The general aim of this thesis is to investigate heterogeneity in the structure of the crust and uppermost mantle of Archaean and Proterozoic terrains in southern Africa and to use the findings to advance our understanding of Precambrian crustal genesis. Teleseismic, regional and local seismic recordings by the broadband stations of the Southern African Seismic Experiment (SASE), Kimberley array, South African National Seismograph Network (SANSN) and the Global Seismic Network (GSN) are used in the inversion procedures to address the aim of this thesis. In the first part of the thesis, the nature of the lower crust across the southern African shield is investigated by jointly inverting receiver functions and Rayleigh wave group velocities. The resultant Vs models show that much of southern Africa has a lower crust that is mafic in composition, whereas the western parts of the Kaapvaal and Zimbabwe Cratons have a lower crust that is intermediate-to-felsic in composition probably due to rifting. The second part of the thesis evaluates the “dipping-sheet” and “continuous-sheet” models of the Bushveld Complex using better-resolved seismic models derived in a two-step approach, employing high-frequency Rayleigh wave group velocity tomography and the joint inversion of high-frequency receiver functions and 2–60 sec Rayleigh wave group velocities. The resultant seismic models favor a “continuous-sheet” model of the Bushveld Complex, although detailed modelling near the centre of the Complex shows that the subsurface mafic layering could be disrupted. The third part of the thesis, is focused on jointly inverting high-frequency teleseismic receiver functions and 10–60 sec Rayleigh wave group velocities to place shear wave velocity constraints on the source of the Beattie Magnetic Anomaly (BMA) at depth and to evaluate existing geophysical models of the BMA source. The resultant Vs models across the BMA suggest the BMA source to be at upper to middle crustal depths (5–20 km) with high velocity layers (≥ 3.5 km/s). Further to this, is a lower crust that is highly mafic (Vs ≥ 4.0 km/s) and a crust beneath the BMA that is on average thicker than 40 km. Plausible models of the BMA source are massive sulphide ore bodies and/or mineralized granulite-facies mid-crustal rocks and/or mineralized Proterozoic anorthosites. v Overall, the findings in this research project are consistent with the broad features of a previous model of Precambrian lithospheric evolution but allows for refinements of that model.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science. Johannesburg, 2017. / Massif-type anorthosites formed in the Proterozoic Eon are the most voluminous anorthosite occurrences on Earth, reaching tens of thousands of square kilometers in aerial extent. While they formed throughout the Proterozoic, most formed during a 700 Ma period between 1800 and 1100 Ma. The rocks are dominated by plagioclase (typically 70 – 95 volume %) of intermediate composition (An40-65). Olivine, orthopyroxene, clinopyroxene and Fe-Ti oxides make up the minor mafic proportion. While most researchers agree that the anorthosites formed from a high-alumina basaltic parental magma, there are disparate views on how that parental magma was generated. Whether the parental magma formed by partial melting of the lower crust, or by mantle melting, is a topic of much debate. The anorthosites commonly have crust-like isotopic signatures, but this could be produced by melting of the lower crust, or by crustal contamination of mantle-derived magmas. Many Proterozoic anorthosite complexes consist of both olivine-bearing and orthopyroxene-bearing anorthosites. This has been attributed to variable amounts of crustal contamination of mantle-derived magmas, based on evidence from isotopes and field relations. While geochemical and petrologic evidence for crustal contamination is plentiful, existing experimental work shows that a thermal divide exists for high-alumina basalts fractionating at lower crustal depths, casting doubts on whether fractionation of a mantle melt could produce anorthosite. Here I use high-pressure experiments to test whether the fractionation of high-alumina basalt can form anorthosites, and to what extent crustal contamination affects the fractionation sequence. The results are compared to new geochemical and petrologic data from the Kunene Anorthosite Complex (KAC), in Angola and Namibia. The KAC is one of the largest anorthosite complexes in the world, with an area of ~18 000 km2. The KAC (1438 – 1319 Ma) has an elongate shape and intruded into Palaeoproterozoic to Mesoproterozoic country rocks (~2200 to 1635 Ma) at the southern margin of the Congo craton. It is associated with a suite of granitoid rocks of variable composition, which are akin to the granitoids associated with nearly all Proterozoic anorthosites. The granitoids have been shown to be coeval with the anorthosites, but were from a chemically independent magma series. The most distinctive granitoids in the KAC are the Red Granites, which outcrop around the southern margins of the complex, and also cross-cut the complex in a NE-SW linear belt, dividing the complex roughly into northern and southern domains. The rocks of the KAC are highly variable in terms of mode, mineral chemistry, and texture, but there is a general trend of more olivine-bearing anorthosites north of the granite belt, and orthopyroxene-bearing anorthosites to the south. The olivine-bearing rocks (or leucotroctolites) typically contain plagioclase and cumulus and/or intercumulus olivine, with lesser interstitial orthopyroxene and/or clinopyroxene, Fe-Ti oxides, and biotite. The orthopyroxene-bearing anorthosites (or leuconorites) contain cumulus plagioclase ± cumulus orthopyroxene, and interstitial orthopyroxene, clinopyroxene, oxides and biotite. The leucotroctolites are characterized by more calcic plagioclase (An56-75), while the leuconorites contain more intermediate plagioclase (An48-56). The variability of the rocks across the complex suggests that the KAC consists of several coalesced plutons with different histories. The petrologic data and field observations in this study are consistent with the leuconorites of the complex being derived from a mantle-derived magma that experienced contamination by silica-rich rocks, crystallizing orthopyroxene rather than olivine, and less calcic plagioclase. The leucotroctolites experienced less or no contamination. To test whether the mineral dichotomy and the variations in plagioclase chemistry observed in Proterozoic anorthosites are due to variably contaminated mantle-derived magma, piston cylinder experiments were conducted on a synthetic high-alumina basalt (HAB) composition, as well as a mixture of this HAB with 30% of a Red Granite composition. Experiments were conducted at 10 kbar, to simulate the depth at which anorthosite differentiation most likely begins (based on Al-in-orthopyroxene geobarometry of highly aluminous orthopyroxene megacrysts that occur in many massifs). The uncontaminated experiments produced olivine as the first liquidus phase, followed by plagioclase (An65-68), and then by clinopyroxene, pigeonite and ilmenite at progressively lower temperatures. Residual liquids evolve towards more silica-rich compositions with decreasing temperature. The contamination experiments produced liquidus orthopyroxene, followed by plagioclase (An51-56), and then by pigeonite at lower temperatures. The experiments show that contamination of a primitive HAB magma by granitic material, most likely produced by partial melting of the lower crust during anorthosite formation, can shift the mineral assemblages of the crystallizing anorthosite from olivinebearing to orthopyroxene-bearing, and produce less calcic plagioclase than the uncontaminated HAB magma. This could explain the observation of olivine-bearing and orthopyroxene-bearing anorthosites in the KAC and many other Proterozoic anorthosites. Previous high-pressure experimental studies, using a slightly more evolved HAB composition, indicated the presence of a thermal divide, which causes liquids to evolve to more Si-poor compositions. The experimental results presented in this study however, do not show a thermal divide, indicating that small variations in experimental starting composition can cause large differences in the liquid line of descent. The results of this study indicate that partial melting of the mantle can produce anorthosite parental magmas, and that the range in mineral assemblages of the anorthosites can be accounted for by crustal contamination of a mantle-derived magma. Fractionation of the experimental starting compositions was also modeled using the MELTS algorithm. These calculations produce a close match to the experimental liquid trends. This allows for modeling of a variety of compositional and environmental variables. The MELTS modeling shows that as little as 10% contamination of HAB magma with a granitic composition may position the magma in the orthopyroxene stability field, forming orthopyroxene-bearing anorthosites. The modeling also shows that a variety of silica-rich contaminants, including granites, granodiorites and tonalities, produce similar results and liquid evolution trends, so a range of granitoid compositions may successfully produce the shift in mineral assemblages of the anorthosites. This suggests that crustal contamination of mantle-derived HAB could be a widespread process and the primary mechanism that produces the distinctive crust-like signatures in Proterozoic anorthosites. In summary, the mineralogical and chemical diversity observed in Proterozoic anorthosites can be produced by variable amounts of crustal contamination of mantle-derived, highalumina basaltic magma. The experimental results in this study combined with field observations, and geochemical and isotopic data, provide evidence for a model of massif-type anorthosite petrogenesis. Orthopyroxene-bearing rocks formed from an originally highalumina basaltic magma that experienced contamination by granitic partial melts of the lower crust, during ponding of the magma at the Moho. This process preconditioned the surrounding crust and possibly prevented further anatexis. Following emplacement of orthopyroxene-bearing anorthosites, subsequent magma pulses ponded at the Moho did not assimilate any/as much granitic material, as they were interacting with preconditioned crust, and formed olivine-bearing anorthosites. With better constraints on the parental magma composition, magma source, and crustal contamination processes, addressing aspects such as the tectonic setting and emplacement mechanisms of these massive intrusions should be prioritized. Understanding these enigmatic aspects of anorthosite petrogenesis is leading the anorthosite community towards answering the ultimate questions of why massif-type anorthosites are restricted to the Proterozoic. / XL2018

Several seismic reflection surveys were conducted in the late 1980s and early 1990s under the auspices of the SA National Geophysics Programme. These surveys targeted the Bushveld Complex, Limpopo Mobile Belt (Limpopo Province), Witwatersrand Basin, Vredefort Dome and the Beattie magnetic anomaly (BMA) in the Southern Karoo. The ~100 km seismic reflection profile described in this study (SAGS-03-92) covers the BMA, the Southern Cape Conductive Belt (SCCB) and the Karoo/Cape Fold Belt boundary. The profile runs from approximately Droëkloof in the south to Beaufort West in the north along the N12 national road. The profile was acquired in 1992, but the complete profile was not interpreted or published prior to this study. The purpose of this study is to successfully reprocess the data and to do a structural and stratigraphic interpretation in order to try and understand the geological history and processes that led up to the formation of the rocks in that area. SAGS-03-92 reveals a clear image of the crust in the southern Karoo. The crust is interpreted to be around 37 km thick in the area of investigation and can be classed into three parts: upper crust, middle crust and lower crust. The upper crust consists of the Karoo and Cape Supergroup rocks that dip slightly to the south. This interpretation has been confirmed by two deep boreholes (BH No. 3 and KW 1/67). The seismic fabric shows quite a strong character in the upper crust and the interpreted boundaries between the different lithologies (The Table Mountain, Bokkeveld and Witteberg Groups of the Cape Supergroup and the Dwyka, Ecca and Beaufort Groups of the Karoo Supergroup) are for the most part quite easy to identify. Within the Cape Fold Belt (CFB), however, the seismic character becomes distorted in such a way that it is very difficult to make out any features. This is possibly due to the severe faulting and folding that occurred when the CFB formed. An unconformity that can continually be followed throughout the profile (although it disappears in the south of the profile possibly due to deformation when the CFB formed) separates the upper crust from the middle crust and the unconformity is clearly indicated by a strong series of reflectors on the seismic profile. The middle crust is interpreted to consist of granitic-gneisses belonging to the Bushmanland Terrane (part of the Namaqua-Natal Belt (NNB)). The seismic profile suggests that the NNB gneisses continue beneath the Cape Fold Belt. The seismic fabric dips steeply to the north. The middle crust also hosts the source of the Beattie Magnetic Anomaly (BMA). There is an area of high reflectivity under the BMA on the seismic profile that differs significantly from the surrounding seismic character. This area is characterised by a beanshaped cluster of strong reflections dipping north and south. It is ~10 km wide, with a thickness of ~8 km and occurs at a depth of ~6 km to ~10 km. The lower crust is interpreted to consist of either granites belonging to the Areachap Terrane, Richtersveld or Kheis Province (NNB) or rocks belonging to the Kheis Province. The seismic fabric of the lower crust dips moderately to the south. The Moho is recognised at ~37 km depth at ~68 km from the south of the profile, but for the rest of the profile, it is unclear where the Moho is encountered. The research done for this study correlates well with work done under the auspices of Inkaba yeAfrica, especially the work done by Ansa Lindeque

Many aspects of Proterozoic massif-type anorthosite petrogenesis have been, and remain, controversial. Mafic lower crust and depleted mantle have both been proposed as mutually exclusive sources of these near-monomineralic, temporally restricted batholiths. The debate surrounding the magma source has also led to uncertainty regarding the tectonic setting of these massifs, with a range of possibilities including convergent, divergent and anorogenic settings. The dramatic geochemical effects of crustal contamination in these massifs are well known and strong crustal signatures are evident in most, if not all, Proterozoic anorthosite massifs. The source debate, in the simplest sense, reduces to whether the ubiquitous crustal signature is derived principally from melting of a lower crust or is an effect of crustal assimilation. The origin of this crustal signature, and whether it obscures the original isotopic composition of the magmas or not, has fuelled the debate surrounding the source of the anorthosites. Using major element, trace element and isotopic compositions, as well as energyconstrained assimilation-fractional-crystallisation (EC-AFC) modelling from samples representing various stages of the polybaric crystallisation history of the magmas, including high-pressure megacrysts, anorthosites and their internal mineral phases, I remove the obfuscating effects of possible crustal contamination and probe the source of the magmas. In order to assess the effects of crustal contamination, if any, anorthosites from three massifs – the Mealy Mountains Intrusive Suite, Nain Plutonic Suite (both in eastern Canada) and Rogaland Anorthosite Province (Norway), have been analysed – all of which intrude into crust of significantly different age and chemical character. Sm-Nd geochronology of high-Al, high-pressure orthopyroxene megacrysts, as well as the comagmatic, host anorthosites, indicate that the magmatic system is long-lived, with an age difference between the megacrysts and hosts of ~110-130 million years. Isotopic compositions of primitive megacrysts qualitatively show that the magmas were derived from melting of the depleted mantle. Strong links between the isotopic offset from depleted mantle evolution and the age and composition of the surrounding crust confirm that the geochemical nature of the crustal contaminant plays a significant role in the petrogenesis of the anorthositic rocks. The geochronological indications of a long-lived magmatic system point to Proterozoic anorthosite formation in a continental magmatic arc – one of the only environments capable of supplying geographically-localised magma and heat to the base of the crust for over 100 million years. Proposed divergent or ‘anorogenic’ settings could not plausibly supply magma to the base of the crust for over 100 m.y. without initiating ocean formation or continental break-up. Anorthosite emplacement at mid-crustal levels may coincide with late- to post-orogenic events in several terranes, but evidence presented for a long-lived magmatic system is incongruent with this proposed setting. In this thesis, I propose that the petrogenesis of these intrusives must span both orogenic and post-orogenic periods. An overlap in megacryst crystallisation age with the onset of calc-alkaline orogenic magmatism in the Sveconorwegian Orogen, both occuring ~100 m.y. before anorthosite emplacement, confirms that initial magma and megacryst formation coincides with the main phase of magmatic and orogenic activity in a convergent magmatic arc. These geochronological constraints have implications for regional geodynamics in the Sveconorwegian Orogen (and the Labrador region) with the evidence providing corroboratory support for a long-lived accretionary orogen, as opposed to the widely-held view that the Sveconorwegian orogeny was predominantly collisional. Compositions of high-pressure megacrysts, anorthosites and analysis of internal isotopic disequilibrium indicates that lower crustal contamination has a significant influence on the isotopic composition of the rocks, with relatively minor contributions from the mid- to upper crust. Energy-constrained AFC modelling confirms that significant lower crustal contamination occurs during ponding of magmas at the Moho and is able to reproduce the observed isochronous isotopic compositions of the megacrysts as well as the compositions of the host anorthosites. Evidence of varying degrees of internal isotopic disequilibrium reinforces the significant role that assimilation of crust of different age and chemical nature have on the compositions of Proterozoic anorthosites. Unexpected patterns of isotopic disequilibrium show that anorthosite petrogenesis is not a “simple” case of progressive crustal contamination during polybaric ascent of viscous, partially-molten 4 magma mushes, but is more likely to involve significant differentiation and solidification at lower crust depths, followed by ascent of high-crystallinity bodies (> 50 % crystallinity) to upper crustal levels. Although the composition of the bulk continental crust is different to plagioclase-rich Proterozoic anorthosites, both are missing a mafic component. It is unclear how this missing mafic component was generated in the continental crust, because most of the evidence for these crustal differentiation processes is sequestered below or near the Moho. However, Proterozoic anorthosites, formed by viscous, plagioclase-rich mushes, entrain rare cumulate megacrysts from these depths and consequently preserve evidence of magmatic differentiation processes at the Moho. The evidence for the formation and sequestration of dense ultramafic cumulates in ponding magmas at the Moho can not only explain the missing mafic component in Proterozoic anorthosites, but also suggests that cumulate formation in crust-forming, arc environments is a significant process and should be taken into account in models dealing with evolution and differentiation of the continental crust. Sampling and petrographic and geochemical analysis of five pegmatitic segregations, or “pods”, from anorthosites of the Mealy Mountains Intrusive Suite reveal a diverse range of compositions from mafic, Fe-rich and Si-poor, to Fe-poor and Sirich felsic compositions and from monzogranite through quartz-monzodiorite and monzodiorite to Fe-P-rich gabbronorite. Each pod shows a range of noteworthy graphic, myrmekitic and symplectic textures on a variety of scales, along with distinctive mineralogical assemblages and highly-enriched trace element compositions. Derivitive minerals (e.g. apatite and zircon), high concentrations of Fe, Ti, P (and in some cases SiO2) and 10-1000 times chondrite enrichment suggest that many of the pods are highly fractionated. U-Pb zircon geochronology reveals that all the pods are the same age as the anorthositic hosts and confirms that the Mealy Mountains Intrusive Suite was emplaced between 1654 and 1628 Ma. Using the aforementioned evidence, I show that the pods represent the fluid-bearing, late-stage crystallisation products of a residual liquid in the massif anorthosite system and provide a window into the final stages of crystallisation in the anorthosite system. A range of rock types (monzonites, monzonorites, ferrodiorites and jotunites) observed in similar pod-like structures, as well as dykes and plutons, have also been documented in other Proterozoic anorthosite massifs. These have, at one time or another, controversially been interpreted as the residual liquids of anorthosite crystallisation. The observation of in-situ pods with similar compositions to all of the aforementioned rock types and displaying textures indicative of late-stage crystallisation support the notion that these associated lithologic units are comagmatic with, but residual to, the anorthosites and are not residual liquids of other crustally-derived rocks, immiscible liquids, parental magmas or cumulates. Isotopic compositions of these highly-fractionated, late-stage pods also overlap with those of anorthosites, lending further evidence to the case that upper crustal contamination plays only a minor role in developing the chemical signature of the anorthosites. With these results I propose that the nature/composition of the residual liquids of Proterozoic anorthosite magmas can vary dramatically, depending on geochemical differences in the original magma pulses and by mixing of mobilised, independently-evolved segregations of residual liquids. This process could explain why so many varied rock types associated with Proterozoic anorthosites have been suggested as residual liquids: these rocks all represent residual liquids resulting from varying degrees of differentiation, subsequent mobilisation, mixing and final solidification as plutons or dykes. Proterozoic anorthosite petrogenesis is an inherently polybaric process and so by its very nature produces a range of complicated and contradictory features which have clouded interpretation of numerous aspects of the rocks formation. In analysing crystallisation products from numerous stages of the anorthosites polybaric history, I have been able to probe the magmatic processes operating at different stages of Proterozoic anorthosite petrogenesis. In doing so I show that the magmas are derived from melting of the depleted mantle in continental-arc-like settings – two controversial aspects of Proterozoic anorthosite petrogenesis. These constraints on the source and tectonic setting will allow renewed investigation into the ultimate question surrounding Proterozoic anorthosites: why are these rock types restricted to the Proterozoic and what clues does this temporal restriction offer about Earth’s geodynamic evolution during this period? The assertion in this thesis that 5 Proterozoic anorthosites formed in arc environments dictates that subduction processes or geodynamic conditions during the Proterozoic favoured the production of voluminous masses of plagioclase, because modern-day magmatic arc terranes show no evidence of anorthosites with similar compositions. However, calcic anorthositic inclusions and xenoliths are observed in modern-day volcanic and continental arcs suggesting that anorthosites may be forming in these environments, but that conditions such as water content or style of subduction are different to the Proterozoic, producing less and compositionally different plagioclase and anorthosite. The results of this thesis shed new light on and refine the petrogenesis of Proterozoic anorthosites, but the focus of research must now shift to explaining the temporal restriction of these intrusions and the implications of this restriction for the geodynamic evolution on Earth during the Proterozoic.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfillment of the requirements for the degree of Doctor of Philosophy. October 2017. / Since the arc assembly and continental collision of the East African Orogen some 640 million years ago, Madagascar has gone through several geodynamic and tectonic episodes that have formed and subsequently modified its lithosphere. This thesis aims to investigate the structure of the crust, the uppermost mantle, and the mantle transition zone beneath Madagascar to gain insights into the relationship between present-day lithosphere structure and tectonic evolution, and to evaluate candidate models for the origin of the Cenozoic intraplate volcanism. To address these issues, local, regional, and teleseismic events recorded by several temporary seismic networks; the MAdagascar-COmoros-MOzambique (MACOMO), the SEismological signatures in the Lithosphere/Asthenosphere system of SOuthern MAdagascar (SELASOMA), and the Réunion Hotspot and Upper Mantle – Réunions Unterer Mantel (RHUM-RUM) were used to complement the seismic events recorded by the permanent seismic stations in Madagascar. The different methods used and the primary results of this study are explained in each section of this thesis. In the first part of this thesis, crustal and uppermost mantle structure beneath Madagascar was studied by analyzing receiver functions using an H-κ stacking technique and a joint inversion with Rayleigh-wave phase-velocity measurements. Results reflect the eastward and northward progressive development of the western sedimentary basins of Madagascar. The thickness of the Malagasy crust ranges between 18 km and 46 km. The thinnest crust (18-36 km thick) is located beneath the western basins and it is due to the Mesozoic rifting of Madagascar from eastern Africa. The slight thinning of the crust (31-36 km thick) along the east coast may have been caused by crustal uplift and erosion when Madagascar moved over the Marion hotspot and India broke away from it. The parameters describing the crustal structure of Archean and Proterozoic terranes, including thickness, Poisson’s ratio, average shear-wave velocity, thickness of mafic lower crust, show little evidence of secular variation. Slow shear-wave velocity of the uppermost mantle (4.2-4.3 km/s) are observed beneath the northern tip, central part and southwestern region of the island, which encompass major Cenozoic volcanic provinces in Madagascar. The second part of the thesis describes a seismic tomography study that determines the lateral variation of Pn-wave velocity and anisotropy within the uppermost mantle beneath Madagascar. Results show an average uppermost mantle Pn-velocity of 8.1 km/s. However, zones of relatively low-Pn-velocity (~7.9 km/s) are found beneath the Cenozoic volcanic provinces in the northern, central, and southwestern region of the island. These low-Pn-velocity zones are attributed to thermal anomalies that are associated with upwelling of hot mantle materials that gave rise to the Cenozoic volcanism. The direction of Pn anisotropy shows a dominant NW-SE direction of fast-polarization in the northern region and around the Ranostara shear zone, in the south-central Madagascar. The anisotropy in the uppermost mantle beneath these regions aligns with the existing geological framework, e.g. volcanic complex and shear zones, and can be attributed to a fossil anisotropy. The Pn anisotropy in the southwestern region, around the Morondava basin, is E-W to NE-SW-oriented. It can be attributed either to the mantle flow from plate motion, the African superplume, or the Mesozoic rifting from Africa. Results from this study do not show any substantial evidence of the formation of a diffuse boundary of the Lwandle plate, cutting through the central region of Madagascar. Station static delays reflect the significant variation in the Moho depth beneath the island. In the third part of the thesis, the thickness of the mantle transition zone beneath Madagascar, which is sensitive to the surrounding temperature variation, has been estimated by stacking receiver functions. Single-station and common-conversionpoint stacking procedures show no detectable thinning of the mantle transition zone and thus no evidence for a thermal anomaly in the mantle under Madagascar that extends as deep as the mantle transition zone. Therefore, this study supports an upper mantle origin for the Cenozoic volcanism. However, the resolution of the study is not sufficient to rule out the presence of a narrow thermal anomaly as might arise from a plume tail. Overall, the findings in this research are broadly consistent with the crustal and upper mantle structure of Madagascar determined by previous studies, but provides significantly greater detail with regard to the crustal and uppermost mantle structure as more seismic stations were used. / LG2018

Orientador: Antenor Zanardo / Banca: Marcos Aurélio Farias de Oliveira / Banca: Antonio José Ranalli Nardy / Banca: Eliane Aparecida Del Lama / Banca: Gergely Andres Julio Szabó / Resumo: As rochas máficas e ultramáficas em foco estão inseridas na Faixa Itapira/Amparo. Ocorrem na forma de corpos tabulares a lenticulares e são representadas por metaperidotitos, xistos ultramáficos e anfibolitos. Rochas metassomáticas aparecem associadas às máficas e ultramáficas. A litoquímica juntamente com dados de campo, a petrografia e a geocronologia mostram que os processos tectono-metamórficos que atuaram sobre essas rochas provocaram mudanças químicas e mobilidade de elementos maiores, menores, traços e terras-raras. O contexto geológico juntamente com os dados obtidos sugere que essas rochas sejam derivadas de fragmentos de crostas oceânicas embutidas na crosta continental durante o Paleoproterozóico e não de ofiólitos brasilianos, como anteriormente aventado. Indicam, também, que não houve geração de material juvenil no Neoproterozóico, apenas retrabalhamento de rochas mais antigas. Diante da possibilidade de os litotipos atribuídos ao Grupo Itapira terem sido gerados em mais de um ciclo geotectônico optou-se pela denominação de Complexo Itapira / Abstract: The metamafic and metaultramafic rocks studied in this work are located in Itapira/Amparo belt. They occur as tabular to lenticular bodies and are represented by metaperidotites, ultramafic schists and amphibolites. Metassomatic rocks are associated with these rocks. Lithochemistry, field data, petrography and geochronology indicate that the tectonic-metamorphic processes which actuated over the studied region produced chemical changes and the mobility of major, minor, trace and rare earth elements. Geological context with such data suggest that these rocks were originated from oceanic crust pieces emplaced in continental crust during Palaeoproterozoic, not from brazilian ophiolites like avocated before. They also indicate that there were no primary material generation on the Late Proterozoic, just reworking of older rocks / Doutor

Submitted by Setor de Tratamento da Informa??o - BC/PUCRS (tede2@pucrs.br) on 2015-05-15T19:46:12Z No. of bitstreams: 1 468722 - Texto Completo.pdf: 1230126 bytes, checksum: 45679926e59fba17cb7e39823a47daf0 (MD5) / Made available in DSpace on 2015-05-15T19:46:12Z (GMT). No. of bitstreams: 1 468722 - Texto Completo.pdf: 1230126 bytes, checksum: 45679926e59fba17cb7e39823a47daf0 (MD5) Previous issue date: 2015-02-20 / Benthic macroinvertebrates occupy a critical position in the food chain, since they are responsible for the exchange of energy between basal resources and higher trophic levels. In order to analyze the physiological behavior of the species throughout the year, we collected 69 individuals of Parastacus brasiliensis promatensis in the central month of each season. The animals collected were measured for carapace length, taking as a criterion the minimum value for capture 20mm after hemolymph were removed in medium containing 10% potassium oxalate (anticoagulant) and left on ice for 24 hours to use only plasma in the analyzes. After capturing the animals were sacrificed by Cryoanesthesia. A water sample from Garapi? stream (San Francisco de Paula, RS) for analysis of physical and chemical parameters was collected. In laboratory subjects were weighed on the total weight and tissue weight to determine the rates of gastric fullness and hepatossomatic, in both genders, and gonadosomatic only in females; as well as the degree of gastric fullness. In the hemolymph were quantified by spectrophotometry proteins, lactate, lipids, triglycerides, glycerol, glucose, cholesterol, VLDL e HDL and glucose. Also analyzed the behavior of three antioxidant enzymes, which were superoxide dismutase, catalase and glutathione s-transferase; as well as a cellular damage measure (lipid peroxidation), in order to describe the oxidative status of this subspecies in different seasons. These analyzes were performed by spectrophotometric methods, gills, in hepatopancreas and abdominal muscle for both genders and in the gonads in females. Data were analyzed by one-way ANOVA followed by Bonferroni or Kruska-Wallis followed by Dunn (17.0 SPSS- or Bioestat). The statistical analysis indicated that there was difference between IH and IG of females throughout the study period. In the spring (reproductive peak) observed an increase in the IG and reduced IH, suggesting allocation of energy hepatopancreas reserves to the gonads; hypothesis reinforced by the analysis of IH in males, where there was no significant difference. Gastric index showed a reduction (p <0.05) in both sexes, in winter which combined with a decrease in ambient temperature and blood glucose control suggest a decreased metabolic rate and habitat exploitation, with possible use of endogenous reserves; combined with a decrease in glycerol and protein in the autumn transition to winter. Both genders showed differences (p <0.5) for lactate levels, as levels possibly linking up with low dissolved oxygen content (3,31 mg / l) in the summer. There was also a significant increase across the lipid chain in both sexes but more pronounced in females in the period corresponding to the apex of reproduction, and the probable cause reproductive preparation directly or increased energy expenditure in this situation. As for oxidative stress, the results suggest that females have a large energy expenditure in protecting the gonadal tissue, especially in the spring (playback apex) while maintaining a high degree of GST enzyme activity, together with the lesser extent of cellular damage when compared with the other tissues. As for the males lipid peroxidation level was higher in the spring, in all tissues. However, the gill tissue proved unable to increase antioxidant activity, and only the muscle and hepatopancreas were able to increase the enzymatic defense in the spring. We can conclude that seasonal factors clearly influence the biological cycle of P. brasiliensis promatensis and demand adjustments in the oxidative balance, requiring a greater demand of enzymatic antioxidant defenses and of the metabolic system. / Os macroinvertebrados bent?nicos ocupam uma posi??o cr?tica na cadeia alimentar, uma vez que eles s?o respons?veis pela troca de energia entre os recursos basais e os n?veis tr?ficos superiores. Com o objetivo de analisar o comportamento fisiol?gico do lagostim Parastacus brasiliensis promatensis ao longo do ano, foram coletados 69 indiv?duos no m?s central de cada esta??o do ano. Os animais coletados foram medidos quanto ao comprimento de cefalot?rax, tendo como crit?rio o valor m?nimo 20 mm para captura, ap?s tiveram a hemolinfa retirada em meio contendo oxalato de pot?ssio 10% (anticoagulante) e deixadas em banho de gelo por 24 horas para utiliza??o apenas do plasma nas an?lises. Ap?s a captura os animais foram sacrificados por crioanestesia. No momento de cada coleta foi obtida uma amostra de ?gua do local de coleta, riacho Garapi? (S?o Francisco de Paula, RS), para an?lise dos par?metros f?sico-qu?micos. Em laborat?rio os indiv?duos foram pesados quanto ao peso total e peso tecidual para determina??o dos ?ndices de reple??o g?strica e hepatossom?tico (IH), em ambos os g?neros, e gonadossom?tico (IG) apenas nas f?meas; como tamb?m o grau de reple??o g?strico. Na hemolinfa quantificamos, por espectrofotometria, as prote?nas, o lactato, os lip?deos, os triglicer?deos, o glicerol, o colesterol VLDL e o HDL e a glicose. Analisamos ainda o comportamento de tr?s enzimas antioxidantes, sendo elas a super?xido dismutase (SOD), a catalase (CAT) e a glutationa S-tranferase (GST); bem como uma medida de dano celular (lipoperoxida??o, LPO), com o objetivo de descrever o status oxidativo desta subesp?cie em diferentes esta??es do ano. Estas an?lises foram realizadas, por m?todos espectrofotom?tricos, nas br?nquias, no hepatop?ncreas e no m?sculo abdominal para ambos os g?neros e, nas g?nadas das f?meas. Os dados foram analisados por ANOVA de uma via seguida de Bonferroni ou Kruska-Wallis seguido de Dunn, nos programas SPSS (vers?o 17.0) ou Bioestat, respectivamente. As analises estat?sticas indicam que houve diferen?a entre o IH E IG de f?meas ao longo do per?odo de estudo. Na primavera (pico reprodutivo) observamos um aumento do IG e uma redu??o do IH, sugerindo aloca??o das reservas energ?ticas do hepatop?ncreas para as g?nadas; hip?tese refor?ada pela an?lise do IH em machos, onde n?o houve diferen?a significativa. O ?ndice g?strico mostrou uma redu??o (p<0,05), em ambos os sexos, no inverno o que aliado a uma diminui??o da temperatura ambiental e manuten??o da glicemia sugerem uma diminui??o da taxa metab?lica e da explora??o do habitat, com poss?vel utiliza??o das reservas end?genas; aliados a uma diminui??o do glicerol e prote?nas na transi??o do outono para o inverno. Ambos os g?neros apresentaram diferen?as (p<0,5) para os n?veis de lactato, com os n?veis relacionando-se possivelmente com o baixo teor de oxig?nio dissolvido (3,31mg/l) encontrado na ?gua no ver?o, sendo estes considerados n?veis hip?xicos. Houve tamb?m um aumento significativo em toda a cadeia lip?dica em ambos os sexos; por?m, mais pronunciado nas f?meas, no per?odo que corresponde ao ?pice da reprodu??o, sendo a prov?vel causa o preparo reprodutivo diretamente e/ou o aumento de gasto energ?tico nesta situa??o. Quanto ao estresse oxidativo, os resultados sugerem que as f?meas apresentam um grande gasto energ?tico na prote??o do tecido gonadal, principalmente na primavera (?pice da reprodu??o), mantendo um alto grau de atividade da enzima GST, aliado ? menor medida de dano celular (LPO) quando comparado com os demais tecidos. J? para os machos o n?vel de lipoperoxida??o foi maior na primavera, em todos os tecidos. Contudo, o tecido branquial se mostrou incapaz de aumentar a atividade antioxidante, sendo apenas o m?sculo e o hepatop?ncreas capazes de incrementarem as defesas enzim?ticas na primavera. Podemos concluir que fatores sazonais influenciam claramente o ciclo bi?logico de P. brasiliensis promatensis e demandam ajustes no balan?o oxidativo, exigindo uma demanda maior das defesas antioxidantes enzim?ticas e do sistema metab?lico.

The issue of granite petrogenesis plays a key role in our overall understanding of the growth and differentiation of continents, as well as in our ability to unravel the tectonic histories of orogenic belts. Granites are ubiquitous magmatic products found in almost all tectonic settings: oceanic and continental rifts (i.e., plagiogranites - extreme basalt differentiates), active continental margins (e.g,. the granitic batholiths of central and southern Andes), continent-continent collision zones (e.g., the orogenic batholiths of the Himalayas, Western Anatolia), post-collisional settings (e.g., the Variscan provinces of Europe), complex within-plates settings (e.g., Limmo massif, Afar, Ethiopia). Furthermore, granitoids are characterized by considerable petrological and geochemical heterogeneity, as they can form from a vast array of sources: sediments (e.g., pelites, arkoses, psammites), metamorphic rocks (e.g., (mica)schists, gneisses, etc.), and igneous rocks (e.g. andesites, dacites, tonalites, etc.). Aside from fertile sources (i.e., protoliths), granite petrogenesis is dependent upon two critical parameters: temperature (to promote melting of the protoliths) and water availability - either as freely available aqueous solutions/vapors (e.g., water input in subduction zones); or water released via dehydration melting of hydrous minerals (e.g., micas, amphiboles). The presence of water in protoliths depresses the melting temperature of mineral components and provides the environment for redistribution of chemical components. Understanding the origins of granitic rocks presents unique challenges, given that in many of the tectonic settings where granites are encountered, it is clear that their modes of formation can involve a spectrum of igneous and metamorphic processes that are not readily accessible for examination, either through the study of modern environments or via analogy to "classical" localities. The petrogenesis and emplacement of granites in post-collisional tectonic settings is one of the thornier challenges, as these rocks appear to be derived via thermal and magmatic processes within highly deformed and compositionally diverse continental crust for which we lack a clear understanding. A number of unconventional and difficult-to-test mechanisms have been posited to drive crustal heating, melting, and subsequent pluton post-collisional emplacement. Although large volumes of granitic magmas have been emplaced in post-collisional settings, the complexities of the processes active in such settings make it challenging to put forward testable models that effectively combine available geochemical, petrologic, and geophysical data. Models for granite genesis away from plate margins (by means of crustal thickening, thermal blanketing, and internal heating from radioactive decay of 40K, 230Th, 235U, and 238U; delamination of the crustal lithosphere and juxtaposition of hot mantle melts at the base of the crust; underplating of mantle melts; or slab brake-off and upwelling of mantle melts) have been successfully applied in comparatively young orogenic regions, such as the Himalayas, the Carpathians, and Turkey. These models have proven challenging to employ in older orogenic belts, given their sometimes intricate tectonic and metamorphic histories, and the loss of pertinent evidence due to the effects of post-emplacement tectonic reworking, and often extensive alteration and erosion. A series of ancient but fresh, age-correlative granitic plutons are exposed in Alpine nappes on the flanks of the Carpathians Mountains in southwestern Romania. These granites, all mapped as intruding the Neoproterozoic basement of the Danubian tectonic terrane, were emplaced during the post-collisional stages of two world-scale orogenies: an older, Pan-African event (~600 Ma) and a younger, Variscan event (~330- 280 Ma). My dissertation is focused on the study of late Variscan post-collisional plutons and associated sub-volcanic dykes, as they are tremendous tools for understanding and quantifying the mantle-crust interaction in post-collisional environments and the overall evolution of the continental crust during the Variscan orogeny. Originally believed to be Proterozoic in age, zircon U/Pb dating showed that the plutons are much younger (Chapter 1 - Post-collisional Late Variscan magmatism in the Danubian domain (South Carpathians, Romania) documented by zircon U/Pb LA-ICP-MS) and correspond to the latest stages of the Variscan orogeny, as recorded elsewhere in the European Variscan provinces. The granitic plutons are relatively small and are generally concordant with the structures preserved by the country rocks. The extraordinary petrological and geochemical heterogeneities, even at pluton scale (Chapter 2 - Petrology and geochemistry of the Late Variscan post-collisional Furătura granitic pluton South. Carpathian Mts. (Romania)) argue against unique protoliths and simple evolutionary processes (e.g., closed-system fractional crystallization; anatexis). Trace elemental data for the Furătura pluton shows that the melts were formed in equilibrium with a garnet-amphibole restite, under pressure-temperature conditions deeper than the plagioclase stability field, implying that the melting took place at depths in excess of 40 km in the continental crust. Stable and radiogenic isotope data suggest that a protolith was of (possibly enriched) mantle affinities, and that the melts were subsequently contaminated in various degrees by deep crustal lithologies. In comparison, other post-collisional Variscan plutons from the Danubian domain (Chapter 4 - The role of the continental crust and lithospheric mantle in Variscan post-collisional magmatism - insights from Muntele Mic, Ogradena, Cherbelezu, Sfârdinu, and Culmea Cernei plutons (Romanian Southern Carpathians)) have trace elemental compositions that suggest they were formed at different levels in the crust, under P-T conditions corresponding to both garnet-amphibole and plagioclase stability fields. Some of the plutons lack mantle geochemical signatures and their isotopic compositions are indicative of substantial involvement of both lower- and upper-crustal rocks in their formation and subsequent evolution. On the other hand, plutons emplaced during the same time interval and most likely in close geographical proximity have trace elemental and isotopic compositions indicating strong input from previously enriched mantle components which experienced various degrees of assimilation fractionation-crystallization and/or assimilation of continental crust material during their evolution. This variability in both protoliths and processes responsible for the formation of the granites, coupled with the presence of mantle signatures in late-orogenic post-collisional melts are strong evidence to support delamination as means of providing both the mantle-derived input and energy required for generation of granitoids in the crust. The pronounced variation in petrological and chemical compositions of synchronous plutons suggests that delamination in the Danubian domain was not a single, large scale event that affected the entire crust, but rather a collection of disparate, spatially and chronologically limited event, that affected the Variscan crust during the latest stages of the orogeny. This hypothesis is further tested on a series of sub-volcanic dykes (the Motru Dyke Swarm) crosscutting the entire Danubian basement (Chapter 3 - Post-collisional magmatism associated with Variscan orogeny in the Danubian Domain (Romanian Southern Carpathians): the Motru Dyke Swarm). Initially, the emplacement age of these dykes was assumed as "pre-Silurian" but our mapping has showed that they intrude components of the Danubian domain that shared a documented common history not earlier than the Carboniferous. Furthermore, the dykes are in intrusive relationship with two of the Danubian Variscan plutons, thus arguing for an early Permian emplacement age. Geochemical data show extraordinary heterogeneities in the dykes' composition and record both mantle and crust involvement in their formation. The dykes were emplaced at much shallower depths in the crust, as compared with the granitic plutons. Still, their isotopic compositions clearly indicate that they sampled both lower- and upper-crustal compositions during their evolution. This means that after the crustal thickening episodes that define continent-continent collisions, during the latest stages of the Variscan orogeny, the crust became progressively thinner, as a way to compensate for its metastable state. Thinning of the crust is greatly favored by delamination of the lithosphere. A delamination event, which usually postdates the cessation of continental collision or prolonged crustal shortening, involves the geologically rapid foundering of negatively buoyant lithosphere comprised of mantle and (potentially) lower crust into underlying hotter and less dense asthenosphere. Such a process will remove the lithospheric mantle (and potentially segments of the lower crust) along pre-existing lineaments or mechanical flaws, and juxtapose hot upwelling asthenosphere against the base of the crust, leading to partial melting. Field, petrological, and geochemical data presented in my dissertation document pronounced variations in the overall composition of synchronous plutons and dykes, and further suggest that delamination in the Danubian domain was an active process. This bears great importance in our understanding of the evolution of the crust and argues that mantle-crust interactions are responsible for the generation of continental crust even in the latest stages of an orogen.

Surface and subsurface data from the Sulaiman thrust belt show that nearly all the 10 km thick sequence of dominantly platform (>7 km) and molasse strata is detached at the deformation front. These strata thicken tectonically to a minimum of 20 km in the hinterland of the Sulaiman fold belt without significant thrust faults at the surface. The balanced structural cross-:section suggests that the tectonic uplift in the Sulaiman fold belt is a result of thin-skinned, passive-roof duplex style of deformation. The duplex sequence of Jurassic and older rocks is separated from the roof sequence by a passive-back thrust in thick Cretaceous shales. The passive-roof sequence remains intact for about 150 km and becomes emergent along a passive-back thrust in the hinterland. The structures are expressed at the surface by fault-related folds in the foreland and out-of-sequence structures (secondary faults and related pop-ups) in the interior. The duplex structure varies from fault-bend folds to anticlinal stacks, and hinterland dipping duplexes. Progressive deformation reveals a series of structural and geometrical features including: (1) broad concentric folding at the fault tip; (2) development of a passive-roof and duplex sequence; (2) forward propagation of the duplex as critical taper is achieved; (4) tear faults and extensional normal faults within the overthrust wedge; and (5) out of sequence (secondary) thrusting. The 349 km long balanced cross-section from the Sulaiman fold belt restores to an original length of 727 km that provides 378 km of shortening in the cover strata of the Indian subcontinent. Minimum estimate of shortening is 328 km. Modelling of the Bouguer gravity profile from the Sulaiman foredeep across the Indian/ Afghan collision zone suggests the depth to the Moho at the Sulaiman deformation front is about 36 km. Depth to Moho increases northward with a gentle gradient of 1.1° (20 m/km) for 280 km to the hinterland where the depth to the Moho is about 42 km. About 150 km north across the Khojak flysch the Moho gradient steepens abruptly to about 7.8° (136 m/km) to attain an average depth of about 57 km in eastern Afghanistan. This suggests that the Sulaiman fold belt is underlain by transitional crust associated with the western passive margin of the Indian subcontinent. / Graduation date: 1992

At collisional mountain ranges the tectonic history of crustal shortening and subsequent post-collisional erosion is preserved in the form of the presently observed gravity anomalies. In this study, models of erosion and isostatic rebound at various stages of collision illustrate the evolution of crustal structure, topography, and resulting gravity anomalies. The Ouachita Mountains of Arkansas, which show a low/high Bouguer gravity couple characteristic of the initial stages of collision, have undergone just 8 km of erosion during the process of completely rebounding the syn-orogenic crustal root. This minor rebound means that the Ouachitas retain a crustal geometry similar to the continental margin prior to collision, including thin transitional and oceanic crust. At more advances stages of collision Bouguer gravity anomalies show a broad low reflecting a thickened crustal root. The width of this low, which relates directly to the amount of crustal shortening, is retained during subsequent erosion and elastic rebound, but the amplitude decays gradually. Thus, the width and amplitude of the low can be used to estimate the degree of convergence and amount of erosion, respectively, for a specific mountain range. For the Scandinavian Caledonides results are consistent with 20 km of erosion following 200 km of crustal shortening. Following a larger magnitude of convergence, about 300 km, the southern Appalachians are estimated to have undergone 28 km of post-collisional erosion. Bouguer gravity profiles across the recently-active Alps compare with a model of 200 km of crustal shortening and 8 to 12 km of erosion. While the Alps have undergone a similar amount of shortening as that estimated for the Caledonides, erosion and post-collisional rebound is at an initial stage, such that a thick section of exotic crust still overlies the underthrusted European Platform. The results of these model comparisons suggest that the crustal geometry ofa collisional mountain range should be viewed as a consequence of the degree of crustal shortening as well as the amount of erosion and isostatic rebound. In models at moderate to advanced stages of shortening ( 200 km), and mature stages of erosion (e.g., Caledonides, Appalachians), the geometry of the crustal "suture" between overthrusting and underthrusting crusts is present as a shallow, subhorizontal de collement beneath the foreland. In the hinterland the suture abruptly steepens, a result of differential uplift during isostatic rebound. This crustal geometry, characteristic of seismic-reflection profiles across many ancient mountain belts, suggests: (1) that the "low angle detachment" observed beneath collisional mountain ranges was originally much deeper and steeper than it is at present; and (2) that steep-dipping seismic reflectors towards the hinterland represent the thrusted contact between converging crustal blocks, but have been steepened as a result of isostatic uplift following erosion. / Graduation date: 1992