This thesis examines and tests acids and conditions, which make the production of nanoporous ceramic at the thin aluminium layer the most effective and provide the highest quality. This paper describes the production of nanoporous structures with pore size 15-400 nm, depending on the electrolyte. Creating a regular hexagonal structure by electrochemical oxidation is dependent on many parameters that affect the regularity of structure and parameters of the ceramics produced. They were investigated primarily by changes in temperature and input voltage. All results were examined by SEM analysis.

Cette thèse est dédiée à une classe particulière de modèles à facteurs dynamiques non linéaires, les modèles à facteurs dynamiques à changement de régime markovien (MS-DFM). Par la combinaison des caractéristiques du modèle à facteur dynamique et celui du modèle à changement de régimes markoviens(i.e. la capacité d’agréger des quantités massives d’information et de suivre des processus fluctuants), ce cadre s’est révélé très utile et convenable pour plusieurs applications, dont le plus important est l’analyse des cycles économiques.La connaissance de l’état actuel des cycles économiques est crucial afin de surveiller la santé économique et d’évaluer les résultats des politiques économiques. Néanmoins, ce n’est pas une tâche facile à réaliser car, d’une part, il n’y a pas d’ensemble de données et de méthodes communément reconnus pour identifier les points de retournement, d’autre part, car les institutions officielles annoncent un nouveau point de retournement, dans les pays où une telle pratique existe, avec un délai structurel de plusieurs mois.Le MS-DFM est en mesure de résoudre ces problèmes en fournissant des estimations de l’état actuel de l’économie de manière rapide, transparente et reproductible sur la base de la composante commune des indicateurs macroéconomiques caractérisant le secteur réel.Cette thèse contribue à la vaste littérature sur l’identification des points de retournement du cycle économique dans trois direction. Dans le Chapitre 3, on compare les deux techniques d’estimation de MS-DFM, les méthodes en une étape et en deux étapes, et on les applique aux données françaises pour obtenir la chronologie des points de retournement du cycle économique. Dans Chapitre 4, sur la base des simulations de Monte Carlo, on étudie la convergence des estimateurs de la technique retenue - la méthode d’estimation en deux étapes, et on analyse leur comportement en échantillon fini. Dans le Chapitre 5, on propose une extension de MS-DFM - le MS-DFM à l’influence dynamique (DI-MS-DFM)- qui permet d’évaluer la contribution du secteur financier à la dynamique du cycle économique et vice versa, tout en tenant compte du fait que l’interaction entre eux puisse être dynamique. / This thesis is dedicated to the study of a particular class of non-linear Dynamic Factor Models, the Dynamic Factor Models with Markov Switching (MS-DFM). Combining the features of the Dynamic Factor model and the Markov Switching model, i.e. the ability to aggregate massive amounts of information and to track recurring processes, this framework has proved to be a very useful and convenient instrument in many applications, the most important of them being the analysis of business cycles.In order to monitor the health of an economy and to evaluate policy results, the knowledge of the currentstate of the business cycle is essential. However, it is not easy to determine since there is no commonly accepted dataset and method to identify turning points, and the official institutions announce a newturning point, in countries where such practice exists, with a structural delay of several months. The MS-DFM is able to resolve these issues by providing estimates of the current state of the economy in a timely, transparent and replicable manner on the basis of the common component of macroeconomic indicators characterizing the real sector. The thesis contributes to the vast literature in this area in three directions. In Chapter 3, I compare the two popular estimation techniques of the MS-DFM, the one-step and the two-step methods, and apply them to the French data to obtain the business cycle turning point chronology. In Chapter 4, on the basis of Monte Carlo simulations, I study the consistency of the estimators of the preferred technique -the two-step estimation method, and analyze their behavior in small samples. In Chapter 5, I extend the MS-DFM and suggest the Dynamical Influence MS-DFM, which allows to evaluate the contribution of the financial sector to the dynamics of the business cycle and vice versa, taking into consideration that the interaction between them can be dynamic.

<p>  </p> <p>Organic-inorganic halide perovskites are at the brink of commercialization as the next generation of light-absorbing materials for solar energy harvesting devices. Perovskites have large absorption coefficients, long charge-carrier lifetimes and diffusion lengths, and a tunable absorption spectrum. Furthermore, these materials can be low-temperature solution-processed, which transfers to low-cost manufacturing and cost-competitive products. The remarkable material properties of perovskites enable a broad product-market fit, encompassing traditional and new applications for solar technology. Perovskites can be deposited on flexible substrates for flexible solar cells, applied in thermochromic windows for power generation and building cooling, or tuned for tandem solar cell application to include in high-performance solar panels. However, perovskites are intrinsically unstable, which has so far prevented their commercialization. Despite large research efforts, including over two thousand publications per year, perovskite solar cells degrade in under one year of operation. In a saturated research field, new ideas are needed to inspire alternative approaches to solve the perovskite stability problem. In this dissertation, we detail research efforts surrounding the concept of a self-healing perovskite solar cell.</p> <p>     A self-healing perovskite solar cell can be classified with two distinctions: mechanically healing and molecularly healing. First, mechanically self-healing involves the material’s ability to recover its intrinsic properties after mechanical damage such as tares, lacerations, or cracking. This type of healing was unique to the organic polymer community and ultra-rare in semiconducting materials. By combining a self-healing polymer with perovskite material, we developed a self-healing semiconducting perovskite composite material which can heal using synergistic grain growth and solid-state diffusion processes at slightly elevated temperatures. The material is demonstrated in flexible solar cells with improved bending durability and a power conversion efficiency reaching 10%. The addition of fluidic polymer enables macroscopic perovskite material movement, which is otherwise brittle and rigid. The results inspire the use of polymer scaffolds for mechanically self-healing solar cells.</p> <p>     The second type of healing, molecular healing, involves healing defects within the rigid crystal domains resulting from ion migration. The same phenomenon which leads to device degradation, also assists the recovery of the device performance after resting the device in the dark. During device operation, perovskite ions diffuse in the perovskite lattice and accumulate at the device interfaces where they undergo chemical reactions or leave the perovskite layer, ultimately consuming the perovskite precursors. The photovoltaic performance can be recovered if irreversible degradation is limited. Ideally, degradation and recovery can match day and night cycling to dramatically extend the lifetime of perovskite solar cells. In this dissertation, we introduce the application of chalcogenide chemistry in the fabrication of perovskite solar cells to control the thin film crystallization process, ultimately to reduce defects in the perovskite bulk and introduce surface functionality which extends the device stability. This new strategy will help improve molecularly self-healing perovskite solar cell by reducing irreversible degradation. Lastly, we present a few other new ideas to inspire future research in perovskite solar cells and assist in the commercialization of the next generation of photovoltaics.</p>