Cílem této práce bylo studium Heuslrových sloučenin pomocí optických a magneto-optických (MO) metod. V případě první sloučeniny, Co2FeGa0.5Ge0.5, jsme studovali výskyt strukturálního disorderu za pomoci spektroskopické elipsometrie, MO spektroskopie a MO Kerrovy magnetome- trie. Experimentální výsledky jsme poté porovnali s teoretickými modely. Doplnili jsme také výsledky našich spolupracovník·, a to včetně X-ray difrakce, atomic-force mikroskopie a ab initio výpočt·, abych potvrdili naši interpretaci naměřených výsledk·. Bylo zjištěno, že strukturální disorder je vskutku pozorovatelný pomocí metod, kterých jsme využili. Jeho výskyt se projevil změnou elektronové struktury vzork·. V případě druhé sloučeniny, Fe2MnGa, jsme vyšetřovali vliv obsahu Fe složky na optické a MO vlastnosti tohoto materiálu. Zjistili jsme, že atomy Fe ovlivňují koncentraci volných elektron·, čímž dodávají sloučenině kovový charakter (v porovnání s Ni2MnGa). Zároveň zvyšují optickou a MO odezvu v blízké infra-červené oblasti spektra. Dále bylo zjištěno, že vzorek s nejvyšším obsahem Fe má nulovou magnetizaci. 1

The developement of a femtosecond-time-resolved spectroscopic ellipsometry setup based on a pump-probe technique is described. The characterization of the setup is presented as well as first results of experiments on a c-plane oriented ZnO thin film are shown. Indications for the study of fast charge-carrier dynamics are given.:Introduction 1 1 Theoretical framework 3 1.1 Zinc oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.1.1 Crystal and band structure . . . . . . . . . . . . . . . . . . . . . 3 1.1.2 Excitons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.2 Dielectric function and electronic transitions . . . . . . . . . . . . . . . . 5 1.2.1 Electronic transitions . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.2.2 Dielectric function . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.3 Charge carrier dynamics . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 1.3.1 High excitation effects . . . . . . . . . . . . . . . . . . . . . . . . 8 1.3.2 Charge carrier density-dependent dielectric function model . . . . 9 1.4 Light polarization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 2 Preliminary experiments 14 2.1 Methods and instrumentation . . . . . . . . . . . . . . . . . . . . . . . . 14 2.2 Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2.3 Experimental challenges . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 2.4 Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 2.4.1 Time-integrated micro-ellipsometry . . . . . . . . . . . . . . . . . 28 2.4.2 Time-resolved ellipsometry . . . . . . . . . . . . . . . . . . . . . . 31 2.4.3 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 3 Conclusive experiments at ELI Beamlines 35 3.1 Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 3.2 Samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 3.3 Demonstration of functionality . . . . . . . . . . . . . . . . . . . . . . . . 49 3.3.1 Time-resolved reflectometry . . . . . . . . . . . . . . . . . . . . . 49 3.3.2 Time-resolved ellipsometry . . . . . . . . . . . . . . . . . . . . . . 51 4 Results and discussion 55 4.1 Time-resolved reflectometry . . . . . . . . . . . . . . . . . . . . . . . . . 55 4.2 Time-resolved ellipsometry . . . . . . . . . . . . . . . . . . . . . . . . . . 60 5 Summary and outlook 63

The aim of the diploma thesis was to cover the changes in body composition by bioimpedance spectroscopy in Czech breastfeeding women during three periods - 3 weeks postpartum, 3 months and 6 months postpartum. Eight healthy breastfeeding women were involved in the study. At each examination there were measured anthropometric parameters and bioimpedance spectroscopy parameters by the Body Composition Monitor. Breast milk was also extracted during the study. We observed a gradual decrease in body weight of monitored women. The median weight loss between the first and third examination was 2,2 kg, the median weight in 6 months postpartum was 1,3 kg higher than the median of prepregnancy body weight, two of the women had lower weight 6 months postpartum than before the pregnancy, the body weight of other six women was higher in a scale between 0,1 kg to 3,1 kg. There were not proven statistically significant differences in body composition during lactation. A trend of decrease of TBW was observed during all lactation periods. A trend of slight increase of ICW was observed between the 3rd week and 3rd month postpartum, and then the decrease of ICW in the 6th month postpartum. An increase of LTM and BCM was measured between the 3rd week and 3rd month postpartum, those values have shown a decrease again...

Orientador: Devaney Ribeiro do Carmo / Resumo: Neste trabalho esta descrito a preparação de nanopartículas de Hexacianoferrato (II) de Cério (III) (NpsCe), em quatro proporções diferentes de solventes a saber: Água/Formamida (100:0; 80:20; 40:60; 0:100), afim de se investigar a influência dos solventes no tamanho, morfologia, nas propriedades físico-químicas, voltamétrica e eletrocatalíticas da NpsCe. As Nps foram caracterizadas pelas técnicas de Espectroscopia na Região do Infravermelho (FTIR), Difração de Raios-X (DRX), Microscopia Eletrônica de Varredura (MEV), Potencial Zeta, Voltametria Cíclica (VC) e Voltametria de Pulso Diferencial (VPD). Dos quatro sistemas estudados apenas o CeHCF-1 (100/0) e o CeHCF - 3 (40/60) se apresentaram sensíveis a concentrações do neurotransmissor L-dopamina permitindo a confecção de uma curva de calibração. O sistema CeHCF-1 apresentou duas regiões linerares de sinal em função da concentração de L-dopamina, com limite de detecção (LD) de 0,125 mmol L-1 e 0,023 mmol L-1 obtido pelas técnicas de VC e VPD, respectivamente. Para o sistema CeHCF-3 observou-se por VC uma região linear de intensidade de corrente anódica e a concentração de L-dopamina com LD de 0,0317 mmol L-1, já por VPD apresentou duas regiões lineares de sinal em função da concentração de L-dopamina, com LD de 1,98 x 10-4 e 0,0104 mmol L-1. O sistema CeHCF – 3 apresentou promissor a detecção e quantificação de DA em amostras reais. Assim realizou-se o estudo para avaliar a seletividade deste frente a substâncias comumente en... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: This work is rearmed to nanoparticles of Cerium (III) Hexacyanoferrate (II) (NpsCe) analog of PB in four different proportions of Water / Formamide solvents (100: 0, 80:20, 40:60, 0: 100 ), to investigate the influence of solvents on the size, morphology, physicochemical, electrochemical and electrocatalytic properties of NpsCe. The Nps were characterized by the techniques of Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Zeta Potential, Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV). Of the four systems studied, only CeHCF-1 (100/0) and CeHCF-3 (40/60) are formed in small concentrations of the neurotransmitter L-dopamine. The CeHCF-1 system showed two signal regions as a function of L-dopamine concentration, with detection limit (LD) of 0.125 mmol L-1 and 0.023 mmol L-1 given by the CV and DPV techniques, respectively. For the CeHCF-3 system it can be seen as a linear signal region as a function of the L-dopamine concentration by the CV technique with LD of 0.0317 mmol L-1, or by DPV through two linear signal regions in the function of the concentration of L-dopamine, with LD of 1.98 x 10-4 and 0.0104 mmol L-1. The launched CeHCF – 3 system promises to detect and quantify DA in real cases. Thus, a study was carried out to reduce the resistance of a substance found in the physiological industries that have the potential of oxidation and reduction of the DA. Substantial subtranslators studied here were Urea and Asco... (Complete abstract click electronic access below) / Mestre

ectroscopic reflectometry is measurement technique that enables the study of the thickness and refractive index of thin layers. This thesis deals with its use for the study of lubrication films within EHD contact and verifies a new approach suggested in recent publications. It is focused on the development of an optical arrangement and mathematical model for the lubrication film thickness measurement within the entire EHD contact. This technique brings the possibility to study the pressure distribution within the contact area through the evaluation of changes in lubricant refractive index.

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第17788号 / 工博第3767号 / 新制||工||1576(附属図書館) / 30595 / 京都大学大学院工学研究科航空宇宙工学専攻 / (主査)教授 斧 髙一, 教授 木村 健二, 教授 立花 明知 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第19185号 / 工博第4062号 / 新制||工||1627(附属図書館) / 32177 / 京都大学大学院工学研究科航空宇宙工学専攻 / (主査)教授 斧 髙一, 教授 木村 健二, 教授 立花 明知 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

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<p>Cuprous oxide (Cu₂O) has recently been proposed as a promising solid-state host for ex-<br> citonic Rydberg states with large principal quantum numbers (n) whose exaggerated wave-<br> function sizes (∝ n²) facilitate gigantic, resonant dipole-dipole (∝ n⁴) and van der Waals<br> (∝ n¹¹) interactions, making them an ideal basis for solid-state Rydberg physics and quan-<br> tum technology. Synthetic, thin-film Cu₂O samples are of particular interest because they<br> can be made defect-free via carefully controlled fabrication and are, in principle, suitable<br> for the observation of extreme single-photon nonlinearities caused by Rydberg blockade. In<br> this work, we present the development of a spectroscopy experiment for characterizing the<br> behavior of Rydberg excitons and use it to study a synthetic thin film of Cu₂O grown on a<br> transparent substrate. We present evidence for the presence of states up to n = 8 and conduct<br> the first temperature-dependent study of Rydberg excitons in a thin film. We also propose<br> a technique for studying Rydberg-Rydberg interactions via the creation of high exciton den-<br> sities and establish a set of rate equations for modeling the processes by which excitons are<br> created, interact with each other, and decay. Finally, we conclude with a discussion of the<br> project’s outlook, as well as what future work will be undertaken to study the interactions<br> between Rydberg excitons and utilize them in scalable, integrable, Rydberg-based quantum<br> devices.<br> </p>

The O9IV star HD 57682, discovered to be magnetic within the context of the Magnetism in Massive Stars (MiMeS) survey in 2009, is one of only eight convincingly detected magnetic O-type stars. Among this select group, it stands out due to its sharp-lined photospheric spectrum. Since its discovery, the MiMeS Collaboration has continued to obtain spectroscopic and magnetic observations in order to refine our knowledge of its magnetic field strength and geometry, rotational period and spectral properties and variability. In this paper we report new Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) spectropolarimetric observations of HD 57682, which are combined with previously published ESPaDOnS data and archival Hα spectroscopy. This data set is used to determine the rotational period (63.5708 ± 0.0057 d), refine the longitudinal magnetic field variation and magnetic geometry (dipole surface field strength of 880 ± 50 G and magnetic obliquity of 79° ± 4° as measured from the magnetic longitudinal field variations, assuming an inclination of 60°) and examine the phase variation of various lines. In particular, we demonstrate that the Hα equivalent width undergoes a double-wave variation during a single rotation of the star, consistent with the derived magnetic geometry. We group the variable lines into two classes: those that, like Hα, exhibit non-sinusoidal variability, often with multiple maxima during the rotation cycle, and those that vary essentially sinusoidally. Based on our modelling of the Hα emission, we show that the variability is consistent with emission being generated from an optically thick, flattened distribution of magnetically confined plasma that is roughly distributed about the magnetic equator. Finally, we discuss our findings in the magnetospheric framework proposed in our earlier study.