This study explored high school communication (i.e., policy translation) of Louisiana statutes pertaining to postsecondary opportunities aligned with the CTE graduation pathway and the implementation of curriculum tracks through high school track-shifting policies. Two research questions guided this study: 1) To what extent do diploma policies listed on high school websites in the Louisiana Acadiana region describe the actual postsecondary opportunities available to students in a CTE program? and 2) What information do high school websites reveal about curriculum track-shifting policies? To answer these questions, I conducted a manifest content analysis (Kleinheksel et al., 2020) of websites for 29 traditional public high schools operated by school districts in Louisiana's Acadiana region. My analysis was guided by a conceptual framework that included horizontal differentiation, track shifting, and misinformation (Rosenbaum, 1978; Sørensen, 1970). Two major themes emerged in the findings: Inconsistent and Incomplete Information about Postsecondary Options for CTE Diploma Pathway Students and Limited Flexibility (Semi-Closed) Curriculum System. These themes and their respective subthemes revealed that high school websites contained inconsistent and incomplete information about graduation pathways that constrains students' postsecondary options. Findings from this study offer implications for practice, policy and policy translation, and future research regarding high school diploma policies, curriculum tracks, track-shifting policies, and curriculum enrollment decisions. This study also offers recommendations for officials at the state level and school leaders at the local level. / Doctor of Philosophy / Postsecondary opportunities means the career and college options students have after high school. This research looked into how high school websites in Louisiana's Acadiana region communicate information about postsecondary opportunities for students who choose the Career and Technical Education (CTE) graduation pathway. It also studied how they handle curriculum track-shifting policies for students. Two research questions guided this study: 1) To what extent do diploma policies listed on high school websites in the Louisiana Acadiana region describe the actual postsecondary opportunities available to students in a CTE program? and 2) What information do high school websites reveal about curriculum track-shifting policies? To answer these questions, I used a specific type of analysis to examine websites for 29 traditional public high schools operated by school districts in the region. My analysis was guided by a framework that included three aspects of policy research related to graduation pathways. Two major themes emerged in the findings: Inconsistent and Incomplete Information about Postsecondary Options for CTE Diploma Pathway Students and Limited Flexibility (Semi-Closed) Curriculum System. My findings showed that high school websites contained inconsistent and incomplete information about graduation pathways that limit students' postsecondary options. This study concludes with recommendations for school and state officials and future researchers to clarify communication about the career and college opportunities available to CTE students once they graduate from high school.

The thesis deals with describing, evaluating, and proposing of possible changes in planning, placement and describing possession activities on railway lines in order to improve transmission and quality of the services provided by the SŽDC. The first chapter describes the environment of rail transport focusing mainly on law and regulations. The second chapter describes the aim of the study, additional category focuses on describing the method of processing of materials. The fifth chapter focuses on selected lines to describe the various closures in specific line sections. Sixth chapter aims on comparison methods of implementation lockout activities on examined lines. The last chapter has to summarize and evaluate results to submit any additional recommendations.

In recent years there have been repeated calls for universities to better equip students with skills which are relevant to business and industry. The field of Information Systems (IS), along with the wider discipline of computing, has often been described as outdated, slow to adopt new technologies and unable to keep up with the fast pace of change of the real world . Exacerbating the issue of academic relevance in relation to industry needs, universities around the world have experienced a growing disinterest in the study of IS and computing, resulting in worryingly low levels of new graduates who do not meet industry demands. To understand the contentious relationship between academia and business in relation to IS, the research presented in this thesis investigates the current IS undergraduate provision in the UK and its alignment with the skill requirements of the IS industry. This is achieved through a two-stage approach of examining the position and expectations of each stakeholder, followed by the development of a method to facilitate the alignment of their inter-related needs. As part of the first stage, the investigation into the academic stakeholder undertakes a holistic analysis of IS curriculum to quantify its content. This leads to the identification of original Career Tracks which specify the IS careers promoted by the curriculum. The second stage involves the investigation of the business stakeholder measuring the careers in demand and the skills that support them. The resulting findings from these investigations show that it is possible to determine the skills required by IS graduates in the UK to meet the demands of industry. This is achieved through the use of a newly developed IS Course Survey Framework that enables the configuration of IS courses to align to specific career tracks, thus mapping directly to the needs of industry as expressed through their job requirements and associated skills demand.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The Tubular Track (TT) railway system is a twin beam modular railway system consisting of two reinforced concrete (RC) beams on which steel rails are continuously supported. The beams are linked with galvanised steel gauge tie bars and continuously supported by soil foundations, and can be used to replace conventional sleeper and ballast railway support. The TT railway system has in the past been analysed with various analysis methods, but were found to obtain con icting results. The con icting results means that one of the analysis methods used for the analysis and design of TT railway sections is either an underestimation or overestimation of section displacements, forces, and stresses; or both methods could even be incorrect. The main emphasis of this investigation is therefore to develop and verify static and dynamic analysis methods and modeling techniques which can be used to simulate the TT railway system accurately. The results and models of the previous analyses are not explicitly investigated in this dissertation, but serve as a motivation for this investigation. The TT system is supported by several soil strata providing vertical support, but geometrically modeling the subgrade strata in the analysis models adds a high level of complexity, and is not feasible for general analysis where soil conditions are mostly unknown. The elastic foundation theory is therefore used to accurately simulate the interaction between beam and foundation and therefore su ciently simpli es the analysis models. Simpli cation of a subgrade foundation by simulating a soil sti ness supporting the TT beam is investigated and analysed by comparing nite element analysis (FEA) results of various soil models using parameters of four known soil formations currently in use at TT railway sections. The FEA of the subgrade formations indicates that there is a linear relationship between the modulus of subgrade reaction for a square plate bearing test and a rectangular, in nitely long plate representing the subgrade support for the TT beams. A square plate bearing test can therefore be performed on site and modi ed to represent the actual subgrade support sti ness of the TT railway structure, whereafter it can be used for the analysis and design of the TT system using one of the proposed analysis methods. The analysis models used range from simple theoretical models based on elastic foundation principles, to two-dimensional (2D) beam elements, and ultimately to complex three-dimensional (3D) solid nite element models. The models used for the analyses are the Single and Double Beam elastic foundation, PROKON 2D beams, ABAQUS 2D beams and ABAQUS 3D solid element models. The alternative analysis methods considered should provide a clear indication of which analysis methods are accurate and feasible for design of the TT system. An in-situ reference model with known de ections and design parameters speci c to a TT railway section is used to analyse the di erent analysis methods' accuracy and validity. The Double Beam, ABAQUS 2D and ABAQUS 3D models were found to provide very similar displacements, bending moments and shear forces for a static analysis, whereas the PROKON and Single Beam models provide unsatisfactory results. The PROKON beam model underestimates the bending moments and shear forces in the rail, and overestimates bending moments and shear forces in the RC beam by a considerably margin. This result can lead to the underdesigning of the rail which could possibly force the RC beam to be subjected to larger maximum bending moments and shear forces than for what it was originally designed for, thereby nullifying or possibly even exceeding the amount for which it was overdesigned. This e ectively accelerates material fatigue, which might be the possible cause of the small cracks in the RC beams which have been found on some TT railway sections, which is currently being investigated. A graphical user interface of the Double Beam method is provided for quick and e cient analysis. Empirical methods used to simulate the dynamic nature of a railway system are often used in the industry to simplify the dynamic loading by determining a dynamic amplitude factor (DAF) to be applied to a static load. An implicit dynamic FEA is therefore performed to obtain the DAF for the reference section, which is subsequently used for the comparison with in-situ de ection results. The results of dynamic analysis validates the proposed empirical analysis method, as the displacements obtained were very similar to actual eld test results, thereby also verifying the accuracy of the proposed analysis methods. The sensitivity of the TT system to design parameters is also investigated to indicate to which parameters the design is sensitive to and where small variations of these parameters require due consideration for future and analysis of the TT railway system. / AFRIKAANSE OPSOMMING: Die Tubular Track (TT) spoorweg stelsel is 'n dubbel balk modulêre treinspoor sisteem bestaande uit twee gewapende beton balke waarop staal spore voortdurend ondersteun word. Die balke word gekoppel deur gegalvaniseerde staal stawe vir laterale styfheid en word deurlopend ondersteun deur grond fondamente, en kan gebruik word om konvensionele dwarslêer en ballast spoorweg ondersteuning te vervang. Die TT spoorweg stelsel was in die verlede met verskeie analiseringsmetodes ontleed, maar het teenstrydige resultate gewerf. Die teenstrydige resultate beteken dat een van die analise metodes wat gebruik word vir die analisering en ontwerp van TT spoorweg seksies 'n onderskatting of oorskatting van verplasings, kragte, en spannings is; of beide metodes kan selfs verkeerd wees. Die hoofklem van hierdie ondersoek is dus die ontwikkeling en veri kasie van statiese en dinamiese analitiese metodes en modellering tegnieke wat gebruik kan word om die TT spoorweg stelsel akkuraat te simuleer. Die resultate en modelle van die vorige ontledings word nie uitdruklik in hierdie proefskrif ondersoek nie, maar dien as 'n motivering van hierdie ondersoek. Die TT stelsel word ondersteun deur verskeie grond strata wat vertikale ondersteuning verskaf, maar meetkundige modellering van die grond strata in die ontledingsmodelle veroorsaak 'n hoë vlak van kompleksiteit wat nie bruikbaar is vir algemene analises waar grondeienskappe meestal onbekend is. Die elastiese fondament teorie word daarom gebruik om die interaksie tussen die balk en die fondament akkuraat te simuleer, en vereenvoudig dus die analitiese modelle voldoende. Vereenvoudiging van 'n grond fondament deur 'n grond styfheid ondersteuning van die TT balk te simuleer is ondersoek en ontleed deur die resultate van eindige element analises van verskillende grond modelle te vergelyk. Bekende ontwerp parameters van vier bekend grondformasies wat tans gebruik word by TT spoorweg seksies word vir hierdie analises gebruik. Die eindige element analises van die grondformasies dui daarop aan dat daar 'n lineêre verwantskap tussen die modulus van grond reaksie vir 'n vierkantige plaat dratoets en 'n reghoekige, oneindige lang plaat dratoets bestaan. 'n Vierkantige plaat dratoets kan dus op terrein uitgevoer en aangepas word om die werklike styfheid van die grond ondersteuning van die TT spoorweg sisteem voor te stel. Die analitiese modelle wat gebruik word wissel van eenvoudige teoretiese modelle wat gebaseer is op elastiese fondament beginsels, twee-dimensionele (2D) balk elemente, asook komplekse driedimensionele (3D) soliede eindige element modelle. Die modelle wat gebruik is vir die ondersoek is die Enkel en Dubbel Balk elastiese fondament, PROKON 2D balke, ABAQUS 2D balke en ABAQUS 3D soliede element modelle. Hierdie reeks bied 'n duidelike aanduiding watter analiseringsmetodes akkuraat en haalbaar is vir die ontwerp van die TT stelsel. 'n In-situ verwysingsmodel met bekende de eksies en ontwerp parameters wat spesi ek is vir 'n TT spoorweg seksie word gebruik om die akkuraatheid en geldigheid van die verskillende analitiese metodes te analiseer. Die Dubbel Balk, ABAQUS 2D en ABAQUS 3D modelle verkry baie soortgelyke verplasings, buigmomente en skuifkragte vir 'n statiese analise, terwyl die PROKON en Enkel Balk modelle onbevredigende resultate verkry. Die PROKON model onderskat die maksimum buigmomente en skuifkragte in die staal spoor, en oorskat buigmomente en skuifkragte in die gewapende beton balk. Hierdie resultaat kan moontlik lei tot die onderontwerp van die staal spoor en dwing moontlik vir die gewapende beton balk om blootgestel te word aan groter buigmomente en skuifkragte as vir wat dit oorspronklik ontwerp is, en verontagsaam sodoende moontlik die kragte waarvoor dit oorontwerp is. Dit versnel e ektief materiaal vermoeiing, wat die moontlike oorsaak is van die klein krake wat gevind is in die gewapende beton balke op sommige TT spoorweg seksies wat tans ondersoek word. 'n Gra ese gebruikerskoppelvlak van die Dubbel Balk model is verskaf vir vinnige en doeltre ende ontleding. Empiriese metodes om die dinamiese aard van 'n spoorweg-stelsel te simuleer word dikwels gebruik in die bedryf om dinamiese belasting te vereenvoudig deur middel van die gebruik van 'n dinamiese amplitude faktor (DAF) wat op 'n statiese belasting aangewend word. 'n Implisiete dinamiese eindige element analise word dus uitgevoer om die DAF te ondersoek, wat daarna gebruik word vir die vergelyking met die in-situ de eksie resultate van die in-situ verwysingsmodel. Die resultate van die dinamiese analise bevestig dat die voorgestelde empiriese analise metode gebruik kan word, omdat die verplasings wat verkry baie soortgelyk was aan werklike veld toets resultate, en daardeur ook die veri ëring van die akkuraatheid van die voorgestelde analise metodes bewerkstellig. Die sensitiwiteit van die TT stelsel vir ontwerp parameters word ook ondersoek om aan te dui watter parameters die ontwerp voor sensitief is, en waar klein variasie in hierdie ontwerp parameters behoorlike oorweging vereis vir die toekomstige analisering en ontwerp van die TT spoorweg stelsel.

No description available.

A dissertação de mestrado desenvolvida tem como objetivo colaborar com a avaliação conceitual da forma erosiva terracete de pisoteio de gado, ainda pouco desenvolvida e, avaliar as perturbações do meio físico associadas ao pisoteio de gado. O objetivo da pesquisa torna-se relevante ao constatar que a temática desenvolvida é objeto de poucas produções acadêmicas. Além disso, no caso brasileiro, a grande área de terras utilizadas para a pastagem gera a necessidade de entendimento do funcionamento dessa paisagem antrópica para se produza formas corretas de manejo e possíveis restrições para o uso do solo a fim de evitar perturbações no meio físico difíceis de serem revertidas. Para elaborar a análise proposta, utilizou-se como embasamento teórico-metodológico a Geomorfologia Antropogênica em que a sociedade humana é inserida como agente de formação do relevo mesmo que indiretamente como no caso de áreas para a pastagem. Na perspectiva da Geomorfologia Antropogênica é necessário uma abordagem multiescalar para entender a magnitude das perturbações geradas no meio físico pelo ser humano. A primeira linha de investigação para o desenvolvimento da dissertação foi a pesquisa bibliográfica multilíngüe sobre o verbete terracete de pisoteio de gado. Completando a pesquisa bibliográfica, a segunda linha de investigação foi a analise em campo das perturbações do meio físico associadas aos terracetes de pisoteio de gado, com parâmetros físicos do solo e morfológicos da vertente. Como área de estudo, foi escolhida uma vertente amostral da parte rural da cidade de Joanópolis SP. A vertente amostral pertence ao Planalto Atlântico com solos pouco espesso e uso agrícola intensa, possibilitando a comparação entre do trecho da vertente preservado e o trecho antrópico com pastagem. Na vertente amostral foram aplicadas técnicas de campo reconhecidas academicamente. Como procedimento inicial utilizou-se o pantômetro por permitir o cálculo preciso da declividade. Com a análise inicial em campo e a elaboração do perfil topográfico, foram selecionados três pontos de controle para a medição de resistência a penetração; medição da densidade do solo e; a análise morfológica do solo. Os resultados evidenciaram que as perturbações geomorfológicas e pedológicas criadas pelo rebanho bovino são intensas e de diversos tipos. O caminhar do gado também promove a exposição do solo, visto que dificulta ou impede o crescimento da pastagem, pois ao compactar o solo, gera resistência a penetração superior ao limite de crescimento radicular. A compactação do solo é mais profunda que o horizonte A e, em solos pouco espessos, como o neossolo estudado nessa pesquisa, o terracete de pisoteio de gado tem um limite físico para a sua profundidade a rocha parental. / The developed dissertation aims to collaborate with the conceptual evaluation of cattle-tracks erosive form, which studies are still little developed, and to evaluate the physical disturbance associated with cattle trampling. The objective of this research is relevant to add the developed subject itself, which has been presented in few academic productions. Besides that, in Brazilian case, the large land area used for grazing, generates the necessity to understand the functionality of the anthropic landscape, in order to produce correct forms of handling and possible use of land restrictions to avoid disturbances in the physical environment, which are difficult to be reversed. Composing the proposed analysis, it was applied as theoretic and methodological praxis the Antropic Geomorphology where in the society is an agent of relief formation even indirectly, like the case of grazing. In perspective of anthropic geomorphology is necessary a multi-scale approach to understand the magnitude of the disturbance generated in the physical environment caused by human being. The first investigation line for the development of this dissertation was the bibliographic multilingual search about the word cattletracks. In completion of the bibliographic search, the second investigation line was the analyses in field about the disturbance in physical environment associated to the cattle-tracks, with physical soil parameters and morphological slope parameters analyses. As study area, a sample slope of Joanópolis rural area was selected. The sample slope belongs to Atlantic plateau with shallow soil e intense agricultural use enabling comparison between the segment with cover forest and segment with grazing. In the sample slope, it was applied field techniques academical lyre cognized. And as an initial procedure it was used the pantometer, which allows accurate calculation of slope. Up the initial field analysis and profile elaboration, three control points were selected in order to measure the penetration resistance, measure the soil density and morphology. The results showed that geomorphological and pedological disturbance created by cattle was intense and from several types.The cattle grazing causes naked soil, because hinders or prevents the growth of pasture, therefore compacts the soil, creates penetration resistance upper to the limit root growth. The soil compact is deeper than the horizon A and, in shallow soil, as the soil of this research, the cattle-tracks has a physical limit for its deepness, which is the parent rock.

Vestiges fragiles et longtemps mésestimés, les empreintes constituent une source précieuse d’informations concernant la fréquentation d’un site. Actuellement largement étudiées en contexte de plein air, elles le sont beaucoup moins en grotte, contexte dans lequel leur étude a connu son apogée entre les années 1970 et le début des années 2000. Ces dernières années, l’intérêt des préhistoriens pour l’ichnologie en milieu souterrain s’est de nouveau manifesté et s’est concrétisé par la reprise de l’étude des empreintes dans plusieurs grottes ornées. Notre étude s’inscrit dans cette dynamique et vise à contribuer à la recherche autour des empreintes à partir du registre karstique et à participer au renouvèlement de la discipline en Préhistoire. Notre intérêt s’est porté sur les empreintes des grottes de Fontanet (Ariège) et de Cussac (Dordogne), d’abord du point de vue de leur formation et de leur conservation au cours du temps, puis de leur contribution à la compréhension de l’appréhension du monde souterrain par l’Homme au Paléolithique.À travers des observations, inventaires, mesures in situ et un travail ex situ grâce aux outils d’imagerie tridimensionnelle, nous avons mené une étude morphologique et morphométrique des empreintes fossiles. La singularité des empreintes de pied de Cussac nous a, en outre, amené à développer une approche expérimentale afin d’appréhender les différents facteurs ayant pu influencer leur morphologie au moment de leur formation et après celle-ci (taphonomie, port de chaussant, autre ?). Ces expérimentations ont mis en évidence un impact du substrat et de sa remobilisation sur la morphologie générale et les dimensions de l'empreinte, ainsi que la préservation de détails comme les orteils. La réalisation d'empreintes à l'aide de chaussants expérimentaux a conduit de plus à envisager l'utilisation de ce type de protection dans la grotte. Notre approche à la fois pluri et interdisciplinaire permet d’affirmer l’unicité des grottes de Fontanet et de Cussac d’un point de vue ichnologique, archéologique et géomorphologique. Tandis qu’à Cussac, la présence humaine semble avoir été limitée (aller/s et retour/s) et avoir répondu à un objectif précis (réalisation des gravures et dépôts humains ?), à Fontanet, la fréquentation semble s’être inscrite dans la durée et a impliqué plusieurs catégories d’individus (présence de juvéniles) et des activités variées.Des comportements souterrains similaires et qui se retrouvent durant l’ensemble du Paléolithique sont aussi mis en évidence (exploration globale des cavités, etc.). Ces travaux se présentent alors comme une contribution essentielle aux discussions relatives à la fonction de ces deux cavités. / Tracks, which are among the most fragile and underestimated archaeological remains, represent a valuable source of information on site frequentation. In the past few years, they were widely studied in open air contexts. However, their analysis in caves, a context in which their study reached its peak between the 1970s and the early 2000s, is much less common. Recently, interest towards ichnology in subterranean environments re-emerged among prehistorians, and the study of tracks in several decorated caves was resumed. Our study is part of this dynamic and aims to contribute to research on tracks from the karst register and to participate in the renewal of the discipline in Prehistory. We study the footprints of the caves of Fontanet (Ariège) and Cussac (Dordogne), focusing firstly on their formation and conservation over time, and secondly on their contribution to the understanding of the subterranean environment appropriation by human in the Palaeolithic.Through observations, inventories, in situ measurements and ex situ work based on three-dimensional imaging tools, we conducted a morphological and morphometric study of fossil tracks. In addition, we have developed an experimental approach to understand the various factors that may have influenced the morphology of footprints at the time of their formation and since their formation. This multidisciplinary and interdisciplinary approach makes it possible to affirm the uniqueness of the Fontanet and Cussac caves from an ichnological, archaeological and geomorphological point of view and at the same time reveals similar behaviours that can be found throughout the Paleolithic period. The profile of individuals who have frequented these two cavities gradually takes shape. We propose several hypotheses concerning their behaviour and activities in this confined and naturally constraining space and contribute to the discussions relating to the function of these two cavities.

Indium phosphide (InP) is an important III-V compound, with a variety of applications, for example, in light emitting diodes (LED), InP based photonic crystals and in semiconductor lasers, heterojunction bipolar transistors in integrated circuit applications and in transistors for microwave and millimeter-wave systems. The optical and electrical properties of this compound can be further tailored by ion implantation or prospectively by swift heavy ion beams. ¶ Thus knowledge of ion-induced disorder in this material is of important fundamental and practical interest. However, the disorder produced during heavy ion irradiation and the subsequent damage accumulation and recovery in InP is far from being completely understood. In terms of the damage accumulation mechanisms, the conclusions drawn in the numerous studies performed have often been in conflict with one another. A factor contributing to the uncertainties associated with these conflicting results is a lack of information and direct observation of the “building blocks” leading to the ultimate damage created at high ion fluences as an amorphous layer. These building blocks formed at lower fluence regimes by single ion impacts can be directly observed as isolated disordered zones and ion tracks for low energy and swift heavy ion irradiation, respectively. ¶ The primary aim of this work has thus been to obtain a better understanding of the disorder in this material through direct observations and investigation of disorder produced by individual heavy ions in both energy regimes (i.e. elastic and inelastic energy deposition regimes) especially with low ion fluence irradiations. In this thesis the heavy ion induced disorder introduced by low energy Au ions (100 keV Au+) and high energy Au (200 MeV Au+16) ion irradiation in InP were investigated using Transmission Electron Microscopy (TEM), Rutherford Backscattering Spectrometry (RBS/C) and Atomic Force Microscopy (AFM). ¶ The accumulation of damage due to disordered zones and ion tracks is described and discussed for both low energy and swift ion irradiation respectively. ¶ The in-situ TEM annealing of disordered zones created by 100 keV Au+ ion irradiation shows that these zones are sensitive to electron beam irradiation and anneal under electron energies not sufficient to elastically displace lattice atoms, i.e. subthreshold energies for both constituent atoms In and P. ¶ Ion tracks due to swift heavy ion irradiation were observed in this material and the interesting track morphology was described and discussed. The surface nanotopographical changes due to increasing fluence of swift heavy ions were observed by AFM where the onset of large increase in surface roughness for fluences sufficient to cause complete surface amorphization was observed. ¶ In addition to InP, the principle material of this project, a limited amount of TEM observation work has been performed on several other important compounds (apatite and monazite) irradiated by 200 MeV Au+ ions for comparative purposes. Again the observed segmental morphology of ion tracks were shown and possible track formation scenario and structure were discussed and similarities were drawn to the previously observed C60 cluster ion tracks in CaF2 as more knowledge and data base exist about defect dynamics and formation in that material.

<p>The work presented in this thesis concernes two sorts of nanostructures: energetic-ion-impact-induced surface tracks and gas-deposited WO₃ nanoparticles. Our aims to characterise these nanostuctures and understand the physical principles behind their formation are of general interests for basic science as well as of the field of nanotechnology.</p><p>AFM studies of irradiated organic surfaces showed that individual ion impacts generate craters, most often accompanied by raised plastically deformed regions. Crater sizes were measured as a function of ion stopping power and incidence angle on various surfaces. Observed crater volumes were converted into estimates of total sputtering yields, which in turn were correlated with data from collector experiments. The observations were compared to predictions of theoretical sputtering models. The observed plastic deformations above grazing-incidence-ion penetration paths agree with predictions of the pressure pulse model. However, closer to the ion track, evaporative sputtering can occur.</p><p>AFM images of gas-deposited WO₃ nanoparticle-films indicated the formation of agglomerates. The size distribution of the agglomerates was measured to be log-normal, <i>i.e.</i> similar to the size distribution of the gas-phase nanoparticles forming the deposit. By simulations we could relatively well reproduce this observation. The agglomerates exhibited high thermal stability below 250°C when considering their size, implying that these porous films can be useful in applications involving elevated temperatures in the 250°C range. The appearance of the nanoparticles in the tapping-mode AFM images was sensitive to the free amplitude of the oscillating tip. We could show by model calculations that the high adhesion between the tip and the sample could account for some of these observations.</p>

The work presented in this thesis concernes two sorts of nanostructures: energetic-ion-impact-induced surface tracks and gas-deposited WO3 nanoparticles. Our aims to characterise these nanostuctures and understand the physical principles behind their formation are of general interests for basic science as well as of the field of nanotechnology. AFM studies of irradiated organic surfaces showed that individual ion impacts generate craters, most often accompanied by raised plastically deformed regions. Crater sizes were measured as a function of ion stopping power and incidence angle on various surfaces. Observed crater volumes were converted into estimates of total sputtering yields, which in turn were correlated with data from collector experiments. The observations were compared to predictions of theoretical sputtering models. The observed plastic deformations above grazing-incidence-ion penetration paths agree with predictions of the pressure pulse model. However, closer to the ion track, evaporative sputtering can occur. AFM images of gas-deposited WO3 nanoparticle-films indicated the formation of agglomerates. The size distribution of the agglomerates was measured to be log-normal, i.e. similar to the size distribution of the gas-phase nanoparticles forming the deposit. By simulations we could relatively well reproduce this observation. The agglomerates exhibited high thermal stability below 250°C when considering their size, implying that these porous films can be useful in applications involving elevated temperatures in the 250°C range. The appearance of the nanoparticles in the tapping-mode AFM images was sensitive to the free amplitude of the oscillating tip. We could show by model calculations that the high adhesion between the tip and the sample could account for some of these observations.