Die Hochmoore des Erzgebirges sind auf Grund ihrer jahrhunderte langen Nutzung und der ökosystemaren Wandelprozesse der vergangenen 10 - 15 Jahre unterschiedlich stark degradiert. Gleichzeitig sind sie durch den Austrag vergleichsweise hoher Austräge von DOC (Dissoloved Organic Carbon) gekennzeichnet. Um den Zusammenhang zwischen dem Zustand der Hochmoore, als Ergebnis in erster Linie der unterschiedlich nutzungsbedingten Degradation und den Stoffausträgen speziell den DOC-Austrägen zu erfassen, wurden mittels landschaftsökologischer Methoden Hochmoortestflächen verschiedener Zustände vergleichend untersucht. Die Ergebnisse lieferten erste Hinweise, dass in Flächen mit natürlicher Regeneration oder anthropogener Wiedervernässung vergleichsweise hohe DOC-Konzentrationen und – Austräge zu beobachten waren. Demgegenüber standen stärker degradierte Flächen mit zum Teil aktueller forstlicher Nutzung (geräumte Entwässerungsgräben), die durch geringere DOC-Konzentrationen und – Austräge charakterisiert waren. Da die gefundenen Zusammenhänge nicht endgültig belegt werden konnten, besteht insbesondere Forschungsbedarf hinsichtlich landschaftshaushaltlicher Untersuchungen unterschiedlich degradierter Hochmoore im Erzgebirge. / Natural peat bogs are known as a sinks especially for carbon because of theire special matter and water balance. The use of peat bogs requiers their drainage, but consequently the peat will decompose unreversible and peatlands turn to a source esspecially for carbon. The peat bogs in the “Erzgebirge Mountains” were used over several centuries. Thats why the peatlands existing nowadays have different states dependent on the duratian of their use. Beside the use peatlands were mostly negativly effected by processes of ecological change in the “Erzgebirge Maountains” in the last 10 to 15 years. As one result of ecological change the increased output of DOC (Dissolved Organic Carbon) into surface waters can be seen. The main source for DOC are peatlands. By the way it seems to exist a connection between the output of DOC and other dissolved substances and the state of the peatlands especially of their ditches. To research this hypothesis four test areas of different state were chosen. Their state and the output of DOC and other dissolved substances were investigated with methods from landscape ecology from 2001-2003. It was the first time, that peatlands in the “Erzgebirge Mountains” were investigated in such a way. The badest state had the test area where the ditches were cleaned in 2000/ 2001 (“Weiße Mulde”, Western “Erzgebirge Mountains”). This test area showed the lowest but constant DOC-concentrations and DOC-output during the investigation period. The test areas “Carlsfeld” and “Löffelsbach” (Western “Erzgebirge Mountains”) had the best state. The state of “Carlsfeld” is related to the narueal closed ditches, which cause the processes of self regeneration. Due to such processes the DOCconcentrations were distinctly higher but very variable in dependence on weather and runoff. The same was supposed to DOC-output. The same valuation got the test area “Löffelsbach”, because of rewetting by technical closed ditches in 2001. During the investigation period the highest DOC-concentrations of all test areas were measured there. Similar to “Carlsfeld” DOC-concentrations and –output were highly variable in dependence on weather and runoff. The state of the test area “Salzflüßchen” (Eastern “Erzgebirge Mountains”) is also related to processes of self regeneration but was valuated bader than “Carlsfeld”, because the effect of former drainage was stronger in this area. In 2005 the rewetting of the test area is planed by “Naturpark Erzgebirge/ Vogtland”. In the consequence the DOC-concentrations and –output will increase similar to “Löffelsbach”. The results of the investigations indicate that a connection exists between state of peatlands and output of dissolved substances esspecially DOC. The results are supported by national and international literature. It will be clear, that more research is necessary especially on the field of comparative investigations of peatlands with different states in the “Erzgebirge Mountains”.

Soil that is heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) is often found at the sites of former gasworks and wood-impregnation plants. Since PAHs are toxic these sites represent a hazard to human health and the environment, and therefore they need to be treated, preferably by a method that destroys the contaminants, and thus eliminates the problem permanently. However, during biological and chemical degradation of PAHs other toxic compounds may be formed. If these transformation products are sufficiently persistent they could potentially accumulate during remedial processes. In the work underlying this thesis the degradation and transformation of PAHs were studied in three remedial processes: viz. a pilot-scale bioslurry reactor, microcosms with wood-rotting fungi and lab-scale treatments with Fenton's reagent. A group of transformation products referred to as oxygenated-PAHs (oxy-PAHs) was found to be particularly important, as these compounds are toxic and were shown to be relatively persistent in the environment. The oxy- PAHs were, for instance, found at significant concentrations in the gasworks soil used in most of the studies. This soil was highly weathered and had therefore been depleted of the more readily degradable compounds. In addition, experiments in which earthworms were exposed to the gasworks soil showed that the oxy-PAHs were more easily taken up in living organisms than PAHs. To facilitate the studies, new extraction and fractionation methods were developed. For instance, pressurized liquid extraction (PLE) was investigated for its reliability and efficiency to extract PAHs and oxy-PAHs from soil. Furthermore, a selective PLE-method was developed that can simultaneously extract and separate the PAHs and oxy-PAHs into two different fractions. This was accomplished by adding a chromatographic material (silica or Florisil) to the extraction cell. Under certain conditions all three remedial processes resulted in increasing amounts of oxy- PAHs in the soil. For example, 1-acenaphthenone and 4-oxapyrene-5-one accumulated in the bioslurry reactor. Similarly, in the soil inoculated with a white-rot fungus 9-fluorenone, benzo[a]anthracene-7,12-dione, 4-hydroxy-9-fluorenone and 4-oxapyrene-5-one accumulated. Finally, in an ethanol-Fenton treatment the concentration of some PAH-quinones increased in the soil. The results show that it might be necessary to monitor oxy-PAHs as well as PAHs during the remediation of PAH-contaminated sites. Otherwise, the soil may be considered detoxified too early in the process. In the long term it would be desirable to include analyses with sufficient marker compounds to follow the possible production and elimination of the oxy-PAHs. However, until such compounds can be identified it is suggested that contaminated soil should be screened for oxy-PAHs in general. The selective PLE-method presented in this thesis could be a useful tool for this.