True-green wavelength emitters at 555 nm are currently dominated by III-V semiconductor-based inorganic materials. Nevertheless, due to high lattice- and thermal-mismatch, the overall power efficiency in this range tends to decline for high current density showing the so-called efficiency droop in the green region (“green gap”). In order to fill the research green gap, this thesis examines the low cost solution-processability of organometal halide perovskites, which presents a unique opportunity for light-emitting devices in the green-yellow region owing to their superior photophysic properties such as high photoluminescence quantum efficiency, small capture cross section of defect states as well as optical bandgap tunability across the visible light regime. Specifically, the mechanisms of radiative recombination in a CH3NH3PbBr3 hybrid perovskite material were investigated using low-temperature, power-dependent (77 K), temperature-dependent photoluminescence (PL) measurements. We noted three recombination peaks at 77K, one of which originated from bulk defect states, and other two from surface defect states. The latter were identified as bound-excitonic (BE) radiative transitions related to particle size inhomogeneity or grain size induced surface state in the sample. Both transitions led to PL spectra broadening as a result of concurrent blue- and red-shifts of these excitonic peaks. The blue-shift is most likely due to the Burstein-Moss (band filling) effect. Interestingly, the red-shift of the second excitonic peak becomes pronounced with increasing temperature leading to a true-green wavelength of 553 nm for CH3NH3PbBr3. On the other hand, red-shifted peak originates from the strong absorption in the second excitonic peak owed to the high density of surface states and carrier filling of these states due to the excitation from the first excitonic recombination. We also achieved amplified spontaneous emission around excitation threshold energy of 350 μJ/cm2 when optically pumped using 475 nm laser pulses, thus supporting the assignment of carrier absorption and re-excitation mentioned above. This dissertation work led to the following article: D. Priante, I. Dursun, M. S. Alias, D. Shi, V. A. Melnikov, T. K. Ng, O. F. Mohammed, O. M. Bakr, and B. S. Ooi, "The recombination mechanisms leading to amplified spontaneous emission at the true-green wavelength in CH3NH3PbBr3 perovskites", Applied Physics Letters, 106, 081902, 2015. DOI: 10.1063/1.4913463

No description available.

In this thesis, we investigate the single-pumped L-band (1570-1610 nm) amplified spontaneous emission fiber source by employing 1480 nm single pumping configuration. Using the 1480 nm-pumped laser, we chose the adequate fiber length and adjusted the pump power to optimize the characteristics of the ASE source. The characteristics are experimentally examined and compared in terms of the output power, mean wavelength, spectral linewidth, and pumping conversion efficiency in four configurations with single-pass forward (SPF), single-pass backward (SPB), double-pass forward (DPF), and double-pass backward (DPB) structures. Among them, the DPF configuration with low mirror reflectance of 8% is the better one to be an L-band ASE fiber source with output power of 13.8 mW, mean wavelength of 1585.7 nm, spectral linewidth of 40.9 nm and pumping efficiency of 13.8%.

During the last decade, the maximum capacity of an optical fiber transmission line more than doubled every year to match the fast-growing communication need. The technology break through in dry fiber fabrication opens the possibility for fiber bandwidth all the way from 1300 nm to 1600 nm. The fast increasing demand of communication capacity results in the emergence of wavelength division multiplexing (WDM) technology, enabling tens of channels with different wavelengths transmitted simultaneously on an optical fiber. In consequence, it raises the requirement of spectral bandwidth of all the optical components used in the optical transport networking systems. Cr4+:YAG has potential to meet this demand because its 3T2¡÷3A2 transition has a strong spontaneous emission that just covers the low-loss window of optical fiber. The crystalline host offers a excellent mechanical characteristic. Such a fiber is, therefore, eminently suitable for super-wideband optical source since the required pump power is expected to be higher. We have successfully demonstrated a diode-laser pumped Cr:YAG crystal fiber ASE light source. The crystal fibers are grown by the laser-heated pedestal growth technique. Using a 46.6 mm-long Cr:YAG single crystal fiber of a 3-dB ASE width of 265 nm and a power spectral density ¡V22.1 dBm/nm was achieved. In the future, to further increase the quantum efficiency and output power we will reduce the core diameter, lengthen the fiber, increase the Cr4+ doping concentration, fabricate double-cladding, coat the fiber facets, and improve the cooling system.

Surface plasmon-polaritons are optical surface waves formed through the interaction of photons with free electrons at the surface of metals. They offer interesting applications in a broad range of scientific fields such as physics, chemistry, biology, and material science. However, many of such applications face limitations imposed by the high propagation losses of these waves at visible and near-infrared wavelengths, which result mainly from power dissipation in the metal. In principle, the propagation losses of surface plasmon-polaritons can be compensated through optical amplification. The objective of this thesis is to provide deeper insights on the physics of surface plasmon-polariton amplification and spontaneous emission in surface plasmon-polariton amplifiers through theoretical and experimental vehicles applied (but not necessarily restricted) to a particular plasmonic mode termed long-range surface plasmon-polariton. On the theoretical side, the objective is approached by developing a realistic theoretical model to describe the small-signal amplification of surface plasmon-polaritons in planar structures incorporating dipolar gain media such as organic dye molecules, rare-earth ions, and quantum dots. This model takes into account the inhomogeneous gain distribution formed near the metal surface due to a non-uniform excitation of dipoles and due to a position-dependent excited-state dipole lifetime that results from near-field interactions between the excited dipoles and the metal. Also, a theoretical model to describe the amplified spontaneous emission of surface plasmon-polaritons supported by planar metallic structures is developed. This model takes into account the different energy decay channels into which an exited dipole located in the vicinity of the metal can relax. The validity of this model is confirmed through experimentation. On the experimental side, the objective is approached by providing a direct experimental demonstration of complete loss compensation in a plasmonic waveguide. The experiments are conducted using the long-range surface plasmon-polariton supported by a symmetric thin gold waveguide incorporating optically pumped organic dye molecules in solution as the gain medium. Also, an experimental study of spontaneous emission in a long-range surface plasmon-polariton amplifier is presented. It is shown that this amplifier benefits from a low spontaneous emission into the amplified mode, which leads to an optical amplifier with low noise characteristics. The experimental setup and techniques are explained in detail.

Surface plasmon-polaritons are optical surface waves formed through the interaction of photons with free electrons at the surface of metals. They offer interesting applications in a broad range of scientific fields such as physics, chemistry, biology, and material science. However, many of such applications face limitations imposed by the high propagation losses of these waves at visible and near-infrared wavelengths, which result mainly from power dissipation in the metal. In principle, the propagation losses of surface plasmon-polaritons can be compensated through optical amplification. The objective of this thesis is to provide deeper insights on the physics of surface plasmon-polariton amplification and spontaneous emission in surface plasmon-polariton amplifiers through theoretical and experimental vehicles applied (but not necessarily restricted) to a particular plasmonic mode termed long-range surface plasmon-polariton. On the theoretical side, the objective is approached by developing a realistic theoretical model to describe the small-signal amplification of surface plasmon-polaritons in planar structures incorporating dipolar gain media such as organic dye molecules, rare-earth ions, and quantum dots. This model takes into account the inhomogeneous gain distribution formed near the metal surface due to a non-uniform excitation of dipoles and due to a position-dependent excited-state dipole lifetime that results from near-field interactions between the excited dipoles and the metal. Also, a theoretical model to describe the amplified spontaneous emission of surface plasmon-polaritons supported by planar metallic structures is developed. This model takes into account the different energy decay channels into which an exited dipole located in the vicinity of the metal can relax. The validity of this model is confirmed through experimentation. On the experimental side, the objective is approached by providing a direct experimental demonstration of complete loss compensation in a plasmonic waveguide. The experiments are conducted using the long-range surface plasmon-polariton supported by a symmetric thin gold waveguide incorporating optically pumped organic dye molecules in solution as the gain medium. Also, an experimental study of spontaneous emission in a long-range surface plasmon-polariton amplifier is presented. It is shown that this amplifier benefits from a low spontaneous emission into the amplified mode, which leads to an optical amplifier with low noise characteristics. The experimental setup and techniques are explained in detail.

In this study, we study the polarization dependence, gain property, and amplified spontaneous emission in Cr4+: YAG crystal fibers. Cr4+: YAG crystal has an ultra-wide bandwidth of 300 nm. Cr4+: YAG crystal fibers fabricated through laser heated pedestal growth technique are suitable for the applications of fiber amplifiers, fiber lasers, and broadband light sources. The experiment results showed that the polarization-dependent loss has a severe variation as the optical wavelength change. The maximum polarization-dependent loss was up to 18 dB. The main reason of such a large polarization-dependent loss is the combination of multimode interference and the birefringence induced by the non-uniformity of optical waveguide structure and residue strain in Cr4+: YAG crystal fibers. Thus, the results of polarization-dependent loss can be used as a feedback parameter to improve the fabrication process. In the experiment of gain property, bi-directional pump and double-pass transmission scheme was adopted and a 0.2 dB net gain was obtained for the first time at signal wavelength of 1400 nm, pumping wavelength of 1060 nm, and total pumping power of 2.8 W. It shows that Cr4+: YAG crystal fiber has potential to be developed as a broadband fiber amplifier. In the measurement of amplified spontaneous emission spectrum, a wide bandwidth of amplified spontaneous emission of 300 nm with total power of 50 £gWwas obtained at 0.2W pumping power condition. The coupling efficiencies from amplified spontaneous emission to single mode fibers and multimode fibers were 1.5 % and 9.9 %, respectively. This result reveals that it has potential to be developed as a broadband light source. To improve the optical properties of Cr4+: YAG crystal fiber in the future, improving the uniformity of optical fiber waveguide and reducing the residue strain in Cr4+: YAG crystal fiber may suppress the polarization-dependent loss; increasing the fiber length, decreasing the mode number, and employing a cladding pump technique with a well-distributed pump power in the crystal fiber to alleviate the excited state absorption may raise the gain performance and the amplified spontaneous emission power.

Recently, with the escalating demands for optical communications, the need for bandwidth in optical communication network has increased. The technology breakthrough in dry fiber fabrication opens the possibility for fiber bandwidth from 1.3 to 1.6 £gm. Cr4+:YAG double-clad crystal fiber (DCF) grown by the co-drawing laser-heated pedestal growth method has a strong spontaneous emission spectrum from 1.3 to 1.6 £gm. Such fiber is, therefore, eminently suitable for broadband optical amplifier, amplifier spontaneous emission (ASE) light source, tunable solid-state laser, and optical coherence tomography (OCT) applications. In this thesis, multilayer dielectric thin films were directly deposited by E-gun coating onto the end faces of the heterostructure Cr4+:YAG DCF. In this way we have successfully improved the extracted ASE power by the high reflection (HR) coatings. The backward ASE in the fiber reflected and propagates with gain through the fiber in the forward direction. In dual-pump scheme, as much as 1.7 mW power (DCF length is 9.5 cm) of collimated output ASE was achieved. The dual-pump scheme and HR thin films provided 1.6 time improvements of the ASE output power. For broadband optical amplifier in dual-pump and double-pass scheme, a 3.7-dB gross gain and a 0.7-dB net loss (DCF length is 8.7 cm) at 1.4-£gm signal wavelength have been successfully developed with HR coatings onto one of the Cr4+:YAG DCF end faces. In addition, we have successfully developed the Cr4+:YAG DCF fiber laser by direct HR coatings onto fiber end faces. A record-low threshold of 96 mW (DCF length is 1.6 cm) with a slope efficiency of 6.9% was achieved at room temperature. It is more than four times lower than any previously reported Cr4+:YAG lasers.

Surface plasmon-polaritons are optical surface waves formed through the interaction of photons with free electrons at the surface of metals. They offer interesting applications in a broad range of scientific fields such as physics, chemistry, biology, and material science. However, many of such applications face limitations imposed by the high propagation losses of these waves at visible and near-infrared wavelengths, which result mainly from power dissipation in the metal. In principle, the propagation losses of surface plasmon-polaritons can be compensated through optical amplification. The objective of this thesis is to provide deeper insights on the physics of surface plasmon-polariton amplification and spontaneous emission in surface plasmon-polariton amplifiers through theoretical and experimental vehicles applied (but not necessarily restricted) to a particular plasmonic mode termed long-range surface plasmon-polariton. On the theoretical side, the objective is approached by developing a realistic theoretical model to describe the small-signal amplification of surface plasmon-polaritons in planar structures incorporating dipolar gain media such as organic dye molecules, rare-earth ions, and quantum dots. This model takes into account the inhomogeneous gain distribution formed near the metal surface due to a non-uniform excitation of dipoles and due to a position-dependent excited-state dipole lifetime that results from near-field interactions between the excited dipoles and the metal. Also, a theoretical model to describe the amplified spontaneous emission of surface plasmon-polaritons supported by planar metallic structures is developed. This model takes into account the different energy decay channels into which an exited dipole located in the vicinity of the metal can relax. The validity of this model is confirmed through experimentation. On the experimental side, the objective is approached by providing a direct experimental demonstration of complete loss compensation in a plasmonic waveguide. The experiments are conducted using the long-range surface plasmon-polariton supported by a symmetric thin gold waveguide incorporating optically pumped organic dye molecules in solution as the gain medium. Also, an experimental study of spontaneous emission in a long-range surface plasmon-polariton amplifier is presented. It is shown that this amplifier benefits from a low spontaneous emission into the amplified mode, which leads to an optical amplifier with low noise characteristics. The experimental setup and techniques are explained in detail.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23160号 / 工博第4804号 / 新制||工||1751(附属図書館) / 京都大学大学院工学研究科分子工学専攻 / (主査)教授 関 修平, 教授 今堀 博, 教授 梶 弘典 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM