The objective of the research presented in this thesis is to validate the parallel-bonded modeling method in the context of coupled thermo-mechanical simulations. The simulation results were compared with analytical and experimental data, in the attempt to assess the usability of this particular modeling method. Previous studies of numerical approaches that related to the thermal fracturing of hard rock had used continuum-based models with constitutive relations. The simulations in the thesis were conducted using Particle Flow Code (PFC) which was chosen for the research because of its several benefits. The code has unique features such as spontaneous damage development without imposed conditions, and emergent properties such as material heterogeneity, and dynamic behavior giving possibility to monitor synthetic seismic events. The basic code has been available since 1995 and research using the code has produced hundreds of publications. The thermal option for the code is a recent addition and lacked verification, validation and applications. The thesis is the answer for that. In the course of the research work new particle clustering and grouping routines were developed and tested. Three modeling studies were conducted varying from laboratory to field scales. The 2D modeling study of the heated cylinder experiment yielded similar results both in fracture-behavioral and acoustic emission (AE) magnitude ranges when compared with the laboratory data. The 3D cubic numerical specimens, created with breakable particle clusters, were heated, and the induced damage was observed by P wave velocity measurements. The results showed trends comparable to the laboratory data: P wave velocity decreases with rising temperatures of up to 250°C and cluster-boundary cracking occurs, comparable to grain-boundary cracking in the heated rock samples. The large 2D tunnel models captured the phenomena observed in-situ displaying the difference in the damage to the roof and floor regions, respectively. This damage was due to the filling material confinement of about 100 kPa on the tunnel floor. In general, the results of the thermo-mechanical simulations were in accordance with the experimental data. The modeled temperature evolutions during the heating and cooling periods were also in accordance with the experimental and analytical data.

The objective of the research presented in this thesis is to validate the parallel-bonded modeling method in the context of coupled thermo-mechanical simulations. The simulation results were compared with analytical and experimental data, in the attempt to assess the usability of this particular modeling method. Previous studies of numerical approaches that related to the thermal fracturing of hard rock had used continuum-based models with constitutive relations. The simulations in the thesis were conducted using Particle Flow Code (PFC) which was chosen for the research because of its several benefits. The code has unique features such as spontaneous damage development without imposed conditions, and emergent properties such as material heterogeneity, and dynamic behavior giving possibility to monitor synthetic seismic events. The basic code has been available since 1995 and research using the code has produced hundreds of publications. The thermal option for the code is a recent addition and lacked verification, validation and applications. The thesis is the answer for that. In the course of the research work new particle clustering and grouping routines were developed and tested. Three modeling studies were conducted varying from laboratory to field scales. The 2D modeling study of the heated cylinder experiment yielded similar results both in fracture-behavioral and acoustic emission (AE) magnitude ranges when compared with the laboratory data. The 3D cubic numerical specimens, created with breakable particle clusters, were heated, and the induced damage was observed by P wave velocity measurements. The results showed trends comparable to the laboratory data: P wave velocity decreases with rising temperatures of up to 250°C and cluster-boundary cracking occurs, comparable to grain-boundary cracking in the heated rock samples. The large 2D tunnel models captured the phenomena observed in-situ displaying the difference in the damage to the roof and floor regions, respectively. This damage was due to the filling material confinement of about 100 kPa on the tunnel floor. In general, the results of the thermo-mechanical simulations were in accordance with the experimental data. The modeled temperature evolutions during the heating and cooling periods were also in accordance with the experimental and analytical data.

Cette thèse porte sur le thème général de la fiabilité des circuits microélectroniques. Le but de notre travail fut de développer un outil de simulation multi-physiques pour la conception des circuits intégrés fiables qui possède les caractéristiques innovatrices suivantes : • (i) L’intégration dans un environnement de conception microélectronique standard, tel que l’environnement Cadence® ; • (ii) La possibilité de simulation, sur de longues durées, du comportement des circuits CMOS analogiques en tenant compte du phénomène de vieillissement ; • (iii) La simulation de plusieurs physiques (électrique-thermique-mécanique) couplées dans ce même environnement de CAO en utilisant la méthode de simulation directe. Ce travail de thèse a été réalisé en passant par trois grandes étapes traduites par les trois parties de ce manuscrit. / This thesis was carried out under the theme of the microelectronics Integrated Circuits Reliability. The aim of our work was to develop a multi-physics simulation tool for the design of reliable integrated circuits. This tool has the following innovative features : • (i) The integration in a standard microelectronics design environment, such as the Cadence® environment ;• (ii) The possibility of efficient simulation, over long periods, of analog CMOS circuits taking into account the aging henomenon ; • (iii) The simulation of multiple physical behaviours of ICs (electrical-thermalmechanical) coupled in the same environment using the direct simulation method. This work was carried out through three main stages detailed in the three parts of this Manuscript.

[EN] Concrete filled steel tubular columns have many advantages in terms of bearing capacity, aesthetics, execution and fire resistance, thanks to the collaborative work of both materials steel and concrete. The effort made in the last decades to rise a high understanding of their behaviour subjected to different loads and assuming multiple variations has resulted in the wide spread of its use between the designers. Nonetheless, how to solve the connection with I-beams is still a handicap and requires a specific study. One of the most common and popular solution to connect open section steel beams (I-beams) to open section steel columns are endplate connections. In the cases of columns with hollow section, special fastenings are needed, which are able to be tightened from one external side and are denominated blind-bolts. Nowadays, there are several fastener systems that allow these types of connections. The characterization of their response and their capacity to support different loads is the objective of several investigations, where the geometrical definition and the material properties are crucial parameters. Despite the promising results of these connections at room temperature regarding their capability to resist bending moments, their performance is un-known at high temperatures. Therefore, the aim of this thesis is the study of the tensile behaviour of blind-bolts in endplate connections to concrete filled tubular columns at elevated temperatures and subjected to bending moment. Primarily, the research comprises the understanding of the pure thermal transfer problem. The temperature distribution through the connection section is obtained experimental and numerically. The thermal parameters that characterize the connections response are determined through the calibration of the numerical models with the experiments. Secondly, the blind-bolt capacity under pull out and at high temperatures is under analysis. During the fire the temperature increases while connection transmits loads from the beam to the column, the objective of this dissertation is to know how the mechanical response of the pulled blind-bolts changes under these conditions. Thus, the study of the material properties dependent on the temperature and their effect on the connection response is covered by the investigation. Furthermore, the influence of the concrete and the type of fastener is a highlighted aspect through the thermal and the fire analysis. Finally, the reliability of these connections to comply with requirements of 30 minutes fire exposure before the collapse is evaluated. As a result, valuable Finite Element models able to simulate the thermal and thermo-mechanical behaviour of the connection are developed, providing useful behavioural patterns of the blind-bolts. Among the main conclusions, it is noted the temperature reduction due to concrete core in concrete filled columns compared to hollow sections, in the exposed bolt surface means 100ºC less. Conversely, a longer bolt shank of the fastener system embedded in concrete has a negligible effect on the temperature of the resistant part of the bolt. Regarding the fire capacity, the concrete core in the steel tube columns presents significant benefits in terms of fire resistance time and connection stiffness. Besides, the bolt anchorage enhances the stiffness at elevated temperatures, however, the failure of the shank next to the bolt head causes that the anchorage does not mean an improvement on the fire time resistance. / [ES] Las columnas tubulares de acero rellenas de hormigón presentan múltiples ventajas en términos de capacidad de carga, estética, ejecución y resistencia al fuego, gracias a la acción combinada de acero y hormigón. El esfuerzo realizado en las últimas décadas por conocer su comportamiento frente a diferentes cargas y bajo distintos parámetros ha dado lugar a una amplia difusión de su uso entre los diseñadores. No obstante, la forma de resolver la conexión con vigas de sección en I sigue siendo un hándicap y requiere un estudio específico. Una de las soluciones más comunes y populares para conectar las vigas de acero de sección abierta (vigas I) a columnas de acero de sección abierta es la conexión con chapa de testa, que en el caso de sección hueca requiere de tornillos especiales denominados tornillos ciegos, puesto que reciben el par de apriete desde una cara de la sección. En la actualidad existen diversos sistemas de fijación que permiten este tipo de conexiones y cuya respuesta y caracterización es objeto de numerosas investigaciones. En este sentido, la definición geométrica de la unión y las propiedades de los materiales son parámetros cruciales en el rendimiento de la conexión. La presente tesis analiza el comportamiento de los tornillos ciegos en el área traccionada de conexiones de placa de testa a columnas tubulares de acero rellenas de hormigón sometidas a momentos de flexión y a elevadas temperaturas. Las prestaciones de esta solución constructiva para la unión viga-columna tubular, junto con la ausencia de datos relacionados con su comportamiento en situación de incendio la convirtió en el objetivo del trabajo. En primer lugar, la investigación aborda el problema de transferencia de calor, analizando experimental y numéricamente la distribución de temperaturas en la sección de la conexión. En esta parte del estudio se obtienen los parámetros térmicos que caracterizan la respuesta térmica de la conexión a través de la calibración de los modelos numéricos con los datos experimentales. En segundo lugar, se realiza el estudio de la capacidad de los tornillos ciegos para soportar cargas de tracción en situación de incendio, es decir, se analiza cómo cambia el comportamiento de la conexión con sus características alteradas debido a las altas temperaturas. El estudio de las propiedades del material en función de la temperatura y su efecto sobre la respuesta de la conexión constituyen una parte importante de la investigación. Además, se evalúa la influencia del hormigón y el tipo de elemento de sujeción tanto en el comportamiento mecánico como termo-mecánico de la conexión. Por último, se estudia la capacidad de las uniones para cumplir con requerimientos de exposición al fuego de 30 minutos previamente al colapso. Como resultado de este trabajo se obtuvieron modelos de elementos finitos capaces de simular la conexión térmica y termo-mecánicamente, proporcionando patrones de comportamiento de gran utilidad en el diseño de las mismas. Entre las principales conclusiones, se observó la reducción de la temperatura en los tornillos gracias al núcleo de hormigón en columnas de hormigón lleno en comparación con secciones huecas, que ya en la superficie expuesta del tornillo se cuantificaba en 100ºC menos. Por el contrario, los elementos de fijación que presentaban mayor longitud de vástago de tornillo embebida en el hormigón, no generaban un efecto significativo sobre la temperatura de la parte resistente del perno. En cuanto a la capacidad resistente frente a fuego, el núcleo de hormigón supuso una mejora en términos de rigidez y de tiempo de resistencia al fuego. Sin embargo, el fallo de los pernos en una sección próxima a la superficie expuesta redujo el efecto esperado del anclaje del tornillo, que si bien implicaba una mayor rigidez de la conexión, no parecía mejorar el tiempo de resistencia a fuego. Finalmente se planteó la necesidad de / [CAT] Els pilars tubulars d'acer omplerts de formigó (CFT) presenten molts avantatges en termes de capacitat de carrega, estètica, execució i resistència al foc, gràcies a l'acció combinada de l'acer i el formigó. L'esforç realitzat en les darreres dècades per conèixer el seu comportament enfront a diferents càrregues i sota distints paràmetres ha donat lloc a una amplia difusió del seu ús entre el dissenyadors. No obstant això, la manera de resoldre la connexió amb bigues de secció en I, continua sent un handicap i requereix d'un estudi específic. Una de les solucions més comuns i populars per a connectar les bigues d'acer de secció oberta (bigues I) a columnes d'acer de secció oberta és la connexió amb 'chapa de testa', que en el cas de la secció buida requereix de perns especials denominats perns cecs perquè es rosquen des d'una cara de la secció. En l'actualitat existeixen diversos sistemes de fixació que permeten aquest tipus de connexions, la resposta i caracterització dels quals es l'objectiu de nombroses recerques. En aquest sentit, la definició geomètrica de la unió i les propietats dels materials son paràmetres crucials en el rendiment de la connexió. Aquesta tesi analitza el comportament dels perns cecs en l'àrea traccionada de connexions de 'chapa de testa', a pilars tubulars d'acer omplerts de formigó, sotmeses a moments de flexió i a elevades temperatures. Les prestacions d'aquesta solució constructiva per a la unió biga-pilar tubular junt amb l'absència de dades relacionades amb el comportament en situació d'incendi, la van convertir en l'objectiu d'aquest treball. En primer lloc, la recerca aborda el problema de transferència de calor, analitzant tant experimental com numèricament la distribució de temperatures en la secció de la connexió. En aquesta part de l'estudi, s'obtenen el paràmetres tèrmics que caracteritzen la resposta tèrmica de la connexió mitjançant el calibratge del models numèrics amb les dades experimentals. En segon lloc, es realitza l'estudi de la capacitat dels perns cecs per a suportar càrregues de tracció en situació d'incendi, es a dir, s'analitza com canvia el comportament de la connexió amb les seues característiques alterades degut a les altes temperatures. L'estudi de les propietats del material en funció de la temperatura i el seu efecte en la resposta de la connexió formen també part de la recerca. Un contingut important d'aquest treball consisteix en determinar l'influencia del formigó i el tipus d'element de fixació tant en el comportament mecànic com termo-mecànic de la connexió. Per últim, s'estudia la capacitat de les unions per a complir amb els requeriments d'exposició al foc de 30 minuts prèviament al col·lapse. Com a resultat d'aquest treball s'obtingueren models d'elements finits amb capacitat per a simular el comportament tèrmic i termo-mecànic de la connexió, proporcionant patrons de comportament de gran utilitat en el disseny. Entre les principals conclusions, es va observar la reducció de la temperatura en els perns gràcies al nucli de formigó en pilars omplerts de formigó en comparació amb el pilars buits, on ja en la superfície esposada del cargol es quantificava en 100 ºC menys. Pel contrari, els elements de fixació que presentaven major longitud de embeguda en el formigó, no generaven un efecte significatiu en la temperatura de la part resistent del pern. En quant a la capacitat resistent davant del foc, el nucli de formigó va suposar una millora en termes de rigidesa i de temps de resistència al foc. Tanmateix, la fallada dels perns en una secció pròxima a la superfície esposada va reduir l'efecte esperat de la fixació del pern, que si be implicava una major rigidesa de la connexió, no semblava millorar el temps de resistència al foc. Finalment, es va plantejar la necessitat de aprofundir en l'anàlisi incorporant un major rang de paràmetres. / Pascual Pastor, AM. (2015). Fire behaviour of blind-bolted connections to concrete filled tubular columns under tension [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/53240 / TESIS

Duplex stainless steels can be very attractive alternatives to austenitic grades due to their almost double strength at equal pitting corrosion resistance. When welding, the duplex alloys normally require addition of filler metal, while the commodity austenitic grades can often be welded autogenously. Over-alloyed consumables are used to counteract segregation of important alloying elements and to balance the two phases, ferrite and austenite, in the duplex weld metal. This work focuses on the weldability of the recently-developed lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101). The pitting corrosion resistance of this grade is better than that of austenitic AISI 304 (EN 1.4307) and can reach the level of AISI 316L (EN 1.4404). The austenite formation is rapid in LDX 2101 compared to older duplex grades. Pitting resistance tests performed show that 1-2.5 mm thick laser and gas tungsten arc (GTA) welded LDX 2101 can have good corrosion properties even when welding autogenously. Additions of filler metal, nitrogen in the shielding gas, nitrogen-based backing gas and use of laser hybrid welding methods, however, increase the austenite formation. The pitting resistance may also be increased by suppressing formation of chromium nitrides in the weld metal and heat affected zone (HAZ). After thorough post-weld cleaning (pickling), pitting primarily occurred 1-3 mm from the fusion line, in the parent metal rather than in the HAZ. Neither the chromium nitride precipitates found in the HAZ, nor the element depletion along the fusion line that was revealed by electron probe microanalysis (EPMA) were found to locally decrease the pitting resistance. The preferential pitting location is suggested to be controlled by the residual weld oxide composition that varies over the surface. The composition and thickness of weld oxide formed on LDX 2101 and 2304 (EN 1.4362, UNS S32304) were determined using X-ray photoelectron spectroscopy (XPS). The heat tint on these lean duplex grades proved to contain significantly more manganese than what has been reported for standard austenitic stainless steels in the AISI 300 series. A new approach to heat tint formation is presented; whereby evaporation of material from the weld metal and subsequent deposition on the already-formed weld oxide are suggested to contribute to weld oxide formation. This is consistent with manganese loss from the weld metal, and nitrogen additions to the GTA shielding gas enhance the evaporation. The segregation of all elements apart from nitrogen is low in autogenously welded LDX 2101. This means that filler wire additions may not be required as for other duplex grades assuming that there is no large nitrogen loss that could cause excessive ferrite contents. As the nitrogen appears to be controlling the austenite formation, it becomes essential to avoid losing nitrogen during welding by choosing nitrogen-containing shielding and backing gas. / QC 20101213

<p>Duplex stainless steels are a very attractive alternative to austenitic grades due to their higher strength and good corrosion performance. The austenitic grades can often be welded autogenously, while the duplex grades normally require addition of filler metal. This is to counteract segregation of important alloying elements and to give sufficient austenite formation to prevent precipitation of chromium nitrides that could have a negative effect on impact toughness and pitting resistance. The corrosion performance of the recently-developed lean duplex stainless steel LDX 2101 is higher than that of 304 and can reach the level of 316. This thesis summarises pitting resistance tests performed on laser and gas tungsten arc (GTA) welded LDX 2101. It is shown here that this material can be autogenously welded, but additions of filler metal, nitrogen in the shielding gas and use of hybrid methods increases the austenite formation and the pitting resistance by further suppressing formation of chromium nitride precipitates in the weld metal. If the weld metal austenite formation is sufficient, the chromium nitride precipitates in the heat-affected zone (HAZ) could cause local pitting, however, this was not seen in this work. Instead, pitting occurred 1–3 mm from the fusion line, in the parent metal rather than in the high temperature HAZ (HTHAZ). This is suggested here to be controlled by the heat tint, and the effect of residual weld oxides on the pitting resistance is studied. The composition and the thickness of weld oxide formed on LDX 2101 and 2304 were determined using X-ray photoelectron spectroscopy (XPS). The heat tint on these lean duplex grades proved to contain significantly more manganese than what has been reported for standard austenitic stainless steels in the 300 series. A new approach on heat tint formation is consequently presented. Evaporation of material from the weld metal and subsequent deposition on the weld oxide are suggested to contribute to weld oxide formation. This is supported by element loss in LDX 2101 weld metal, and nitrogen additions to the GTA shielding gas further increase the evaporation.</p><p> </p>

Ce projet de thèse se situe dans le cadre de l'étude de la fiabilité prédictive de nouveaux concepts d'assemblages microélectroniques de type « system in package » SiP. L'objectif est de développer une méthodologie de fiabilité prédictive adaptée aux nouveaux concepts d'assemblage qui permet d'optimiser et de prédire les performances dès la phase de conception. Elle est ensuite appliquée sur des projets concrets. Cette méthodologie de fiabilité prédictive fait intervenir des études expérimentales, des simulations thermomécaniques et des analyses statistiques pour traiter les données et évaluer la fiabilité et les risques de défaillance. L'utilisation d'outils de simulation des composants électroniques est bien adaptée pour aider à l'évaluation des zones les plus fragiles, la mise en place des règles de conception et la détermination des paramètres les plus influents avec une réduction du temps de mise en marché d'un produit fiable et une optimisation des performances. Les études réalisées sur le silicium avec deux tests : bille sur anneau et test trois points montrent que le rodage et l'épaisseur ont une influence sur la variation de la contrainte et la déflexion du silicium à la rupture. Avec le test trois points, le déclenchement des fissures est lié à la qualité de sciage et de rodage. Cependant avec le test bille sur anneau, seule la qualité de surface influence le déclenchement des fissures. Le test bille sur anneau est bien adapté pour évaluer la qualité de surface du silicium. Avec les techniques chimiques de réduction de contraintes, comme la gravure humide et plasma, la résistance à la rupture a été considérablement améliorée. Ces tests de rupture sur le silicium ont permis de caractériser la rupture du silicium sous une contrainte de flexion et de compléter les résultats de simulation. Ces travaux démontrent, le besoin et l'utilité du prototypage virtuel des composants électroniques et de l'utilisation d'une méthodologie prédictive dans l'évaluation de la fiabilité en l’appliquant sur des composants réels. / This thesis project is a study of the predictive reliability of new microelectronic package concepts such as "system in package" SiP. The objective is to develop a reliable predictive methodology adapted to the new assembly concepts to optimize and to predict the performance at the design phase. Then, the methodology is applied to concrete projects. This methodology of predictive reliability involves the use of experimental studies, thermomechanical simulations and statistical analysis to process the data and assess the reliability and risks of failure. The use of simulation tools for electronic components is well suited to assist in the evaluation of the most fragile areas, the setting up of design rules and the determination of the most influential parameters with a reduction in the setup time market for a reliable and optimized performance. Studies on silicon strength are conducted with two tests: ball on ring test and on three-point bend test show that the grinding and the thickness influence the variation of the stress and deflection of the silicon at break. With the three points bend test, the onset of crack is linked to defects in sawing and grinding zone. However, with the ball on ring test, only the surface quality influences the initiation of cracks. The ball on ring test is well suited for evaluating the quality of the silicon surface. Chemical techniques of stress release, such as wet etching and plasma etching, improve significantly the strength of silicon samples. These tests on silicon dies are used to characterize the breakdown of silicon under bending test and to complete the simulation results. We have demonstrated in this work, the need and the usefulness of the virtual prototyping of electronic components and the use of a predictive methodology in assessing reliability.

Duplex stainless steels are a very attractive alternative to austenitic grades due to their higher strength and good corrosion performance. The austenitic grades can often be welded autogenously, while the duplex grades normally require addition of filler metal. This is to counteract segregation of important alloying elements and to give sufficient austenite formation to prevent precipitation of chromium nitrides that could have a negative effect on impact toughness and pitting resistance. The corrosion performance of the recently-developed lean duplex stainless steel LDX 2101 is higher than that of 304 and can reach the level of 316. This thesis summarises pitting resistance tests performed on laser and gas tungsten arc (GTA) welded LDX 2101. It is shown here that this material can be autogenously welded, but additions of filler metal, nitrogen in the shielding gas and use of hybrid methods increases the austenite formation and the pitting resistance by further suppressing formation of chromium nitride precipitates in the weld metal. If the weld metal austenite formation is sufficient, the chromium nitride precipitates in the heat-affected zone (HAZ) could cause local pitting, however, this was not seen in this work. Instead, pitting occurred 1–3 mm from the fusion line, in the parent metal rather than in the high temperature HAZ (HTHAZ). This is suggested here to be controlled by the heat tint, and the effect of residual weld oxides on the pitting resistance is studied. The composition and the thickness of weld oxide formed on LDX 2101 and 2304 were determined using X-ray photoelectron spectroscopy (XPS). The heat tint on these lean duplex grades proved to contain significantly more manganese than what has been reported for standard austenitic stainless steels in the 300 series. A new approach on heat tint formation is consequently presented. Evaporation of material from the weld metal and subsequent deposition on the weld oxide are suggested to contribute to weld oxide formation. This is supported by element loss in LDX 2101 weld metal, and nitrogen additions to the GTA shielding gas further increase the evaporation. / QC 20101126