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Conductivity studies of beta-aluminaHunter, Catherine C. January 1981 (has links)
The a.c. conductivity of the solid electrolyte beta-alumina with blocking Au electrodes has been examined by complex plane analysis using the complex impedance (Z*), admittance (A*), modulus (M*) and permittivity (epsilon*) formalisms. The electrode response which gives rise to the characteristic "spikes" in the Z* plots is attributed to a highly resistive layer on the surface of beta-alumina. This is found on single crystal and polycrystalline materials, and is sensitive both to the effects of polishing and the uptake of water vapour. Water vapour does not affect the bulk properties. For the first time, both the conductivity and the modulus spectra of single crystal beta"-alumina have been reported. It is confirmed that beta"-alumina has a much higher activation energy (~27kJ/mole) than beta-alumina (16.0kj/mole) and thus has a lower conductivity at lower temperatures (100°C). On this basis, an attempt has been made to explain the behaviour of the (commercial) polycrystalline sinters which are mixtures of beta and beta" phases. While the grain boundary activation energy remains constant at ~ 26kJ/mole, the bulk activation energy varies with beta/beta" content. The mixtures of approx 50-70% beta" content have the lowest bulk activation energy. These effects may be related in some way to the method of charge compensation, and in particular to the interstitial oxygen content (Oi2-). A "mixed-alkali" effect has been discovered in Na/Ag beta-aluminas which is remarkably similar to the effects found in glass. Both conductance minima and modulus (M") peak "narrowing" are observed. The results add some support to the weak electrolyte theory of beta-alumina, and also offer an interesting new exception to Jonscher's "universal" dielectric behaviour.
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Biodiversity in human-modified landscapes : case studies, the state of research, and implications for conservationTrimble, Morgan Jayne January 2014 (has links)
Protected areas (PAs) cover 12.9% of Earth’s land, while just 5.8% has strict protection for
biodiversity (Earth’s variety of ecosystems, species, and genetic variation). Constraints of
size and configuration, mismanagement, anthropogenic pressure, and climate change
hamstring the capacity of PAs to conserve biodiversity. Increasingly, studies of
biodiversity in human-modified landscapes provide an evidence base to support policies to
make land outside of PAs as amenable as possible for biodiversity persistence.
I reviewed research on biodiversity in sub-Saharan Africa’s human-modified
landscapes within four ecosystem categorizations: rangelands, tropical forest, Cape Floristic Region, and urban and rural built environment. I found potential for humanmodified
landscapes to contribute to conservation across ecosystems. Available research
could guide policy-making; nonetheless, several issues require further investment, e.g.
research deficiencies, implementation strategies, and conflict with biodiversity.
I also conducted case studies that could support land-use planning in South Africa’s
coastal forest, part of a biodiversity hotspot. By comparing herpetofaunal communities
over a land-use gradient, I found old-growth forest harbored the highest richness and
abundance. Richness was low in sugar cane cultivation and degraded forest but substantial
in acacia woodland and eucalyptus plantation. Composition differed between natural and
anthropogenic vegetation types. Functional group richness decreased monotonically along
the gradient, driven by sensitivity of fossorial herpetofauna and vegetation-dwelling frogs.
Environmental variables were good predictors of frog abundance, but less so for reptiles.
Maintaining forest and preventing degradation is important for herpetofaunal conservation
while restoration and plantations have more value than cultivation.
Old-growth remnants and post-disturbance regenerating vegetation also provide
habitat for birds. However, occurrence does not ensure persistence. I calculated population
trends for 37 bird species and general trends in overall bird density in different vegetation types. Seventy-six percent of species assessed have declined, 57% significantly so at an
average rate of 13.9% per year. Overall, bird density fell at 12.2% per year across
vegetation types. Changes in rainfall, habitat area, and survey coverage may partly explain
trends. However, species with larger range extents declined more sharply than others and
may be responding to environmental changes on a broad scale. These results cast doubt on
the future persistence of birds in this human-modified landscape and justify further study. Such studies can support sensible land-use management; however, biases in study
topics should not lead to gaps in the evidence base. By reviewing the global literature, I
demonstrated clear geographical bias among biomes and geopolitical regions and
taxonomic bias among species groups. Furthermore, distribution of published papers did
not generally reflect threats of low PA coverage, high land conversion, and high human
population density. Forests were the subject of 87% of papers, and 75% focused on the
Americas and Europe, while Africa and Asia were critically understudied.
This thesis highlights that managing human-modified landscapes for biodiversity
could contribute to conservation. However, responses to land uses are complex, locationand
species-specific, and often poorly understood, hindering integration of information into
policy recommendations. Further research is needed to elucidate what, where, and how
biodiversity persists alongside humans to enhance conservation efficacy, especially in
understudied regions. / Thesis (PhD)--University of Pretoria, 2014. / gm2014 / Zoology and Entomology / unrestricted
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The state of network research / Tillståndet för nätverksforskningZhu, Haoyu January 2020 (has links)
In the past decades, networking researchers experienced great changes. Being familiar with the development of networking researches is the first step for most scholars to start their work. The targeted areas, useful documents, and active institutions are helpful to set up the new research. This project is focused on developing an assistant tool based on public accessed papers and information on the Internet that allows researchers to view most cited papers in networking conferences and journals. NLP tools are implemented over crawled full-text in order to classify the papers and extract the keywords. Papers are located based on authors to show the most active countries around the world that are working in this area. References are analyzed to view the most cited topics and detailed paper information. We draw some interesting conclusions from our system, showing that some topics attract more attention in the past decades. / Under de senaste decennierna upplevde nätverksundersökningar stora förändringar. Att känna till utvecklingen av nätverksundersökningar är det första steget för de flesta forskare att starta sitt arbete. De riktade områdena, användbara dokument och aktiva institutioner är användbara för att skapa den nya forskningen. Projektet fokuserade på att utveckla ett assistentverktyg baserat på offentliga åtkomstpapper och information via internet. Som gör det möjligt för forskare att se de mest citerade artiklarna i nätverkskonferenser och tidskrifter. NLP- verktyg implementeras över genomsökt fulltext för att klassificera papperet och extrahera nyckelorden. Artiklar är baserade på författare för att visa de mest aktiva länderna runt om i världen som arbetar inom detta område. Hänvisningar analyseras för att se det mest citerade ämnet och detaljerad pappersinformation. Vi drar några intressanta slutsatser från vårt system och visar att något ämne inte lockar till sig mer under de senaste decennierna.
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Biophysical studies of cholesterol in unsaturated phospholipid model membranesWilliams, Justin A. January 2013 (has links)
Indiana University-Purdue University Indianapolis (IUPUI) / Cellular membranes contain a staggering diversity of lipids. The lipids are heterogeneously
distr
ibuted to create regions, or domains, whose physical properties differ from the bulk
membrane and play an essential role in modulating the function of resident proteins. Many
basic questions pertaining to the formation of these lateral assemblies remain. T
his research
employs model membranes of well
-
defined composition to focus on the potential role of
polyunsaturated fatty acids (PUFAs) and their interaction with cholesterol (chol) in restructuring
the membrane environment. Omega
-
3 (n
-
3) PUFAs are the main
bioactive components of fish
oil, whose consumption alleviates a variety of health problems by a molecular mechanism that is
unclear. We hypothesize that the incorporation of PUFAs into membrane lipids and the effect
they have on molecular organization may be, in part, responsible. Chol is a major constituent in
the plasma membrane of mammals. It determines the arrangement and collective properties of
neighboring lipids, driving the formation of domains via differential affinity for different lipids
. T
he m
olecular organization of 1
-[
2
H
31
]palmitoyl
-2-
eicosapentaenoylphosphatidylcholine (PEPC
-
d
31
) and 1
-[
2
H
31
]palmitoyl
-2-
docosahexaenoylphosphatidylcholine (PDPC
-d
31
) in membran
es with
sphingomyelin (SM) and chol (1:1:1 mol) was compared
by solid
-
state
2
H NMR spectroscopy.
Eicosapentaenoic (EPA) and docosahexaenoic (DHA) acids are the two major n
-
3 PUFAs found in
fish oil, while PEPC
-d
31
and PDPC
-d
31
are phospholipids containing the respective PUFAs
at the
sn
-
2 position and a perdeuterated palmitic acid a
t the sn
-
1 position
.
Analysis of s
pectra
recorded as a function of temperature indicate
s
that in both cases, formation of PUFA
-
rich (less
ordered) and SM
-
rich (more ordered) domains occurred. A surprisingly substantial proportion of
PUFA was found to infil
trate the more ordered domain. There was almost twice as much DHA
(65%) as EPA (30%)
. The implication is
that n
-
3 PUFA
s
can incorporate
into lipid rafts, which
are
domains
enriched in SM and chol in the plasma membrane,
and
potentially
disrupt the activity of signaling proteins that reside therein. DHA, furthermore, may be the more potent component
of fish oil.
PUFA
-
chol interactions were also examined through affinity measurements. A novel method
utilizing electron paramagnetic resonance (EPR) was develope
d, to monitor
the partitioning of a
spin
-
labeled
analog
of chol
, 3β
-
doxyl
-
5α
-
cholestane (chlstn), between large unilamellar vesicles
(LUVs) and met
hyl
-
β
-
cyclodextrin (mβCD). The EPR spectra for
chlstn in the two environments
are distinguishable due to the substantial differences in tumbling rates
, allowing
the
population
distribution
ratio to
be determined by spectral simulation. Advantages of this approach include
speed of implementation and a
vo
idance of potential
artifact
s associated with
physical
separation of LUV and mβCD
. Additionally, in a check of the method, t
he relative partition
coefficients between lipids measured for the spin label analog agree with values obtained for
chol by isothermal titration calorimetry (ITC). Results from LUV with different composition
confirmed
a hierarchy of
decreased
sterol affinity for phospholipids with increasing
acyl chain
unsaturation
, PDPC possessing half the affinity of the corresponding monounsaturated
phospholipid.
Taken together, the results of
these studies
on model membranes demonstrate the potential for
PUFA
-
driven alteration of the architecture of biomembranes, a mechanism through which
human health may be impacted.
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Factors Influencing Indiana Residents' Level of Interest in Engaging with Purdue UniversityAshley E Rice (6615803) 15 May 2019 (has links)
The land-grant university system was founded in the 19th century as a public means to help improve people’s everyday lives. A century and a half later, the challenges that the public faces to live a quality life are constantly changing, creating a need for the land-grant system to respond and adapt to continue to fulfill its mission. While the literature contains a wealth of conceptual papers addressing the role and mission of land-grant universities, relatively few papers could be found that reported empirical data or proposed and tested metrics for public engagement constructs. The current study sought to address this void in the literature through the investigation of factors influencing Indiana residents’ level of interest in engaging with Purdue University. Mail survey methods were used in which up to three contacts were made with adult members of 4,500 Indiana households identified through address-based sampling. Stratified random sampling was employed to ensure adequate rural household participation for other project purposes. Usable responses were received from 1,003 households representing 87 Indiana counties for a total response rate of 26%. <br><div><br> </div><div> A theoretical perspective was developed from Public Sphere Theory and the social science writings of Jurgen Habermas and Alexis de Tocqueville. Descriptive findings revealed some to moderate concerns about community and social issues such as affordable health care, violent crime, pollution and prescription drug abuse. Moderate levels of anomie, or perceived social disconnectedness, were also reported by respondents. Several items tapped respondents’ past levels of interaction with and current perceptions of Purdue University. Nearly a fifth of respondents reported interacting with Purdue University by having visited a website for news or information, followed by interacting with a Purdue University Extension professional. Regarding perceptions of Purdue University, the results of this study revealed relative consensus among respondents that Purdue University makes a positive contribution to the state of Indiana through its educational, research and outreach programs. For a majority of the perceptual items regarding Purdue University, more than one-third of the respondents neither agreed nor disagreed with the statement, suggesting some areas in which the university might improve its reputational standing with Indiana residents in the future. Nearly one-quarter to about half of the respondents indicated interest in topical areas addressed by Purdue Extension programs as well as an interest in engaging with the university. Respondents reported the highest levels of interest in free Extension programs in their local area, followed by the topics of science and technology, health and well-being, and gardening.</div><div><br> </div><div> A predictive model of respondent interest in engaging with Purdue University was developed and tested using binary logistic regression procedures. The model was shown to be of modest utility in accounting for variance in respondent interest in engaging with Purdue University, explaining 12% to 16% of total variance. Past interaction with Purdue University, perceived level of concern for social and community issues, and highest level of education were the strongest predictors in the model.</div><div><br> </div><div> The current research was completed in 2019 as Purdue University celebrated its 150th anniversary. Results and implications of this study provide important insight into current engagement levels, concerns and perceptions of residents within the state of Indiana, whom the university is mandated to serve. One of the study’s primary contributions is the establishment of baseline engagement data on current levels of Indiana residents’ interest in engaging with Purdue University on selected topics. Findings from this study could be of benefit to university administrators, faculty, staff and Extension professionals in assessing and improving future programming and setting strategic priorities. This study also adds to the conceptual and empirical body of literature, which may help inform future public engagement efforts at other land-grant universities. Periodic social science and public opinion research is needed to keep pace with the changing needs and perceptions of Indiana residents. Different data collection modes should be utilized to reach more audience segments and add to the growing knowledge base of public engagement.</div>
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