Self-heating in storage facilities of biomass pellet can lead to spontaneous combustion. This has resulted in many fires over the years, causing both financial and environmental losses. In order to assess the risk for spontaneous combustion of biomass pellets during storage, it is important to know how prone the fuel is to self-heating, i.e. to determine its reactivity. This thesis presents experimental work performed to develop a sensitive screening test procedure for biomass pellets, using isothermal calorimetry for direct measurement of the heat production rate. This method can be used to compare the reactivity of different biomass pellets. This could be useful for e.g. facility owners to gain better knowledge of their fuels propensity for self-heating and thereby facilitate safer storage. The screening test procedure can also be used for research purposes. Experiments have been performed with 31 different biomass pellet batches to investigate how the pellet composition, origin, etc. influence the reactivity of the pellets. The results from these experiments clearly show a significant difference in reactivity between different types of pellets. The results indicate that pine/spruce mix pellets are significantly more reactive than all other types of pellets tested, and that pellets consisting of 100 % pine are more reactive than pellets consisting of 100 % spruce. Pellets produced from winery wastes, straw, or eucalyptus, have low reactivity compared to pellets consisting of pine and/or spruce. The reactivity of the pellets was shown to be reduced by either introducing certain types of anti-oxidants into the pellets or by extracting lipids from the raw material of pellets. The screening test procedure is already being used today by some facility owners for assessing their fuels propensity for self-heating. The procedure is also one of the suggested test methods in “ISO/CD 20049 Solid biofuels — Determination of self-heating of pelletized biofuels”. / This thesis presents experimental work performed to develop a sensitive screening test procedure for biomass pellets, using isothermal calorimetry for direct measurement of the heat production rate. This method can be used to directly compare the reactivity, that is how prone the fuel is to self-heating, of different batches of biomass pellets. The results could be used for safety assessment by the industry or for research purposes to investigate how different factors influence the self-heating potential. Experiments were performed with 31 different biomass pellet batches to investigate how the pellet composition, origin, etc. influence the heat release rate. The results clearly show that there is a significant difference in reactivity between different types of pellets. Pine/spruce mix pellets are more reactive than the other types of pellets tested and pellets consisting of 100 % pine are more reactive than pellets consisting of 100 % spruce. Pellets produced from winery wastes, straw, or eucalyptus, have low reactivity compared to pellets consisting of pine and/or spruce. The results also show that the reactivity of the pellets can be reduced by either introducing certain types of anti-oxidants into the pellets or by extracting lipids from the raw material of pellets.

Wood pellets are offering opportunities for a cleaner-burning biofuel but major concerns are overshadowing their potential. Tony Bi and UBC’s Clean Energy Research Centre are engineering solutions.

The thesis is a technical solution for heating two apartment buildings. The project is designed in two versions. The first variant is source of heat boilers for pellets, in the second variant, the heat source heat pumps type of land / water. Part of this work is an experiment which deals with the measurement of floor heating.

Public and private incentive programs have encouraged conversions to high efficiency, low emissions wood heating systems as a strategy to promote renewable energy and support local economies in the Northeastern US. Despite these efforts, the adoption of these systems remains slow. The study that is the subject of this dissertation examines several social, economic, policy and environmental factors that affect the decisions of individuals and small-scale institutions (local business and community facilities) to transition to automated wood pellet boilers and furnaces (AWPH) utilizing local fuel sources. Due to the complexity and risk associated with conversion, the transition to these systems can help further both a practical and theoretical understanding of the global transition to non-fossil fuel technologies. Chapter One of this dissertation examines this notion in more detail, as well as spells out the research questions of this study. Chapter Two delves into the research methods and their implications for other studies of energy transitions. These methods include interviews with 60 consumers, technology and fuel suppliers, and NGO and state agency personnel. These provided in-depth qualitative data which are complemented by a four-state survey (New Hampshire, Vermont, New York, and Maine) of adopters and informed non-adopters of AWPH systems (n=690; 38% response rate). Interview and survey questions, as well as subsequent coding, was developed through use of diffusion of innovation theory, the multi-level perspective on sociotechnical transitions, as well as through collaboration with industry experts and research partners. Chapters Three and Four offer a discussion of the results and their implications. Specifically, Chapter Three examines the complex system actors, elements, and interactions that are part of the transition from fossil fuel technology to AWPH. Chapter Four focuses on the data surrounding state and private programs that encourage the use of AWPH and the implications that this data has for effective climate mitigation and energy policy. Data show that AWPH consumers, who should be considered “early adopters” due to the small number of AWPH adopters in the region, are largely value-driven but are also concerned about upfront costs and lack of available technical support and fuel delivery options. Both environmental values (e.g. desire to find alternative to fossil fuels, concern for air quality and belief in climate change) and social values (e.g. support for the local economy and wood products industry) influenced consumer decisions, especially when fuel oil prices were low. Financial incentives, which are offered by all four states in the study region, were highly influential, but additional decision support offered by a non-profit (e.g. site visits, informational workshops, local print media) were rated highly by consumers where they were available. These additional supports, as well as the community-based nature of the non-profit program, enabled a broader range of people (lower income, more risk averse) to choose AWPH as well as created more efficiency in the supply chain. This approach created a reinforcing feedback loop between broader early adopters of AWPH, normalization of AWPH technology and its associated infrastructure, and increased levels of technical support and fuel availability. These findings suggest that efforts to increase adoption of renewable technologies that use locally harvest fuels take a community-based and system-wide approach, targeting both consumer and supplier motivations and barriers.

Um bei der Herstellung der Holzpellets den Energieaufwand zu minimieren und gleichzeitig die Qualitätsanforderungen der DINplus zu erfüllen, werden häufig Presshilfsmittel beim Pelletieren eingesetzt, bisher vor allem Mais- und Weizenstärke. Um flexibler auf veränderte Markt- und Rohstoffbedingungen reagieren zu können, besteht von Seiten der Hersteller Bedarf an alternativen Presshilfsmitteln. Allerdings ist deren Einfluss auf das Verbrennungs-, Emissions- und Ascheerweichungsverhalten nur unzureichend erforscht. Im Rahmen eines Forschungsprojektes zur Optimierung der Pelletproduktion wurden in dieser Diplomarbeit Versuche durchgeführt, um den Einfluss verschiedener natürlicher Presshilfsmittel, der Pelletqualität (Feinanteil, Stückigkeit) und der Feuerungsart (Unterschub- und Abwurffeuerung mit Brennerschale) auf das Emissionsverhalten (Kohlenmonoxid-, Stickoxid-, Gesamtkohlenstoff und Staubgehalt im Abgas), den Anlagenbetrieb (Brennstoffförderraten, Abgasverluste, Luftüberschuss) und das Ascheerweichungsverhalten beim Betrieb von zwei Kleinfeuerungsanlagen mit DINplus-konformen Holzpellets, zu untersuchen.

The majority of low income households in South Africa have limited access to electricity, and typically cook on stoves fuelled by paraffin. Paraffin represents a fossil fuel. It is a relatively cheap fuel in South Africa. Another fuel that can also be used for cooking is wood pellets, which is a renewable fuel. It can be used in a similar way to that of paraffin and is relatively cheap compared to other renewable energy sources. To investigate if living conditions among low income households can be improved the focus of the study was to evaluate the sustainability of cooking on paraffin and wood pellets. This was done by comparing social, environmental and economic aspects associated with the two cooking fuels. The social aspects were investigated through an interview study, the environmental aspect through a comparative life cycle assessment (LCA) and the economic aspects through a partial life cycle cost analysis (LCCA) focusing on the user phase.   The interview study showed that paraffin users considered four aspects as the most important when cooking, namely safety, health, affordability and quality. The study also found that the majority were willing to change to another cooking fuel if these aspects were fulfilled. The LCA showed that both systems score the highest on 9 out of 18 environmental impact categories over a 16-year perspective. The economic analysis showed that the user phase of the wood pellet system is more economically beneficial during the 16-year time period than the paraffin system. It was concluded that wood pellets could be used as an option to paraffin for cooking and would most likely increase living conditions for low income households. / Majoriteten av låginkomsthushåll i Sydafrika har begränsad tillgång till elektricitet och vanligtvis sker matlagningen på paraffinspisar. Paraffin är ett fossilt bränsle. Det är ett relativt billigt bränsle i Sydafrika. Ett annat bränsle som också kan användas för matlagning är träpellets som är ett förnyelsebart bränsle. Det kan användas på liknande sätt som för paraffin och är ganska billigt i jämförelse med andra förnybara energikällor. För att undersöka om levnadsförhållanden för låginkomsthushåll kan förbättras låg fokus för denna studie på att utvärdera hållbarheten för att laga mat på paraffin och träpellets. Detta genomfördes genom att jämföra sociala, miljömässiga och ekonomiska aspekter associerade med dessa bränslen för matlagning. De sociala aspekterna undersöktes genom en intervjustudie, de miljömässiga aspekterna genom en jämförande livscykelanalys (LCA) och de ekonomiska aspekterna gjordes genom en livscykelkostnadsanalys (LCCA) för användarfasen.   Intervjustudien visade att paraffinanvändare anser att fyra aspekter är de viktigaste vid matlagning, nämligen säkerhet, hälsa, kostnad och kvalitet. Studien visade också att majoriteten var villiga att byta till ett annat bränsle för matlagning om dessa aspekter var uppfyllda. Livscykelanalysen visade att båda systemen hade högst miljöpåverkan i 9 av 18 miljöpåverkanskategorier vardera inom ett 16-årsperspektiv. Den ekonomiska analysen visade att under en 16-årsperiod var användarfasen mer kostnadseffektiv för matlagning på träpellets jämfört med paraffin. Studien visade att träpellets kan användas som ett alternativ för paraffin vid matlagning och kommer troligtvis öka levnadsförhållanden för låginkomsthushåll.

The majority of low income households in South Africa have limited access to electricity, and typically cook on stoves fuelled by paraffin. Paraffin represents a fossil fuel. It is a relatively cheap fuel in South Africa. Another fuel that can also be used for cooking is wood pellets, which is a renewable fuel. It can be used in a similar way to that of paraffin and is relatively cheap compared to other renewable energy sources. To investigate if living conditions among low income households can be improved the focus of the study was to evaluate the sustainability of cooking on paraffin and wood pellets. This was done by comparing social, environmental and economic aspects associated with the two cooking fuels. The social aspects were investigated through an interview study, the environmental aspect through a comparative life cycle assessment (LCA) and the economic aspects through a partial life cycle cost analysis (LCCA) focusing on the user phase. The interview study showed that paraffin users considered four aspects as the most important when cooking, namely safety, health, affordability and quality. The study also found that the majority were willing to change to another cooking fuel if these aspects were fulfilled. The LCA showed that both systems score the highest on 9 out of 18 environmental impact categories over a 16-year perspective. The economic analysis showed that the user phase of the wood pellet system is more economically beneficial during the 16-year time period than the paraffin system. It was concluded that wood pellets could be used as an option to paraffin for cooking and would most likely increase living conditions for low income households. / Majoriteten av låginkomsthushåll i Sydafrika har begränsad tillgång till elektricitet och vanligtvis sker matlagningen på paraffinspisar. Paraffin är ett fossilt bränsle. Det är ett relativt billigt bränsle i Sydafrika. Ett annat bränsle som också kan användas för matlagning är träpellets som är ett förnyelsebart bränsle. Det kan användas på liknande sätt som för paraffin och är ganska billigt i jämförelse med andra förnybara energikällor. För att undersöka om levnadsförhållanden för låginkomsthushåll kan förbättras låg fokus för denna studie på att utvärdera hållbarheten för att laga mat på paraffin och träpellets. Detta genomfördes genom att jämföra sociala, ekologiska och ekonomiska aspekter associerade med dessa bränslen för matlagning. De sociala aspekterna undersöktes genom en intervjustudie, de miljömässiga aspekterna genom en jämförande livscykelanalys (LCA) och de ekonomiska aspekterna gjordes genom en livscykelkostnadsanalys (LCCA) för användarfasen. Intervjustudien visade att paraffinanvändare anser att fyra aspekter är de viktigaste vid matlagning, nämligen säkerhet, hälsa, kostnad och kvalitet. Studien visade också att majoriteten var villiga att byta till ett annat bränsle för matlagning om dessa aspekter var uppfyllda. Livscykelanalysen visade att båda systemen hade högst miljöpåverkan i 9 av 18 miljöpåverkanskategorier vardera inom ett 16-årsperspektiv. Den ekonomiska analysen visade att under en 16-årsperiod var användarfasen mer kostnadseffektiv för matlagning på träpellets jämfört med paraffin. Studien visade att träpellets kan användas som ett alternativ för paraffin vid matlagning och kommer troligtvis öka levnadsförhållanden för låginkomsthushåll.

Wood pellet production has become an advancing industry for the sake of reducing greenhouse emissions into the atmosphere especially, in European Union countries. Researchers and industry executives seek new methods and materials to improve the pelletization process. Rice hulls or husks has the potential to aid in wood pelletization as they possess high calorific values. This study focuses on using rice hull derived bio-oil from pyrolysis, which will also decrease ash content, as an additive to aid in the wood pelletization process. Using two groups of rice hull derived bio-oil as an additive in wood pelletization: Group 1 uses heavy bio-oil at 0.2 and 0.5% concentration plus a control group, and Group 2 uses bio-oil with light keys added from distillation process at 0.2% and 0.5% concentration plus a control group, we hope to increase durability and calorific value in wood pellets while producing at a lower cost.

<p>This thesis evaluates the use of Fourier Transform Infrared Spectroscopy (FTIR) as an approach to the increasingly difficult air sampling challenges within the field of occupational and environmental hygiene. The application of FTIR is exemplified by the assessment of emissions from and exposures in the sawmill and pellet industries. </p><p>Open path FTIR was applied in the sawsheds and the terpene levels were monitored for several days. Traditional adsorbent sampling was used to evaluate the FTIR measurements. The volatile emissions from wood pellets were investigated in warehouses and in domestic storage rooms. </p><p>The installation of open path FTIR in the harsh sawmill environment proved useful, however, attention must be paid to vibrations, beam blockage and limited sensitivity. Adsorbent sampling showed good agreement with open path FTIR. The uncontrolled airflows in sawsheds caused significant underestimation of emission rates. By the use of FTIR and a tracer gas a more accurate estimate was obtained. The total emission from processing of Scots pine was estimated to 660 g/m³ of roundwood under bark, and can amount to 700 tons annually from a large sawmill.</p><p>Hexanal (111±32 mg/m³) and CO (56±4mg/m³) were recorded in pellet warehouses. Storage of wood pellets constitutes a potential occupational and domestic health hazard. Experiments from kiln drying of lumber show that the emissions of hexanal and carbon monoxide are not limited to wood pellets but are caused by general degradation processes of wood, facilitated by drying at elevated temperature. This is the first published report where low-temperature emission of carbon monoxide from wood materials is described. </p><p>The FTIR method is a significant advancement in measurement technology. The retrieved data offers unparalleled information. It offers robust, convenient and efficient monitoring of gases over extended periods. FTIR spectroscopy should be considered a standard technique within the field of occupational and environmental hygiene.</p>

This thesis evaluates the use of Fourier Transform Infrared Spectroscopy (FTIR) as an approach to the increasingly difficult air sampling challenges within the field of occupational and environmental hygiene. The application of FTIR is exemplified by the assessment of emissions from and exposures in the sawmill and pellet industries. Open path FTIR was applied in the sawsheds and the terpene levels were monitored for several days. Traditional adsorbent sampling was used to evaluate the FTIR measurements. The volatile emissions from wood pellets were investigated in warehouses and in domestic storage rooms. The installation of open path FTIR in the harsh sawmill environment proved useful, however, attention must be paid to vibrations, beam blockage and limited sensitivity. Adsorbent sampling showed good agreement with open path FTIR. The uncontrolled airflows in sawsheds caused significant underestimation of emission rates. By the use of FTIR and a tracer gas a more accurate estimate was obtained. The total emission from processing of Scots pine was estimated to 660 g/m3 of roundwood under bark, and can amount to 700 tons annually from a large sawmill. Hexanal (111±32 mg/m3) and CO (56±4mg/m3) were recorded in pellet warehouses. Storage of wood pellets constitutes a potential occupational and domestic health hazard. Experiments from kiln drying of lumber show that the emissions of hexanal and carbon monoxide are not limited to wood pellets but are caused by general degradation processes of wood, facilitated by drying at elevated temperature. This is the first published report where low-temperature emission of carbon monoxide from wood materials is described. The FTIR method is a significant advancement in measurement technology. The retrieved data offers unparalleled information. It offers robust, convenient and efficient monitoring of gases over extended periods. FTIR spectroscopy should be considered a standard technique within the field of occupational and environmental hygiene.