• Refine Query
  • Source
  • Publication year
  • to
  • Language
  • 144
  • 105
  • Tagged with
  • 252
  • 252
  • 129
  • 34
  • 34
  • 30
  • 29
  • 25
  • 21
  • 20
  • 19
  • 17
  • 15
  • 14
  • 13
  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
211

A study of wave induced electron precipitation at low and middle latitudes.

Friedel, Reiner Hans-Walter. January 1991 (has links)
Wave induced electron precipitation (WIEP) can modify the ionosphere above a sub-ionospherically propagating VLF signal in such a way as to perturb the amplitude and phase of the signal: The "Trimpi Event". In this thesis trimpi events are used in a study of WIEP events and in the responsible mechanism: The gyroresonant interaction. Trimpi activity at middle latitudes (SANAE, Antarctica, L = 4.02) and low latitudes (Durban, RSA , L = 1.69) together with the corresponding theory for the gyroresonant interaction is examined and compared. A newly developed computerised system for the detection and analysis of trimpi events has been developed in Durban. This system has been used to analyse tape data recorded at SANAE. Trimpi events were found on various transmitter paths to SANAE and a complete study of 1982 data has led to the establishment of trimpi characteristics as seen at SANAE: an absence of positive events and causative whistlers, a preference for short duration events (t < 25s), the occurrence of some very large events (up to 90% signal attenuation) , two minima in occurrence near 0015 and 0400 h Local Time, low occurrence and occurrence rate of events and evidence that interactions with non-ducted whistlers are of importance. The computerised sytem was then extended to collect data at Durban simultaneously from up to 20 transmitters worldwide. Examination of data from this survey showed very low occurrence rates of trimpis but yielded some daytime events for which the effectiveness of the gyroresonance interaction, which successfully explains the trimpi event at middle and low latitudes, had to be questioned. Thus a fully relativisic test particle simulation of the gyroresonant interaction was used to examine the effectiveness of gyroresonance at low L for producing trimpi events. This simulation was run for a wide range of interaction parameters and yielded the following constraints for effective pitch angle scattering (and hence precipitation) of electrons at low L: wave intensities in excess of 150 nT, wave frequencies in excess of 10 kHz and background electron densities at least one order of magnitude higher than normal. First data from the OMSKI project, a sophisticated VLF receiver operated at Durban as part of an international project, shows further evidence of low-latitude trirmpi activity. A survey of one month's continuous data is presented. In face of the evidence that trimpi events that occur at low L have the same signature as those at middle L but that the standard gyroresonance interaction is insufficient to cause them, alternate scenarios that could enhance the interaction were sought. In particular distortions in the ambient magnetic field (eg. PC-5 pulsations) were modelled using a new dipole-like background field model. This simulation showed that distortions which tend to reduce magnetic field curvature along field lines can significantly enhance the gyroresonant conditions and hence the interaction. A new set of conditions for effective gyroresonance at low L is thus established and contrasted with the more lenient conditions at middle L. A study of "frequency tracking" as a means to prolong resonance showed that natural whistlers do not posess the required frequency /time characteristics for this mechanism, and that artificial waves in a narrow range around the equatorial resonance frequency would ~ well suited for this purpose. An overview of the status of worldwide Trimpi detection networks together with the S.P.R.I. 's role in this regard is presented. / Thesis (Ph.D.)-University of Natal, Durban, 1991.
212

Investigation of conceptual and language difficulties affecting the understanding of several mechanics concepts among some African teachers and students.

Moji, Nthobane Cable. January 1998 (has links)
The results of national examination in matric and universities showed that African students were performing very poorly in their studies and examinations in science and in physics in particular. The objective in this study was to investigate some of the difficulties both African teachers and students, that meant African learners, had in understanding physics, specifically mechanics. The study consisted of investigation of two themes, namely, conceptual and language difficulties. Conceptual Difficulties were investigated by means of three questionnaire tasks. Task One investigated learners' understanding of the concepts of force, energy, power, momentum, speed and other related mechanics concepts in the context of boulders rolling down and up a mountain slope. Task Two investigated subjects' understanding of the force on a ball that was thrown up by the hand, went up to the highest position, and then turned and fell freely back to the ground. Task Three investigated learners' understanding of the positions where speeds, velocities, accelerations and forces were equal on a ball as it was going up and on its way down. The Pilot group, among whom the wide pilot work of this study was done through some haphazard questionnaire, consisted of pre-service and in-service teachers selected from the North East Free State Highlands which was regarded as an appropriate location with a number of institutions with the necessary research subjects, ,since it was neither much urban nor much rural. Intensive study and analysis was done on this pilot work and it led to some real research study to be conducted within a more "focussed" group, namely, the Student group. This Student group which consisted of the first year physics students on the Pietermaritzburg Campus of the University of Natal, was selected for purposes of comparison. Two kinds of Reference groups were devised: for the Conceptual Difficulties investigation the Reference group consisted of physics lecturers and professors from several universities. Their unanimous responses together were regarded as a memorandum through which to correct the responses of the study subjects. For the Language Difficulties investigation the Reference group consisted of African physicists from several universities. There was no unanimous consensus on their mechanics concepts translations into their vernaculars. Analysis of written results and interviews showed that African students experienced Conceptual Difficulties in mechanics. The Conceptual Difficulties were similar to those conducted in many other countries around the world by physics education researchers. The Language Difficulties were of two types. Firstly, a translation from a single mother tongue term into multiple English (the language of instruction) terms revealed a lack of clear concepts differentiation among the subjects. Secondly, there was no consensus, even amongst African physicists, as to which vernacular terms and English terms correspond. In addition, the interaction of the use of African vernaculars with an alternative conceptualisation seemed to have resulted to many of the research subjects believing in a quantity that is intrinsic to a person or object. This quantity had attributes of several different mechanics quantities, such as force, momentum, energy and power. Two tasks were used in the second theme where Language Difficulties were investigated. Translations of conceptual terms that were supplied in Task One and Task Three of the first theme were given and examined. The phenomenon of reverse translation from mother tongue to English was identified as a source of Language Difficulties due to the availability of limited words for these conceptual terms in the vernaculars spoken in South Africa. However, the effect language on the subjects' understanding of mechanics was not simply the result of the lack of vocabulary, the study also showed that the research subjects conceptualised physics concepts differently from physicists, this was revealed by analysing their use of both English and their vernaculars. The results of the investigations were then discussed and compared with those obtained by other research workers in similar studies around the world. Some approaches in teaching physics to African students in an endeavour to alleviate these unearthed difficulties were proposed and recommended in the conclusion. It was further encouraged that more investigations would show to appropriately and successfully instruct the African learners the physics concepts, since some institutions lately managed to produce African physicists and physics professors. / Thesis (Ph.D.)-University of Natal, Pietermaritzburg, 1998.
213

The influence of rotating and locked magnetic islands on edge transport in Tokoloshe tokamak.

Van Vuuren, Gary Wayne. January 1993 (has links)
The turbulence and fluctuation induced transport in the edge plasma of the Tokoloshe tokamak was studied using a Langmuir probe array. In this thesis three separate experiments are presented, each of which examines a particular aspect of the edge plasma. In the first experiment measurements of edge plasma parameters are presented. These include standard parameters (such as Ne, Op , Te, etc.) as well as features such as the velocity shear, T(t) during periods of both high and low Mirnov activity, Te/Te and Q. These are compared with results from other machines as well as predictions of several turbulence theories. It was found that many of the results are very similar to those obtained on other machines and that, since the operating parameter space on Tokoloshe is well within the parameter space described by drift wave theories, resistivity-driven gradient driven turbulence theories do not describe the edge turbulence. In the second experiment external windings are used to produce fields which can slow and lock magnetic islands in the toroidally rotating plasma. Edge parameters are again presented and these results compared with those from the so-called 'reference' plasmas, i.e. ones in which no locking occurred. During locking some parameters are dramatically altered, e.g.Te/Te Standard transport theory ignores the effect of Te/Te since they are usually small in reference discharges. During the locked phase, however, certain measurements used to deduce T and Q are greatly affected by increases in Te/Te. As a result, certain assumptions regarding these measurements are no longer valid. Comparison of results for different island positions (produced by different coils) indicates that the assumption of poloidal and toroidal symmetry of edge conditions is invalid. The third experiment investigates the high frequency (~60 kHz), low amplitude, magnetic oscillation which characterises the locked phase and which exhibits some small degree of correlation with the fluctuations observed on (e.g.) Of'. Since over 80% of the spectral power of Te/Te lies below 70 kHz and since Of /Te depends strongly on Te/Te , it is suggested that the magnetic mode and these large variations in Te, may be due to a similar physical process. / Thesis (Ph.D.)-University of Natal, 1993.
214

Computational studies of percolation : determination of the cluster number scaling function for lattices in 2 dimensions.

30 September 2010 (has links)
The main aim of this work is to study percolation theory on regular two dimensional / Thesis (M.Sc.)-University of Natal, Pietermaritzburg, 2002.
215

Mossbauer spectroscopy and x-ray diffraction study of (Cd, Zn) substituted mixed ferrites.

Msomi, Justice Zakhele. January 2002 (has links)
The study of magnetic properties and structures of Zn and Cd substituted mixed ferrites has been carried out using Mossbauer spectroscopy and X-ray diffraction on powdered samples at about 300 K. Two series of mixed ferrites, (Cd, Zn)xCol-xFe2-xAlxO4 and (Cd, Zn)xCo0.9Fe1.7-xTi0.4O 4 (where 0≤ x≤1.0) were synthesized. In the former series the effect of simultaneous site dilution by Zn or Cd and Ai atoms on tetrahedral (A) and octahedral (B) sites is investigated and in the latter the effect of single site dilution by Zn or Cd is also studied. The Mossbauer spectra show that the compounds transform with increase in x from ordered to disordered magnetic states. Systematic decrease in the hyperfine fields indicating weakening of the magnetic coupling with an increase in x is observed. We report the presence of a cross over effect with respect to the hyperfine fields on A and B sites at low concentration of diamagnetic ions in the simultaneously diluted series. Both series of compounds show no significant changes in isomer shifts with x. Differences in the evolution of Fe atoms on A and B sites between Zn and Cd based compounds are observed. The results of our analysis show that Zn and Cd ions occupy both tetrahedral and octahedral sites. The spinel structure of the compounds studied in this work is confirmed by X-ray diffraction (XRD). The lattice parameters derived from XRD show systematic change with x consistent with Vergard's law. In Cd based samples an increase of the lattice parameter with x is explained on the basis of the size difference of the cations involved. However, an anomalous behavior of the lattice parameter is observed in Zn based samples. The average grain sizes of the samples were determined from the line width of the (311) XRD intensity lines using the Scherrer formula. These vary between 50 nm and 70 nm for all the samples except for Zn and Al substituted samples which show a systematic anomalous reduction for x ≥ 0.4 in grain size. The porosity, x-ray and bulk densities of the samples are also presented. / Thesis (M.Sc.)-University of Natal, Durban, 2002.
216

Ultrafast structural dynamics in 4Hb-TaSe2 observed by femtosecond electron diffraction

Erasmus, Nicolas 03 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: In this thesis the structural dynamics, upon photo-excitation, of the charge-densitywave (CDW) material 4Hb-TaSe2 is investigated on the time-scale of atomic motion and simultaneously on the spatial-scale of atomic dimensions. CDW materials have been of interest since their discovery in the 1970’s because of their remarkable non-linear and anisotropic electrical properties, gigantic dielectric constants, unusual elastic properties and rich dynamical behaviour. Some of these exotic properties were extensively investigated in thermal equilibrium soon after their discovery but only recently have ultrafast techniques like femtosecond spectroscopy become available to study their out-of-equilibrium behaviour on the time-scale of atomic motion. By studying their behaviour on this time-scale a more in-depth understanding of their macroscopic properties can be gained. However, to do investigations on the atomic time-scale and simultaneously directly observe the evolution of the atomic arrangements is another challenge. One approach is through the previously mentioned technique of femtosecond pump-probe spectroscopy but converting the usual ultrashort optical probing source to an ultrashort electron or x-ray source that can diffract off the sample and reveal structural detail on the atomic level. Here, the femto-to-picosecond out-of-equilibrium behaviour upon photo-excitation in 4Hb-TaSe2 is investigated using an ultrashort electron probe source. Two variations of using an electron probe source are used: conventional scanning Femtosecond Electron Diffraction (FED) and a new approach namely Femtosecond Streaked Electron Diffraction (FSED). The more established FED technique, based on femtosecond pumpprobe spectroscopy, is used as the major investigating tool while the FSED technique, based on ultrafast streak camera technology, is an attempt at broadening the scope of available techniques to study structural dynamics in crystalline material on the subpicosecond time-scale. With these two techniques, the structural dynamics during the phase transition from the commensurate- to incommensurate-CDW phase in 4Hb-TaSe2 is observed through diffraction patterns with a temporal resolution of under 500 fs. The study reveals strong coupling between the electronic and lattice systems of the material and several time-constants of under and above a picosecond are extracted from the data. Using these time-constants, the structural evolution during the phase transition is better understood and with the newly gained knowledge, a model of all the processes involved after photo-excitation is proposed. / AFRIKAANSE OPSOMMING: In hierdie tesis word die strukturele dinamika van die lading-digtheid-golf (LDG) materiaal 4Hb-TaSe2 ondersoek op die tydskaal van atomiese bewegings en gelyktydig op die ruimtelikeskaal van atomiese dimensies. LDG materie is al van belang sedert hul ontdekking in die 1970’s as gevolg van hul merkwaardige nie-lineêre en anisotrope elektriese eienskappe, reuse diëlektriese konstantes, ongewone elastiese eienskappe en ryk dinamiese gedrag. Sommige van hierdie eksotiese eienskappe is omvattend ondersoek in termiese ewewig kort na hul ontdekking, maar eers onlangs is dit moontlik deur middle van ultravinnige tegnieke soos femtosekonde spektroskopie om hulle uit-ewewigs gedrag te bestudeer op die tydskaal van atomiese beweging. Deur die gedrag op hierdie tydskaal te bestudeer kan ’n meer insiggewende begrip van hul makroskopiese eienskappe verkry word. Om ondersoeke in te stel op die atomiese tydskaal en gelyktydig direk die evolusie van die atoom posisie te waarneem is egter ’n moeilike taak. Een benadering is deur middle van femtosekonde “pump-probe” spektroskopie maar dan die gewone optiese “probe” puls om te skakel na ’n electron of x-straal puls wat van die materiaal kan diffrak en dus strukturele inligting op die atomiese vlak kan onthul. Hier word die femto-tot-pico sekonde uit-ewewig gedrag in 4Hb-TaSe2 ondersoek met behulp van elektron pulse. Twee variasies van die gebruik van ’n elektron bron word gebruik: konvensionele “Femtosecond Electron Diffraction” (FED) en ’n nuwe benadering, naamlik, “Femtosecond Streaked Electron Diffraction” (FSED). Die meer gevestigde FED tegniek, wat gebaseer is op femtosekonde “pump-probe” spektroskopie, word gebruik as die hoof ondersoek metode terwyl die FSED tegniek, wat gebaseer is op die ultra vinnige “streak camera” tegnologie, ’n poging is om beskikbare tegnieke uit te brei wat gebruik kan word om strukturele dinamika in materie te bestudeer op die sub-picosekonde tydskaal. Met behulp van hierdie twee tegnieke, word die strukturele dinamika tydens die fase oorgang van die ooreenkomstige tot nie-ooreenkomstige LDG fase in 4Hb-TaSe2 deur diffraksie patrone met ’n tydresolusie van minder as 500 fs waargeneem. Die studie toon ’n sterk korrelasie tussen die elektroniese sisteem en kristalrooster. Verskeie tydkonstantes van onder en bo ’n picosekonde kon ook uit die data onttrek word en gebruik word om die strukturele veranderinge beter te verstaan. Hierdie nuwe kennis het ons in staat gestel om ’n model van al die betrokke prosesse voor te stel.
217

Phase transitions in transition metal dichalcogenides studied by femtosecond electron diffraction

Haupt, Kerstin Anna 12 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: Low-dimensional materials are known to undergo phase transitions to differently or- dered states, when cooled to lower temperatures. These phases often show a periodic modulation of the charge density (called a charge density wave – CDW) coupled with a periodic perturbation of the crystal lattice (called a periodic lattice distortion – PLD). Although many experiments have been performed and much has been learnt about CDW phases in low-dimensional materials, the reasons for their existence are still not fully understood yet. Many processes, involving either strong electron–electron or electron–lattice coupling, have been observed which all might play a role in explaining the formation of different phases under different conditions. With the availability of femtosecond lasers it has become possible to study materials under highly nonequilibrium conditions. By suddenly introducing a known amount of energy into the system, the equilibrium state is disturbed and the subsequent relax- ation processes are then observed on timescales of structural and electronic responses. These experiments can deliver valuable information about the complex interactions between the different constituents of condensed matter, which would be inaccessible under equilibrium conditions. We use time resolved electron diffraction to investigate the behaviour of a CDW system perturbed by a short laser pulse. From the observed changes in the diffraction patterns we can directly deduce changes in the lattice structure of our sample. A femtosecond electron diffraction setup was developed at the Laser Research In- stitute in Stellenbosch, South Africa. Short laser pulses produce photo electrons which are accelerated to an energy of 30 keV. Despite space charge broadening effects, elec- tron pulses shorter than 500 fs at sample position can be achieved. Technical details of this system and its characterisation as well as sample preparation techniques and analysis methods are described in detail in this work. Measurements on two members of the quasi-two-dimensional transition metal di- chalcogenides, namely 4Hb-TaSe2 and 1T-TaS2, are shown and discussed. Both show fast (subpicosecond) changes due to the suppression of the PLD and a rapid heating of the lattice. When the induced temperature rise heats the sample above a phase tran- sition temperature, a complete transformation into the new phase was observed. For 4Hb-TaSe2 we found that the recovery to the original state is significantly slower if the PLD was completely suppressed compared to only disturbing it. On 1T-TaS2 we could not only study the suppression of the original phase but also the formation of the higher energetic CDW phase. Long (100 ps) time constants were found for the tran- sition between the two phases. These suggest the presence of an energy barrier which has to be overcome in order to change the CDW phase. Pinning of the CDW by de- fects in the crystal structure result in such an energy barrier and consequently lead to a phase of domain growth which is considerably slower than pure electron or lattice dynamics. / AFRIKAANSE OPSOMMING: Dit is bekend dat lae-dimensionele materie fase oorgange ondergaan na anders ge- ori¨enteerde toestande wanneer afgekoel word tot laer temperature. Hierdie fases toon dikwels ’n periodiese modulasie van die elektron digtheid (genoem ’n “charge density wave” – CDW), tesame met ’n periodiese effek op die kristalrooster (genoem ’n “peri- odic lattice distortion” – PLD). Alhoewel baie eksperimente al uitgevoer is en al baie geleer is oor hierdie CDW fase, is die redes vir hul bestaan nog steeds nie ten volle verstaan nie. Baie prosesse, wat of sterk elektron–elektron of elektron–fonon interaksie toon, is al waargeneem en kan ’n rol speel in die verduideliking van die vorming van die verskillende fases onder verskillende omstandighede. Met die beskikbaarheid van femtosekonde lasers is dit nou moontlik om materie onder hoogs nie-ewewig voorwaardes te bestudeer. Deur skielik ’n bekende hoeveel- heid energie in die stelsel in te voer, word die ewewigstaat versteur en word die daar- opvolgende ontspanning prosesse waargeneem op die tydskaal van atomies struktu- rele en elektroniese bewiging. Hierdie eksperimente kan waardevolle inligting lewer oor die komplekse interaksies tussen die verskillende atomiese komponente van ge- kondenseerde materie, wat ontoeganklik sou wees onder ewewig voorwaardes. Ons gebruik elektrondiffraksie met tyd resolusie van onder ’n pikosekonde om die gedrag van ’n CDW stelsel te ondersoek nadat dit versteur is deur ’n kort laser puls. Van die waargenome veranderinge in die diffraksie patrone kan ons direk aflei watse veranderinge die kristalstruktuur van ons monster ondergaan. ’n Femtosekonde elektronendiffraksie opstelling is ontwikkel by die Lasernavors- ingsinstituut in Stellenbosch, Suid-Afrika. Kort laser pulse produseer foto-elektrone wat dan na ’n energie van 30 keV versnel word. Ten spyte van Coulomb afstoting ef- fekte, kan elektron pulse korter as 500 fs by die monster posisie bereik word. Tegniese besonderhede van hierdie opstelling, tegnieke van die voorbereiding van monsters asook analise metodes word volledig in hierdie tesis beskryf. Metings op twee voorbeelde van kwasi-tweedimensionele semi-metale, naamlik 4Hb-TaSe2 en 1T-TaS2, word gewys en bespreek. Beide wys ’n vinnige (subpikosekon- de) verandering as gevolg van die versteuring van die PLD en ’n vinnige verhitting van die kristalrooster. Wanneer die ge¨ınduseerde temperatuur bo die fase oorgang tempe- ratuur styg, is ’n volledige transformasie na die nuwe fase waargeneem. Vir 4Hb-TaSe2 het ons gevind dat die herstelling na die oorspronklike toestand aansienlik stadiger is as die PLD heeltemal viernietig is in vergelyking met as die PLD net versteur is. Met 1T-TaS2 kon ons nie net alleenlik die vernietiging van die oorspronklike fase sien nie, maar ook die vorming van ’n ho¨er energie CDW fase. Lang (100 ps) tydkonstante is gevind vir die oorgang tussen die twee fases. Hierdie dui op die teenwoordigheid van ’n energie-versperring wat eers oorkom moet word om die CDW fase voledig te ver- ander. Vaspenning van die CDW deur defekte in die kristalstruktuur veroorsaak so’n energie versperring en gevolglik lei dit tot ’n fase van groeiende CDW gebiede wat heelwat stadiger as pure elektron of kritalrooster dinamika is.
218

The role played by quasi-elastic and inelastic break-up of the 12C and 16O projectiles in the production of intermediate mass fragments at 14-35 MeV/u

Mira, Joele Paulus 12 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: See full text for the abstract / AFRIKAANSE OPSOMMING: Sien volteks vir die opsomming
219

Ultrafast photodynamics of ZnO solar cells sensitized with the organic indoline derivative D149

Rohwer, Egmont Johann 04 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: The initial charge transfer from dye molecules' excited states to the conduction band of a semiconductor, after absorption of visible light by the former, is critical to the performance of Dye sensitized Solar Cells (DSC). In a ZnO-based DSC sensitized by the organic indoline derivative D149, the dynamics associated with charge transfer are investigated with femtosecond transient absorption spectroscopy. The time-resolved measurement of the photo-initiated processes reveal electron transfer rates corresponding to excited state lifetimes of 100s of fs, consistent with previously measured high absorbed photon to current conversion efficiencies. The photo-electrode measured as an isolated system shows decay times of bound electrons in excited states of the dye to be ~150 fs and shows the subsequent emergence of absorption bands of the oxidized molecules. When the I-/I-3 redox couple is added to the system, these excited state lifetimes change and are found to be dependent on the cation in the electrolytic solution. Small cations like Li+ reduce the excited state lifetime to sub-100 fs, whilst larger cations like the organic tetrabutylammonium result in longer lifetimes of 240 fs. The action of the electrolyte can be observed by the reduced lifetime of the oxidized dye molecules' absorption bands. The effect of operating parameters and changes in the production protocol of the DSC on the primary charge injection are also investigated and reported on. / AFRIKAANSE OPSOMMING: Die aanvanklike ladingsoordrag vanuit kleurstofmolekules' opgewekte toestande tot in die leidingsband van 'n halfgeleier, na absorpsie van sigbare lig deur eersgenoemde, is van kritiese belang vir die uitset van halfgeleier-gebaseerde sonkragselle wat met kleurstowwe vir absorpsie verhoging, gebind is. In hierdie werk word hierdie proses en verwante fotodinamika in die geval van 'n ZnO sonkragsel gekleur met indolien D149 ondersoek d.m.v femtosekonde-tydopgelosde absorpsiespektroskopie. Hierdie metings onthul elektron-oordragstempos wat ooreenstem met lewenstye van opgewekte toestande in die orde van 100 fs. Hierdie is met voorheen-bepaalde hoë foton-tot-stroom omskakelingsdoeltreffendheid ooreenkomstig. Die foto-elektrode, as geïsoleerde sisteem beskou, toon afvalstye van gebonde elektrone in opgewekte toestande van ~150 fs, en die gevolglike opkoms van absorpsie deur geoksideerde molekules word waargeneem. As die I-/I-3 redoks oplossing tot die sisteem bygevoeg word, verander die opgewekte toestande se afvalstye en toon 'n katioon-afhanklikheid. Klein katioone soos Li+ verkort die afvalstye tot onder 100 fs, terwyl groter katioone soos die organiese tetra-butielammonium langer afvalstye (240 fs) tot gevolg het. Die werking van die elektrolitiese oplossing kan waargeneem word deur die verkorte lewenstyd van die absorpsiebande wat aan die geoksideerde molekules toegeken is. Die uitwerking van operasionele parameter asook veranderinge in die produksie protokol op die primêre ladingsoordrag word ondersoek en verslag daarop word gelewer.
220

Impact of the 138,139La radiative strength functions and nuclear level densities on the galactic production of 138La

Kheswa, Bonginkosi Vincent 12 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: 138La is a very long-lived and low abundant p-isotope. Most p-nuclei with Z > 54 are thought to be produced through photodisintegration of s- and r-process seed nuclei. However, this p-process cannot satisfactorily explain the observed abundance of 138La, and more exotic processes, such as ve + 138Ba → 138La + e− have to be considered. This v-process can reproduce the observed solar abundance of 138La, but the significance of the p-process cannot be ruled out due to very high uncertainties in its predicted reaction rates. These errors have been discussed to be mainly due to the unavailability of the experimental nuclear level densities and radiative strength functions of 138,139La, which are critical ingredients for astrophysical reaction rate calculations based on the Hauser-Feshbach approach. Thus, nuclear physics measurements are necessary to place the nuclear properties on a strong footing, in order to make statements regarding the importance of p- and v-processes. In this research project the experimental nuclear level densities and radiative strength functions of 138,139La were measured below the neutron thresholds. From this new experimental data, the Maxwellian averaged cross sections for the 137La(n, y) and 138La(n, y) reactions, at the p-process temperature of 2.5⇥109 K, were computed with the TALYS code. Using these reaction rates the nucleosynthesis calculations in the O/Ne-rich layers of Type II supernovae were performed. The results imply that the standard p-process still under-produces 138La, which puts the v-process on a very strong footing as the main production process for 138La. / AFRIKAANSE OPSOMMING: 138La is ’n p-isotoop met ’n baie lang halfleeftyd. Daar word tans vermoed dat p-nukiede met Z > 54 geproduseer word deur fotodisintegrasie van sen r-proses saadnukliede. Nogtans verklaar hierdie p-proses die waargenome natuurlike voorkoms van 138La nie behoorlik nie, en meer eksotiese prosesse soos byvoorbeeld ve+ 138Ba → 138La + e− moet in aanmerking geneem word. Hierdie v-proses kan die waargenome natuurlike voorkoms van 138La verklaar, maar die belangrikheid van die p-proses kan nie afgewys word nie weens die onsekerheid in die voorspelde reaksie snelheid. Sodanige onsekerhede word bespreek en word hoofsaaklik toegeskryf aan die gebrek aan eksperimentele vlakdigthede en stralings sterkefunksies van die kerne 138,139La, wat van kritiese belang is vir berekeninge van astrofisiese reaksie snelhede gebaseer op die Hauser-Feshbach benadering. Kernfisiese metings is derhalwe noodsaaklik om die eienskappe van kerne op ’n stewige grondslag te plaas sodat uitlatings gemaak kan word omtrent die belangrikheid van p- en v-prosesse. In hierdie esperimentele navorsingsprojek is die kern vlakdigthede en stralings sterkefunksies van 138,139La onder die neutron reaksiedrumpels gemeet. Die nuwe gemete data maak dit moontlik om die Maxwell-gemiddelde kansvlakke vir die 137La(n, y) en 138La(n, y) reaksies by ’n p-proses temperatuur van 2.5 x 109 K met die TALYS program te bereken. Hierdie reaksie snelhede is daarna gebruik om berekeninge van elementvorming in die O/Ne-ryke lae van Tipe-II supernovas te maak. Die resultate wys uit dat die stadaard p-proses nie genoegsame 138La produseer nie, wat derhalwe die v-proses op ’n baie stewige grondslag plaas as die hoof produksie proses vir 138La.

Page generated in 0.0759 seconds