No description available.

No description available.

Induktiefgekoppelde-plasmareaktore (IGP’s) het toepassings in verskeie industrieë, insluitend die voorbereiding van metaalpoeiers vir laagvervaardiging. Die skermgas (ook skutgas gnoem) speel ’n belangrike rol in die termiese afskerming van die reaktorwand in ’n IGP. Die energie wat verloor word deur die wand van die reaktor kan verminder word deur die hittesone weg van die wand af te beweeg. Hierdie verplasing van die hittesone word bereik deur ’n skermgas te gebruik wat moeiliker ioniseer as die plasmagas. Die ioniseringsgraad van waterstof is laer as dié van argon weens die hoër elektriese geleidingsvermoë van argon by soortgelyke temperature. Waterstof word dus in klein hoeveelhede in die skutgas gebruik met argon as die hoof bestandeel en hoofplasmagas. Die waterstof voorkom dus plasmavorming naby die wand. Die skutgas het ook ’n heelwat hoër vloeisnelheid en verminder sodoende die beskikbare tyd vir hitte-oordrag na die wand. Die besondere hoë temperature wat in ’n IGP bereik word, belemmer egter die meting van eenvoudige lesings soos vloeisnelheid en temperatuur. Rekenaarmodelle voorsien ons van die geleentheid om die fisiese en chemiese eienskappe van ’n plasma te ondersoek asook die nodige gereedskap om die gedrag van die plasma te analiseer sonder eksperimentele lesings. Daar is verskeie numeriese modelle van IGP-sisteme in die literatuur alhoewel nie een van dié modelle die effek van die skutgassamestelling in ag neem nie. Die hoeveelheid waterstof in die skutgas kan groot newe-effekte hê op die plasmagas a.g.v. die hoër ionisasiepotensiaal van waterstof. ’n Oormaat waterstof in die skutgas is ook ’n verkwisting van voermateriaal. Albei die faktore het ’n invloed op die ekonomiese uitvoerbaarheid van die plasmaproses. Hierdie navorsing het beoog om die optimale skutgassamestelling te vind vir die reaktor wat by Necsa gebruik word vir sferoïedisering. Die werk is uitgevoer met die kommersiële eindige-elementsagtewarepakket COMSOL Multiphysics R. Hierdie rekenaarmodel dui daarop dat die wand beskerm kan word van plasmavorming met ’n waterstof/argon skutgas wat sodoende ook die energieverliese deur die wand verminder. Waterstof verbeter die skutgas se hitte-oordragvermoë, maar verskuif die hittesone weg van die wand af. As gevolg van hierdie twee kompeterende meganismes bestaan daar ’n optimale bedrywingspunt by 3 vol% H2 in die skutgas. Die model is bevestig deur die energiebalans van die model te vergelyk met eksperimentele resultate. / Dissertation (MEng)--University of Pretoria, 2020. / Advanced Metals Initiative Suid Afrikaanse Akademie vir Wetenskap en Kuns / Chemical Engineering / MEng / Unrestricted

The inductively coupled plasma mass spectrometer (ICP-MS) is the instrument of choice for trace and ultra-trace elemental analysis. However, the ICP-MS suffers from matrix effects. Matrix effects occur when instrument response varies as the composition of the sample matrix is changed. Matrix effects, or non-spectroscopic interferences, limit the accuracy of routine analysis. Identification of the sources of matrix effects provide a basis for reducing or eliminating them. As inaccuracies in the ICP-MS are more severe than those in the ICP atomic emission spectrometer, the problem may be due, at least in part, to the vacuum interface used to couple the plasma source and mass spectrometer. The research herein is a study of matrix effect sources in the first stage of the vacuum interface. This study utilized laser-induced fluorescence of atomic species to identify factors affecting analyte transport through the sampling orifice of the vacuum interface. Several non-idealities in the performance of the interface were found. (1) Operating conditions and sample compositions can negatively affect the efficiency with which ions are extracted through the vacuum interface coupling the plasma source to the mass spectrometer. (2) The sampling cone itself was found to suppress and narrow ion distributions in the plasma. (3) Changes in the degree of ionization were identified in the first vacuum stage. The evidence of recombination and state-changing collisions was observed in the first vacuum stage at lower power settings. Matrix effects occur in the first vacuum stage, the first step of the ion extraction process. This work shows that changes in ion transport through the first vacuum stage of the vacuum interface of an ICP-MS affect the overall performance of the instrument.

The Direct Simulation Monte Carlo algorithm as coded in FENIX is used to model the transport of trace ions in the first vacuum stage of the inductively coupled plasma mass spectrometer. Haibin Ma of the Farnsworth group at Brigham Young University measured two radial trace density profiles: one 0.7 mm upstream of the sampling cone and the other 10 mm downstream. We compare simulation results from FENIX with the experimental results. We find that gas dynamic convection and diffusion are unable to account for the experimentally-measured profile changes from upstream to downstream. Including discharge quenching and ambipolar electric fields, however, makes it possible to account for the way the profiles change.

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23484号 / 工博第4896号 / 新制||工||1765(附属図書館) / 京都大学大学院工学研究科社会基盤工学専攻 / (主査)教授 渦岡 良介, 教授 木村 亮, 准教授 澤村 康生 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

An investigation on noise transmission through the steering gear system is focused on the area of vehicle NVH (Noise Vibration and Harshness). From previous investigations it is well known that noise transmission through the steering system sometimes has a significant influence referring to tire road noise. In these cases, the interface force between steering gear and vehicle subframe is usually of interest during early stages of vehicle development. The target of the current work is to validate an approach based on a method, commonly known as the “Blocked force method” for noise and vibration testing, and check if it is possible to estimate the interface forces based on this method. This method became popular for mechanical testing in the middle 1900s [1] [2] [3], because of its easy applicability. The basic idea is to fix the component on a rigid plate and measure the interface force at the coupling points with force transducers inserted in between. It has a considerable potential in practical use, because if the blocked force could provide a good estimation for the interface force in noise transmission, it enables an efficient measurement of critical NVH behaviors without having to resort to the complete vehicle.However intuitively, the blocked force data could not be used directly. As a result, a coupled system equation is used for the coupling of the steering gear and the car body. Both the inertance of car body and steering system are taken into account, and thus introduces a compensation for the difference between vehicle and test bench. The method is validated against the transfer function measured on the full vehicle as the reference and compare this with the result calculated with the measured “Blocked force” data. Siemens Test.Lab is used for data acquisition and first data processing. Matlab is used for data post processing. Matrix symmetrization and singular value truncation is used to deal with the ill-conditioned data of steering gear inertance. A hybrid model with Finite Element data is proposed. Two test conditions are investigated: one set is with rigid coupling and the other is decoupled with rubber.

The integration of high-quality (Q)-factor 3-D filters with highly efficient antennas is addressed in this dissertation. Integration of filters and antennas into inseparable units eliminates the transitions between the otherwise separate structures resulting in more compact and efficient systems. The compact, highly efficient integrated 3-D filter/antenna systems, enabled by the techniques developed herein, allow for the realization of integrated RF front ends with significantly- reduced form factors. Integration of cavity filters with slot antennas in a single planar substrate is first demonstrated. Due to the high Q factor of cavity resonators, the efficiency of the integrated filter/antenna system is found to be the same as that of a reference filter with the same filtering characteristics. This means a near 100% efficient slot antenna is achieved within this integrated filter/antenna system. To further reduce the footprint of the integrated systems, vertically integrated filter/antenna systems are developed. We then demonstrate the integration of cavity filters with aperture antenna structures which enable larger bandwidths compared with slot antennas. The enhanced bandwidths are made possible through the excitation and radiation of surface waves. To obtain omnidirectional radiation patterns , we integrate cavity filters with monopole antennas. Finally, the integration of filters with patch antennas is addressed. Unlike the other filter/antenna integration examples presented, in which the antenna is utilized as an equivalent load, the patch antenna provides an additional pole in the filtering function. The presented techniques in this dissertation can be applied for filter/antenna integration in all microwave, and millimeter-wave frequency regions

An approach to integrated frequency-comb filtering is presented, building from a background in photonic crystal cavity design and fabrication. Previous work in the development of quantum information processing devices through integrated photonic crystals consists of photonic band gap engineering and methods of on-chip photon transfer. This work leads directly to research into coupled-resonator optical waveguides which stands as a basis for the primary line of investigation. These coupled cavity systems offer the designer slow light propagation which increases photon lifetime, reduces size limitations toward on-chip integration, and offers enhanced light-matter interaction. A unique resonant structure explained by various numerical models enables comb-like resonant clusters in systems that otherwise have no such regular resonant landscape (e.g. photonic crystal cavities). Through design, simulation, fabrication and test, the work presented here is a thorough validation for the future potential of coupled-resonator filters in frequency comb laser sources.

With the increasing demand for small and cost efficient DC/DC converters, the power converters are expected to operate with high efficiency. Magnetics components design is one of the biggest challenges in achieving the higher power density and higher efficiency due to the significant portion of magnetics components volume in the whole power system. At the same time, most of the experimental phenomena are related to the magnetics components. So, good magnetics components design is one of the key issues to implement low voltage high current DC/DC converter. Planar technology has many advantages. It has low profile construction, low leakage inductance and inter-winding capacitance, excellent repeatability of parasitic properties, cost efficiency, great reliability, and excellent thermal characteristics. On the other side, however, planar technology also has some disadvantages. Although it improves thermal performance, the planar format increases footprint area. The fact that windings can be placed closer in planar technology to reduce leakage inductance also often has an unwanted effect of increasing parasitic capacitances. In this dissertation, the planar magnetics designs for high current low voltage applications are thoroughly investigated and one CAD design methodology based on FEA numerical analysis is proposed. Because the frequency dependant parasitic parameters of magnetics components are included in the circuit model, the whole circuit analysis is more accurate. When it is implemented correctly, integrated magnetics technique can produce a significant reduction in the magnetic core content number and it can also result in cost efficient designs with less weight and smaller volume. These will increase the whole converter's power density and power efficiency. For high output current and low output voltage applications, half bridge in primary and current doublers in secondary are proved to be a very good solution. Based on this topology, four different integrated magnetics structures are analyzed and compared with each other. One unified model is introduced and implemented in the circuit analysis. A new integrated magnetics component core shape is proposed. All simulation and experimental results verify the integrated magnetics design. There are several new magnetics components applications shown in the dissertation. Active transient voltage compensator is a good solution to the challenging high slew rate load current transient requirement of VRM. The transformer works as an extra voltage source. During the transient periods, the transformer injects or absorbs the extra transient to or from the circuit. A peak current mode controlled integrated magnetics structure is proposed in the dissertation. Two transformers and two inductors are integrated in one core. It can force the two input capacitors of half bridge topology to have the same voltage potential and solve the voltage unbalance issue. The proposed integrated magnetics structure is simple compared with other methods implementing the current mode control to half bridge topology. Circuit analysis, simulation and experimental results verify the feasibility of these applications.