京都大学 / 新制・課程博士 / 博士(工学) / 甲第25251号 / 工博第5210号 / 京都大学大学院工学研究科社会基盤工学専攻 / (主査)教授 安原 英明, 准教授 橋本 涼太, 准教授 澤村 康生 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

Thesis (MEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: Expansive soils, one of the problematic soils, are encountered on all continents with exception of polar continents. Problems caused by their heaving and shrinking behaviour, particularly to light structures, have been reported from different countries to place large financial burden on developers. For this reason, many techniques have been developed and applied to prevent and/or remediate the damage caused by these soils. Soil stabilization with traditional chemical additives has been applied successfully since ancient times. In addition to traditional additives such as lime, cement, fly ash, etc., some non-traditional additives, such as polymer based products, salts, etc. have been used effectively for soil treatment. On the other hand, industries are increasingly challenged by waste management in an acceptable and environmentally friendly manner. In this regard, a number of researches have been done on using industrial waste for soil improvement purposes. The study and understanding of basic reactions involved in lime-soil stabilization persuaded many researchers to study the applicability of lime-rich products for soil treatment. Studies conducted by Khalid et al. (2012); Muchizuki et al. (2004) and Thacker (2012) showed that lime-rich products such as pulp fly and bottom ashes and CaO by-products, can be applied for soil stabilization. This research was thus performed to investigate the effect of lime-rich paper mill waste ash on expansive soil properties. Two commonly listed soil engineering properties namely volume change and strength were investigated. Soil strength was examined in terms of unconfined compressive strength (UCS), due to its correlations with a number of other soil properties, and the volume change in terms of free swell and swelling pressure. In addition to these two engineering properties, dry density and moisture content were also studied due to their involvement in structural design, as well as gradation, Atterberg limits and California Bearing Ratio (CBR). The choice of these properties was also influenced by the availability of a standard (ASTM D4609-08) specifically developed to assess the effectiveness of admixtures for soil stabilization. Two main types of materials were used namely three clay materials and paper mill ash. According to the index properties, commonly used for expansive soil classification, three clays were classified into low, medium and high degrees of potential expansiveness. The ash results from the combustion of paper mill sludge, sawdust, bark, coal ash and bituminous coal in a multi-fuel boiler for the purpose of electricity and steam production. The tests mentioned above were conducted on both untreated and treated clays and the results were compared. Since the study was carried out on this material based on the fact that it contains lime, the procedure applied for lime-soil stabilization was considered. In general, it was observed that ash-soil treatment has a number of effects similar to lime-treatment and almost all studied properties were enhanced for all clays. It can thus be concluded that the paper mill ash from a multi-fuel boiler can be efficiently used for expansive soil treatment. For optimum use of this material for expansive soil treatment, more tests and further researches have been recommended. / AFRIKAANSE OPSOMMING: Uitsettende gronde, een van die probleemtipe-gronde, kom op alle kontinente voor, behalwe die twee poolkontinente. Probleme veroorsaak deur uitswellende en inkrimpende gedrag van hierdie gronde, veral finansiële onkostes van ligte strukture is al in baie lande aangemeld. Vir hierdie rede is baie tegnieke ontwikkel en toegepas om skade wat deur hierdie tipe gronde veroorsaak is, te voorkom en/of herstel. Hierdie tegnieke sluit grondstabilisasie met chemiese bymengsels in, veral tradisionele bymengsels, wat met groot sukses in die verre verlede toegepas en na moderne tye oorgedra is. Bykomend tot tradisionele bymengsels soos kalk, sement, vlieg-as ensovoorts is ʼn aantal nie-tradisionele bymiddels soos polimeergebaseerde produkte, soute en ander produkte ontwikkel vir grondstabilisasie. Aan die ander kant raak industrieë toenemend daarmee gemoeid om afvalstowwe op ʼn aanvaarbare en omgewingsvriendelike wyse te bestuur. Op hierdie gebied is ʼn aantal navorsingsprojekte al uitgevoer om industriële afval vir grondverbetering te gebruik en sodoende die las op nywerhede te verlig. Navorsing is onderneem om die basiese reaksies wat onstaan tydens stabilisasie van grond met tradisionele en moderne middels te bepaal en om die geskiktheid van kalkryke produkte vir grondstabilisasie te ondersoek. Baie navorsing is uitgevoer wat aangetoon het dat kalkhoudende produkte soos pulp vlieg- en oondresidu-as, asook CaO neweprodukte gebruik kan word vir stabilisasie. Gebaseer hierop is hierdie projek onderneem om die effek van papiermeulas, verkry deur die verbranding in ʼn veelvuldige brandstof-stoomketel, op die gedrag van uitsettende grond te ondersoek. Tydens hierdie studie is twee algemene ingenieurseienskappe van grond, naamlik sterkte en volumeverandering ondersoek. Grondsterkte is geëvalueer in terme van eenassige druksterkte (EDS) as gevolg van ? deur middel van die korrelasie met ʼn aantal ander grondeienskappe, en die volumeverandering in terme van vry-swel en sweldruk. Addisioneel tot hierdie twee grondeienskappe is droë digtheid en waterinhoud ook bestudeer aangesien beide in struktuurontwerp betrokke is. Verdere eienskappe wat ondersoek is, is gradering, Atterberggrense en Kaliforniese drakragverhouding (KDV). Die keuse van hierdie eienskappe is beïnvloed deur die beskikbaarheid van ʼn toetsstandaard (ASTM D4609-08) wat spesifiek ontwikkel is om die effektiwiteit van bymengsels vir grondstabilisasie te evalueer. Hierdie standaard is deurgaans as verwysing tydens die projek gebruik. Daar is waargeneem dat as-behandeling van grond ʼn aantal effekte het soortgelyk aan kalkbehandeling, met die uitsondering van die droë digtheid en optimum waterinhoud van een van die gronde wat getoets is. Byna al die eienskappe wat ondersoek is, soos EDS, KDV, ensovoorts, is verbeter behalwe in die geval van die eerste klei waarvan die plastisiteitsindeks verhoog het en die grond meer plasties geraak het. Daar kan dus afgelei word dat papiermeule-as vanaf ʼn stoomketel wat veelvuldige tipes brandstof gebruik geskik is vir die behandeling van uitsettende grond. Om die optimumgebruik van hierdie materiaal vir die stabilisasie van swellende klei te bepaal, is meer toetse en projekte nodig.

published_or_final_version / abstract / Civil Engineering / Doctoral / Doctor of Philosophy

Este trabalho apresenta a avaliação dos efeitos da estabilização química com cal e cimento na condutividade hidráulica e resistência à compressão de um solo arenoso proveniente da Formação Botucatu (Estado de São Paulo, Brasil), com o objetivo de obter um material menos permeável e mais resistente. O projeto e análise de experimentos foram realizados através de um planejamento fatorial 3², com duas variáveis independentes: teor de umidade e porcentagem de estabilizante, variando em três níveis cada. Foi utilizado cal hidratada CH-III, cimento Portland CP II-Z32 e água fornecida pela concessionária local. Os ensaios de condutividade hidráulica (K) foram executados em permeâmetros de carga constante. Foram realizados ensaios de resistência a compressão simples (RC) após 7 e 28 dias de cura. As amostras de solo estabilizado e natural foram compactadas na energia Proctor Normal. Na avaliação da estrutura das amostras de solo estabilizado verificou-se a alteração da matriz de poros promovida pela adição de cal e cimento. Após a obtenção dos resultados, análises estatísticas possibilitaram avaliar os efeitos das variáveis independentes sobre o K e RC. Pelo método de superfície de respostas foi possível demonstrar o comportamento das misturas e identificar a tendência de alteração das propriedades. As amostras de solo-cimento alcançaram reduções de condutividade hidráulica de até 9,5 x 10-7 m/s e o menor valor experimental de K foi de 1,4 x 10-8 m/s. Os ensaios de RC, com 28 dias de cura, apresentaram acréscimo de resistência de até 5,1 MPa e os resultados obtidos possuem uma variação, aproximadamente, entre 0,1 e 5,1 MPa. O procedimento adotado permitiu avaliar a influência dos fatores e determinar as misturas ótimas para cada estabilizante. / A laboratory study was conducted to evaluate the effects of lime and cement stabilization over the hydraulic conductivity and unconfined compressive strength of a sandy soil from Botucatu Formation (São Paulo State, Brazil) with the intend to generate a less permeable and more resistant material. The experiment was performed using the technique of factorial design 3², with the two independent variables: moisture content and stabilizer percentage, varying on three levels each. Hydraulic conductivity (K) was measured in constant-head permeameters. Unconfined compressive strength (CS) was measured after 7 and 28 days of curing. The samples of stabilized and natural soils were compacted with the normal Proctor energy. The evaluation of the stabilized soil structure verified a pore matrix modification promoted by lime and cement addition. With the results of the characterization, statistical analysis allowed to assess the effects of the variable factors on K and CS. The response surface method was used to demonstrate the hydraulic and compressive strength behavior of the stabilized soil. The soil-cement hydraulic conductivity achieved reductions up to 9.5 x 10-7 m/s and the lowest K experimental value was 1.4 x 10-8 m/s. The compressive strength, with 28 days of curing, presented an increase in CS up to 5.1 MPa and the obtained results showed a range between 0.1 and 5.1 MPa. The adopted experimental procedure allows the assessment of the variables influence and the determination of the optimal mixtures for each stabilizer.

A numerical investigation was conducted to evaluate the geotechnical safety and slope stability of Municipal Solid Waste (MSW) landfills, considering the effects of geosynthetic reinforcements, biodegradation of the waste, and associated changes in material properties, and extreme wind force simulating hurricane conditions. Three different landfill slopes, 1:1, 1:2, and 1:3 having the height of 122m and width of 2134m, were analyzed using Limit Equilibrium Method (SLOPE/W) and Finite Element Modeling (ANSYS). Techniques developed in this study were used to analyze a case history involving a geogrid reinforced mixed landfill expansion located in Austria. It was found that few years after construction of the landfill, there is a significant decrease in the FS due to biodegradation. Extreme wind loading was also found to cause a substantial loss in the FS. The geosynthetic reinforcement increased the slope stability and approximately compensated for the damaging effects of biodegradation and wind loading. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2016. / FAU Electronic Theses and Dissertations Collection

Esta pesquisa teve como objetivo estudar a dosagem de cal para a estabilização de um solo de comportamento laterítico (LG\') e outro não laterítico (NG\'). Para a estabilização foram utilizadas duas cales dolomíticas (CH-I e CH-III) e aplicados dois métodos de dosagem de solo-cal (ASTM D 6276 e o método de Thompson). Os teores de cal indicados pelos métodos foram baixos e não convergiram para o mesmo valor, por isso, para os ensaios mecânicos foram adotados os teores de 5%, 7,5% e 10% de cal. Os corpos de prova de solo-cal foram curados em uma estufa ventilada a uma temperatura controlada de 50°C por 0, 2, 7 e 14 dias. No programa experimental, foram feitas avaliações de propriedades mecânicas, de resistência à compressão simples (RCS), sem e após imersão, e do módulo de resiliência (MR); e avaliações de microestruturas, a partir de imagens de microscopia eletrônica de varredura (MEV) e espectroscopia de energia dispersiva (EDS) e de resultados de difração de raios X (DRX). Os resultados do estudo das propriedades mecânicas mostraram que: (i) com o teor de cal adequado as misturas solo-cal apresentaram importantes incrementos de resistência, sendo que após 14 dias de cura, as RCS aumentaram 3,5 a 4 vezes para as misturas NG\'+10% CH-I e LG\'+10% CH-I, respectivamente; (ii) houve manutenção de uma parcela de RCS mesmo após imersão em água (por 4h), o que foi atribuído à ocorrência das reações cimentantes; (iii) a adição de cal aumentou o MR do solo independente do tipo e do teor de cal empregado e mudou o comportamento resiliente da mistura, que passou a se comportar como material granular. Com relação à análise da microestrutura, pode-se constatar (iv) mudança de textura do solo e formação de compostos cimentantes, a partir das imagens de MEV; (v) alterações na composição química das misturas ao longo do período de cura, como notado nos resultados de EDS; e (vi) a formação de novos picos nos difratogramas dos materiais, evidenciando a formação de novos compostos minerais. As misturas estudadas nessa pesquisa, no geral, mostraram bons resultados após a estabilização e ainda que podem ser usadas como camadas de pavimentos se a dosagem for feita de maneira adequada. / This research aimed to study the lime content for stabilization of a lateritic (LG\') and a non-lateritic (NG\') soil. For the stabilization, two dolomitic limes (CH-I and CH-III) were used and two soil-lime procedures to estimate de lime content were applied (ASTM D 6276 and Thompson\'s method). The lime contents indicated by the methods were low and did not converge to the same value, therefore, for the mechanical tests were adopted the lime contents of 5%, 7.5% and 10% of lime. Soil-lime samples were cured in an air circulated oven at a controlled temperature of 50°C for 0, 2, 7 and 14 days. In the experimental program, evaluations of mechanical properties, unconfined compressive strength (UCS), without and after immersion in water, and the resilience modulus (RM) were evaluated; reviews of microstructures, images from scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) and results of X-ray diffraction (XRD) were analysed. The results of the mechanical properties showed that: (i) with the appropriate lime content, the soil-lime mixtures presented significant increases in strength, and after 14 days of cure, the UCS increased by 3.5 to 4 times for the mixtures NG\'+ 10% CH-I and LG\' + 10% CH-I, respectively; (ii) there was maintenance of a UCS portion even after immersion in water (for 4 h), which was attributed to the occurrence of cementing reactions; (iii) addition of lime increased the RM of the soil independent of the type and lime content applied and changed the resilient behavior of the mixture, which behave as a granular material. Regarding the analysis of the microstructure, we can verify (iv) change of soil texture and formation of cementing compounds, from SEM images; (v) changes in the chemical composition of the mixtures over the curing period, as noted in the EDAX results; and (vi) the formation of new peaks in the diffractograms of the materials, evidencing the formation of new mineral compounds. The mixtures studied in this research, in general, showed good results after stabilization and that can be used as layers of pavements if the properly content of lime is applied.

University of Macau / Faculty of Science and Technology / Department of Civil and Environmental Engineering

Civil engineers are at times required to stabilize sulfate bearing clay soils with calcium based stabilizers. Deleterious heaving in these stabilized soils may result over time. This dissertation addresses critical questions regarding the consequences of treating sulfate laden soils with calcium-based stabilizers. The use of a differential scanning calorimeter was introduced in this research as a tool to quantify the amount of ettringite formed in stabilized soils. The first part of this dissertation provides a case history analysis of the expansion history compared to the ettringite growth history of three controlled low strength mixtures containing fly ash with relatively high sulfate contents. Ettringite growth and measurable volume changes were monitored simultaneously for mixtures subjected to different environmental conditions. The observations verified the role of water in causing expansion when ettringite mineral is present. Sorption of water by the ettringite molecule was found to be a part of the reason for expansion. The second part of this dissertation evaluates the existence of threshold sulfate levels in soils as well as the role of soil mineralogy in defining the sensitivity of soils to sulfate-induced damage. A differential scanning calorimeter and thermodynamics based phase diagram approach are used to evaluate the role of soil minerals. The observations substantiated the difference in sensitivity of soils to ettringite formation, and also verified the existence of a threshold level of soluble sulfates in soils that can trigger substantial ettringite growth. The third part of this dissertation identifies alternative, probable mechanisms of swelling when sulfate laden soils are stabilized with lime. The swelling distress observed in stabilized soils is found to be due to one or a combination of three separate mechanisms: (1) volumetric expansion during ettringite formation, (2) water movement triggered by a high osmotic suction caused by sulfate salts, and (3) the ability of the ettringite mineral to absorb water and contribute to the swelling process.

Expansive soils occurring in arid and semi-arid climate regions of the world cause serious problems on civil engineering structures. Such soils swell when given an access to water and shrink when they dry out. Several attempts are being made to control the swell-shrink behavior of these soils. Soil stabilization using chemical admixtures is the oldest and most widespread method of ground improvement. In this study, waste limestone dust and waste dolomitic marble dust, by-products of marble industry, were used for stabilization of expansive soils. The expansive soil is prepared in laboratory as a mixture of kaolinite and bentonite. Waste limestone dust and waste dolomitic marble dust were added to the expansive soil with predetermined percentage of stabilizer varying from 0 to 30 percent. Grain size distribution, consistency limits, chemical and mineralogical composition, swelling percentage, and rate of swell were determined for the samples. Swelling percentage decreased and rate of swell increased with increasing stabilizer percentage. Also, samples were cured for 7 days and 28 days before applying swell tests. Curing of samples affects swell percentages and rate of swell in positive way.

Modification of black cotton soils by chemical admixtures is a common method for stabilizing the swell-shrink tendency of expansive soils. Advantages of chemical stabilization are that they reduce the swell-shrink tendency of the expansive soils and also render the soils less plastic. Among the chemical stabilization methods for expansive soils, lime stabilization is most widely adopted method for improving the swell-shrink characteristics of expansive soils. Lime stabilization of clays in field is achieved by shallow mixing of lime and soil or by deep stabilization technique. Shallow stabilization involves scarifying the soil to the required depth and lime in powder or slurry form is spread and mixed with the soil using a rotovator. The use of lime as deep stabilizer has been mainly restricted to improve the engineering behaviour of soft clays Deep stabilization using lime can be divided in three main groups: lime columns, lime piles and lime slurry injection. Lime columns refer to creation of deep vertical columns of lime stabilized material. Lime piles are usually holes in the ground filled with lime. Lime slurry pressure injection, as the name suggests, involves the introduction of a lime slurry into the ground under pressure. Literature review brings out that lime stabilization of expansive clays in field is mainly performed by mixing of lime and soil up to shallow depths. The use of lime as deep stabilizer has been mainly restricted to improve the engineering behaviour of soft clays. Use of lime in deep stabilization of expansive soils however has not been given due attention. There exists a definite need to examine methods for deep stabilization of expansive soils to prevent the deeper soil layers from causing distress to the structures in response to the seasonal climatic variations. In addition, there exists a need for in-situ soil stabilization using lime in case of distressed structures founded on expansive soil deposits. The physical mixing of lime and soil in shallow stabilization method ensures efficient contact between lime and clay particles of the soil. It however has limitation in terms of application as it is only suited for stabilization of expansive soils to relatively shallow depths. Studies available have not compared the relative efficiency of the lime pile technique and lime-soil mixing method in altering the physico-chemical, index and engineering properties of expansive black cotton soils. To achieve the above objectives laboratory experiments are performed that study: 1. the efficacy of lime piles in stabilizing compacted black cotton soil specimens from Chitradurga District in Karnataka. The efficiency of lime piles in chemically stabilizing the compacted black cotton soil mass was investigated as a function of: a)amount of lime contained in the lime pile b)radial migration of lime from the central lime pile c)migration of lime as a function of soil depth 2. the relative impact of the lime pile technique and lime-soil mixing method in altering the physico-chemical, index and engineering properties of expansive black cotton soil. The organization of this thesis is as follows After the first introductory chapter, a detailed review of literature performed towards highlighting the need to examine stabilization of expansive soils using lime pile technique is brought out in Chapter 2. Chapter 3 presents a detailed experimental programme of the study. 25 mm and 75 mm diameter lime piles were installed in the compacted soil mass to study the influence of amount of lime contained in the lime pile on the soil properties. The amount of quick lime contained in the 25 mm and 75 mm lime piles corresponded to 1 % and 3 % by dry weight of the soil mass respectively. Radial and vertical migration of lime from the central lime pile was examined by sampling soil specimens at different radial distances from the central lime pile and at different depths of soil sample. At a given depth and radial distance, migration of lime was estimated by comparing the exchangeable cation composition, pH and pore salinity of the treated soil with that of the natural (untreated) black cotton soil specimen. Alterations in the soil engineering properties at a given depth and radial distance were evaluated by comparing the index properties, swell potential and unconfined compressive strength of the lime pile treated soil specimen with those of the untreated specimen. To compare the relative efficiency of lime mixing and lime pile technique in altering the swelling behaviour of black cotton soil, batches of black cotton soil specimens were treated with 1 % and 3 % quick lime on dry soil weight basis. The compacted soil-lime mixes were cured at moisture contents of 31-34 % for a period of 10 days. The physico-chemical, index and engineering properties of the 1 % lime mixed specimens are compared with those of the 25 mm lime pile treated specimens. The properties of the 3 % lime mixed soil specimens are compared with those of the 75 mm lime pile treated specimens. Chapter 4 examines the efficacy of lime piles in stabilizing compacted black cotton soil specimens from Chitradurga District in Karnataka. Experimental results showed that controlling the swell potential of deep expansive soil deposits is possible by the lime pile technique. Treatment with lime pile caused migration of dissociated calcium and hydroxyl ions into the surrounding soil mass. In case of 25 mm lime pile, the experimental setup allowed measurement of migration of lime up to three times the lime pile diameter. In case of 75 mm lime pile, the experimental setup allowed measurement of migration of lime up to 1.6 times pile diameter. In both experiments, migration of lime was also uniform through out the soil depth of 280 mm. Migration of calcium and hydroxyl ions increased the pore salinity and pH of the treated soil mass. The increase in pH caused clustering of additional exchangeable calcium ions at the negative clay particle edges. The increased pore salinity and exchangeable calcium ions reduced the diffuse ion layer thickness that in turn suppressed the plasticity index and the swell potential of the compacted expansive soil. The laboratory results hence bring out that lime pile treatment in the field can substantially reduce the swell potential of the soil at least to a radial extent of 2 to 3 times the lime pile diameter. The 75 mm lime pile contained lime content in excess of the initial consumption of lime (ICL) value of the black cotton soil - namely 2.6 %. Laboratory results showed that migration of hydroxyl ions even from the 75 mm pile could not elevate the soil pH to levels required for soil-lime pozzoIonic reactions (pH ≥12). The very low solubility of lime in water (< 1 g/litre) and the impervious nature of the black cotton soil are considered to have impeded efficient interactions between lime and soil in course of treatment of the expansive soil with lime piles. Absence of soil-lime pozzolonic reactions precluded the formation of cementation compounds in the lime pile treated soil specimens. Cementation compounds formed by the soil-lime pozzolonic reactions are responsible for the much higher strengths of lime stabilized soils. Consequently, treatment with 25 mm pile had no impact on the unconfined compressive strength of the black cotton soil. Comparatively, treatment with 75 mm lime pile slightly increased the strength of the treated soil due to increased inter-particle attraction and particle flocculation. Chapter 5 compares the relative efficiency of the lime pile technique and lime-soil mixing method in altering the physico-chemical, index and engineering properties of expansive black cotton soil. Experimental results showed that mixing of soil and lime promote stronger chemical interactions between lime released hydroxyl ions and clay particles than that achieved by diffusion of lime from a central lime pile. The more alkaline pH of the lime mixed soil specimens rendered the clay particle edges more negative. Consequently, more calcium ions were adsorbed at the clay particle edges of the lime mixed soil specimens imparting them higher exchangeable calcium contents than the lime pile treated soil specimens. Also, at 3 % lime addition, the pH of the lime-mixed soil was sufficiently high (in excess of 12) to cause dissolution of silica and alumina from the clay lattice necessary for the formation of cementation compounds. The stronger lime modification reactions plus the lime-soil pozzolonic reactions (applicable for soil treated with lime content greater than ICL value) achieved by the lime mixing technique rendered the expansive soil much less plastic, much less expansive and much stronger than the lime pile treated specimens. The results of the laboratory study hence suggest that if a choice exists in the field between conventional method of spreading-mixing-compacting of soil-lime mixes and treating the ground with lime piles, the former technique should be adopted because of its greater efficacy in stabilizing the expansive soil. Chapter 6 summarizes the findings of the study.