In both the chemical and mechanical pulping process, the logs are cut into wood chips by a disc chipper before fibre separation. To make the wood chipping process more efficient, one have to investigate in detail the coupling between process parameters and the quality of the chips. One objective of this thesis was to obtain an understanding of the fundamental mechanisms behind the creation of wood chips. Another objective with the thesis was to investigate whether it was possible to, in a way tailor the chipping process so as to reduce the energy consumption in a following mechanical refining process. Both experimental and analytical/numerical approaches have been taken in this work. The first part of the experimental investigations, were performed with an in-house developed chipping device and a digital speckle photography equipment. The results from the experimental investigation showed that the friction between the log and chipping tool is probably one crucial factor for the chip formation. Further more it was found that the indentation process is approximately self-similar, and that the stress field over the entire crack-plane is critical for chip creation. The developed analytical model predicts the normal and shear strain distribution and to be more specific, the model can predict the compressive stresses parallel to the fibre direction for an assumed linear elastic and orthotropic material. The analytical distributions were found to be in reasonable agreement with the corresponding distributions obtained from a finite element analysis. To be able to study the chipping process under realistic conditions, which for example means to use chipping rates representative for a real wood chipper, a laboratory chipper was developed. Details regarding the chipper and how to evaluate the force measurements are given together with an example of how the force on the cutting tool (the knife) varies with time during cutting. To investigate the influence of a certain chipping process parameter, the chips were after production in the laboratory chipper, refined in a pilot refiner during conditions optimized for TMP (thermomechanical pulp) and CTMP (chemithermomechanical pulp) processes. It was concluded that the details concerning the chip process had a large impact on e.g. the energy consumption in both first stage and second stage refining. Results showing this are given in this thesis. / För både kemisk och mekanisk pappersmassa så tillverkas flis av trädstockar med hjälp av en skivhugg innan fibrerna separeras. För att göra flisningsprocessen mer effektiv, måste kopplingen mellan processparametrar och fliskvalitet studeras. Ett mål med denna avhandling är att ge fundamental kunskap om mekanismerna bakom bildandet av träflis. Både experimentella och analytiska/numeriska metoder har använts i detta arbete. De experimentella undersökningarna har gjorts med hjälp av egen utvecklad utrustning. Resultaten från den experimentella undersökningen visar att friktionen mellan stammen och flisningsverktyget har betydelse vid flisning. Vidare observerades det att inträngnings processen är approximativt självlik (self similar) och att det är spänningsfältet över hela sprickplanet som är kritiskt för bildandet av en flis. Den utvecklade analytiska modellen förutsäger normal- och skjuvspänningsfördelningen över sprickplanet och kan mer specifikt förutsäga den kompressiva belastning som verkar parallellt fiberriktningen i ett linjärt elastiskt och ortotropt material (trä). De analytiskt bestämda fördelningarna stämmer relativt väl överens med motsvarande fördelningar beräknad med finit element analys. För att kunna studera flisningsprocessen under realistiska förhållanden, vilket bl.a. betyder att skärhastigheter som är representativa för en verklig process skall användas, så utvecklades inom ramen för avhandlingsarbetet, en laboratoriesflishugg. Detaljer rörande flishuggen samt hur uppmätta lastsignaler skall utvärderas ges tillsammans med ett exmpel på hur kraften på skärverktyget (kniven) varierar under ett skärförlopp. Inverkan av en viss flisningsprocessparameter undersöktes genom att flis tillverkades i laboratorieflishuggen varefter de raffinerades i en pilotraffinör under förhållanden som var optimerade för TMP (termomekanisk massa) och CTMP (kemitermomekanisk massa) processerna. Det konstaterades att detaljer i flisningsprocessen hade stor inverkan på t.ex. energiåtgången i både första stegs – och andrastegsraffinering. Resultat som verifierar detta ges i avhandlingen. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 4: Submitted. Paper 5: Submitted.</p>

Mechanical pulps are used in paper products such as magazine or news grade printing papers or paperboard. Mechanical pulping gives a high yield; nearly everything in the tree except the bark is used in the paper. This means that mechanical pulping consumes much less wood than chemical pulping, especially to produce a unit area of printing surface. A drawback of mechanical pulp production is the high amounts of electrical energy needed to separate and refine the fibers to a given fiber quality. Mechanical pulps are often produced from slow growing spruce trees of forests in the northern hemisphere resulting in long, slender fibers that are well suited for mechanical pulp products. These fibers have large varieties in geometry, mainly wall thickness and width, depending on seasonal variations and growth conditions. Earlywood fibers typically have thin walls and latewood fibers thick. The background to this study was that a more detailed fiber characterization involving evaluations of distributions of fiber characteristics, may give improved possibilities to optimize the mechanical pulping process and thereby reduce the total electric energy needed to reach a given quality of the pulp and final product. This would result in improved competitiveness as well as less environmental impact. This study evaluated the relation between fiber characteristics in three types of mechanical pulps made from Norway spruce (Picea abies), thermomechanical pulp(TMP), stone groundwood pulp (SGW) and chemithermomechanical pulp (CTMP). In addition, the influence of fibers from these pulp types on sheet characteristics, mainly tensile index, was studied. A comparatively rapid method was presented on how to evaluate the propensity of each fiber to form sheets of high tensile index, by the use of raw data from a commercially available fiber analyzer (FiberLabTM). The developed method gives novel opportunities of evaluating the effect on the fibers of each stage in the mechanical pulping process and has a potential to be applied also on‐line to steer the refining and pulping process by the characteristics of the final pulp and the quality of the final paper. The long fiber fraction is important for the properties of the whole pulp. It was found that fiber wall thickness and external fibrillation were the fibercharacteristics that contributed the most to tensile index of the long fiber fractions in five mechanical pulps (three TMPs, one SGW, one CTMP). The tensile index of handsheets of the long fiber fractions could be predicted by linear regressions using a combination of fiber wall thickness and degree of external fibrillation. The predicted tensile index was denoted BIN, short for Bonding ability INfluence. This resulted in the same linear correlation between BIN and tensile index for 52 samples of the five mechanical pulps studied, each fractionated into five streams(plus feed) in full size hydrocyclones. The Bauer McNett P16/R30 (passed 16 meshwire, retained on a 30 mesh wire) and P30/R50 fractions of each stream were used for the evaluation. The fibers of the SGW had thicker walls and a higher degree of external fibrillation than the TMPs and CTMP, which resulted in a correlation between BIN and tensile index on a different level for the P30/R50 fraction of SGW than the other pulp samples. A BIN model based on averages weighted by each fiber´s wall volume instead of arithmetic averages, took the fiber wall thickness of the SGW into account, and gave one uniform correlation between BIN and tensile index for all pulp samples (12 samples for constructing the model, 46 for validatingit). If the BIN model is used for predicting averages of the tensile index of a sheet, a model based on wall volume weighted data is recommended. To be able to produce BIN distributions where the influence of the length or wall volume of each fiber is taken into account, the BIN model is currently based on arithmetic averages of fiber wall thickness and fibrillation. Fiber width used as a single factor reduced the accuracy of the BIN model. Wall volume weighted averages of fiber width also resulted in a completely changed ranking of the five hydrocyclone streams compared to arithmetic, for two of thefive pulps. This was not seen when fiber width was combined with fiber wallthickness into the factor “collapse resistance index”. In order to avoid too high influence of fiber wall thickness and until the influence of fiber width on BIN and the measurement of fiber width is further evaluated, it is recommended to use length weighted or arithmetic distributions of BIN and other fiber characteristics. A comparably fast method to evaluate the distribution of fiber wall thickness and degree of external fibrillation with high resolution showed that the fiber wallthickness of the latewood fibers was reduced by increasing the refining energy in adouble disc refiner operated at four levels of specific energy input in a commercial TMP production line. This was expected but could not be seen by the use of average values, it was concluded that fiber characteristics in many cases should be evaluated as distributions and not only as averages. BIN distributions of various types of mechanical pulps from Norway spruce showed results that were expected based on knowledge of the particular pulps and processes. Measurements of mixtures of a news‐ and a SC (super calendered) gradeTMP, showed a gradual increase in high‐BIN fibers with higher amounts of SCgrade TMP. The BIN distributions also revealed differences between the pulps that were not seen from average fiber values, for example that the shape of the BINdistributions was similar for two pulps that originated from conical disc refiners, a news grade TMP and the board grade CTMP, although the distributions were on different BIN levels. The SC grade TMP and the SC grade SGW had similar levels of tensile index, but the SGW contained some fibers of very low BIN values which may influence the characteristics of the final paper, for example strength, surface and structure. This shows that the BIN model has the potential of being applied on either the whole or parts of a papermaking process based on mechanical or chemimechanical pulping; the evaluation of distributions of fiber characteristics can contribute to increased knowledge about the process and opportunities to optimize it.

Membrane filtration processes are widely utilized across different industrial sectors for biological and environmental separations. Examples of the former are sterile filtration and protein fractionation via microfiltration (MF) and ultrafiltration (UF) while drinking water treatment, tertiary treatment of wastewater, water reuse and desalination via MF, UF, nanofiltration (NF) and reverse-osmosis (RO) are examples of the latter. A common misconception is that the performance of membrane separation is solely dependent on the membrane pore size, whereas a multitude of parameters including solution conditions, solute concentration, presence of specific ions, hydrodynamic conditions, membrane structure and surface properties can significantly influence the separation performance and the membrane’s fouling propensity. The conventional approach for studying filtration performance is to use a single lab- or pilot-scale module and perform numerous experiments in a sequential manner which is both time-consuming and requires large amounts of material. Alternatively, high-throughput (HT) techniques, defined as the miniaturized version of conventional unit operations which allow for multiple experiments to be run in parallel and require a small amount of sample, can be employed. There is a growing interest in the use of HT techniques to speed up the testing and optimization of membrane-based separations. In this work, different HT screening approaches are developed and utilized for the evaluation and optimization of filtration performance using flat-sheet and hollow-fiber (HF) membranes used in biological and environmental separations. The effects of various process factors were evaluated on the separation of different biomolecules by combining a HT filtration method using flat-sheet UF membranes and design-of-experiments methods. Additionally, a novel HT platform was introduced for multi-modal (constant transmembrane pressure vs. constant flux) testing of flat-sheet membranes used in bio-separations. Furthermore, the first-ever HT modules for parallel testing of HF membranes were developed for rapid fouling tests as well as extended filtration evaluation experiments. The usefulness of the modules was demonstrated by evaluating the filtration performance of different foulants under various operating conditions as well as running surface modification experiments. The techniques described herein can be employed for rapid determination of the optimal combination of conditions that result in the best filtration performance for different membrane separation applications and thus eliminate the need to perform numerous conventional lab-scale tests. Overall, more than 250 filtration tests and 350 hydraulic permeability measurements were performed and analyzed using the HT platforms developed in this thesis. / Thesis / Doctor of Philosophy (PhD) / Membrane filtration is widely used as a key separation process in different industries. For example, microfiltration (MF) and ultrafiltration (UF) are used for sterilization and purification of bio-products. Furthermore, MF, UF and reverse-osmosis (RO) are used for drinking water and wastewater treatment. A common misconception is that membrane filtration is a process solely based on the pore size of the membrane whereas numerous factors can significantly affect the performance. Conventionally, a large number of lab- or full-scale experiments are performed to find the optimum operating conditions for each filtration process. High-throughput (HT) techniques are powerful methods to accelerate the pace of process optimization—they allow for multiple experiments to be run in parallel and require smaller amounts of sample. This thesis focuses on the development of different HT techniques that require a minimal amount of sample for parallel testing and optimization of membrane filtration processes with applications in environmental and biological separations. The introduced techniques can reduce the amount of sample used in each test between 10-50 times and accelerate process development and optimization by running parallel tests.