoelétrico. No presente trabalho, novos materiais multiferróicos foram propostos através da substituição de cátions A e B na estrutura cristalina R3c por átomos magnéticos e não magnéticos e investigados por meio de simulações computacionais baseadas na Teoria do Funcional de Densidade. Os materiais investigados apresentam alta estabilidade em condições ambientes e em altas pressões, bem como propriedades eletrônicas e ópticas que sugerem estes como alternativas viáveis para desenvolvimento de dispositivos eletrônicos e aplicação em processos de fotodegradação e técnicas de water splitting fotocatalítico. Sobretudo, as propriedades magnéticas e ferroelétricas são orientadas ao longo das direções [111] e x ([100]), respectivamente, evidenciando um comportamento anisotrópico no material. Assim sendo, tais propriedades são tangenciais entre si mostrando a possibilidade de um controle destas a partir de campo elétrico aplicado na direção [111] resultando na perturbação do ordenamento magnético ou por meio de um campo magnético aplicado na direção x para obter uma resposta ferroelétrica do material. A estes fatos apresentados, os resultados obtidos também evidenciam uma origem molecular do acoplamento magnetoelétrico não só em estrutura R3c, mas em quaisquer outras estruturas cristalinas, uma vez que pode-se concluir que a origem molecular das propriedades multiferróicas consiste na existência de propriedades tangenciais e dependentes ao longo da célula unitária do material, sendo que tal dependência sugere o acoplamento entre estas. De tal modo, o presente trabalho representa uma primeira descrição teórica ampla de como tais propriedades são observadas nos materiais investigados em função da modificação química da estrutura cristalina, além da descrição das propriedades gerais dos materiais propostos, apontando estes como alternativas em potencial para desenvolvimento de dispositivos eletrônicos e quaisquer aplicações baseadas no multiferroísmo ou em materiais inteligentes. / The development of materials aiming technological applications has been the focus of several scientific manuscripts and, among investigated materials stands out the multiferroics, which are considered as the next generation of materials to smart devices development. The multiferroism consists on the simultaneous existence of a magnetic ordering and ferroelectric or ferroelastic properties in a same crystalline phase, being the most common kind of multiferroism observed between the ferroelectricity and the magnetics ordering and also known as magnetoelectric coupling. In this work, new multiferroic materials were proposed from A and B cations replacement in R3c structures by magnetic and non-magnetic atoms; the materials were evaluated by computational simulations based on Density Functional Theory. The investigated materials presents high stability under room condition and high pressures in R3c structures, as well as electronic and optical properties suggesting then as viable alternatives to development of electronic devices and photocatalytic process, such as water splitting and photodegradation. Moreover, the ferroelectric and magnetic properties are oriented on [111] and x ([100]) directions, respectively, showing an anisotropic behavior in the material. Thus, such properties are tangent each other indicating the control possibility from an electric field applied along [111] direction resulting on a magnetic response or from a magnetic field applied along x direction to obtain a ferroelectric response. Therefore, the obtained results clarify the molecular origin of the magnetoelectric coupling for R3c materials and any other crystalline structures since the coupling arises from the fact that the magnetism and ferroelectricity are tangent each other and, consequently, dependents, indicating the coupling between both properties. This work represents the first deep description of how the multiferroism can be affected by chemical modification and also the first report about the general properties of evaluated materials, indicating these materials as potential alternative to development of electronic devices and any application based on multiferroism or smart materials.

The increasing prevalence of digital fabrication technologies and the emergence of a novel materiality in contemporary craft practice have created the need to redefine the critical context of digital jewellery and wearable futures. Previous research in this area, such as that presented by Sarah Kettley (2007a) and Jayne Wallace (2007), has provided the foundations for further enquiry but has not been advanced significantly since its inception. The artistic research presented in this thesis focuses on how smart materials and microelectronic components could be used to create synergetic digital jewellery objects and wearable futures that reflect changes in the body of their wearer and their environment through dynamic responses. Laying the foundations for a theory of <i>Interactive</i> <i>Craft</i> through evaluating different aspects of creative practice that relate to responsive objects with a close relationship to the human body is at the centre of this enquiry. Through identifying four distinct categories of wearable object, the <i>Taxonomy of the Wearable Object</i> is formulated and clearly delineates the current existing conceptual, technological and material perspectives that govern the relationships between different types of wearable objects. A particular focus is placed on exploring the concept of <i>Digital Enchantment</i> and how it could be utilised to progress towards developing the <i>Uncanny Object</i> that appears to possess biological characteristics and apparent agency, yet is a fully artificial construct. The potential for the practical application of a design methodology guided by playful engagement with novel materials, microelectronics and digital fabrication technologies is analysed, taking into account Ingold’s concept of the <i>textility of making </i>(Ingold, 2011). Through exploring the notion of the <i>Polymorphic</i> <i>Practitioner</i> in the context of <i>Alchemical Practice</i>, a model for experiential knowledge generation through engaging in cross-disciplinary collaboration is developed. This is supported by a qualitative survey of European materials libraries, including accounts of site visits that evaluate the usefulness of materials libraries for creative practitioners invested in novel materiality as well as visually documenting a selection of the visited libraries’ most intriguing material holdings. Utilising a scientific testing protocol, a practical body of work that centres on conducting extensive experiments with smart materials is developed, with a particular focus on testing the compatibility and colour outcomes of chromic pigments in silicone. The resulting chromic silicone samples are collated, together with sourced smart materials, in a customised materials library. Investigational prototypes and the <i>Microjewels</i> collection of digital jewellery and wearable futures that responds to external and bodily stimuli whilst engaging the wearer through playful interaction are presented as another outcome of this body of research.

We study the plasticity mechanisms of diffusionless martensite phase transformation in Nickel-Titanium, one of the most widely used shape memory alloys. The research here involves four thrusts focusing on different length and time scales: (I) Molecular statics and dynamics simulations are applied to study the nanotwin structures and temperature-driven B2 → B19′ phase transitions. (II) Molecular dynamics simulations are performed to explore the stress-driven martensitic phase transformation governing the pseudoelasticity and shape memory effects in NiTi nanopillars. (III) Monte Carlo simulations are conducted to characterize the temperature- driven B2 → B19 phase transition and the patterning of martensitic nanotwins in NiTi thin films. (IV) Phase field simulations are performed to predict the formation and evolution of complex martensitic microstructures, including the detailed analysis of twin compatibility under complex loading conditions. We also study the nucleation-controlled plasticity mechanisms in different metals of Cu, Al and Ni. Our work focuses on understanding how dislocations nucleate in single crystals. Interatomic potential finite element method is applied to determine when, where and how dislocations nucleate during nanoindentation in metals such as Cu, Al and Ni.