This dissertation presents a discussion of blocky and randomly functionalized sulfonated syndiotactic polystyrene copolymers. These copolymers have been prepared over a range of functionalization (from 2% to 10%) in order to assess the effect of the incorporation of these polar side groups on both the thermal behavior and morphology of these polymer systems. The two different architectures are achieved by conducting the reaction in both the heterogeneous gel-state to obtain blocky copolymers and in the homogeneous solution state to obtain randomly functionalized copolymers. In order to compare both the thermal properties and morphology of these two systems several sets of samples were prepared at comparable levels of sulfonation. Thermal analysis of these two systems proved that the blocky functionalized copolymers provided superior properties with regard to the speed and total amount of the crystalline component of sulfonated syndiotactic polystyrene. Above 3% functionalizion the randomly functionalized copolymer was no longer able to crystallize, whereas, the blocky functionalized copolymer is able to crystallize even at a functionalization level of 10.5% sulfonate groups. When considering the morphology of these systems even at low percentages of sulfonation it is clear that the distribution of these groups is different based on the amplitude of the signal measured by small angle x-ray scattering. Additionally, methods were developed to describe both the distribution of ionic multiplets, which varies between blocky and randomly functionalized systems, but also the distribution of crystals. At a larger scale ultra-small angle x-ray scattering was employed to attempt to understand the clustering of ionic multiplets in these systems. Randomly functionalized polymers should a peak that is attributed to ion clusters, whereas blocky polymers show no such peak. Additional studies have also been done to look at the analysis of crystallite sizes in these systems when there are multiplet polymorphs present, it was observed the polymorphic composition is drastically different. All of these studies support that these systems bear vastly different thermal behavior and possess significantly different morphologies. This supports the hypothesis that this gel-state heterogeneous functionalization procedure produces a much different chain architecture compared to homogeneous functionalization in the solution-state. / Doctor of Philosophy / Polymers are a class of chemicals that are defined by having a very large set of molecules that are chemically linked together where each unit (monomer) is repeated within the chemical structure. In particular, this dissertation focuses on the construction what are termed as "blocky" copolymers, which are defined by having two chemically different monomers that are incorporated in the polymer chain. The "blocky" characteristic of these polymers means that these two different monomers are physically segregated from each other on the polymer chain, where long portions of the chain that are of one type, followed by another section of the polymer that has the other type of monomer. The goal of creating this type of structure is to try to take advantage of the properties of both types of monomers, which can create materials with superior synergistic properties. In this case a hydrophobic (water hating) monomer is combined with a hydrophilic (water loving) chain. This hydrophobic component in the polymer is able to crystallize, which provides mechanical and thermal stability in the material by acting as a physical tether to hold neighboring chains together. With the other set of hydrophilic monomers, which in this case have an ionic component incorporated, we can now take advantage of this chemical components ability to aide in the transportation of ions. Transportation of ions is useful in a variety of commercially relevant applications, two of the most important applications of these ionic materials is in membranes that can be used to purify water or membrane materials in fuel cell technologies, specifically for proton exchange membranes. The focus of this research in particular was to create a simple synthesis technique that can create these blocky polymer chain architectures, which is done by performing the reaction while the polymer is made into a gel. The key to this is that the crystals within the gel act as a barrier to chemical reactions, creating conditions where we have substantial portions of the material that are able to be functionalized and the crystals within the material that are protected from being functionalized. By looking at the thermal characteristics, such as melting temperatures and amount of crystals within these systems we have seen that functionalizing these polymers in the heterogeneous gel state gives substantially better properties than functionalizing these materials randomly. Much like oil and water, incompatible polymer chains will phase separate from each other. In this case the hydrophobic and ionic components will phase separate from each other. The shape and distribution of these phase separated structure will dictate many of the material properties, which can be described by modeling the data collected from x-ray scattering experiments. All of this information will tell us based on the initial conditions that these polymers were created in, what properties should be expected based on the morphology and thermal behavior. This gives a better understanding of how to fine tune these properties based on the structure of the gel and chemical reaction conditions.

Este trabalho visa o projeto, modelagem e fabricação de estruturas multicamadas baseadas em polímeros para aplicações como sensores ópticos integrados. A grande motivação para este trabalho está no fato de que estas estruturas, diferente da geometria Mach-Zehnder, dispensam o uso de litografia pois são completamente planares. Isto permite uma diminuição no custo de fabricação dos dispositivos além de permitir que estruturas mais curtas sejam utilizadas. Em se tratando de óptica integrada, as dimensões reduzidas da estrutura impõem severas penalidades no processo de lançamento de potência óptica na mesma. Por isso, será considerada neste estudo a utilização de prismas para o acoplamento de entrada do acoplador. Esta técnica, além de reduzir drasticamente os problemas de alinhamento decorrentes de acoplamento convencional do tipo \"End Fire\", permite uma transferência de potência óptica superior a 80% entre a fibra e o guia retangular. As variações na transferência de potência entre os guias de ondas da estrutura multicamada serão medidas através de um fotodetetor MSM integrado ao sensor. Este detetor, além de sua extrema facilidade de fabricação e baixos custos, torna o conjunto sensor mais robusto. Em se tratando de uma proposta de plataforma para sensores, serão também investigadas possíveis aplicações para esta estrutura, como por exemplo: refratômetro integrado, sensor de glicose, sensor de adulteração de combustível, etc. A análise das estruturas será efetuada por meio de técnicas de modelagem analíticas (Técnica da Matriz de Transferência - TMT e Teoria de Modos Acoplados - TMA), e numéricas (Método da Propagação de Feixe de Ângulo Largo formulado em Diferenças Finitas - WA-FD-BPM). Esta última permite que a estrutura do fotodetetor seja levada em consideração simultaneamente nas simulações. / This work concerns with design, modeling and fabrication of polymer based planar multilayer structures for integrated optic sensor applications. The motivation for this work is that planar multilayer structures, differently from the Mach-Zehnder geometry, do not require a lithographic process. As a consequence, significantly cheaper and shorter structures can be realized. The reduced dimensions of the structure, by its turn, pose a severe penalty in terms of optical power coupling. Therefore, this investigation will focus primarily on input (and output) prism coupling configuration. This technique, besides reducing the alignment requirements observed for conventional end-fire coupling, allows optical power coupling efficiency as high as 80% from fiber to rectangular waveguide. Any optical power transfer between the waveguides of the multilayer structure will be detected by an MSM photodetector integrated with the sensor. This low cost photodetector, besides improving the structure robustness, is quite ease to fabricate. Since the idea of this work is to develop a platform for integrated optic sensors, it will also be investigated possible applications for this structure, such as: integrated optic refractometer, glucose sensor and fuel adulteration sensor. The analysis of such structures will be carried out by means of analythical (Transfer Matrix Technique-TMT and Coupled Mode Theory-CMT) and numerical (Wide-Angle Finite Difference Beam Propagation Method-WA-FD-BPM) modeling techniques. The WA-FD-BPM technique allows one to simulate the multilayer waveguide and the MSM photodetector simultaneously.

Le bassin Ionien, en Méditerranée centrale, abrite une zone de subduction à vergence Nord-Ouest où la plaque Afrique plonge sous les blocs Calabro-Péloritain au Nord-Est de la Sicile. Cette subduction résulte de la lente convergence entre les plaques tectoniques Afrique et Eurasiatique. Bien que de nombreuses campagnes d’exploration scientifique ont été menées dans cette zone particulière, plusieurs questions géodynamiques restent débattues. Tout d’abord la croûte pavant le bassin Ionien pourrait être soit de nature continentale amincie et représenter une extension de la plaque Afrique, soit océanique (Néo-Téthys) faisant de ce bassin l’un des plus anciens domaines océaniques au monde. L’escarpement de Malte représente un vestige de l’ouverture du bassin, mais les mécanismes de rifting et notamment la géométrie d’ouverture du bassin restent débattus. Cette subduction est en retrait vers le Sud-Est depuis les derniers 35 Ma, mais est aujourd’hui confinée à l’étroit bassin Ionien. Afin d’accommoder ce retrait de la plaque plongeante dans le bassin, une grande faille de déchirure lithosphérique de bord de subduction (STEP fault en anglais pour « subduction Transform Edge Propagator ») doit se propager le long de la marge Est-Sicilienne. Cependant, sa position en surface reste difficile à déterminer dans l’épais prisme d’accrétion recouvrant le bassin. Ces questions ont été explorées par modélisation des données de sismique grand angle de la campagne DIONYSUS (Octobre 2014, R/V Meteor) le long de deux profils perpendiculaires à la marge Est-Sicilienne. Des modélisations gravimétriques en 3D ont aussi été réalisées dans le but de localiser la plaque plongeante en profondeur sous les blocs Calabro-Péloritains. La sismicité des trois structures majeures du bassin : l’escarpement de Malte, l’AFS (Alfeo Fault System), et l’IFS (Ionian Fault System) a permis d’étudier leurs activités à l’actuel. Les résultats obtenus permettent d’observer une croûte océanique au fond du bassin. La structure profonde de l’escarpement de Malte est observée comme une zone d’amincissement crustal abrupt, ce qui est caractéristique des marges transformantes. Un profond bassin sédimentaire asymétrique (11 km) est observé au Sud du détroit de Messine. Il s’est probablement ouvert récemment entre les blocs continentaux Péloritain et Calabre. Dans le lobe Ouest du prisme d’accrétion Calabrais, le modèle de vitesse permet d’observer l’indentation du prisme clastique interne dans le prisme évaporitique externe. Des modélisations analogiques utilisant sable et silicone ont permis de démontrer la récente activité de ce lobe. L’interprétation des modèles de vitesse permet de localiser la faille STEP le long de l’AFS sur les deux profils. / In the Ionian Sea (central Mediterranean) the slow convergence between Africa and Eurasia results in the formation of a narrow subduction zone. The nature of the crust of the subducting plate remains debated and could represent the last remnants of the Neo-Tethys ocean. The origin of the Ionian basin is also under discussion, especially concerning the rifting mechanisms as the Malta Escarpment could represent a remnant of this opening. This subduction retreats toward the south-east (motion occurring since the last 35 Ma) but is confined to the narrow Ionian basin. A major lateral slab tear fault is required to accommodate the slab rollback.This fault is thought to propagate along the eastern Sicily margin but its precise location remains controversial.This PhD project focussed on the deep sedimentary and crustal structures of the eastern Sicily margin and the Malta Escarpment (ME). Two two-dimensional P wave velocity models were modelled by forward Modelling of wide-angle seismic data, acquired onboard the R/V Meteor during the DIONYSUS cruise in 2014.A 3D gravity model of the region was also performed to constrain the depth of the subducting slab bellow the Calabro-Peloritan backstops. The seismicity of the three structures identified in the velocity models (ME, Alfeo fault System, Ionian Fault System) permits to study their recent activity. The results image an oceanic crust within the Ionian basin as well as the deep structure of the Malta Escarpment, which presents characteristics of a transform margin. A deep and asymmetrical sedimentary basin is imaged south of the Messina strait and seems to have opened between the Calabrian and Peloritan continental terranes. In the western lobe of the Calabrian accretionary prism, the southern velocity model allows to observe the indentation of the internal clastic wedge into the external evaporitic wedge, thus showing the recent activity of this lobe. The interpretation of the velocity models suggests that the major STEP fault is located east of the Malta Escarpment, along the Alfeo Fault System.

L'inversion des marges passives apparaît comme le premier stade vers l'initiation de nouvelles zones de subduction. Cette étape cruciale dans la tectonique des plaques soulève néanmoins encore de nombreuses questions. L'étude des marges actuellement réactivées en compression apparaît ainsi comme essentielle pour mieux comprendre ce processus. Ces marges sont peu nombreuses, situées dans des contextes géodynamiques variés, et les facteurs déterminant leur évolution mal contraints. Située au nord de l'Afrique, la marge algérienne fait partie de ces rares exemples potentiels à travers le monde. L'évolution de cette marge formée au Miocène en contexte d'arrière-arc s'intègre dans le puzzle complexe de l'histoire de la Méditerranée occidentale. Elle est depuis quelques millions d'années réactivée en compression dans le cadre de la convergence lente entre les plaques européenne et africaine, générant un potentiel sismogène fort au nord de l'Algérie. La relative jeunesse du bassin algérien, la charge sédimentaire, les forces aux limites compressives, constituent des conditions favorables à la formation d'une future subduction. A la suite des travaux menés depuis une dizaine d'années, les principales lacunes de connaissances identifiées portent sur (1) la structuration profonde du bassin algérien et de sa marge sud (type de marge, nature du socle,dimension et nature de la transition océan-continent, style et distribution de la déformation compressive), et (2) l'histoire de l'évolution cinématique et géodynamique du bassin, ce qui limite à l'heure actuelle une analyse approfondie des modalités d'inversion de cette marge. L'étude menée se focalise sur la marge centre-algérienne, dans le secteur de Tipaza (à l'ouest d'Alger), un endroit clé pour la compréhension des mécanismes d'ouverture du bassin algérien. Le traitement et l'analyse de nouvelles données de sismique profonde grand-angle et multitraces acquises dans le cadre du projet franco-algérien SPIRAL (Sismique Profonde et Investigations Régionales en Algérie, 2009) ont notamment permis de déterminer la structure crustale du bassin algérien et de sa marge sud, ainsi que la structuration pseudo-3D d'une structure spécifique au secteur d'étude constituée par le haut topographique sous-marin de Khayr-al-Din. L'analyse de la structure profonde de la marge indique un certain nombre de structures héritées de son évolution complexe : (1) une croûte de nature continentale de plus de 15 km d'épaisseur sur le haut de marge (banc de Khayr-al-Din), (2)une croûte fine de nature océanique de 5-6 km d'épaisseur dans le bassin incluant des vitesses légèrement élevées à sa base (7,2 km/s - 7,3 km/s), (3) des similitudes avec des marges formées dans des contextes de déformation transformante, (4) un approfondissement progressif de l'ensemble de la pile sédimentaire et l'épaississement des sédiments Plio-Quaternaire, depuis le bassin profond distal vers le pied de marge,coïncidant avec (5) une flexuration à grande longueur d'onde du socle. Les résultats obtenus apportent de nouvelles contraintes sur (1) la géométrie et la nature de la marge et du bassin, (2) l'évolution de la marge,suggérant une histoire multiphasée comprenant un stade de rifting et/ou d'accrétion océanique, suivi d'un épisode de déformation coulissante tardive liée à la migration du bloc Alboran vers l'ouest, et d'une reprise en compression distribuée du bassin profond au haut de la marge au Plio-Quaternaire; (3) les modalités de réactivation qui se traduisent par des chevauchements aveugles néoformés à pendages sud, notamment au pied du banc de Khayr-al-Din, suggérant un soulèvement du banc de 0,2 mm/an à 0,75 mm/an au Plio-Quaternaire et un début d'écaillage crustal. / The inversion of passive margins appears to be one of the first steps towards the initiation of new subduction zones. This crucial step in plate tectonics nevertheless still raises many questions. The study of margins currently reactivated by compressional tectonics is thus essential to better understand this process. These margins are uncommon, located in different geodynamic settings, and the factors determining their evolution are poorly constrained. The Algerian margin, located in North Africa, is one of handful of modern examples worldwide. The evolution of this margin, rifted during the Miocene, in a back-arc setting, is part ofthe complex puzzle of the western Mediterranean. Since a few million years, the margin has suffered inversion and compression in the framework of slow on going convergence between the European and African plates. This convergence generates moderate to strong earthquakes in North Algeria. The relatively young age of the Algerian basin, the large sediment load, and the compressive forces, constitute favorable conditions to the formation of a future subduction zone. Studies from the past ten years indicate, that themain unresolved questions are related to (1) the deep structure of the Algerian basin and its southern margin (the type of margin, the nature of the basement, the dimension and nature of the ocean-continent transition, the style and the distribution of the compressional deformation), and (2) the history of the kinematic and geodynamic evolution of the basin. All of these unknowns have prevented a complete and thorough analysis of modalities of the Algerian margin inversion. This study focuses on the Central Algerian margin, in the area of Tipaza (West of Algiers), a key region to understand the mechanism of the opening of the Algerian basin. Processing and analysis of a deep wide-angle and multichannel seismic new data set acquired in the context of the French-Algerian project SPIRAL (Sismique profonde et Investigation Régionales en Algérie, 2009)have enabled us to determine the crustal structure of the Algerian basin and its southern continental margin,as well as the pseudo-3D structure of a specific feature in the study area: the submarine topographic highformed by the Khayr-al-Din bank. The analysis of the deep structure of the margin reveals features inherited from its complex evolution: (1) a crust of continental nature of more than 15 km thick at the upper margin(Khayr-al-Din Bank), (2) a thin crust of oceanic nature, 5-6 thick in the deep basin, including slightly high velocities at its base (7.2 km/s - 7.3 km/s), (3) similarities with margins formed in context of transform deformation, (4) a progressive deepening of the whole sedimentary cover and the thickening of the Plio-Quaternary sediments, from the distal deep basin towards the margin foot, coeval with (5) a long wavelengthflexuration of the basement in the basin. Results from this study provide new constraints on (1) the geometryand nature of the margin and the basin, (2) the evolution of the margin, suggesting a multiphased history including a stage of rifting and/or oceanic spreading, a transcurrent episode due to the westward migration of the Alboran block, and a diffuse Plio-Quaternary compressional reactivation distributed from the deep basinto the upper margin; (3) the mechanisms of the reactivation marked by newly formed south-dipping blind-thrusts, especially at the foot of the Khayr-al-Din bank, and suggesting a Plio-Quaternary uplift of the bankof 0.2 mm/y to 0.75 mm/y and the early stages of imbricate thrusting of crustal scales.

La marge NE Américaine est une des marges les mieux étudiées au monde, elle a fait l’objet de plusieurs études géophysiques. En comparaison, la marge africaine reste peu étudiée car uniquement deux campagnes océanographiques y ont été menées : la campagne Sismar (2001) au large de la Meseta et la campagne Dakhla (2002) au large du Sahara. La structure profonde de la marge canadienne est connue grâce aux profils de sismique grand-angle SMART-1, 2 et 3. Le premier objectif du projet MIRROR était d’acquérir des profils combinant sismique grand-angle et sismique réflexion sur un segment homologue au profil SMART-1. La comparaison entre les segments homologues de ces deux marges ayant pour but de mieux comprendre le mode d’ouverture de l'océan Atlantique Central. Une comparaison entre les modèles Sismar, Dakhla et Mirror montre que la croûte continentale est plus épaisse au nord et s'amincit vers le sud. La largeur de la zone de transition est plus étroite au sud et les profils Sismar sont localisés sur un bassin sédimentaire posé sur une croûte continentale très amincie. La comparaison avec la marge homologue montre que l'épaisseur, la structure de la croûte continentale et la zone d'amincissement sont très semblables. Par contre, il existe une zone de manteau exhumé et serpentinisé sur le profil Canadien qui n'a pas d’homologue sur la marge africaine. De plus, l'épaisseur de la croûte océanique est différente avec 8 km sur la côte africaine et seulement 3-4 km sur la marge canadienne. Plusieurs hypothèses ont été proposées pour expliquer cette différence (a) une différence d’âge entre les deux croûtes (b) un épaississement lié au passage du point chaud des Canaries (c) une accrétion asymétrique. / The NE American margin represents one of the best studied margins in the world, it was the subject of several scientific programs. In comparison, the conjugate NW African margin remains fairly unknown, only two deep seismic cruises were acquired: the SISMAR cruise (2001) offshore the Meseta and the DAKHLA cruise (2002) offshore the Sahara. The deep structure of the Canadian margin is known due to the SMART wide-angle seismic profiles 1, 2 and 3. The first objective of the MIRROR project was to acquire combined wide-angle and deep reflection seismic data offshore a segment conjugate to the SMART-1 profile. The comparison between the homologous segments of these two margins aimed to better understand the opening mechanism of the Central Atlantic Ocean. A comparison between Sismar, Dakhla and Mirror models shows that the continental crust is thicker in the north and thins toward the south. The width of the transition zone is narrower south and Sismar profiles are located on a sedimentary basin placed on a very thinned continental crust. Comparing the Mirror profile with that of the Canadian conjugate margin (Smart 1) shows that the thickness, the structure of the continental crust and the thinning is very similar. However, zones of exhumed and serpentinized mantle were imaged along the Canadian profile that have no conjugate on the African margin. Moreover, the thickness of the oceanic crust is variable with 8 km on the African side and only 3-4 km on the Canadian margin. Several hypotheses have been proposed to explain this difference (a) an age difference between the two types of crust (b) thickening associated with the passage of the Canary hotspot (c) an asymmetric accretion or (d) an accretion at slow to ultra-slow speading centers.

Este trabalho visa o projeto, modelagem e fabricação de estruturas multicamadas baseadas em polímeros para aplicações como sensores ópticos integrados. A grande motivação para este trabalho está no fato de que estas estruturas, diferente da geometria Mach-Zehnder, dispensam o uso de litografia pois são completamente planares. Isto permite uma diminuição no custo de fabricação dos dispositivos além de permitir que estruturas mais curtas sejam utilizadas. Em se tratando de óptica integrada, as dimensões reduzidas da estrutura impõem severas penalidades no processo de lançamento de potência óptica na mesma. Por isso, será considerada neste estudo a utilização de prismas para o acoplamento de entrada do acoplador. Esta técnica, além de reduzir drasticamente os problemas de alinhamento decorrentes de acoplamento convencional do tipo \"End Fire\", permite uma transferência de potência óptica superior a 80% entre a fibra e o guia retangular. As variações na transferência de potência entre os guias de ondas da estrutura multicamada serão medidas através de um fotodetetor MSM integrado ao sensor. Este detetor, além de sua extrema facilidade de fabricação e baixos custos, torna o conjunto sensor mais robusto. Em se tratando de uma proposta de plataforma para sensores, serão também investigadas possíveis aplicações para esta estrutura, como por exemplo: refratômetro integrado, sensor de glicose, sensor de adulteração de combustível, etc. A análise das estruturas será efetuada por meio de técnicas de modelagem analíticas (Técnica da Matriz de Transferência - TMT e Teoria de Modos Acoplados - TMA), e numéricas (Método da Propagação de Feixe de Ângulo Largo formulado em Diferenças Finitas - WA-FD-BPM). Esta última permite que a estrutura do fotodetetor seja levada em consideração simultaneamente nas simulações. / This work concerns with design, modeling and fabrication of polymer based planar multilayer structures for integrated optic sensor applications. The motivation for this work is that planar multilayer structures, differently from the Mach-Zehnder geometry, do not require a lithographic process. As a consequence, significantly cheaper and shorter structures can be realized. The reduced dimensions of the structure, by its turn, pose a severe penalty in terms of optical power coupling. Therefore, this investigation will focus primarily on input (and output) prism coupling configuration. This technique, besides reducing the alignment requirements observed for conventional end-fire coupling, allows optical power coupling efficiency as high as 80% from fiber to rectangular waveguide. Any optical power transfer between the waveguides of the multilayer structure will be detected by an MSM photodetector integrated with the sensor. This low cost photodetector, besides improving the structure robustness, is quite ease to fabricate. Since the idea of this work is to develop a platform for integrated optic sensors, it will also be investigated possible applications for this structure, such as: integrated optic refractometer, glucose sensor and fuel adulteration sensor. The analysis of such structures will be carried out by means of analythical (Transfer Matrix Technique-TMT and Coupled Mode Theory-CMT) and numerical (Wide-Angle Finite Difference Beam Propagation Method-WA-FD-BPM) modeling techniques. The WA-FD-BPM technique allows one to simulate the multilayer waveguide and the MSM photodetector simultaneously.

La demande toujours croissante de connectivité et de débit de données requiert une rupture dans la conception des futurs réseaux de communication et systèmes radio. Plusieurs applications émergentes en bande millimétrique, notamment les réseaux mobiles de cinquième génération (5G) et les communications satellites, exigent des antennes large bande qui assurent une grande couverture angulaire, tout en étant à la fois compactes, facilement intégrables et à bas coût.Cette thèse propose des systèmes antennaires multifaisceaux large bande et à très grande couverture angulaire, appelés «Continuous Transverse Stub Antenna» (CTS), pour réaliser un bon compromis de l’ensemble de ces objectifs. L’architecture de l’antenne comprend un réseau de fentes longues excitées par un réseau d’alimentation en chandelier, basé sur des guides d’onde à plans parallèles. Cette structure est excitée par un formateur de faisceaux quasi-optique co-intégré. La première partie du manuscrit présent des nouveaux modèles numériques qui facilitent la conception de chaque sous-système de l’antenne et permettent l’analyse des performances globales, soit en termes d’adaptation, soit en termes de diagrammes de rayonnement. Ces outils sont exploités pour la conception d’antenne et pour étudier les limites en balayage. La thèse se poursuit en présentant de nouvelles solutions technologiques et de nouveaux design pour intégrer les antennes CTS dans des modules multicouches planaires et à faible profil. La conception et la caractérisation de deux antennes intégrées en technologie LTCC pour des points d’accès 5G à 60 GHz sont discutées. L’une des deux est à faisceau fixe, l’autre est à balayage électronique, avec une couverture de ±40°, de faibles lobes secondaires et un niveau élevé de recoupement des faisceaux. Enfin, nous proposons l’association de radomes polarisants planaires à faible profil aux antennes CTS, pour réaliser des systèmes rayonnants en polarisation circulaire. Une méthodologie systématique pour la conception de polarisateurs à très large bande est présentée, ainsi qu’un design couvrant entièrement la bande Ka pour des applications satellites. / The ever-growing demand for fast and seamless connectivity shows the need of new wireless standards and technologies. Novel broadband, wide-angle scanning antennas achieving an optimal trade-off among size, gain, efficiency and costs are crucial to the development of emerging applications at millimeter waves, such as fifth-generation (5G) mobile networks and satellite communications. In this thesis, multibeam parallel-fed continuous transverse stub (CTS) array antennas are proposed as possible candidates for future mm-wave communications and are developed to tackle these requirements. The antenna architecture comprises an array of long slots, a corporate feed network based on parallel plate waveguides (PPWs) and an integrated quasi-optical beamformer. First, novel numerical models for the analysis of each subsystem and of the overall antenna, are presented, which enable an efficient and modular design of CTS antennas. These tools are exploited to derive design guidelines and assess the scanning performance. Then, novel design and technological solutions for the integration of CTS antennas in flat, low-profile multilayer modules are discussed. The design and characterization of two prototypes in LTCC technology, for 60-GHz mobile access points are presented: a fixed beam array and a switched-beam antenna with a field of view of ±40°, low SLLs and high beam overlap. Finally, planar linear-to-circular polarization converters are proposed to realize circularly polarized CTS antenna systems. A procedure to achieve an ultra-wideband, low-loss polarization conversion is outlined and a design for Ka-band satellite application is presented.

Dans ce travail de thèse, nous analysons la structure crustale de la marge est-algérienne et du bassin adjacent (région d’Annaba), à partir d’un ensemble de nouvelles données acquises durant la Campagne SPIRAL’2009 incluant un profil sismique terre-mer de ~240 km de long, des lignes sismiques réflexion pénétrante 360-traces, et des profils gravimétriques et magnétiques. Nous avons par ailleurs disposé pour cette étude de données complémentaires incluant notamment un ensemble de profils de sismique réflexion offrant des résolutions complémentaires. La structure crustale ainsi établie nous permet de discuter les nombreux modèles cinématiques d’ouverture du bassin est-algérien proposés dans la littérature, afin de caler dans le temps la formation du bassin par rapport à la collision. Elle permet également de discuter la localisation de la déformation liée à la réactivation de la marge, par rapport aux grands domaines lithosphériques du système marge-bassin, afin de mieux comprendre les modalités de l’inversion. Dans le bassin profond, la modélisation directe des temps d’arrivée et des amplitudes des ondes réfractées et réfléchies met en évidence une croûte océanique anormalement mince de 5-5.5 km d’épaisseur, composée de deux couches. La première, de 2.2 km d’épaisseur, montre des vitesses comprises entre 4.8 à 6.0 km/s impliquant un fort gradient; la seconde de 3.3 km d’épaisseur, présente des vitesses comprises entre 6.0 à 7.1 km/s et un plus faible gradient de vitesse. La modélisation des temps d’arrivées des ondes S fourni pour cette couche un coefficient de Poisson de 0.28, indiquant qu’elle est majoritairement constituée de gabbros. / In this study, we determine the deep structure of the eastern Algerian basin and its southern margin in the Annaba region (easternmost Algeria), to better constrain the plate kinematic reconstruction in this region. This study is based on new geophysical data collected during the SPIRAL cruise in 2009 that included a wide-angle, 240-km-long, onshore-offshore seismic profile, multichannel seismic reflection lines, and gravity and magnetic data, which was complemented by the available geophysical data for the study area. The analysis and modeling of the wide-angle seismic data using travel-times and amplitudes, and integrated with the multichannel seismic lines, reveal the detailed structure of an ocean-to-continent transition. In the deep basin, there is an ~5.5-km-thick oceanic crust that is composed of two layers. The upper layer of the crust is defined by a high velocity gradient and P-wave velocities between 4.8 km/s and 6.0 km/s from the top to the bottom. The lower crust is defined by a lower velocity gradient and P-wave velocity between 6.0 km/s and 7.1 km/s. The Poisson ratio in the lower crust deduced from S-wave modeling is 0.28, which indicates that the lower crust is composed mainly of gabbros. Below the continental edge, a typical continental crust with P-wave velocities between 5.2 km/s and 7.0 km/s from the top to the bottom shows a gradual seaward thinning of ~15 km over an ~35-km distance.

High Spectral Resolution Lidar (HSRL) is a backscatter lidar technique that employs an optical/spectral filter to distinguish between particulate (Mie) and molecular (Rayleigh) backscattered light. By separating the two types of returns, higher accuracy measurements are possible that will enable improved climate models, air quality measurements, and climate forecasting. A spaceborne HSRL instrument can provide great impact in these areas by enabling near-continuous measurements across the Earth, however the optical filter technology has typically been too complex for reliable long-duration space flight due to the need for complicated and costly electro-optic feedback loops, extra alignment detectors, and additional laser sources. Furthermore, these complexities limit the filter from use in other applications. In this research, a high-performance, ultra-narrowband interferometric optical filter with a specific thermo-optical behavior has been designed and built. The interferometer has been designed such that it can be reliably adjusted/tuned by simply monitoring and adjusting the temperature. The greatly reduced operational complexity was made possible through high-accuracy thermal characterization of the interferometer materials, combined with detailed Structural-Thermal-Optical-Performance (STOP) modeling to capture the complicated interactions between the materials. The overall design process, fabrication procedures, and characterization of the optical filter are presented. / Doctor of Philosophy / LiDAR (an acronym for Light Detection and Ranging) is a technology that can be used to measure properties of the atmosphere. It is similar to radar, but uses much smaller light waves rather than larger radio waves, enabling more detailed information to be obtained. High Spectral Resolution Lidar (HSRL) is a lidar technique that uses a high precision optical filter to distinguish between light that scatters from particulates (such as dust, smoke, or fog) and light that scatters from molecules (such as oxygen, nitrogen, or carbon dioxide) in the atmosphere. By separating the two types of backscattered light, higher accuracy measurements are possible that will enable improvements in climate models, air quality measurements, and climate forecasting. A spaceborne HSRL instrument can provide great impact in these areas by enabling near-continuous measurements across the Earth; however, the optical filter technology has typically been too complex for reliable long-duration spaceflight due to the need for complicated and expensive additional hardware. In this research, a high-performance HSRL optical filter that can be reliably operated by simply monitoring and adjusting the temperature has been designed, built, and tested. The greatly-reduced operational complexity has been made possible through a new process that enables more accurate prediction of the complicated interactions between the materials of the optical filter. This process is based on a combination of high-accuracy characterization of the materials and detailed structural-thermal-optical-performance (STOP) modeling. The overall design process, fabrication procedures, and characterization of the optical filter are presented.

The ability to quickly develop predictions of the time-to-failure under different loading levels allows designers to choose the best polymeric material for a specific application. Additionally, it helps material producers to design, manufacture, test, and modify a polymeric material more rapidly. In the case of polymeric pipes, previous studies have shown that there are two possible time-dependent failure mechanisms corresponding to ductile and brittle failure. The ductile mechanism is evident at shorter times-to-failure and results from the stretching of the amorphous region under loading and the subsequent plastic deformation. Empirical results show that many high-performance polyethylene (PE) materials do not exhibit the brittle failure mechanism. Hence, it is critical to understand the ductile mechanism and find an approach to predict the corresponding times-to-failure using accelerated means. The aim of this study is to develop an innovative rupture lifetime acceleration protocol for PE pipes which is sensitive to the structure, orientation, and morphology changes introduced by changing processing conditions. To accomplish this task, custom fixtures are developed to admit tensile and hoop burst tests on PE pipes. A pressure modified Eyring flow equation is used to predict the rupture lifetime of PE pipes using the measured mechanical properties under axial tensile and hydrostatic pressure loading in different temperatures and strain rates. In total, the experimental method takes approximately one week to be completed and allows the prediction of pipe lifetimes for service lifetime in excess of 50 years. / Master of Science / Steel, cast and galvanized iron, and asbestos cement (AC) pipelines have been historically used in water management services. However, they often experienced deterioration because of corrosion and encrustation, resulting in 23 to 27 bursts per 100 miles of pipeline in the US per year. Therefore, plastic pipes were developed to carry liquids (water and sewage), gases, etc. The Plastic Pipe Institute (PPI) requires a service life of at least 50-years for plastic pipes. Hence, pipe producers and material suppliers continuously attempt to improve the materials and manufacturing processes used for plastic pipes to increase their service lifetimes. However, there is still no plastic pipe that has been in service for 50 years. Therefore, a few techniques have been developed to accelerate the aging process and to predict if the plastic pipe is able to endure the 50-year lifetime without failure. In this work, a combined experimental and analytical framework is presented to develop accelerated lifetime estimates for plastic pipes. Custom axial tensile and internal pressurization fixtures are developed to measure the pipe response; the analytical method is used to extend the results to predict 50-year (and beyond) behavior.