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Nanoscale systems have sizes intermediate between atomic and macroscopic ones. Therefore their treatment often requires a combination of methods from atomic and condensed matter physics. The conventional Landau-Zener theory, being a powerful tool in atomic physics, often fails to predict correctly nonadiabatic transition probabilities in various nanostructures because it does not include many-body effects typical for mesoscopics. In this research project the generalizations of the Landau-Zener theory that solve this problem were studied. The multistate, multiparticle and nonunitary extensions of the theory have been proposed and investigated. New classes of exactly solvable models have been derived. I discuss their applications in problems of the molecular condensate dissociation and of the driven charge transport. In application to the physics of nanomagnets new approaches in modeling the influence of the environment on the Landau-Zener evolution are proposed and simple universal formulas are derived for the extensions of the theory that include the coupling to noise and the nuclear spin bath.

The main topic of this doctoral thesis is asymptotic properties of zeros in polynomial families arising as eigenfunctions to exactly-solvable differential operators. The study was initially inspired by a number of striking results from computer experiments performed by G. Masson and B. Shapiro for a more restrictive class of operators. Our research is also motivated by a classical question going back to S. Bochner on a general classification of differential operators possessing an infinite sequence of orthogonal eigenpolynomials. In general however, the sequence of eigenpolynomials of an exactly-solvable operator is not an orthogonal system and it can therefore not be studied by means of the extensive theory known for such systems. Our study can thus be considered as the first steps to a natural generalization of the asymptotic behaviour of the roots of classical orthogonal polynomials. Exactly-solvable operators split into two major classes: non-degenerate and degenerate. We prove that in the former case, as the degree tends to infinity, the zeros of the eigenpolynomial are distributed according to a certain probability measure which is compactly supported on a tree and which depends only on the leading term of the operator. Computer experiments indicate the existence of a limiting root measure in the degenerate case too, but that it is compactly supported (conjecturally on a tree) only after an appropriate scaling which is conjectured (and partially proved) in this thesis. One of the main technical tools in this thesis is the Cauchy transform of a probability measure, which in the considered situation satisfies an algebraic equation. Due to the connection between the asymptotic root measure and its Cauchy transform it is therefore possible to obtain detailed information on the limiting zero distribution.

Nanoscale systems have sizes intermediate between atomic and macroscopic ones. Therefore their treatment often requires a combination of methods from atomic and condensed matter physics. The conventional Landau-Zener theory, being a powerful tool in atomic physics, often fails to predict correctly nonadiabatic transition probabilities in various nanostructures because it does not include many-body effects typical for mesoscopics. In this research project the generalizations of the Landau-Zener theory that solve this problem were studied. The multistate, multiparticle and nonunitary extensions of the theory have been proposed and investigated. New classes of exactly solvable models have been derived. I discuss their applications in problems of the molecular condensate dissociation and of the driven charge transport. In application to the physics of nanomagnets new approaches in modeling the influence of the environment on the Landau-Zener evolution are proposed and simple universal formulas are derived for the extensions of the theory that include the coupling to noise and the nuclear spin bath.

Given a configuration of pebbles on the vertices of a graph, a pebbling move is defined by removing two pebbles from some vertex and placing one pebble on an adjacent vertex. The cover pebbling number of a graph, γ (G), is the smallest number of pebbles such that through a sequence of pebbling moves, a pebble can eventually be placed on every vertex simultaneously, no matter how the pebbles are initially distributed. We determine Bose-Einstein and Maxwell-Boltzmann cover pebbling thresholds for the complete graph. Also, we show that the cover pebbling decision problem is NP-complete.

This thesis was concerned with classifying the real indecomposable solvable Lie algebras with codimension one nilradicals of dimensions two through seven. This thesis was organized into three chapters. In the first, we described the necessary concepts and definitions about Lie algebras as well as a few helpful theorems that are necessary to understand the project. We also reviewed many concepts from linear algebra that are essential to the research. The second chapter was occupied with a description of how we went about classifying the Lie algebras. In particular, it outlined the basic premise of the classification: that we can use the automorphisms of the nilradical of the Lie algebra to find a basis with the simplest structure equations possible. In addition, it outlined a few other methods that also helped find this basis. Finally, this chapter included a discussion of the canonical forms of certain types of matrices that arose in the project. The third chapter presented a sample of the classification of the seven-dimensional Lie algebras. In it, we proceeded step-by-step through the classification of the Lie algebras whose nilradical was one of four specifically chosen because they were representative of the different types that arose during the project. In the appendices, we presented our results in a list of the multiplication tables of the isomorphism classes found.

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