Please read the abstract in the section 00front of this document / Dissertation (MSc)--University of Pretoria, 2009. / Microbiology and Plant Pathology / unrestricted

Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA). The research program was conducted to study equilibrium characteristics and kinetics of chloride removal by UHLA process, study interactions between chloride and sulfate or silica, and develop a model for multicomponent removal by UHLA. Kinetics of chloride removal with UHLA was investigated. Chloride removal was found to be fast and therefore, removal kinetics should not be a limitation to applying the UHLA process. Equilibrium characteristics of chloride removal with UHLA were characterized. Good chloride removal was obtained at reasonable ranges of lime and aluminum doses. However, the stoichiometry of chloride removal with UHLA deviated from the theoretical stoichiometry of calcium chloroaluminate precipitation. Equilibrium modeling of experimental data and XRD analysis of precipitated solids indicated that this deviation was due to the formation of other solid phases such as tricalcium hydroxyaluminate and tetracalcium hydroxyaluminate. Effect of pH on chloride removal was characterized. Optimum pH for maximum chloride removal was pH 12 ± 0.2. Results of equilibrium experiments at different temperatures indicated that final chloride concentrations slightly increased when water temperature increased at temperatures below 40oC. However, at temperatures above 40oC, chloride concentration substantially increased with increasing water temperature. An equilibrium model was developed to describe chemical behavior of chloride removal from recycled cooling water using UHLA. Formation of a solid solution of calcium chloroaluminate, tricalcium hydroxyaluminate, and tetracalcium hydroxyaluminate was found to be the best mechanism to describe the chemical behavior of chloride removal with UHLA. Results of experiments that studied interactions between chloride and sulfate indicated that sulfate is preferentially removed over chloride. Final chloride concentration increased with increasing initial sulfate concentration. Silica was found to have only a small effect on chloride removal. The equilibrium model was modified in order to include sulfate and silica reactions along with chloride in UHLA process and it was able to accurately predict the chemical behavior of simultaneous removal of chloride, sulfate, and silica with UHLA.

The successful industrial applications of pinch analysis techniques in energy optimisation and wastewater minimisation have resulted in the recent studies of combined mass and heat integration. Kim and Smith (2001) have demonstrated that operation of cooling water networks in series, rather than the conventional parallel arrangement improve cooling tower and cooling water network performance in new and retrofit design. In this work, utilising a superstructure to determine the mathematical formulation that characterises a cooling water network supplied by multiple cooling water sources, which often occurs in practice, extends this methodology. It is further demonstrated that the optimum cooling water supply to a network of cooling-water-using operations supplied by multiple sources is determined by considering the entire framework of sources and cooling-water-using operations, that is, unified targeting. This optimum is better than that obtained from considering individual subsets of cooling-water-using operations and its respective source, that is, single source targeting. Relevant practical constraints were included in the formulations to enhance robustness and applicability to real life situations. Practical constraints consisted of maximum return temperatures to cooling water sources, as wells as dedicated water sources and sinks of cooling-water-using operations. This concept was applied to an illustrative example and a case study of the Sasol Synfuels (Pty) Limited cooling water system that consisted of individual networks supplied by separate water sources. For the case with maximum water reuse the single source targeting method yielded an improvement of 11.6% over the parallel target for the illustrative example. In comparison, superior results were obtained with the developed unified targeting method, which yielded an improvement of 18.4%. Likewise, for the case with the aforementioned practical constraints 6.8% and 7.6% improvements were forecasted for the single source and unified targeting methods respectively. For the maximum reuse scenario of the case study, improvements of 37.9% and 41.0% over the parallel target were obtained using the single source and unified targeting methods, respectively. Similarly, considering practical constraints improvements of 20.3% and 31.1% were obtained. In both the illustrative example and case study the unified targeting method resulted in superior results than the single source targeting methods. / Dissertation (MEng (Chemical Engineering))--University of Pretoria, 2008. / Chemical Engineering / unrestricted

Cooling water systems are generally designed with a set of heat exchangers arranged in parallel. This arrangement results in higher cooling water flowrate and low cooling water return temperature thus reducing cooling tower efficiency. Previous research on cooling water systems has focused mainly on heat exchanger network thus excluding the interaction between heat exchanger network and the cooling towers. The studies completed on cooling water system in which the interaction between the cooling tower and the heat exchanger network was taken into consideration were limited to systems with single cooling tower. The main aim of this study was to develop a design methodology for synthesis and optimization of cooling water systems with multiple cooling towers. The design intends to debottleneck the cooling towers by reducing the circulating water flowrate. The study focuses mainly on cooling systems consisting of multiple cooling towers that supply a common set of heat exchangers. In this work the mathematical optimization technique was developed for optimization and synthesis of cooling water system. The heat exchanger network was synthesized using the mathematical optimization technique. This technique is based on superstructure in which all opportunities for cooling water reuse are explored. The cooling tower model was used to predict the thermal performance of the cooling towers while taking the thermal conditions of the associated heat exchanger network into account. The propose technique debotlleneck the cooling towers by decreasing the circulating water flowrate. This implies that a given set of cooling towers can manage an increased heat load. From the case studies, 22% decrease in circulating water flowrate was realized. The blowdown and makeup were also decreased by 7%. Furthermore, the cooling tower effectiveness was also improved by 4%. A decrease in the overall circulation water has an added benefit of decreasing the overall power consumption of the circulating pumps. There is also a potential for the reduction of makeup and blowdown water flowrate. / Dissertation (MEng)--University of Pretoria, 2011. / Chemical Engineering / unrestricted

Fartyg använder sig av stora dieselmotorer för framdrift och för att producera elektricitet ombord. Motorerna samt diverse kringsystem har behov av kylning och till detta används kemikaliebehandlat vatten i ett slutet kylsystem. Vid tömning och läckage från systemet tenderar det kemikaliebehandlade vattnet att hamna med länsvattnet. Länsvattnet genomgår en reningsprocess innan det pumpas överbord. Denna reningsprocess är inte utformad för att avskilja kemikalier och dessa tenderar att hamna i havet. I arbetet har en beräkningsmodell tagits fram för att kunna approximera den mängd kylvattenkemikalier som årligen släpps ut ifrån världshandelsflottan. Information om kylvattenkemikalierna har inhämtats via Kemikalieinspektionen samt MSB RIB gällande deras miljöpåverkan och toxicitet. Resultatet visar att en beaktansvärd mängd kemikalier potentiellt kan hamna i havet årligen. Några av kemikalierna beskrivs som giftiga för vattenlevande organismer och akvatiska system. Samt att kemikalierna även kan anrikas i naturen och vara cancerframkallande. / Shipping vessels use large diesel engines for propulsion and for producing electricity. The engines as well as various peripheral systems need to be cooled and for this; chemically treated water in a closed cooling system is used. During leakage and the emptying of the cooling water system, the chemically treated water tends to end up with the bilge water. Bilge water undergoes a purification process before it is pumped overboard. The purification process is not designed to separate chemicals therefore these tend to end up in the sea. A model has been developed for approximating the amount of cooling water chemicals annually emitted from the world merchant fleet. Information regarding the cooling water chemicals has been taken from the Swedish Chemicals Agency and the Swedish Civil Contingencies Agency on its environmental impact and toxicity. The results show that a considerable amount of chemicals can potentially end up in the sea annually and that some of the chemicals described as toxic to aquatic organisms, toxic to aquatic systems, are enriched in nature and may be carcinogenic.

Orientador: Roger Josef Zemp / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química / Made available in DSpace on 2018-08-25T15:18:44Z (GMT). No. of bitstreams: 1 Silva_IgorMacieldeOliveirae_M.pdf: 2922871 bytes, checksum: 4b7ffbcbf31e3be71d4453d00d6c7592 (MD5) Previous issue date: 2014 / Resumo: Sistemas de água de resfriamento são o método mais comum de rejeição de calor na indústria. Sistemas convencionais de água de resfriamento recirculante possuem uma rede de trocadores de calor em uma configuração paralela, demandando grande quantidade de circulação de água e torres de resfriamento. Embora a reutilização de água de resfriamento reduza a quantidade de água que é necessária no sistema e aumente o desempenho e capacidade da torre de resfriamento, a queda de pressão na rede de trocadores de calor pode aumentar devido ao seu arranjo em série-paralelo. Este estudo introduz uma metodologia para projetar diferentes sistemas de água de resfriamento e para analisar os impactos da reutilização de água sobre a queda de pressão na rede de trocadores de calor e sobre a torre de resfriamento. A partir de um modelo de super-estrutura, utiliza-se um algoritmo combinatorial com o auxílio da ferramenta de otimização Solver do Microsoft Excel para resolver um problema não-linear (NLP) de cada estrutura de rede de trocadores de calor. A queda de pressão em redes de trocadores de calor é avaliada por uma metodologia baseada na Teoria dos Grafos e utiliza os algoritmos de ordenação por topologia e de caminho crítico. Utiliza-se o método de Merkel para modelar a altura de uma torre de resfriamento e poder avaliar o volume necessário de uma torre de resfriamento para cada rede de trocadores de calor. Um estudo de caso é utilizado para ilustrar cada passo a medida que a metodologia é desenvolvida, buscando prover fundamentos para um estágio conceitual durante o projeto de um sistema de água de resfriamento / Abstract: Cooling water systems are the most common method of waste heat disposal in industry. Conventional recirculating cooling water systems have a heat exchanger network in a parallel arrangement, demanding not only substantial cooling water flow, but also large cooling towers. Although cooling water reuse reduces the amount of water that is recirculated in the system, thereby increasing the cooling tower capacity and performance, the pressure drop in the heat exchanger network may significantly increase due to series-parallel arrangements. This study introduces a methodology to design different cooling water systems and to analyse the cooling water reuse impacts on the heat exchanger network pressure drop and on the cooling tower size. From a superstructure model, a combinatorial algorithm in conjunction with the optimisation tool Solver in Microsoft Excel is used to solve a non-linear problem for each heat exchanger network structure. Pressure drop in heat exchanger networks is evaluated by a methodology that is based on Graph Theory and that uses topological sorting and critical path algorithms. Merkel's method is used to model the cooling tower height and to assess the required cooling tower volume for each heat exchanger network. A case study is used to illustrate each step as the methodology is developed, aiming to provide a basis for a conceptual stage during the cooling water system design / Mestrado / Engenharia Química / Mestre em Engenharia Química

Cooling water systems are needed to dissipate heat. The mist from open system cooling towers has been implicated as a source of infections of Legionella pneumophila. As a result biocide is added to cooling water systems, but the addition of biocide worsens biofouling, scaling and corrosion. Increasing environmental pressure has resulted in a move away from biocides which are usually chlorine based chemicals, so that the use of ozone instead has recently been reported as a way of controlling microbiological growth. This study aims to compare the corrosion rates (using calculated and measured surface areas) of different metals exposed to chemically treated and ozone treated cooling water in an industrial cooling water system. The types of corrosion were also observed and recorded. The scales from different components of the cooling systems as well as scale from chemically and ozone treated D tower water were characterized qualitatively using X-ray diffraction (XRD), Thermo gravimetric Analysis (TGA) and Atomic Absorption Spectroscopy. The D tower is a cooling water circuit in which the cooling water is from the Vaal River. As expected, the stainless steel has the lowest corrosion rate of 0.000 milli inches/year followed by brass with 1.531 milli inches/year and lastly mild steel (2.098 milli inches/year). Water quality rather than the presence or absence of ozone determines the corrosion rate. This confirms the findings reported in the literature. Scale from chemically treated water contains many different compounds while scale from ozone treated contains only different polymorphs of CaCO3, which is present in the water source and magnesium calcite.

Cooling water systems are used to remove excess heat from a chemical process to the atmosphere. The primary components of these systems are the cooling tower and the heat exchanger network. There is a strong interaction between these individual components, thus their performances are interrelated. Most published research in this area has focused mainly on optimization of the individual components i.e. optimization of heat exchanger network or optimization of the cooling towers. This approach does not optimize the cooling water system as a whole. Previous research work in which a holistic approach was used is limited to cooling water systems with single cooling water source. This work presents a technique for integrated optimization of complex cooling water systems. The system under consideration consists of multiple cooling towers each supplying a set of heat exchangers. A superstructural approach is employed to explore all possible combinations between the heat exchangers and the cooling towers. The cooling water reuse opportunities within the heat exchanger networks are also explored. A detailed mathematical model consisting of the cooling towers and the heat exchanger networks model is developed. Two practical scenarios are considered and the mathematical formulations for Case I and II yield nonlinear programing (NLP) and mixed integer nonlinear programming (MINLP) structure respectively. Although the reuse/recycle philosophy offers a good debottlenecking opportunity, the topology of the associated cooling water network is more complex, hence prone to higher pressure drop than the conventional parallel design. This is due to an increased network pressure drop associated with additional reuse/recycle streams. Therefore, it is essential to consider pressure drop during the synthesis of cooling water networks where the reuse/recycle philosophy is employed. The on-going research in this area is only limited to cooling water networks consisting of a single cooling water source. The common technique used is mathematical optimization using either superstructural or non superstructural approach. This work further presents a mathematical technique for pressure drop optimization in cooling water systems consisting of multiple cooling towers. The proposed technique is based on the Critical Path Algorithm and the superstructural approach. The Critical Path Algorithm is used to select the cooling water network with minimum pressure drop whilst the superstructural approach allows for cooling water reuse. The technique which was previously used in a cooling water network with single source is modified and applied in a cooling water network with multiple sources. The mathematical formulation is developed considering two cases. Both cases yield mixed integer nonlinear programming (MINLP) models. The cooling tower model is also used to predict the exit condition of the cooling tower given the inlet conditions from the cooling water network model. The results show up to 29% decrease in total circulating cooling water flowrate when the cooling water system is debottlenecked without considering pressure drop. Consequently, the overall cooling towers effectiveness was improved by up to 5%. When considering pressure drop the results showed up to 26% decrease in total circulating water flowrate. / Thesis (PhD)--University of Pretoria, 2013. / gm2013 / Chemical Engineering / unrestricted

Hamnefjärden är ett havsområde utanför Oskarshamns kärnkraftverk som har en förhöjd temperatur jämfört med vad som har varit naturligt innan Oskarshamnsverket togs i bruk. Sedan dess har kylvattnet från anläggningen påverkat ekologin med konstanta plymer av varmvattentillförsel med hög temperatur. I och med detta har påverkan av dessa utsläpp undersökts med hjälp av en sammanställning av litteratur gällande de fysikaliska och biologiska påverkningarna som skett på Hamnefjärden. Mätningar där Hamnefjärden jämförts med ett referensområde, visar att den lokala ekologin har påverkats av varmvattnet till en grad. Stora temperaturskillnader i mynningen för kylvattnet visar på stor fysikalisk påverkan men de biologiska verkar mindre påtagliga. / Hamnefjärden is a sea area outside of Oskarshamn nuclear powerplant which has an increased temperature compared to what was natural before the powerplant was started. Ever since the cooling water from the powerplant has been affecting the ecology with constant plumes of inflow with heated water. This discharge has thus been investigated by compiling literature about the physical and biological effects on Hamnefjärden. Surveys, in which Hamnefjärden has been compared to a reference area, shows that the local ecology has been affected by the heated water somewhat. Large differences in temperature in the estuary of the coolingwater indicates large physical effects but the biological effects seem smaller.

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