In this work, the technique of designing and optimizing broadband volume transmission holograms using dichromate gelatin (DCG) is summarized for solar spectrum-splitting application. Spectrum splitting photovoltaic system uses a series of single bandgap PV cells that have different spectral conversion efficiency properties to more fully utilize the solar spectrum. In such a system, one or more high performance optical filters are usually required to split the solar spectrum and efficiently send them to the corresponding PV cells. An ideal spectral filter should have a rectangular shape with sharp transition wavelengths. DCG is a near ideal holographic material for solar applications as it can achieve high refractive index modulation, low absorption and scattering properties and long-term stability to solar exposure after sealing. In this research, a methodology of designing and modeling a transmission DCG hologram using coupled wave analysis for different PV bandgap combinations is described. To achieve a broad diffraction bandwidth and sharp cut-off wavelength, a cascaded structure of multiple thick holograms is described. A search algorithm is also developed to optimize both single and two-layer cascaded holographic spectrum splitters for the best bandgap combinations of two- and three-junction SSPV systems illuminated under the AM1.5 solar spectrum. The power conversion efficiencies of the optimized systems under the AM1.5 solar spectrum are then calculated using the detailed balance method, and shows an improvement compared with tandem structure.

Les concentrateurs photovoltaïques sont parmi les technologies d'énergies solaires les plus prometteuses. Ils ont une efficacité allant jusqu'à deux fois celle des panneaux photovoltaïques conventionnels. Malgré les avancements en recherche et développement, les concentrateurs photovoltaïques demeurent des systèmes relativement complexes. Cette même complexité laisse place à l'innovation et à la possibilité de réduire considérablement les coûts de fabrication. Dans le cadre de cette thèse, deux sites de tests sont développés et déployés pour faire l'analyse des performances des concentrateurs photovoltaïques plats. Quatre designs de cellules solaires sont caractérisés en laboratoire et incorporés dans les panneaux prototypes pour ensuite être individuellement étudiés. Les quatre designs sont ensuite comparés l'un à l'autre, et selon leurs emplacements, pour comprendre comment le design de la cellule affecte la performance des panneaux.

M.Tech. / Artisanal mine of sandstones especially in rural area are facing numerous challenges including the use of inadequate tools for the processing of sandstones. Since the current processing technique has limitations which consist of the use of hammer and chisels, there is a need to develop environmentally friendly and cost effective techniques for the processing of sandstones. In this project, six different sandstones samples (yellowish, blackish, reddish, greenish, greyish and whitish) from QwaQwa rural area were collected and characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM/EDS) and an optical microscope. In addition, physical properties of sandstones were also carried out including compressive strength, dielectric properties and water absorption. Furthermore sandstones samples were irradiated using multi- and single- mode microwave cavities to investigate the effect on the mineralogy of sandstones. The analysis of mineralogical change was carried out using XRD. Additionally a microwave multimode cavity was used to investigate the weight loss of sandstones after being irradiated. A microwave cavity was designed based on the characteristics of sandstones and it was simulated. A photovoltaic solar system was sized to power the microwave cutter. The experimental work was carried out on a laboratory scale. The XRD analysis revealed that quartz was the major mineral present in all sandstones which confirms that QwaQwa sandstones are quartz based sandstones. Feldspar minerals such as illite and albite were also found. Additional minerals were identified at trace level including glauconite, kaolonite, crysobalite and orthoclase. On the other hand, the XRD results of the irradiated samples using a single- and multi- mode cavity for 60 seconds revealed a strong presence of quartz which means no significant changes were observed. However, some minor overlapped peaks suspected to be muscovite (KAl2(Si3Al)O10(OH,F)2) in three samples (blackish, greyish and yellowish) were noticed. XRF study showed that the chemical elements available in the six sandstones samples are: aluminium, calcium, iron, potassium, magnesium, manganese, sodium, phosphorus, silicon and titanium.

<p>Renewable energy adoption is critical when considering future energy grids and how they impact the environment, economy and society. While fossil fuels have traditionally been employed to generate the electricity used across every facet of the global economy, renewables are becoming increasingly more attractive as a substitute. Fossil fuels have historically outperformed their clean energy counterparts in terms of levelized cost. However, over the last few decades renewables have become extremely cost competitive and are starting to outpace their opposition as advancements in technology continue. As the cost gap between “brown” and “green” energy sources decreases, energy grid mixes will adopt more sustainably responsible generation, positively impacting the planet.</p> <p>In the following thesis, two studies are presented which demonstrate new innovations for decreasing the cost of offshore wind energy and how renewables and desalination can be integrated along the US-Mexico border. The first study describes an itemized breakdown of how substituting the mechanical transmission with hydraulics can lower the life-time cost of an offshore wind turbine. The second analysis details a complex wind and solar powered clean water production and distribution network to combat ongoing water scarcity along the US-Mexico border. Both concepts push the boundaries of scientific innovation and its application for solving social and economic issues. </p>

The global consumption of fossil fuels continues to increase due to the rapid growth of energy demand, as a consequence of expanding population and human activities. Fast climate change is another inescapable issue caused by humans that need to be addressed. The development of solar energy conversion technologies is widely considered as one of the most promising solutions to sustainably maintain a modern lifestyle of the society and create a carbon-neutral social development operation mode. The solar energy is carried and delivered in the form of electromagnetic fields. Therefore, the efficiency of photon collection is the primary factor to create any solar energy conversion systems. Through the inspiration from nature, the functionalized disorder, with a specific design and engineering, can introduce unusual light-matter interaction behaviors, and thus offer a potential capability to achieve perfect light harvesting. In my thesis, we develop complex Epsilon-Near-Zero (ENZ) metamaterials that can be used either as light capturing networks or the photoactive media by turning the energy damping ratio between radiative and non-radiative channels. We successfully integrate it into thin-film photovoltaic modules with showing an excellent performance enhancement led by broadband light localization effect. Thanks to universal of such complex ENZ metamaterials, with combining a thin layer of dielectric, we further develop efficient hot-carriers driven plasmonic photo-catalysts for artificial green chemical fuel synthesis. The detailed theoretic analysis is presented in this work.

With the increasing pressure of providing reliable potable water in a sustainable way, it is important to understand water phase change phenomena (condensation and evaporation) as the water phase change is involved in many processes such as membrane distillation and solar still which can be a feasible choice of supplementing the present potable water access. In the present thesis, we first elucidate the role of wettability of water condensation substrate by combining the droplet growth dynamics and droplet population evolution. The results show that wettability has a negligible effect on water condensation rate in an atmospheric environment. After confirming the role of substrate wettability, we provide a quantitative analysis of the effect of substrate geometry on water condensation in the atmospheric environment. The analysis can help to predict the efficiency of water condensation rate with a given substrate of a certain geometry with the aid of computational simulation tools. The results show that water condensation can be increased by 40% by rationally designing the geometry of the condensation surface. However, the condensation rate in the atmospheric environment is relatively slow due to the presence of non-condensable gas. In order to increase the condensation rate, a relatively pure vapor environment is desired, in which condensed water will be the major heat transfer barrier. Coalescence induced jumping of condensed droplets on superhydrophobic surfaces is an interesting phenomenon to help faster removal of condensed droplets. However, it is still not clear how to optimize the overall heat transfer efficiency by condensation on such surfaces. We observed an interesting phenomenon on a superhydrophobic nano-cones array, on which water preferentially condenses within larger cavities among the nanocones. Droplets growing form larger cavities have larger growth rate. This finding can possibly provide a solution to optimizing heat transfer efficiency. Finally, a nylon-carbon black composite is prepared by electrospinning to enhance water evaporation under solar radiation. The composite shows an interesting light absorption property. In a wet state, the composite can absorb around 94% of the incident sunlight. The composite also shows strong mechanical and chemical stability. Thus, the composite is considered to be a practical candidate to be applied in the solar distillation process.

A steady-state numerical model of a PV/microchannel integrated direct-expansion CO2 heat pump (PV-DXHP) water heater is developed, validated, and analyzed in the present study. To accomplish the objectives, a numerical model of a microchannel evaporator integrated into a CO2 PV DXHP is developed and validated. The effects of evaporator operating parameters on the heat absorption and pressure drop are analyzed. Utilizing the evaporator model, the PV-DXHP model is developed, and the baseline values of the heat pump operating parameters are determined from the evaporator parametric study. The PV-DXHP demonstrates high water heating capability, while maintaining a reasonably high COP. The COP has the highest dependency on the CO2 mass flow rate, while the water outlet temperature has the highest dependency on the water mass flow rate. The results are highly promising and indicate the system has potential to help meet the energy requirements for residential and industrial water heating demands.

Exploiting solar energy technology for both heating and cooling purposes has the potential of meeting an appreciable portion of the energy demand in buildings throughout the year. By developing an integrated, multi-purpose solar energy system, that can operate all twelve months of the year, a high utilisation factor can be achieved which translates to more economical systems. However, there are still some techno-economic barriers to the general commercialisation and market penetration of such technologies. These are associated with high system and installation costs, significant system complexity, and lack of knowledge of system implementation and expected performance. A sorption heat pump module that can be integrated directly into a solar thermal collector has thus been developed in order to tackle the aforementioned market barriers. This has been designed for the development of cost-effective pre-engineered solar energy system kits that can provide both heating and cooling. This thesis summarises the characterisation studies of the operation of individual sorption modules, sorption module integrated solar collectors and a full solar heating and cooling system employing sorption module integrated collectors. Key performance indicators for the individual sorption modules showed cooling delivery for 6 hours at an average power of 40 W and a temperature lift of 21°C. Upon integration of the sorption modules into a solar collector, measured solar radiation energy to cooling energy conversion efficiencies (solar cooling COP) were between 0.10 and 0.25 with average cooling powers between 90 and 200 W/m2 collector aperture area. Further investigations of the sorption module integrated collectors implementation in a full solar heating and cooling system yielded electrical cooling COP ranging from 1.7 to 12.6 with an average of 10.6 for the test period. Additionally, simulations were performed to determine system energy and cost saving potential for various system sizes over a full year of operation for a 140 m2 single-family dwelling located in Madrid, Spain. Simulations yielded an annual solar fraction of 42% and potential cost savings of €386 per annum for a solar heating and cooling installation employing 20m2 of sorption integrated collectors.

A solar simulator was used to test whether a carbon black additive could increase the solar absorption of a low temperature organic PCM (consisting of a eutectic mixture of palmitic acid and stearic acid). Various PCM and carbon black composites (0.01 % to 6 %) were tested, with the 0.06 % carbon black composites showing the fastest temperature increase, reaching 75 °C much quicker (350 % faster) than the pure PCM. All of the tested PCM composites reached 75 °C in less than half the time it took the pure PCM. It can therefore be seen that carbon black is very effective at increasing the solar absorption of the PCM. The carbon black did not have a negative impact on the melting/solidifying onset temperature or the latent heat of the PCM. This proves that at these low concentrations carbon black can help reduce the shortcomings of the PCM without adversely affecting its energy storage properties. The optimal carbon black concentration changes with the size of the PCM: a shallow PCM layer (2 cm) showed the fastest temperature increase at higher concentrations (between 0.06 % and 0.5 % carbon black), while the deep PCM layer (9 cm) showed the fastest temperature increase at lower concentrations (between 0.01 % and 0.08 % carbon black). The poor optical properties of the PCM were vastly improved by the carbon black, making the composite an effective direct solar absorber. The carbon black, however, does not provide meaningful thermal conductivity enhancements. Therefore additional heat transfer enhancements (like graphite) are needed if this novel PCM composite is to be used in a combined system (direct solar absorber, heat transfer fluid and energy storage system). / Dissertation (MEng)--University of Pretoria, 2016. / Chemical Engineering / MEng / Unrestricted

In 2018 alone, the global energy demand grew by 2.3% and will rise by 1.3% each year to 2040 [1] making it the fastest growth rate in the last decade predominantly driven by a robust global economy and increased heating and cooling needs. This tremendous need resulted in using fossil fuels to meet nearly 70% of the growth, but also promoted solar and wind generation to have a double-digit growth pace, with solar alone increasing by 31%. Terrestrial solar energy at AM1.5 is generally given at 1kW/m2, which is a vast free source of energy that can be harvested to meet the global demand for electricity [2]. A major obstacle for large scale solar power production is obscuration of sunlight on solar collectors caused by dust deposition or ‘soiling’ as the power plants are located in semi-arid or desert regions. Soiling could result in energy-yield output losses of about a third of the total power output of the installation [3] as water is a scarce commodity, resulting in lesser cleaning cycles of the solar collectors. Electrodynamic Screen (EDS) films can restore the efficiency of solar power installations without the use of water, manual labor or robots and can be retrofitted onto the sun facing surfaces of solar collectors, including concentrating solar power mirrors (CSP) and photovoltaic (PV) modules. Applying a low frequency pulsed voltage to the electrodes which form the central unit of the EDS films charges the dust on the collector surface and ejects it using a travelling wave. The electrodes are of paramount importance to the EDS film as they are the primary working unit of the device. Copper is the current choice of electrode material but it is susceptible to electromigration and has serious environmental disadvantages with respect to corrosion and instability. Copper electrodes also do not meet the transmission efficiency (TE) requirements as the opaque electrodes absorb and obstruct the incident sunlight through shadowing, hurting the output efficiency of the photovoltaic modules. Hence for the EDS film to be a strong candidate as a cleaning technology, it must have environmentally durable electrodes that meet the TE needs. For this purpose (1) I have developed a screen printable ink with zinc oxide (ZnO) and silver nanowire (AgNW) that is transparent in nature which satisfies the TE requirements of the EDS film which were previously unmet; this ink referred to as AgNW_ZnO Hybrid Ink throughout this document is my original contribution for the optimization of the optical performance of the EDS film technology. (2) I have established the environmental durability, stability and functionality of the electrodes of the EDS film through standardized, vigorous testing which were not performed before. To do so, I have followed the testing standards specified under the Accelerated Weathering (QUV) ASTM G154 tests which are used to validate the environmental viability of materials (3) My study and findings on the top surface component of the EDS film proposes measures of action that will enhance the removal of dust and suggests alternative, more cost efficient replacements for the ultrathin glass layer which serves as the current design’s top layer (4) My experiments and results on the charging mechanism/behavior of dust particles upon EDS film activation contribute to optimizing the design parameters used for both the EDS film and the power supply unit used to power it. These contributions allow for increasing the output power restoration of PV modules and specular reflection restoration of CSP mirrors that have the EDS film on their optical surfaces.