Significant effort has been placed on the development of surfaces which reduce the amount of drag experienced by a fluid as it passes over the surface. Alterations to the fluid itself, as well as the chemical and physical composition of the surface have been investigated with varying success. Investigations into turbulent drag reduction have been mostly limited to those involving bubbles and riblets. Superhydrophobic surfaces, which combine hydrophobic surface chemistry with a regular array of microfeatures, have been shown to provide significant drag reduction in the laminar regime, with the possibility of extending these results into turbulent flows. Direct numerical simulations are used to investigate the drag reducing performance of superhydrophobic surfaces in turbulent channel flow. Slip velocities, wall shear stresses, and Reynolds stresses are considered for a variety of superhydrophobic surface microfeature geometry configurations at friction Reynolds numbers of Re = 180, Re = 395, and Re = 590. This work provides evidence that superhydrophobic surfaces are capable of reducing drag in turbulent flow situations by manipulating the laminar sublayer and turbulent energy cascade. For the largest micro-feature spacing of 90 microns an average slip velocity over 80% of the bulk velocity is obtained, and the wall shear stress reduction is found to be greater than 50%. The simulation results suggest that the mean velocity profile near the superhydrophobic wall continues to scale with the wall shear stress, but is offset by a slip velocity that increases with increasing micro-feature spacing.

One approach recently proposed for reducing the frictional resistance to liquid flow in microchannels is the patterning of micro-ribs and cavities on the channel walls. When treated with a hydrophobic coating, the liquid flowing in the microchannel wets only the top surfaces of the ribs, and does not penetrate into the cavities, provided the pressure is not too high. The net result is a reduction in the surface contact area between channel walls and the flowing liquid. For micro-ribs and cavities that are aligned normal to the channel axis (principal flow direction), these micropatterns form a repeating, periodic structure. This thesis presents numerical results of a study exploring the momentum and thermal transport in a parallel plate microchannel with such microengineered walls. The liquid-vapor interface (meniscus) in the cavity regions is approximated as flat in the numerical analysis. Two conditions are explored with regard to the cavity region: 1) The liquid flow at the liquid-vapor interface is treated as shear-free (vanishing viscosity in the vapor region), and 2) the liquid flow in the microchannel core and the vapor flow within the cavity are coupled through the velocity and shear stress matching at the interface. Predictions reveal that significant reductions in the frictional pressure drop (as large as 80%) can be achieved relative to the classical smooth channel Stokes flow. In general, reductions in the friction factor-Reynolds number product (fRe) are greater as the cavity-to-rib length ratio is increased (increasing shear-free fraction), as the relative module length (length of a rib-cavity module over the channel hydraulic diameter) is increased, as the Reynolds number decreases, and as the vapor cavity depth increases. The thermal transport results predict lower average Nusselt (Nu) numbers as the cavity-to-rib length ratio is increased (increasing shear-free fraction), as the relative module length (is increased, and as the Reynolds number decreases with little dependence on cavity depth. The ratio of Nu to fRe was evaluated to characterize the relative change in heat transfer with respect to the reduction in driving pressure. Results show that the benefits of reduction in driving pressure outweigh the cost of reduction in heat transfer at higher Reynolds numbers and narrower relative channel widths.

Due to the increase of application in a number of emerging technologies, a growing amount of research has focused on the reduction of drag in microfluidic transport. A novel approach reported in the recent literature is to fabricate micro-ribs and cavities in the channel wall that are then treated with a hydrophobic coating. Such surfaces have been termed super- or ultrahydrophobic and the contact area between the flowing liquid and the solid wall is greatly reduced. Further, due to the scale of the micropatterned structures, the liquid is unable to wet the cavity and a liquid meniscus is formed between ribs. This creates a liquid-vapor interface at the cavity regions and renders surfaces with alternating regions of no-slip and of reduced shear on the microscale. This thesis reports the numerical study of hydrodynamically fully-developed laminar and turbulent flows through a parallel plate channel with walls exhibiting micro-ribs and cavities oriented parallel to the flow direction, where fully developed turbulent flow is considered in a time-averaged sense. Three laminar flow models are implemented to investigate the liquid-vapor interface and to account for the effects of the vapor motion in the cavity regions. For each of the laminar flow models, the liquid-vapor interface was idealized as a flat interface. As a benchmark for the proceeding laminar flow models, the first model considers the case of a vanishing shear stress at the interface between the liquid and vapor domains. Effects of the vapor motion in the cavity are then accounted for in a one-dimensional cavity model where the vapor velocity is considered to be dependent on the wall normal coordinate only, followed by a two-dimensional cavity model that accounts for the vapor velocity's dependence on the transverse coordinate as well. The vapor cavity is modeled analytically and is coupled to the liquid domain by equating the fluid velocities and shear stresses at the liquid-vapor interface. In the turbulent flow model the liquid-vapor interface is idealized as a flat interface with a zero shear stress boundary condition. In general the numerical predictions show a reduction in the total frictional resistance as the cavity width is increased relative to the channel width, the channel height-to-width aspect ratio is decreased, and the vapor cavity depth is increased. The frictional resistance is also reduced with increased Reynolds number in the turbulent flow case. In the range of parameters examined for each fluid flow regime, reductions in drag as high as 91% and 90% are reported for the laminar flow and turbulent flow models, respectively. Under similar conditions however, the turbulent flow results indicate a greater reduction in flow resistance than for the laminar flow scenario. Based on an analysis of the obtained data, analytical expressions are proposed for both laminar and turbulent flow which facilitates the prediction of the frictional resistance.

Selbstreinigende, ultrahydrophobe Oberflächen lassen sich in der Technik vielfältig einsetzen. Das ultrahydrophobe Verhalten beruht einerseits auf einer Rauigkeit im μm-Bereich und andererseits auf der chemischen Zusammensetzung der Oberfläche. Durch den gegebenen Oberflächenaufbau sind derartige Materialien jedoch empfindlich gegen Verschleiß. In diesem Beitrag wird ein Schichtverbund bestehend aus Aluminiumoxid und zwei polymeren Komponenten vorgestellt. Die Aluminiumoxidschicht wird auf dem Wege der anodischen Oxidation erzeugt. Dieses seit langem bekannte Verfahren ermöglicht nicht nur die Oxidation der Aluminiumoberfläche, sondern gestattet es, auch, definierte Oberflächenprofile einzustellen. Durch den gezielten Einbau des hochmolekularen Polymers Chitosan in die mikroprofilierte Aluminiumoxidschicht wurde eine mechanische Stabilisierung der Schicht im Sinne eines anorganisch-organischen Composites erreicht. Außerdem dienten die Amino-Seitengruppen des Chitosans als reaktives Interface für die notwendige chemische Hydrophobierung und als Reaktionszentrum für Vernetzungen, wodurch eine weitere mechanische Stabilisierung bewirkt wird. Der Schichtaufbau hat wesentlichen

Periodic, micropatterned superhydrophobic surfaces, previously noted for their ability to provide drag reduction in the laminar flow regime, have been demonstrated capable of reducing drag in the turbulent flow regime as well. Superhydrophobic surfaces contain micro or nanoscale hydrophobic features which can support a shear-free air-water interface between peaks in the surface topology. Particle image velocimetry and pressure drop measurements were used to observe significant slip velocities, shear stress, and pressure drop reductions corresponding to skin friction drag reductions approaching 50%. At a given Reynolds number, drag reduction was found to increase with increasing feature size and spacing, as in laminar flows. No observable drag reduction was noted in the laminar regime, consistent with previous experimental results and theoretical predictions for the channel geometry considered. In turbulent flow, viscous sublayer thickness appears to be the relevant length scale as it approaches the scale of the superhydrophobic microfeatures; performance was seen to increase with further reduction of the viscous sublayer. These results indicate superhydrophobic surfaces may provide a significant drag reducing mechanism for marine vessels.

Selbstreinigende, ultrahydrophobe Oberflächen lassen sich in der Technik vielfältig einsetzen. Das ultrahydrophobe Verhalten beruht einerseits auf einer Rauigkeit im μm-Bereich und andererseits auf der chemischen Zusammensetzung der Oberfläche. Durch den gegebenen Oberflächenaufbau sind derartige Materialien jedoch empfindlich gegen Verschleiß. In diesem Beitrag wird ein Schichtverbund bestehend aus Aluminiumoxid und zwei polymeren Komponenten vorgestellt. Die Aluminiumoxidschicht wird auf dem Wege der anodischen Oxidation erzeugt. Dieses seit langem bekannte Verfahren ermöglicht nicht nur die Oxidation der Aluminiumoberfläche, sondern gestattet es, auch, definierte Oberflächenprofile einzustellen. Durch den gezielten Einbau des hochmolekularen Polymers Chitosan in die mikroprofilierte Aluminiumoxidschicht wurde eine mechanische Stabilisierung der Schicht im Sinne eines anorganisch-organischen Composites erreicht. Außerdem dienten die Amino-Seitengruppen des Chitosans als reaktives Interface für die notwendige chemische Hydrophobierung und als Reaktionszentrum für Vernetzungen, wodurch eine weitere mechanische Stabilisierung bewirkt wird. Der Schichtaufbau hat wesentlichen