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Constructing Poly(Ionic Liquid)s-Based Composite Solid State Electrolytes and Application in Lithium Metal BatteriesLi, Jiajia January 1900 (has links)
The pursuit of reliable and high-performance batteries has fueled extensive research into new battery chemistries and materials, aiming to enhance the current lithium-ion battery technologies in terms of energy density and safety. Among the potential advancements, solid-state batteries (SSBs) have captured significant attention as the next-generation energy storage technology. One key factor contributing to their appeal is the utilization of solid-state electrolytes (SSEs) with a wide electrochemical stability window (ESW), making SSBs compatible with high-voltage cathodes. The energy density of SSBs can be further improved by employing the “holy-grail” anode, Li-metal, which boasts the lowest working voltage (-3.04 V vs. Li+/Li) and an ultrahigh theoretical capacity (3860 mAh g−1). Consequently, these batteries are referred to as lithium metal batteries (LMBs). However, realizing the full potential of LMBs presents formidable challenge, including the low ionic conductivity of current SSEs, large interfacial resistance between SSE and electrodes, uncontrollable interfacial reactions, and the growth of Li dendrites. Typically, SSEs can be categorized into three types. Among these, solid composite electrolytes (SCEs) are considered the most promising choice for solid-state LMBs due to their combination of high ionic conductivity and excellent mechanical strength from inorganic solid electrolytes (ISEs) and the flexibility and good interface compatibility provided by solid polymer electrolytes (SPEs). Polymeric ionic liquids (PolyILs), which contain both ionic liquid-like moieties and polymer frameworks, have emerged as highly attractive alternatives to traditional polymers in SCEs. The overall objective of this thesis was to develop PolyIL-based SCEs with enhanced ionic conductivity, wide ESW, high Li+ transference number, and reduced electrodes/electrolyte interface resistance. The main progress achieved in this thesis is as follows: 1. We selected three F-based Li-salts to prepare SPEs using poly(ethylene oxide) and polyimide. The investigation focused on assessing the impact of molecular size, F content, and chemical structures (F-connecting bonds) of these Li-salts. Additionally, we aimed to uncover the formation process of LiF in the solid electrolyte interphase (SEI). The result revealed that the F-connecting bond plays a more significant role than the molecular size and F element content, resulting in slightly better cell performance using LiPFSI compared to LiTFSI and substantially better performance compared to LiFSI. The preferential breakage of bonds in LiPFSI was found to be related to its position to Li anode. Consequently, we proposed the LiPFSI reduction mechanism based on these findings. 2. Using the template method, we synthesized a monolayer SCE with enhanced Li+ transference number and high ionic conductivity. In this study, boron nitride (BN) nanosheets with a high specific surface area and richly porous structure were employed as inert inorganic filler. These BN nanosheets played a crucial role in homogenizing the Li+ flux and facilitating the Li+ transmission to suppress Li dendrite growth. When integrated into a LiFePO4//Li cell with the optimized SCE, the assembled battery demonstrated remarkable cycling performance. 3. A monolayer GSCE with multifunctionality was synthesized via a natural sedimentation and subsequent UV-curing polymerization technique. This innovative method capitalizes on intrinsic gravity, allowing for the integration of multiple functions within a single layer, thereby eliminating the additional interlayer resistance. The developed GSCE provides an optimum Li+ transportation path and enhanced Li+ transference number, leading to an enhanced ionic conductivity and a long cycle life of Li//Li cells and SSLMBs. Compared with the monolayer uniform SCEs, the gradient structure also alleviates the uncoordinated thermal expansion between fillers and PolyIL, avoiding increased stress during the cycle and battery capacity fade.
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The Thermal and Mechanical Characteristics of Lithiated PEO LAGP Composite ElectrolytesDenney, Jacob Michael January 2020 (has links)
No description available.
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Investigation on the effect of pore size and surface area of mesoporous silica on the conductivity of solid composite electrolytes / Undersökning av effekten av porstorlek och ytarea av mesoporös kiseldioxid på ledningsförmågan hos fasta kompositelektrolyterPedaprolu, Hitesh Khanna January 2022 (has links)
Solid-state batteries are gaining a lot of attention in the commecial sector today. Development of the solid state electrolytes is an important part in making commercially viable solid-state batteries. While many solid-state electrolytes are struggling with low ionic conductivity, some have shown comparatively high conductivities that can be engineered to perform better to be implemented for consumer market. Silica based solid composite electrolytes (SCEs) are one of the materials that are of huge interest as solid-state electrolytes. As a continuation of the previous research into the silica based SCE’s, the current work focuses on the study of SCEs based on the commercially available mesoporous silica (MPS) of different pore sizes and nanosized silica powder (SNP). Ionic Liquid electrolyte (ILE) based on Li-TFSI and BMP-TFSI mixture was used to prepare composities under different humidity conditions. The effect of the extent of -OH group functionalization of silica, determined by FTIR on treated and untreated powders, on ionic conductivity was also evaluated. Obtained composities were evaluated with electrochemical impedance spectroscopy (EIS) and analysed with TGA to establish correlations based on particle size and pore characteristics of MPS powder. Camparison with SNP was also made in anticipation to draw correlations with MPS. It was found that the pore size and pore volume change have more impact on the conductivity compared to surafce area of commercially obtained MPS and an unexplored pheonomenon was observed in case of SNP based SCE’s. Glovebox (GB) samples at relative humidity (RH)-0.005% have higher conductivity than dryroom samples at RH-0.5%. These findings can be used for a future reference in evaluating commercial MPS based composites as solid-state electrolytes. / Solid-state-batterier får stor uppmärksamhet i den kommersiella sektorn idag. Utveckling av fasta elektrolyter är en viktig del för att göra kommersiellt gångbara solid state-batterier. Medan många fasta elektrolyter kämpar med låg jonledningsförmåga, har vissa visat jämförelsevis höga ledningsförmåga som kan konstrueras för att prestera bättre för att implementeras för konsumentmarknaden. Kiselbaserade fasta kompositelektrolyter (SCE) är ett av de material som är av stort intresse som fasta elektrolyter. Som en fortsättning på den tidigare forskningen om de kiselbaserade SCE:erna fokuserar det nuvarande arbetet på studiet av SCE:er baserade på den kommersiellt tillgängliga mesoporösa kiseldioxiden (MPS) av olika porstorlekar och nanosized kiseldioxidpulver (SNP). Jonisk flytande elektrolyt (ILE) baserad på Li-TFSI och BMP-TFSI-blandning användes för att framställa kompositer under olika luftfuktighetsförhållanden. Effekten av omfattningen av -OH-gruppfunktionalisering av kiseldioxid, bestämd med FTIR på behandlade och obehandlade pulver, på jonkonduktiviteten utvärderades också. Erhållna sammansättningar utvärderades med elektrokemisk impedansspektroskopi (EIS) och analyserades med TGA för att fastställa korrelationer baserat på partikelstorlek och poregenskaper hos MPS-pulver. Kamparison med SNP gjordes också i väntan på att dra korrelationer med MPS. Det visade sig att porstorleken och porvolymsförändringen har mer inverkan på konduktiviteten jämfört med ytan för kommersiellt erhållen MPS och ett outforskat fenomen observerades i fallet med SNP-baserade SCE. Handskbox (GB) prover vid relativ fuktighet (RH)-0,005 % har högre konduktivitet än torrrumsprover vid RH-0,5 %. Dessa resultat kan användas för en framtida referens vid utvärdering av kommersiella MPS-baserade kompositer som fasta elektrolyter.
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The anode and the electrolyte in the MCFCBodén, Andreas January 2007 (has links)
A goal of the Swedish government is to increase the usage of renewable fuels and biomass-based fuels. Fuel cells, and especially the MCFC, are useful for these types of fuels. The Swedish market may benefit from the MCFC in two ways: increased efficiency of the biofuels and also utilisation of produced heat in district heating. Most of the commercial MCFC systems today are optimised for use with methane. The possibility to utilise biomass in Sweden makes it important to study how the MCFC may be adapted or optimised for good performance and low degradation with gas produced from biomass or other renewable fuels. This thesis is focused on methods that may be used to investigate and evaluate MCFC electrodes and electrolytes with renewable fuels i.e. CO2-containing gases. The methods and results are both experimental and mathematically modelled. The objectives of this thesis are to better understand how the performance of the anode is dependent on different fuels. Anode kinetics and the water-gas shift reaction have been investigated as well as the possibility to increase cell lifetime by increasing the initial electrolyte amount by having the anode as a reservoir. The effect of segregation of cations in the electrolyte during operation has also been studied. It was found that if the gas composition at the current collector inlet is in equilibrium according to the water gas-shift reaction the gas composition inside the electrode is almost uniform. However, if the gas is not in equilibrium then the concentration gradients inside the current collector have a large effect on the gas composition inside the electrode. The conversion of the gas in the gas flow channels according to the water-gas shift reaction depends on the gas flow rate. For an anode used in a gas mixture of humidified hydrogen and carbon dioxide that are not in equilibrium some solubility of Ni in a (Li/Na)2CO3 mixture was found. To have the anode act as an electrolyte reservoir to prolong cell lifetime the anode pore size should be carefully matched with that of the cathode and a bimodal pore-size distribution for the anode is preferable to have as good performance as possible for as large electrolyte filling degree interval as possible. Modelling results of segregation of cations in the electrolyte during operation indicate that the electrolyte composition changes during operation and that the lithium ions are enriched at the anode for both types of electrolyte used for the MCFC. The electrolyte composition changes are small but might have to be considered in long-time operation. The results from this thesis may be used to better understand how the MCFC may be used for operation with renewable fuels and how electrodes may be designed to prolong cell lifetime. / Ett av den svenska regeringens mål är att öka användandet av förnyelsebara bränslen och bränslen från biomassa. Bränsleceller och framförallt MCFC är användbara för dessa typer av bränslen. Den svenska marknaden kan dra fördelar av MCFC på två sätt; ökad bränsleutnyttjandegrad och utnyttjande av producerad värme för fjärrvärme. De flesta kommersiella MCFC-systemen idag är optimerade för användning av metan. Möjligheten att använda biomassa på den svenska marknaden gör det viktigt att studera hur MCFC kan anpassas eller optimeras för bra prestanda och låg degradering för användning med gas från biomassa eller andra förnyelsebara bränslen. Fokus i denna avhandling är på metoder som kan användas för att undersöka och utvärdera MCFC-elektroder och -elektrolyter med förnyelsebara bränslen, dvs. gaser innehållande CO2. Metoderna och resultaten är både experimentella och matematiskt modellerade. Målet med denna avhandling är att bättre förstå hur anodens prestanda beror på användningen av olika bränslen. Anodens kinetik och vattengasskiftreaktionen har studerats liksom möjligheten att förlänga cellens livstid genom att öka den initiala mängden elektrolyt medelst användning av anoden som reservoar. Effekten av segregation av katjoner i elektrolyten under last har också undersökts. Om gassammansättningen är i jämvikt enligt vattengasskiftreaktionen vid inloppet till strömtilledaren kommer gassammansättningen att vara nära uniform inuti elektroden. Om ingående gas inte är i jämvikt kommer stora koncentrationsgradienter uppkomma i strömtilledaren och påverka gassammansättningen i elektroden. Omsättningen med avseende på vattenskiftreaktionen av gasen i flödeskanalen verkar vara beroende av gasens flödeshastighet. För en anod som används i en uppfuktad blandning av vätgas och koldioxid som inte är i jämvikt befanns det att Ni har en viss löslighet i (Li/Na)2CO3. För att kunna använda anoden som reservoar för elektrolyt för att förlänga livstiden för MCFC skall anodens porstorleksfördelning överensstämma med katodens och ha en bimodal porstorleksfördelning för att ge en tillräckligt god prestanda i ett så stort elektrolytfyllnadsgradsintervall som möjligt. Modelleringsresultat för segregering av katjoner i elektrolyten under drift visar att litiumjoner anrikas i anoden för båda typerna av elektrolyt som används i MCFC. Elektrolytkoncentrationsförändringarna är små men kan behövas tas i beaktande vid långa driftstider. Denna avhandlings resultat kan användas för att bättre förstå hur MCFC skall anpassas för drift med förnyelsebara bränslen och hur elektroder kan utformas för att förlänga livstiden. / QC 20100630
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DESIGN AND CHARACTERIZATION OF A PEO-BASED POLYMER COMPOSITE ELECTROLYTE EMBEDDED WITH DOPED-LLZO: ROLE OF DOPANT IN BULK IONIC CONDUCTIVITYAndres Villa Pulido (8083202) 06 December 2019 (has links)
Ionic conductivity of solid polymer electrolytes (SPEs) can be enhanced by the addition of fillers, while maintaining good chemical stability, and compatibility with popular cathode and anode materials. Additionally, polymer composite electrolytes can replace the flammable organic liquid in a lithium-ion battery design and are compatible with lithium metal. Compatibility with Li-metal is a key development towards a next-generation rechargeable Li-ion battery, as a Li-metal anode has a specific capacity an order of magnitude higher than LiC6 anodes used today in everyday devices. The addition of fillers is understood to suppress the crystalline fraction in the polymer phase, increasing the ionic conductivity, as Li-ion conduction is most mobile through the amorphous phase. A full model for a conduction mechanism has not yet constructed, as there is evidence that a semi-crystalline PEO-based electrolyte performs better than a fully amorphous electrolyte. Furthermore, it is not yet fully understood why the weight load of fillers in PCEs can range from 2.5%wt to 52.5%wt, in order to achieve high ionic conductivity (~10-4S/cm). This work seeks to investigate the conduction mechanism in the PCE through the use of doped-Li7La3Zr2O12 as a filler and analysis of the PCE microstructure. In this work, a solid-state electrolyte, doped-Li7La3Zr2O12 (LLZO) was synthesized via a sol-gel method, and characterized. The effect of doping and co-doping the Li, La and Zr sites in the LLZO garnet was investigated. A PEO-based polymer composite electrolyte (PCE) was prepared by adding bismuth doped LLZO (Li7-xLa3Zr2-xBixO12) as a filler. The bismuth molar ratio was changed in value to study the dopant role on the bulk PCE ionic conductivity, polymer phase crystallinity and microstructure. Results suggest that small variations in dopant can determine the optimal weight load of filler at which the maximum ionic conductivity is reached. By understanding the relationship between filler properties and electrochemical properties, higher performance can be achieved with minimal filler content, lowering manufacturing costs a solid-state rechargeable Li-ion battery.<br>
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