The location of fronts has a direct influence on both the physical and biological processes in the Southern Ocean. However, until recently fronts have been poorly resolved by available data and climate models. In this thesis we utilise a combination of high resolution satellite data, model output and ARGO data to improve our basic understanding of fronts. A method is derived whereby fronts are identified as local maxima in sea surface height gradients. In this way fronts are defined locally as jets, rather than continuous-circumpolar water mass boundaries. A new climatology of Southern Ocean fronts is presented. This climatology reveals a new interpretation of the Subtropical Front. The currents associated with the Subtropical Front correspond to the western boundary current extensions from each basin, and we name these the Dynamical Subtropical Front. Previous studies have instead suggested that the Subtropical Front is a continuous feature across the Southern Ocean associated with the super gyre boundary. A comprehensive assessment of the relationship between front locations and wind stress is conducted. Firstly, the response of fronts to a southward shift in the westerly winds is tested using output from a 100 year climate change simulation on a high resolution coupled model. It is shown that there was no change in the location of fronts within the Antarctic Circumpolar Current as a result of a 1.3° southward shift in the westerly winds. Secondly, it is shown that the climatological position of the Subtropical Front is 5-10° north of the zero wind stress curl line, despite many studies assuming that the location of the Subtropical Front is determined by the zero wind stress curl. Finally, we show that the nutrient supply at ocean fronts is primarily due to horizontal advection and not upwelling. Nutrients from coastal regions are entrained into western boundary currents and advected into the Southern Ocean along the Dynamical Subtropical Front. / <p>At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Submitted.</p>

In this dissertation, the aim is to investigate the empirical relationship between the partial pressure of CO2 (pCO2) and other ocean variables in the Southern Ocean, by using a small percentage of the available data. CO2 is one of the main greenhouse gases that contributes to global warming and climate change. The concentration of anthropogenic CO2 in the atmosphere, however, would have been much higher if some of it was not absorbed by oceanic and terrestrial sinks. The oceans absorb and release CO2 from and to the atmosphere. Large regions in the Southern Ocean are expected to be a CO2 sink. However, the measurements of CO2 concentrations in the ocean are sparse in the Southern Ocean, and accurate values for the sinks and sources cannot be determined. In addition, it is difficult to develop accurate oceanic and ocean-atmosphere models of the Southern Ocean with the sparse observations of CO2 concentrations in this part of the ocean. In this dissertation classical techniques are investigated to determine the empirical relationship between pCO2 and other oceanic variables using in situ measurements. Additionally, sampling techniques are investigated in order to make a judicious selection of a small percentage of the total available data points in order to develop an accurate empirical relationship. Data from the SANAE49 cruise stretching between Antarctica and Cape Town are used in this dissertation. The complete data set contains 6103 data points. The maximum pCO2 value in this stretch is 436.0 μatm, the minimum is 251.2 μatm and the mean is 360.2 μatm. An empirical relationship is investigated between pCO2 and the variables Temperature (T), chlorophyll-a concentration (Chl), Mixed Layer Depth (MLD) and latitude (Lat). The methods are repeated with latitude included and excluded as variable respectively. D-optimal sampling is used to select a small percentage of the available data for determining the empirical relationship. Least squares optimization is used as one method to determine the empirical relationship. For 200 D-optimally sampled points, the pCO2 prediction with the fourth order equation yields a Root Mean Square (RMS) error of 15.39 μatm (on the estimation of pCO2) with latitude excluded as variable and a RMS error of 8.797 μatm with latitude included as variable. Radial basis function (RBF) interpolation is another method that is used to determine the empirical relationship between the variables. The RBF interpolation with 200 D-optimally sampled points yields a RMS error of 9.617 μatm with latitude excluded as variable and a RMS error of 6.716 μatm with latitude included as variable. Optimal scaling is applied to the variables in the RBF interpolation, yielding a RMS error of 9.012 μatm with latitude excluded as variable and a RMS error of 4.065 μatm with latitude included as variable for 200 D-optimally sampled points. / Thesis (MSc (Applied Mathematics))--North-West University, Potchefstroom Campus, 2012

In this dissertation, the aim is to investigate the empirical relationship between the partial pressure of CO2 (pCO2) and other ocean variables in the Southern Ocean, by using a small percentage of the available data. CO2 is one of the main greenhouse gases that contributes to global warming and climate change. The concentration of anthropogenic CO2 in the atmosphere, however, would have been much higher if some of it was not absorbed by oceanic and terrestrial sinks. The oceans absorb and release CO2 from and to the atmosphere. Large regions in the Southern Ocean are expected to be a CO2 sink. However, the measurements of CO2 concentrations in the ocean are sparse in the Southern Ocean, and accurate values for the sinks and sources cannot be determined. In addition, it is difficult to develop accurate oceanic and ocean-atmosphere models of the Southern Ocean with the sparse observations of CO2 concentrations in this part of the ocean. In this dissertation classical techniques are investigated to determine the empirical relationship between pCO2 and other oceanic variables using in situ measurements. Additionally, sampling techniques are investigated in order to make a judicious selection of a small percentage of the total available data points in order to develop an accurate empirical relationship. Data from the SANAE49 cruise stretching between Antarctica and Cape Town are used in this dissertation. The complete data set contains 6103 data points. The maximum pCO2 value in this stretch is 436.0 μatm, the minimum is 251.2 μatm and the mean is 360.2 μatm. An empirical relationship is investigated between pCO2 and the variables Temperature (T), chlorophyll-a concentration (Chl), Mixed Layer Depth (MLD) and latitude (Lat). The methods are repeated with latitude included and excluded as variable respectively. D-optimal sampling is used to select a small percentage of the available data for determining the empirical relationship. Least squares optimization is used as one method to determine the empirical relationship. For 200 D-optimally sampled points, the pCO2 prediction with the fourth order equation yields a Root Mean Square (RMS) error of 15.39 μatm (on the estimation of pCO2) with latitude excluded as variable and a RMS error of 8.797 μatm with latitude included as variable. Radial basis function (RBF) interpolation is another method that is used to determine the empirical relationship between the variables. The RBF interpolation with 200 D-optimally sampled points yields a RMS error of 9.617 μatm with latitude excluded as variable and a RMS error of 6.716 μatm with latitude included as variable. Optimal scaling is applied to the variables in the RBF interpolation, yielding a RMS error of 9.012 μatm with latitude excluded as variable and a RMS error of 4.065 μatm with latitude included as variable for 200 D-optimally sampled points. / Thesis (MSc (Applied Mathematics))--North-West University, Potchefstroom Campus, 2012

Previous numerical and theoretical results based on constant diapycnal diffusivity suggested the abyssal meridional overturning circulation (MOC) should weaken as winds over the Southern Ocean intensify. We corroborate this result in a simple ocean model, but find it does not hold in more complex models. First, models with a variable eddy transfer coefficient and simple yet dynamic atmosphere and sea-ice models show an increase, albeit slightly, of the abyssal MOC under increasing winds. Second, the abyssal MOC significantly strengthens with winds when diapycnal diffusivity is parameterized to be energetically supported by the winds. This tests the emerging idea that a significant fraction of the wind energy input to the large-scale ocean circulation is removed by mesoscale eddies and may then be transferred to internal lee waves, and thence to bottom-enhanced diapycnal mixing. A scaling theory of the abyssal MOC is extended to incorporate this energy pathway, corroborating our numerical results. / Graduate / 0415 / gstanley@uvic.ca

L'océan Austral aux moyennes latitudes est l'un des endroits les plus tempétueux sur Terre. On peut donc supposer que le passage de ces tempêtes intenses sur cette variabilité océanique intense peut avoir un impact fort sur la variabilité intra-saisonnière des couches de surface où vit le phytoplancton. Pour autant, cet impact sur le taux de croissance du phytoplancton et sa variabilité reste encore très méconnu. C'est à cette question que s'efforce de répondre ce travail de thèse visant à faire progresser la compréhension de la variabilité intra-saisonnière de la production primaire de l'océan Austral. Nos expériences de modélisation suggèrent que les apports en Fer dissous (DFe) dans les eaux de surface à l'échelle intra-saisonnière par les tempêtes jouent un rôle bien plus actif et déterminant qu'on ne le pensait pour expliquer la productivité estivale importante de l'océan Austral. Deux idées importantes ressortent: 1. Les interactions tempête-tourbillon peuvent fortement augmenter l'amplitude et l'extension du mélange vertical agissant sur des couches traditionnellement considérées comme superficielles, mais également en subsurface. Ces deux régimes de mélange possèdent des dynamiques différentes mais agissent de concert pour augmenter les flux de DFe à la surface des océans. 2. Les tempêtes génèrent des courants inertiels qui peuvent considérablement renforcer les vitesses verticales w par interaction avec les tourbillons. Cela favorise l'advection verticale de DFe à la surface de l'océan, et avoir un effet plusieurs jours après la tempête. Ces interactions entre les tempêtes et les tourbillons peuvent considérablement intensifier la variabilité production primaire. / The Southern Ocean is one of the stormiest places on earth; here strong mid-latitude storms frequently traverse large distances of this ocean. The presence of the passage of intense storms and meso to sub-mesoscale eddy variability has the potential to strongly impact the intra-seasonal variability of the upper ocean environment where phytoplankton live. Yet, exactly how phytoplankton growth rates and its variability are impacted by the dominance of such features is not clear. Herein, lies the problem addressed by the core of this thesis, which seeks to advance the understanding of intra-seasonal variability of Southern Ocean primary production. Model experiments have suggested that intra-seasonal storm-linked physical supplies of dissolved iron (DFe) during the summer played a considerably more active and influential role in explaining the sustained summer productivity in the surface waters of the Southern Ocean than what was thought previously. This was through two important insights: 1. Storm-eddy interactions may strongly enhance the magnitude and extent of upper-ocean vertical mixing in both the surface mixed layer as traditionally understood as well as in the subsurface ocean. These two mixing regimes have different dynamics but act in concert to amplify the DFe fluxes to the surface ocean. 2. Storm initiated inertial motions may, through interaction with eddies, greatly reinforce w and thus, enhance the vertical advection of DFe to the surface ocean, an effect that may last several days after the storm. Such storm-eddy dynamics may greatly increase the intra-seasonal variability of primary production.

La production primaire (PP) dans l'Océan Austral joue un rôle crucial dans la capacité des océans à absorber le carbon atmosphérique. Elle est caractérisée par une forte limitation en Fer et par un cycle saisonnier très marqué, présentant un bloom planctonique en fin d'hiver, plus ou moins intense selon les régions. Ma thèse est centrée sur la compréhension des mécanismes qui contrôlent ce bloom et sa variabilité, ainsi que sur les éléments, présents et futurs, qui contrôlent son intensité. J'ai abordé le premier aspect (phénologie et mécanismes) en mettant en place une approche mécaniste basée sur une nouvelle configuration du modèle biogéochimique PISCES forcé par un environnement physique 1D idéalisé. Cette méthodologie m'a permis de réconcilier les différentes théories sur la formation des blooms aux hautes-latitudes, d'identifier les spécificités du bloom de l'Océan Austral et de proposer des critères adaptés à sa détection dans les observations. En outre, les résultats de cette étude de modélisation ont été confrontés à ceux issues d'une deuxième approche, basée sur des observations satellitaires, ce qui a permis la localisation géographique des différentes phénologies de bloom que j'ai identifiées dans l'Océan Austral. Pour répondre au deuxième aspect (altération et changements futurs), j'ai également suivi une double approche. J'ai d'abord examiné comment les limitations par la lumière et par le fer se combinent, via la variabilité du cycle saisonnier du mélange vertical, et pilotent ainsi la production primaire dans l'Océan Austral actuel à l'aide de la configuration idéalisée présentée plus haut. Dans un deuxième temps, cette analyse a permis d'aider à l’interprétation des variations de PP observées dans les projections climatiques issues de 8 modèles couplés (CMIP5). L'ensemble de mes résultats permet de mieux comprendre les processus physiques et biologiques qui contrôlent la croissance du phytoplancton dans l'Océan Austral et d'appréhender comment la modification de ces processus peut entraîner des altérations de la PP dans une région clé pour l'évolution future du climat. / Primary production (PP) in the Southern Ocean (SO) plays a crucial role on atmospheric carbon uptake. PP in this ocean is highly iron-limited and presents a marked seasonal cycle. Such a seasonal cycle has a strong productive phase in late winter, called bloom, which distribution and intensity is highly variable. My PhD focus on two specific aspects of the PP in the SO: first, the mechanisms that drive such a bloom and its dynamics and, second, the elements able to control the bloom intensity at present and in the future. The first aspect (bloom phenology and mechanisms) was addressed by setting up a mechanistic approach based on a novel model configuration: a complex biogeochemical model (PISCES) forced by a 1D idealised physical framework. This methodology allowed me to conciliate the different bloom formation theories and to identify the SO bloom specificities. Moreover, I proposed how to use different bloom detection criteria to properly identify bloom from observations. Such criteria were then tested in a complementary observation-based approach (with satellite and in-situ data) to characterise different bloom phenologies and its spatial distribution in the SO. The second aspect (bloom intensity and future change) was also addressed by a twofold approach. First, using the 1D model, I studied how seasonal variability of vertical mixing combine light and Fe limitation to drive PP. Secondly, I used such an analysis to interpret PP trends observed in 8 coupled model climatic projections (CMIP5 models). My PhD thesis results allow for a better understanding of the physical and biological processes controlling phytoplankton growth. My conclusions also suggest how an alteration of these processes by Climate Change may influence PP in the whole SO, a key region for future climate evolution.

La biogéochimie de l’Océan austral joue un rôle crucial dans la régulation de la production primaire marine globale en contrôlant la disponibilité des nutriments dans les eaux de surface des basses latitudes. Les variations du cycle du silicium (Si) sont nombreuses et son couplage avec les autres éléments n’est pas encore bien compris dans cet océan. Les résultats issus de deux approches isotopiques différentes suggèrent qu’une pompe de Si active est rapidement initiée au printemps par la transition d’un mode de production de silice biogénique régénéré à une production dite « nouvelle ». L’évolution saisonnière de la composition isotopique naturelle du Si (δ30Si) est principalement contrôlée par l’équilibre entre les rapports « dissolution/production » et « Si-supply/Si-uptake » qui découplent la dynamique isotopique des réservoirs de Si dissout et particulaire (respectivement DSi et BSi). Nous avons également utilisé les mesures de δ30Si pour retracer les flux saisonniers de BSi vers l’océan profond. Ces résultats confirment que le δ30Si n’est pas altéré durant la sédimentation des particules. L’évolution saisonnière du δ30Si a permis de quantifier pour la première fois certains processus contrôlant la production des diatomées et leur devenir, tels que les évènements de mélange alimentant la ML en nutriments, ou l’évolution saisonnière de la vitesse de sédimentation des particules. Ces résultats confirment que le δ30Si du DSi et de la BSi, combinés aux techniques isotopiques de mesure des flux dans la ML, sont des outils prometteurs dans l’amélioration de nos connaissances du cycle du Si et apportent des informations nouvelles à intégrer aux modèles biogéochimiques. / Southern Ocean biogeochemistry plays a crucial role on global marine primary production by impacting the nutrient availability even in low latitude surface water. Variations in the silicon (Si) cycle are large and its coupling to other nutrient biogeochemical cycles is still not well understood in this ocean. Results of two different isotopic approaches suggested that a strong silicon pump was quickly initiated in spring by a switch from regenerated to new biogenic silica production. The seasonal evolution of natural Si isotopic composition (δ30Si) was mainly driven by the balance between the “dissolution to production” and “Si-supply to Si-uptake” ratios that decoupled the isotopic dynamics of particulate and dissolved Si-pools (DSi and BSi, repectively). We also used δ30Si measurements to track seasonal flows of BSi to the deep sea with. These results confirmed that the δ30Si is well preserved during particles settling. The seasonal evolution of δ30Si signal allows for the first time to quantify important features about the processes controlling the diatoms’ productivity and its fate, such as mixing events that bring nutrient in the ML or the seasonal evolution of particles sinking velocities. These insights confirm that the δ30Si of DSi and BSi, combined to isotopic technics to measure Si fluxes in the ML, are promising tools to improve our understanding on the Si-biogeochemical cycle and provide new constraints for application to biogeochemical models.

La biosphère océanique module la concentration de CO2 atmosphérique via la pompe biologique (transfert vertical de carbone organique particulaire - POC - de l'océan de surface vers le fond) et la contre-pompe des carbonates (émission de CO2 lors de la précipitation du carbone inorganique particulaire - PIC). Cette thèse a pour but (1) d'identifier la contribution de différents groupes planctoniques à l'export de POC et PIC à échelle annuelle dans des zones de production contrastée de l'océan Austral et (2) de comprendre comment cette diversité influence la stœchiométrie et la labilité du matériel exporté.Des déploiements de pièges à particules à proximité les iles Kerguelen et de la Géorgie du Sud montrent que la fertilisation naturelle en fer augmente l'intensité mais pas l'efficacité de l'export de POC. Les spores de résistance de diatomées pilotent une fraction importante (40-60 %) de l'export annuel de POC dans chacun des sites productifs. L'analyse taxonomique des diatomées mène à l'identification de groupes consistants qui impactent la séquestration préférentielle du C ou du Si. Lors d'une campagne estivale, nous associons l'abondance relative de diatomées et dinoflagellés à la stœchiométrie N:P de la matière organique et soulignons l'importance des couches de transition pour le découplage des cycles du C et Si. L'étude de la composition en lipides du matériel exporté nous permet d'identifier les spores de diatomées comme des vecteurs de matière organique contenant des acides gras riches en énergie. A Kerguelen, la faible contre-pompe des carbonates est due à dominance des coccolithophoridés dans l'export de PIC au Sud du Front Polaire. / Marine biosphere impacts the atmospheric CO2 concentration by two main processes: the biological pump (vertical transfer of particulate organic carbon - POC - from the surface to the deep ocean) and the carbonate counter pump (CO2 emission during particulate inorganic - PIC - precipitation). The objectives of this PhD are (1) to identify the relative contribution of different plankton groups to POC and PIC export at annual scale in regions of contrasted productivity in the Southern Ocean and (2) to understand how this diversity impacts the elemental stoichiometry and lability of the exported material.Annual sediment trap deployments in the vicinity of the Kerguelen and South Georgia island plateaus have demonstrated that natural iron fertilisation increases the intensity but not the efficiency of export. Diatom resting spore formation drives an important fraction (40-60 %) of the annual carbon export in the productive sites. The taxonomic analyses of exported diatoms lead to the identification of consistent groups that impact the preferential export of C or Si. During a summer cruise, we associate the relative abundance of diatoms and dinoflagellates to the N:P stoichiometry of particulate organic matter and highlight the importance of transition layers for C and Si uncoupling. The study of the lipid composition of export leads to the identification of diatom resting spore as preferential vectors for the export energy-rich fatty acids. At Kerguelen, the low carbonate counter-pump is due to the dominance of coccolithophores contribution to PIC export south of the Polar Front.

The Great Australian Bight (GAB) is an extensive W-E striking continental margin basin that drifted northwards during the Cenozoic following rifting and separation from Antarctica in the mid/late Cretaceous. Seafloor spreading accelerated in the mid-Eocene and was associated with local volcanism. The mid-Eocene succession of the GAB is conspicuously mounded and separates a dominantly siliciclastic succession below from a fully marine carbonate succession above. The mounded succession was penecontemporaneous with major changes in global climate, oceanographic conditions and tectonic re-organization in the region, and thus may hold important clues as to the palaeo-environmental changes associated with these changes. The mid Eocene has so far only been described locally or in passing, usually by studies focused on either the siliciclastics below or the carbonates above. It was therefore chosen as a major focus point for the research project reported herein. Exploration activity in the GAB has been limited despite the presence of a working petroleum system and large target structures, but industry interest has increased over the past few years leading to 3D seismic surveys being acquired in the GAB. The focus for exploration is the Cretaceous succession beneath the relatively thin Cenozoic cover, which however, is still important in terms of shallow hazards and as overburden to the anticipated productive sections. As is often the case, the new 3D seismic data shows many overburden features in great detail and thus affords new insights to be gained that improve our understanding of the post-rift evolution of the marginThis thesis expands upon and reinterprets a pre-existing sequence framework in the Cenozoic GAB based from ODP Leg 182 results. A vast database of 2D and 3D seismic surveys has been integrated with exploration wells and borehole data and several surfaces have been calibrated to borehole and well constraints, then mapped to the maximum lateral extent across the available dataset. Surface mapping provided new insight into sequence deposition and palaeoenvironmental settings. Structure maps and thickness maps highlight key depocentre locations and trends over the Cenozoic GAB as well as stacked mass debris aprons. The newly discovered sequences raise new questions regarding trigger mechanisms in a-seismic areas and feed into industry geohazard perception models. The base surface of the Cenozoic framework hosts a plethora of mounded features across shelf and basinal section. All mounds within the dataset have been mapped. A set a bryozoan reef mounds have been interpreted lying parallel to the margin as linear complexes over 500 km. They coincide with the underlying siliciclastic delta clinoform breakpoints and provide insight into the changing palaeoenvironment at the 43 Ma mark, cessation of siliciclastics and regional marine transgression. Further mound mapping aided by 3D attribute extractions along the base Cenozoic unconformity led to the interpretation of a series of enigmatic igneous-based mounded features. The discoveries have been included in a comparative study, comparing all mounded features (igneous or carbonate) and contrasting their individual characteristics of geometry, seismic facies, dimension in order to understand mound origin and emplacement. A new grouping of mounds in the GAB has been established, the origin and emplacement mechanisms of which contribute to the global knowledge base.

No description available.