A novel design of hybrid thermal energy storage (HTES) using Phase Change Material (PCM) was evaluated using a mathematical model. Both single and multi-tank (cascaded) storage were explored to span small to large-scale applications (200-1600 litres). The storage element was based on the concept of a fully-mixed modular tank which is charged and discharged indirectly using two immersed coil heat exchangers situated at the bottom and top of the tank. A three-node model was developed to simulate different thermal behaviors during the operation of the storage element. Experiments were conducted on full-scale 200-l single-tank sensible heat storage (SHS) and hybrid thermal energy storage (HTES) to provide validation for the mathematical model. The HTES incorporated rectangular PCM modules submerged in the water tank. Satisfactory agreement was found between the numerical results and the experimental results obtained by Mather (2000) on single and multi-tank SHS. In addition, good agreement was noticed with the experiments performed by the author on single-tank SHS and HTES at McMaster University. The developed model was found to provide high levels of accuracy in simulating different operation conditions of the proposed design of storage element as well as computational efficiency. A parametric study was undertaken to investigate the potential benefits of the HTES over the SHS, operating under idealistic conditions. The HTES can perform at least two times better than the SHS with the same volume. The PCM volume fraction, melting temperature and properties were found to have critical impact on the storage gains of the HTES. All the parameters must be adjusted such that: (1) the thermal resistance of the storage element is minimized, and (2) most of the energy exchange with the storage element takes place in the latent heat form. The performance of the single-tank HTES was evaluated numerically while operating in a solar thermal domestic hot water (DHW) system for a single-family residence. The PCM parameters were selected to maximize the solar fraction during the operation on a typical spring day in Toronto. The use of the HTES can reduce the tank volume by 50% compared to the matched size of the SHS tank. However, the HTES was found to underperform the SHS when the system was operated in different days with different solar irradiation intensities. The effect of different draw patterns was also investigated. The results indicated that thermal storage is needed only when the energy demand is out-of-phase with the energy supply. For the same daily hot water demand, different consumption profiles; ex. dominant morning, dominant evening, dominant night and dispersed consumptions, showed slight impact on the performance of the system. The concept of multi-tank (cascaded) HTES storage was explored for medium/large scale solar heating applications such as for restaurants, motels, and multi-family residences. The design was based on the series connection of modular tanks through the bottom and top heat exchangers. Each individual tank had a PCM with different melting temperature. The results showed that the cascaded storage system outperformed the single-tank system with the same total volume as a result of the high levels of sequential or tank-to-tank stratification. The use of the cascaded HTES resulted in slight improvement in the solar fraction of the system. / Thesis / Doctor of Philosophy (PhD)

In hot climate areas, the electrical load in a building spikes, but not by the same amount daily due to various conditions. In order to cover the hottest day of the year, large cooling systems are installed, but are not fully utilized during all hot summer days. As a result, the investments in these cooling systems cannot be fully justified. A solution for more optimal use of the building cooling system is presented in this dissertation using Cool Thermal Energy Storage (CTES) deployed at a district level. Such CTES systems are charged overnight and the cool charge is dispatched as cool air during the day. The integration of the CTES helps to downsize the otherwise large cooling systems designed for the hottest day of the year. This reduces the capital costs of installing large cooling systems. However, one important question remains - how much of the CTES should be charged during the night, such that the cooling load for the next day is fully met and at the same time the CTES charge is fully utilized during the day. The solution presented in this dissertation integrated the CTES with Photovoltaics (PV) power forecasting and building load forecasting at a district level for a more optimal charge/discharge management. A district comprises several buildings of different load profiles, all connected to the same cooling system with central CTES. The use of forecasting for both the PV and the building cooling load allows the building operator to more accurately determine how much of the CTES should be charged during the night, such that the cooling system and CTES can meet the cooling demand for the next day. Using this approach, the CTES would be optimally sized, and utilized more efficiently during the day. At the same time, peak load savings are achieved, thus benefiting an electric utility company. The district presented in this dissertation comprises PV panels and three types of buildings – a mosque, a clinic and an office building. In order to have a good estimation for the required CTES charge for the next day, reliable forecasts for the PV panel outputs and the electrical load of the three buildings are required. In the model developed for the current work, dust was introduced as a new input feature in all of the forecasting models to improve the models' accuracy. Dust levels play an important role in PV output forecasts in areas with high and variable dust values. The overall solution used both the PV panel forecasts and the building load forecasts to estimate the CTES charge for the next day. The presented method was tested against the baseline method with no forecasting system. Multiple scenarios were conducted with different cooling system sizes and different CTES capacities. Research findings indicated that the presented method utilized the CTES charge more efficiently than the baseline method. This led to more savings in the energy consumption at the district level. / Doctor of Philosophy / In hot weather areas around the world, the electrical load in a building spikes because of the cooling load, but not by the same amount daily due to various conditions. In order to meet the demand of the hottest day of the year, large cooling systems are installed. However, these large systems are not fully utilized during all hot summer days. As a result, the investments in these cooling systems cannot be fully justified. A solution for more optimal use of the building cooling system is presented in this dissertation using Cool Thermal Energy Storage (CTES) deployed at a district level. Such CTES systems are charged overnight and the cool charge is dispatched as cool air during the day. The integration of the CTES helps to downsize the otherwise large cooling systems designed for the hottest day of the year. This reduces the capital costs of installing large cooling systems. However, one important question remains - how much of the CTES should be charged during the night, such that the cooling load for the next day is fully met and at the same time the CTES charge is fully utilized during the day. The solution presented in this dissertation integrated the CTES with Photovoltaics (PV) power forecasting and building load forecasting at a district level for a more optimal charge/discharge management. A district comprises several buildings all connected to the same cooling system with central CTES. The use of the forecasting for both the PV and the building cooling load allows the building operator to more accurately determine how much of the CTES should be charged during the night, such that the cooling system and CTES can meet the cooling demand for the next day. Using this approach, the CTES would be optimally sized and utilized more efficiently. At the same time, peak load is lowered, thus benefiting an electric utility company.

Master of Science / Department of Mechanical and Nuclear Engineering / Donald L. Fenton / Emergency cooling systems are applied to any application where the loss of cooling results in damage to the product, loss of data, or equipment failure. Facilities using chilled water for cooling that experience an electrical power outage, even a small one, would cause the chiller to shut down for 20 minutes or more. If emergency cooling is not available, temperatures would continue to increase to dangerous levels, potentially damaging the facility. Examples of facilities that could be protected by having emergency cooling systems are data centers, hospitals, banks, control rooms, laboratories, clean rooms, and emergency shelters among others. This project addresses the current lack of information and methods needed to correctly design emergency cooling systems. Three application uses were investigated for the possible benefits of having emergency cooling systems. The software TRNSYS was used to simulate five typical emergency cooling systems for each of the three applications. The characteristics and differences of the systems developed from the simulations were then analyzed and documented. The five systems simulated include a pressurized chilled water tank (parallel), atmospheric chilled water tank (parallel and series), low temperature chilled water tank (parallel), and ice storage tank (series). Simulations showed that low temperature chilled water tanks were less stratified than regular chilled water tanks by approximately 10%. Simulations also showed that the differences between atmospheric and pressurized tanks were negligible. Each tank discharged energy in the same manner and managed to replenish itself in the same amount of time. Examination of the different system configurations showed that tanks in series with the thermal load have issues with recharging due to its inability to isolate itself from the thermal load. It was also observed that while low temperature chilled water and ice storage tanks had the potential of reducing the storage tank volume, the amount of time ragged cooling will last is decreased by at least a factor of two. The examination of the five systems produced the desired design methodologies needed to address the lack of information on emergency cooling systems. With the reported information designers can effectively engineer systems to meet their needs.

The increasing demand for energy in combination with a greater awareness for our environmental impact have encouraged the development of sustainable energy sources, including materials for energy storage. Latent heat thermal energy storage by the use of phase change material (PCM) have become an area of great interest. It is a reliable and efficient way to reduce energy consumption. PCMs store and release latent heat, which means that the material can absorb the excess of heat energy, save it and release it when needed. By introducing soy wax as a biobased PCM and apply it on textile, one can achieve a thermoregulation material to be used in buildings and smart textiles. By replacing the present most used PCM, paraffin, with soy wax one cannot only decrease the use of fossil fuel, but also achieve a less flammable material. The performance of soy wax PCM applied on a textile fabric have not yet been investigated but can be a step towards a more sustainable energy consumption. The soy wax may also broaden the application for PCM due to its low flammability. The aim is to develop an environmental friendly latent heat thermal energy storage material to be used within numerous application fields.

Concentrating solar power plants can integrate cost-effective thermal energy storage systems and thereby supply controllable power on demand, an advantage against other renewable technologies. Storage integration allows a solar thermal power plant to increase its load factor and to shift production to periods of peak demand. It also enables output firmness, providing stability to the power block and to the grid. Thus, despite the additional investment, storage can enhance the performance and economic viability of the plants. However, the levelized cost of electricity of these plants yet remains higher than for other technologies, so projects today are only viable through the provision of incentives or technology-specific competitive bid tenders. It is the variability of the solar resource, the myriad roles that storage can assume, and the complexity of enhancing the synergies between the solar field, the storage and the power block, what makes the development of adequate policy instruments, design and operation of these plants a challenging process. In this thesis a comprehensive methodology for the pre-design and analysis of concentrating solar power plants is presented. The methodology is based on a techno-economic modeling approach that allows identifying optimum trade-off curves between technical, environmental, and financial performance indicators. A number of contemporary plant layouts and novel storage and hybridization concepts are assessed to identify optimum plant configurations, in terms of component size and storage dispatch strategies. Conclusions highlight the relevance between the sizing of key plant components, the operation strategy and the boundaries set by the location. The interrelation between critical performance indicators, and their use as decisive parameters, is also discussed. Results are used as a basis to provide recommendations aimed to support the decision making process of key actors along the project development value chain of the plants. This research work and conclusions are primarily meant to set a stepping stone in the research of concentrating solar power plant design and optimization, but also to support the research towards understanding the value of storage in concentrating solar power plants and in the grid. / Koncentrerad solkraft erbjuder möjligheten att integrera kostnadseffektiv termisk energilagring och därmed behovsstyrd kraftkontroll. Detta är en viktig fördel jämfört med andra förnybara energiteknologier. Lagringsintegration tillåter solkraftsanläggningar att öka sin lastfaktor och skifta produktion till tider med största efterfrågan. Vidare möjliggör lagring fast elproduktion vilket leder till förbättrad nät- och kraftturbinstabilitet. Därför kan termisk lagring öka anläggningsprestanda och ekonomiskt värde trots ökande initiala kapitalkostnader. I termer av specifik elproduktionskostnad (LCOE) ligger koncentrerade solkraftsanläggningar med lagring fortfarande högre än andra kraftteknologier och anläggningsprojekt blir endast lönsamma genom subventionsmodeller eller teknologispecifika konkurrensutsatta anbudsförfaranden. Att hitta adekvata policylösningar och optimala design och operationsstrategier är en utmanande process eftersom det gäller att hitta rätt balans mellan variabel solinstrålning, lagring av energi och tid för produktion genom optimal design och operation av solmottagarfält, kraftblock och lagringskapacitet. I denna avhandling presenteras en omfattande metodik för pre-design och analys av koncentrerande solkraftverk. Metodiken baseras på en tekno-ekonomisk modelleringsansats som möjliggör identifiering av optimala avvägningssamband för tekniska, ekonomiska och miljöprestanda indikatorer. Metodiken tillämpas på ett antal moderna anläggningslayouter  och lagrings- och hybridiseringskoncept för att identifiera optimal kraftanläggningsdesign i termer av komponentprestanda och lagringsanvändningsstrategier. I slutsatsen poängteras relevansen av att hitta rätt storlek på nyckelkomponenter i relation till lagringsstrategi och randvillkoren som ges av konstruktionsläget för optimal ekonomisk och miljömässig prestanda. Resultaten används för att formulera rekommendationer till nyckelaktörer i beslutsprocessen genom hela kraftanläggningens värdekedja från politisk beslutsfattare till anläggningsingenjör. Forskningen och slutsatserna i detta arbete skall i första hand ta ett steg framåt för optimering och design av solkraftsanläggningar men även tillhandahålla en metodik för utvärdering av lagringslösningar och dess specifika värde för solkraftsanläggningar och elnätet. / <p>QC 20160829</p>

Concentrated solar power (CSP) has the potential of fulfilling the world’s electricity needs. Parabolic-trough system using synthetic oil as the HTF with operating temperature between 300 and 400o C, is the most matured CSP technology. A thermal storage system is required for the stable and cost effective operation of CSP plants. The current storage technology is the indirect two-tank system which is expensive and has high energy consumption due to the need to prevent the storage material from freezing. Latent heat storage (LHS) systems offer higher storage density translating into smaller storage size and higher performance but suitable phase change materials (PCMs) have low thermal conductivity, thus hindering the realization of their potential. The low thermal conductivity can be solved by heat transfer enhancement in the PCM. There is also lack of suitable commercially-available PCMs to cover the operating temperature range. In this study, a hybrid cascaded storage system (HCSS) consisting of a cascaded finned LHS and a high temperature sensible or concrete tube register (CTR) stages was proposed and analysed via modelling and simulation. Fluent CFD code and the Dymola simulation environment were employed. A validated CFD phase change model was used in determining the heat transfer characteristics during charging and discharging of a finned and unfinned LHS shell-and-tube storage element. The effects of various fin configurations were investigated and heat transfer coefficients that can be used for predicting the performance of the system were obtained. A model of the HCSS was then developed in the Dymola simulation environment. Simulations were conducted considering the required boundary conditions of the system to develop the best design of a system having a capacity of 875 MWhth, equivalent to 6 hours of full load operation of a 50 MWe power plant. The cascaded finned LHS section provided ~46% of the entire HCSS capacity. The HCSS and cascaded finned LHS section have volumetric specific capacities 9.3% and 54% greater than that of the two-tank system, respectively. It has been estimated that the capital cost of the system is ~12% greater than that of the two-tank system. Considering that the passive HCSS has lower operational and maintenance costs it will be more cost effective than the twotank system considering the life cycle of the system. There is no requirement of keeping the storage material above its melting temperature always. The HCSS has also the potential of even lower capital cost at higher capacities (>6 hours of full load operation).

Submitted by Silvana Teresinha Dornelles Studzinski (sstudzinski) on 2015-10-26T16:14:39Z No. of bitstreams: 1 Jutaí Juarez Estrázulas_.pdf: 1716303 bytes, checksum: ac095da5508e03eaab20ab1008f22067 (MD5) / Made available in DSpace on 2015-10-26T16:14:39Z (GMT). No. of bitstreams: 1 Jutaí Juarez Estrázulas_.pdf: 1716303 bytes, checksum: ac095da5508e03eaab20ab1008f22067 (MD5) Previous issue date: 2015-06-12 / CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Inúmeras aplicações residenciais, comerciais e industriais voltadas ao gerenciamento térmico tem seus custos operacionais reduzidos quando um sistema de armazenamento de energia térmica é incorporado. Tal tipo de sistema pode, por exemplo, absorver energia térmica oriunda de fonte solar, de reaproveitamento de calor de processo industrial ou mesmo proveniente de energia elétrica (nos horários em que esta é menos onerosa), e liberá-la em um horário em que estas fontes de calor não estejam presentes e em que a energia elétrica, se utilizada, seria mais onerosa.Os PCMs (Phase Change Materials), devido ao seu alto calor latente de fusão, são materiais que representam uma alternativa viável à implementação de sistemas de armazenamento de energia térmica. No entanto, inúmeros PCMs ainda não tiveram suas características e propriedades fluidodinâmicas investigadas suficientemente. Assim, este trabalho apresenta um estudo numérico da mudança de fasede PCMs da família RT,em cavidades cilíndricas, visando o armazenamento térmico de energia através de calor latente (LHTES). O estudo foi realizado através de simulação numérica por CFD, com o software ANSYS Fluent. O modelo numérico adotado é bidimensional e é composto pelas equações da conservação da massa, quantidade de movimento e energia. Além destas, foi utilizada a técnica de modelamento entalpia-porosidade. A malha computacional é do tipo hexaédrica, com refinamento junto às paredes da geometria e na região de interface entre o PCM e o ar. O modelo implementado foi validado com resultados numéricos e experimentais da literatura, obtendo-se bons resultados. Foi avaliado o processo de fusão de cinco diferentes tipos de PCMs (RT 4, RT 35, RT 35HC (alta capacidade), RT 55 e RT 82), cada um deles com três intervalos de temperatura (T=10, 20 e 30 °C).Além disto, para T=10 ºC, os PCMS RT 27, RT 35, RT 35 HC e RT 82 foram testados para cinco diferentes valores de constante C (Mushy Zone), totalizando trinta diferentes situações. Paraos PCMs RT 4, RT 35, RT55 e RT82, aumentando-se o T de 10 oC para 20 oC e de 10 oC para 30 oC, para frações líquidas entre 0,4 e 0,8, a redução média dos tempos de fusão foide, aproximadamente, 55,8% e 71,8% e os incrementos médios no fluxo de calor foram de 63% e 111 %, respectivamente. Para o RT35HC, as reduções médias nos tempos de fusão foram de 51,6% e de 67,8%, para a mesma faixa de fração líquidae mesmos T. O RT35HC, quando comparado com o RT 35, possui calor latente de fusão 41,1% maiore os seus tempos de fusão são entre 100% à 134% superiores, dependendo do T utilizado. / Several residential, commercial and industrial applications focused on thermal management have their operating costs reduced when a thermal energy storage system is incorporated to them. This type of system can provide, can, for example, absorb thermal energy from solar source, heat reuse from industrial process or even from electrical power (during the time this is less expensive) and release it at a time that these heat sources are not present and the electrical power, if used, would be more expensive.The Phase Change Materials (PCMs), due to their high latent heat of fusion, are materials that represent a viable alternative to the implementation of thermal energy storage systems. However, many PCMs have not had their characteristics and fluid dynamics properties sufficiently investigated. Thus, this paper presents a numerical study of RT phase change materials family, inside cylindrical cavities, aiming at the thermal energy storage trough latent heat (LHTES). The study was conducted through a CFD numerical simulation, with ANSYS Fluent software. The numeric model adopted is two-dimensional and is composed by mass conservation, movement amount and energy equations. In addition, the enthalpy-porosity modeling technique was used. The computational mesh is hexaedric, with refinement along the walls of geometry and at the interface area between the PCM and air. The model was validated with numerical and experimental results available in the literature, achieving good results. The fusion process of five different PCMs (RT 4, RT 35, RT 35 HC (high capacity), RT 55 and RT 82) was evaluated, each one of them with three temperature ranges (T= 10, 20 e 30 °C). Furthermore, for T=10 °C, the PCMs RT 27, RT 35, RT 35 HC and RT 82 were tested for five different values of C constant (Mushy Zone) totaling thirty different situations. For PCMs RT 4, RT 35, RT 55 and RT 82, increasing T from 10 oC to 20 oC and from 10 oC to 30 oC, for liquid fraction between 0,4 and 0,8, the average reduction in fusion time were, approximately, 55.8% and 71.8% and the average increase in heat flow were 63% and 111% respectively. For RT 35 HC, the average reductions in fusion time were 51.6% and 67.8% for the same liquid fraction range and same T. The RT 35 HC, when compared to RT 35, has latent heat of fusion 41.1% greater and its fusion times are between 100% to 134% greater, depending on T used.

abstract: Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for mitigating early-age cracking and freeze-and-thaw induced damage, have also been proposed. Hence, the focus of this dissertation is to develop a detailed understanding of the physic-chemical and thermo-mechanical characteristics of cementitious systems and novel coating systems for wall-elements containing PCM. The initial phase of this work assesses the influence of interface properties and inter-inclusion interactions between microencapsulated PCM, macroencapsulated PCM, and the cementitious matrix. The fact that these inclusions within the composites are by themselves heterogeneous, and contain multiple components necessitate careful application of models to predict the thermal properties. The next phase observes the influence of PCM inclusions on the fracture and fatigue behavior of PCM-cementitious composites. The compliant nature of the inclusion creates less variability in the fatigue life for these composites subjected to cyclic loading. The incorporation of small amounts of PCM is found to slightly improve the fracture properties compared to PCM free cementitious composites. Inelastic deformations at the crack-tip in the direction of crack opening are influenced by the microscale PCM inclusions. After initial laboratory characterization of the microstructure and evaluation of the thermo-mechanical performance of these systems, field scale applicability and performance were evaluated. Wireless temperature and strain sensors for smart monitoring were embedded within a conventional portland cement concrete pavement (PCCP) and a thermal control smart concrete pavement (TCSCP) containing PCM. The TCSCP exhibited enhanced thermal performance over multiple heating and cooling cycles. PCCP showed significant shrinkage behavior as a result of compressive strains in the reinforcement that were twice that of the TCSCP. For building applications, novel PCM-composites coatings were developed to improve and extend the thermal efficiency. These coatings demonstrated a delay in temperature by up to four hours and were found to be more cost-effective than traditional building insulating materials. The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2018

Though economically favorable when compared to other renewable energy storage technologies, thermal energy storage systems for concentrating solar thermal power (CSP) plants require additional cost reduction measures to help transition CSP plants to the point of grid-parity. Thermocline packed bed storage is regarded as one potential low cost solution due to the single tank requirement and low cost storage media. Thus sensible heat storage (SHS) and latent heat storage (LHS) packed bed systems, which are two thermocline varieties, are frequently investigated. LHS systems can be further classified as single phase change material (PCM) systems or cascaded systems wherein multiple PCMs are employed. This study compared the performance of SHS, single PCM, and cascaded PCM direct storage systems under the conditions that may be encountered in utility-scale molten salt CSP plants operating between 565°C and 288°C. A small-scale prototype SHS packed bed system was constructed and operated for use in validating a numerical model. The drawbacks of the latent heat storage process were discussed, and cascaded systems were investigated for their potential in mitigating the issues associated with adopting a single PCM. Several cascaded PCM configurations were evaluated. The study finds that the volume fraction of each PCM and the arrangement of latent heat in a 2-PCM and a 3-PCM system influences the output of the system, both in terms of quality and quantity of energy. In addition to studying systems of hypothetical PCMs, real salt PCM systems were examined and their selection process was discussed. A preliminary economic assessment was conducted to compare the cost of SHS, single-PCM LHS, cascaded LHS, and state-of-the-art 2-tank systems. To the author's knowledge, this is the first study that compares the cost of all three thermocline packed bed systems with the 2-tank design. The SHS system is significantly lower in cost than the remaining systems, however the LHS system does show some economic benefit over the 2-tank design. If LHS systems are to be viable in the future, low cost storage media and encapsulation techniques are necessary.

The objective of this study is to synthesize nanomaterials by mixing molten salt (alkali nitrate salt eutectics) with inorganic nanoparticles. The thermo-physical properties of the synthesized nanomaterials were characterized experimentally. Experimental results allude to the existence of a distinct compressed phase even for the solid phase (i.e., in the nanocomposite samples). For example, the specific heat capacity of the nanocomposites was observed to be enhanced after melting and re-solidification - immediately after their synthesis; than those of the nanocomposites that were not subjected to melting and re-solidification. This shows that melting and re-solidification induced molecular reordering (i.e., formation of a compressed phase on the nanoparticle surface) even in the solid phase - leading to enhancement in the specific heat capacity. Numerical models (using analytical and computational approaches) were developed to simulate the fundamental transport mechanisms and the energy storage mechanisms responsible for the observed enhancements in the thermo-physical properties. In this study, a simple analytical model was proposed for predicting the specific heat capacity of nanoparticle suspensions in a solvent. The model explores the effect of the compressed phase – that is induced from the solvent molecules - at the interface with individual nanoparticles in the mixture. The results from the numerical simulations indicate that depending on the properties and morphology of the compressed phase – it can cause significant enhancement in the specific heat capacity of nanofluids and nanocomposites. The interfacial thermal resistance (also known as Kapitza resistance, or “Rk”) between a nanoparticle and the surrounding solvent molecules (for these molten salt based nanomaterials) is estimated using Molecular Dynamics (MD) simulations. This exercise is relevant for the design optimization of nanomaterials (nanoparticle size, shape, material, concentration, etc.). The design trade-off is between maximizing the thermal conductivity of the nanomaterial (which typically occurs for nanoparticle size varying between ~ 20-30nm) and maximizing the specific heat capacity (which typically occurs for nanoparticle size less than 5nm), while simultaneously minimizing the viscosity of the nanofluid. The specific heat capacity of nitrate salt-based nanomaterials was measured both for the nanocomposites (solid phase) and nanofluids (liquid phase). The neat salt sample was composed of a mixture of KNO3: NaNO3 (60:40 molar ratio). The enhancement of specific heat capacity of the nanomaterials obtained from the salt samples was found to be very sensitive to minor variations in the synthesis protocol. The measurements for the variation of the specific heat capacity with the mass concentration of nanoparticles were compared to the predictions from the analytical model. Materials characterization was performed using electron microscopy techniques (SEM and TEM). The rheological behavior of nanofluids can be non-Newtonian (e.g., shear thinning) even at very low mass concentrations of nanoparticles, while (in contrast) the pure undoped (neat) molten salt may be a Newtonian fluid. Such viscosity enhancements and change in rheological properties of nanofluids can be detrimental to the operational efficiencies for thermal management as well as energy storage applications (which can effectively lead to higher costs for energy conversion). Hence, the rheological behavior of the nanofluid samples was measured experimentally and compared to that of the neat solvent (pure molten salt eutectic). The viscosity measurements were performed for the nitrate based molten salt samples as a function of temperature, shear rate and the mass concentration of the nanoparticles. The experimental measurements for the rheological behavior were compared with analytical models proposed in the literature. The results from the analytical and computational investigations as well as the experimental measurements performed in this proposed study – were used to formulate the design rules for maximizing the enhancement in the thermo-physical properties (particularly the specific heat capacity) of various molten salt based inorganic nanomaterials. The results from these studies are summarized and the future directions are identified as a conclusion from this study.