It is essential to properly monitor in-situ soil compaction properties during most earthwork construction projects. Traditional in-situ soil compaction monitoring methods are often limited in their application. As a result, new methods are being developed to more accurately measure in-situ compaction parameters. Time domain reflectometry (TDR) is one such method. Relying on the propagation of an electromagnetic wave through the soil sample, TDR can be used to measure both in-situ moisture content as well as soil dry density. Although TDR is relatively new to the field of geotechnical engineering, it has previously been implemented in other fields with success. Researchers at Purdue University have made several advances to further incorporate the use of TDR technology into the field of geotechnical engineering and as a result an innovative TDR measurement system has been developed for compaction control monitoring. The method was standardized in the form of ASTM D 6780 in 2002. Further advancements led to an improved method referred to as the Purdue one-step TDR method. Research has indicated that the ASTM TDR method is sufficiently accurate for application in compaction monitoring applications. A comparison between the ASTM TDR method and traditional methods was carried out to evaluate the accuracy of the TDR method to traditional methods. To further expand the application of the TDR method, a correlation was developed between the TDR spike driving process with the in-situ CBR test. A comprehensive review of previous research was conducted to examine recent advancements leading to the improved Purdue one-step method. A study was also performed to evaluate the effect of variable pore fluid conductivity on the calibration of the Purdue one-step method.

The benefits of intentional friction damping to reduce the occurrence of wear and premature failure of turbomachinery bladed-disk assemblies are well known and many studies on this topic have focused on the analysis and prediction of the complicated nonlinear forced response exhibited by these structures. In this research, extensions of the recently introduced multi-harmonic Hybrid Frequency-Time method are proposed for the efficient analysis of the response of realistic structures featuring displacement-dependent nonlinearities, such as the friction and impact phenomena that may occur in the presence of friction dampers or when two parts of the same structure periodically contact each other. These theoretical extensions are adapted to the study of large scale, industrial bladed-disk structures that may feature cyclic symmetry or mistuning. Two analysis techniques are developed for the modeling of displacement-dependent nonlinearities. In the first technique friction dampers are modeled as nonlinear operators representing the contact forces acting on the blades, from the simple case of monodirectional friction with constant normal load to the more complex case of three dimensional contact with variable normal load. The analysis of the forced response of several nonlinear systems illustrates the capabilities of this approach as well as the complexity of the typical behavior exhibited by friction damped structures. The second technique introduced helps analyze structures experiencing intermittent contact or friction between two parts or sub-components of the same assembly. This method is applied to the study of the forced response of several simple systems and is used with great efficiency to predict the nonlinear behavior of a beam with a crack. This approach also allows the dampers to be modeled realistically as stand-alone components appended to the bladed disk assembly. In this case the bladed disk assembly as well as the friction dampers are modeled as independent structures that interact at their contacting interfaces. This allows the use of detailed finite element models of dampers rather than having to make simplifying assumptions regarding their geometry. These two methods are applied to the study of the nonlinear forced response a realistic bladed-disk assembly featuring a wedge damper model and a structure-like damper model.

<p>Metal forming is widely used in the industry to produce cans, tubes, car chassis, rods, wires etc. Forming certain materials such as stainless steel, aluminium and titanium, is often difficult, and problems associated with transfer of work material to the tool material are frequent. Transferred material may scratch and deform the following manufactured pieces, a phenomenon named galling. Lubricants can, to some degree, solve these problems. However, many forming oils are hazardous to the environment, and therefore it is highly desirable to replace them or get rid of them.</p><p>This thesis investigates the nature of the galling phenomenon and tries to explain under which conditions such problems arise. Dry sliding tests have been performed in a dedicated load-scanner equipment. Difficult work materials have been tested against tool materials under various conditions and the samples have then been studied by advanced analytical techniques, such as ESCA and TEM, to study the detailed tribological mechanisms occurring in the contact between work and tool material.</p><p>The general assumption is that material transfer only occurs when there is metal to metal contact. In this work it has been found that, for stainless steel, the oxide plays a very important role for the sticky behaviour of stainless steel, and that metal to metal contact is not a necessary condition for galling.</p><p>Several PVD-coated tool materials have been tested and it was found that vanadium nitride coatings can be tuned regarding their chemical composition, to be more galling resistant than conventional coatings.</p><p>The surface roughness of the tool material is very strongly coupled to the tools ability to resist galling. The smoother the tool surface, the less risk of material transfer and galling.</p><p>Some work materials, like aluminium and titanium, transfer to even the smoothest tool materials. A proposed explanation for this is that their oxides are much harder than the bulk material and the tool material matrix. When deforming the work material, the oxide will fracture into small hard scales, which can indent the tool material. Indented hard scales will then contribute to material transfer of more work material to the tool.</p>

Quality protein maize (QPM), high protein corn (HPC) and food grade maize (FGM) were processed into tortillas and direct expanded extruded snacks. QPM had similar test weight, density and kernel size with 45% more lysine and 38% more tryptophan compared to FGM. HPC had the largest kernel with density and test weight similar to FGM. During alkaline cooking, HPC absorbed water faster than QPM and FGM. White QPM required shorter cooking time and had less dry matter losses compared to FGM. All corn varieties had excellent pericarp removal at the optimum cooking time. Tortillas from QPM had better pliability and rollability after storage compared to FGM and HPC. HPC tortillas had lower rupture force after storage. The use of QPM for tortilla production may reduce energy and sewage cost, and could produce a tortilla with longer shelf stability with improved nutritional value. Decorticated and non-decorticated QPM, FGM and HPC grain were processed into corn meal and direct expanded snacks. A modified short scale dry milling system was used to produce the corn meal. QPM produced more coarse meal with greater fat content compared to FGM. Decortication decreased fiber content and coarse meal yield. Non-decorticated meal had greater protein, fiber and fat content compared to decorticated meal. The modified short flow milling system provides reduced lost fractions for extrusion into nutritionally improved products. Extrusion was performed in a low cost friction extruder. QPM extruded faster than FGM and HPC. FGM required greater specific mechanical energy than QPM. Extrudates from FGM were the most expanded followed by QPM and HPC. Extrudates from the three corn varieties were acceptable to the panelists and decortication did not affect acceptability. The improved nutritional value of QPM, was retained during dry milling and extrusion. Current QPM varieties can be processed into tortillas with longer shelf stability and meal for extrusion into a wide variety of snacks and other foods. These may have application in specialty health foods and in developing countries where maize is a staple food.

Along this dissertation I propose to walk the reader through several macroeconomic implications of information asymmetries, with a special focus on financial issues. This exercise is mainly theoretical: I develop stylized models that aim at capturing macroeconomic phenomena such as self-fulfilling liquidity dry-ups, the rise and the fall of securitization markets, and the creation of systemic risk. The dissertation consists of three chapters. The first one proposes an explanation to self-fulfilling liquidity dry-ups. The second chapters proposes a formalization of the concept of market discipline and an application to securitization markets as risk-sharing mechanisms. The third one offers a complementary analysis to the second as the rise of securitization is presented as banker optimal response to strict capital constraints. Two concepts that do not have unique acceptations in economics play a central role in these models: liquidity and market discipline. The liquidity of an asset refers to the ability for his owner to transform it into current consumption goods. Secondary markets for long-term assets play thus an important role with that respect. However, such markets might be illiquid due to adverse selection. In the first chapter, I show that: (1) when agents expect a liquidity dry-up on such markets, they optimally choose to self-insure through the hoarding of non-productive but liquid assets; (2) this hoarding behavior worsens adverse selection and dries up market liquidity; (3) such liquidity dry-ups are Pareto inefficient equilibria; (4) the government can rule them out. Additionally, I show that idiosyncratic liquidity shocks à la Diamond and Dybvig have stabilizing effects, which is at odds with the banking literature. The main contribution of the chapter is to show that market breakdowns due to adverse selection are highly endogenous to past balance-sheet decisions. I consider that agents are under market discipline when their current behavior is influenced by future market outcomes. A key ingredient for market discipline to be at play is that the market outcome depends on information that is observable but not verifiable (that is, information that cannot be proved in court, and consequently, upon which enforceable contracts cannot be based). In the second chapter, after introducing this novel formalization of market discipline, I ask whether securitization really contributes to better risk-sharing: I compare it with other mechanisms that differ on the timing of risk-transfer. I find that for securitization to be an efficient risk-sharing mechanism, it requires market discipline to be strong and adverse selection not to be severe. This seems to seriously restrict the set of assets that should be securitized for risk-sharing motive. Additionally, I show how ex-ante leverage may mitigate interim adverse selection in securitization markets and therefore enhance ex-post risk-sharing. This is interesting because high leverage is usually associated with “excessive” risktaking. In the third chapter, I consider risk-neutral bankers facing strict capital constraints; their capital is indeed required to cover the worst-case-scenario losses. In such a set-up, I find that: 1) banker optimal autarky response is to diversify lower-tail risk and maximize leverage; 2) securitization helps to free up capital and to increase leverage, but distorts incentives to screen loan applicants properly; 3) market discipline mitigates this problem, but if it is overestimated by the supervisor, it leads to excess leverage, which creates systemic risk. Finally, I consider opaque securitization and I show that the supervisor: 4) faces uncertainty about the trade-off between the size of the economy and the probability and the severity of a systemic crisis; 5) can generally not set capital constraints at the socially efficient level.

Study of liquid film dynamics is of significant importance to the understanding and control of various industrial processes that involve spray cooling (condensation), heating (boiling), coating, cleaning and lubrication. For instance, the critical heat flux (CHF) of boiling heat transfer is one of the key parameters ensuring the efficiency and safety of nuclear power plants under both operational and accident conditions, which occurs as the liquid layers (microlayer and macrolayer) near the heater wall lose their integrity. However, an experimental quantification of thin liquid film dynamics is not straightforward, since the measurement at micro-scale is a challenge, and further complicated by the chaotic nature of boiling process. The object of present study is to develop experimental methods for the diagnosis of liquid film dynamics, and to obtain data for the film instability under various conditions. A dedicated test facility was designed and constructed where micro conductive probes and confocal optical sensors were used to measure the thickness and dynamic characteristics of a thin liquid film on various heater surfaces, while a high speed camera was used to get visual observation. Extensive tests were performed to calibrate and verify the two thickness measuring systems. The micro conductive measuring system was proven to have a high reliability and repeatability with maximum system error less than 5µm, while the optical measuring system is capable of recording the film dynamics with spatial resolution of less than 1 mm. The simultaneous measurement on the same liquid film shows that the two techniques are in a good agreement with respect to accuracy, but the optical sensors have a much higher acquisition rate up to 30 kHz, which are more suitable for rapid process. The confocal optical sensors were therefore employed to measure the dynamic thickness of liquid films (ethanol, hexane and water) evaporating on various horizontal heater surfaces (aluminum, copper, silicon, stainless steel and titanium) to investigate the influences of heat flux, the surface and liquid properties on the film instability and the critical thickness. The critical thickness of water film evaporating on various surfaces was measured in the range of 60-150 mm, increasing with the increased contact angle or increased heat flux (evaporating rate) and also with the decreased thermal conductivity of the heater material. The data suggest the conjugate heat transfer nature of the evaporating liquid film dynamics at higher heat fluxes of interest to boiling and burnout. In the case of hexane on the aged titanium surface with contact angle of ~3o, the liquid film is found resilient to rupture, with film oscillations at relatively large amplitude ensuing as the averaged film thickness decreases below 15 µm. To interpret our experimental findings on liquid film evolution and its critical thickness at rupture, a theoretical analysis is also performed to analyze the dynamics of liquid films evaporating on heater surfaces. While the influences of liquid properties, heat flux, and thermal conductivity of heater surface are captured by the simulation of the lubrication theory, influence of the wettability is considered via a minimum free energy criterion. The thinning processes of the liquid films are generally captured by the simulation of the lubrication theory. For the case with ideally uniform heat flux over the heater surface, the instability of the liquid film occurs at the thickness level of tens micro meters, while for the case of non-uniform heating, the critical thicknesses for the film rupture are closer to  the experimental data but still underestimated by the lubrication theory simulation. By introducing the minimum free energy criterion to considering the influence of surface wettability, the obtained critical thicknesses have a good agreement with the experimental ones for both titanium and copper surfaces, with a maximum deviation less than ±10%. The simulations also explain why the critical thickness on a copper surface is thinner than that on a titanium surface. It is because the good thermal conductivity of copper surface leads to uniform temperature distribution on the heat surface, which is responsible for the resilience of the liquid film to rupture. A silicon wafer with an artificial cavity fabricated by Micro Electronic Mechanical System (MEMS) technology was used as a heater to investigate the dynamics of a single bubble in both a thick and thin liquid layer under low heat flux (&lt;60 kW/m2). The maximum departure diameter of an isolated bubble in a thick liquid film was measured to be 3.2 mm which is well predicted by the Fritz equation. However, in a thin liquid layer with its thickness less than the bubble departure diameter, the bubble was stuck on the heater surface with a dry spot beneath. A threshold thickness of the liquid film which enables the dry spot rewettable was obtained, and its value linearly increases with increasing heat flux. In addition, another test section was designed to achieve a constant liquid film flow on a titanium nano-heater surface which helps to successfully carry boiling in the liquid film from low heat flux until CHF. Again, the confocal optical sensor was employed to measure the dynamics of the liquid film on the heater surface under varied heat flux conditions.  A statistical analysis of the measured thickness signals that emerge in a certain period indicates three distinct liquid film thickness ranges: 0~50 µm as microlayer, 50~500 µm as macrolayer, 500~2500 µm as bulk layer. With increasing heat flux, the bulk layer disappears, and then the macrolayer gradually decreases to ~105 µm, beyond which instability of the liquid film may lose its integrity and CHF occurs. In addition, the high-speed camera was applied to directly visualize and record the bubbles dynamics and liquid film evolution. Dry spots were observed under some bubbles occasionally from 313 kW/m2 until CHF with the maximum occupation fraction within 5%.  A dry spot was rewetted either by liquid receding after the rupture of a bubble or by the liquid spreading from bubbles’ growth in the vicinity. This implies that the bubbles’ behavior (growth and rupture) and their interactions in particular are of paramount importance to the integrity of liquid film under nucleate boiling regime. / QC 20111205 / VR-2005-5729, MSWI

<p><font face="Tahoma"> <p align="left">The purpose of this study is to evaluate the need for prophylactic antibiotic treatment in third molar surgery and to establish specific guidelines for antibiotic prophylaxis in the department of Maxillo-Facial and Oral Surgery (MFOS) at Tygerberg Academic, Groote Schuur and Mitchells Plain Hospitals.</p> </font></p>

Metal forming is widely used in the industry to produce cans, tubes, car chassis, rods, wires etc. Forming certain materials such as stainless steel, aluminium and titanium, is often difficult, and problems associated with transfer of work material to the tool material are frequent. Transferred material may scratch and deform the following manufactured pieces, a phenomenon named galling. Lubricants can, to some degree, solve these problems. However, many forming oils are hazardous to the environment, and therefore it is highly desirable to replace them or get rid of them. This thesis investigates the nature of the galling phenomenon and tries to explain under which conditions such problems arise. Dry sliding tests have been performed in a dedicated load-scanner equipment. Difficult work materials have been tested against tool materials under various conditions and the samples have then been studied by advanced analytical techniques, such as ESCA and TEM, to study the detailed tribological mechanisms occurring in the contact between work and tool material. The general assumption is that material transfer only occurs when there is metal to metal contact. In this work it has been found that, for stainless steel, the oxide plays a very important role for the sticky behaviour of stainless steel, and that metal to metal contact is not a necessary condition for galling. Several PVD-coated tool materials have been tested and it was found that vanadium nitride coatings can be tuned regarding their chemical composition, to be more galling resistant than conventional coatings. The surface roughness of the tool material is very strongly coupled to the tools ability to resist galling. The smoother the tool surface, the less risk of material transfer and galling. Some work materials, like aluminium and titanium, transfer to even the smoothest tool materials. A proposed explanation for this is that their oxides are much harder than the bulk material and the tool material matrix. When deforming the work material, the oxide will fracture into small hard scales, which can indent the tool material. Indented hard scales will then contribute to material transfer of more work material to the tool.

More often consumers demand instant dry soup that can be prepared with a water temperature below 100o C, which is currently not possible, because the dry soup becomes too thin when using water with a lower temperature. In this study, various kinds of starch studies were made to optimize the starch used in the existing product to make it more viscous at both high and low temperatures. The result was that one of the two starches present in the existing product was retained by change in quantity as it contributed to important flavor parameters. The second was removed and replaced with a starch that made the product more viscous at lower temperatures. To find out if the new product differed from the existing product a viscosity measurement and a sensory paired preference test were made. The viscosity measurement contributed objective data that clarified whether differences existed or not. The sensory paired preference test provided insight into which of the two product variants the consumers preferred. The new starch contributes to higher viscosity at temperatures below 100 ° C and is significantly different from the existing product and is preferred by consumers when prepared at lower temperatures. The exclusion of one of the existing starches resulted in lack of mouth feel at 100oC which consumers perceive as negative. In order for this result to be possible to use to optimize the existing product it requires further product development for the company to gain customer satisfaction. / Fler och fler konsumenter efterfrågar Varma Koppen som kan tillagas med vatten vid lägre temperaturer än kokande vatten, vilket i nuläget inte är möjligt då pulversoppan blir för tunn vid tillsats av kallare vatten. I denna studie har olika sorters stärkelse arbetats med för att optimera det stärkelseinnehåll som finns i den befintliga produkten för att göra den viskös vid både höga och låga temperaturer. Resultatet blev att en av de två stärkelser som förekom i den befintliga produkten behölls men förändrades i mängd då den bidrog till viktiga smakparametrar. Den andra plockades bort och ersattes med en stärkelse som gjorde produkten mer viskös vid lägre temperaturer. För att ta reda på om den nya produkten skiljde sig ifrån den befintliga utfördes en viskositetsmätning och ett sensoriskt parvist preferenstest. Viskositetsmätningen bidrog med objektiv data som klargjorde ifall skillnader fanns eller inte. Det sensoriskt parvisa preferenstestet gav en inblick i vilken av de två produktvarianterna som konsumenterna föredrog. Den nya stärkelsen bidrar till högre viskositet vid temperaturer under 100oC och skiljer sig signifikant från den befintliga produkten och föredras av konsumenterna vid lägre temperaturer. Uteslutandet av en av de befintliga stärkelserna har dock bidragit till en försämrad munkänsla vid 100o C som konsumenterna ser som negativ. För att detta resultat ska kunna användas för att ge en optimerad pulversoppa krävs därför vidare produktutveckling på företaget.

A MEMS-based micro-electro-discharge machining technique that is enabled by the actuation of micromachined planar electrodes defined on the surfaces of the workpiece is developed that eliminates the need of numerical control machines. First, the planar electrodes actuated by hydrodynamic force is developed. The electrode structures are defined by patterning l8-µm-thick copper foil laminated on the stainless steel workpiece through an intermediate photoresist layer and released by sacrificial etching of the resist layer. The planer electrodes are constructed to be single layer structures without particular features underneath. All the patterning and sacrificial etching steps are performed using dry-film photoresists towards achieving high scalability of the machining technique to large-area applications. A DC voltage of 80-140 V is applied between the electrode and the workpiece through a resistance-capacitance circuit that controls the pulse energy and timing of spark discharges. The parasitic capacitance of the electrode structure is used to form a resistance capacitance circuit for the generation of pulsed spark discharge between the electrode and the workpiece. The suspended electrodes are actuated towards the workpiece using the downflow of dielectric machining fluid, initiating and sustaining the machining process. Micromachining of stainless steel is experimentally demonstrated with the machining voltage of 90V and continuous flow of the fluid at the velocity of 3.4-3.9 m/s, providing removal depth of 20 µm. The experimental results of the electrode actuation match well with the theoretical estimations. Second, the planar electrodes are electrostatically actuated towards workpiece for machining. In addition to the single-layer, this effort uses double-layer structures defined on the bottom surface of the electrode to create custom designed patterns on the workpiece material. The suspended electrode is electrostatically actuated towards the wafer based on the pull-in, resulting in a breakdown, or spark discharge. This instantly lowers the gap voltage, releasing the electrode, and the gap value recovers as the capacitor is charged up through the resistor. Sequential pulses are produced through the self-regulated discharging-charging cycle. Micromachining of the stainless-steel wafer is demonstrated using the electrodes with single-layer and double-layer structures. The experimental results of the dynamic built-capacitance and mechanical behavior of the electrode devices are also analyzed.