Two metakaolins were evaluated for use as supplementary cementitious materials in cement-based systems. The metakaolins varied in their surface area (11.1 v. 25.4 m2/g), but were quite similar in mineralogical composition. Performance of metakaolin mixtures was compared to control mixtures and to mixtures incorporating silica fume as partial replacement for cement at water-to-cementitious materials ratios of 0.40, 0.50, and 0.60. In this study, the early age properties of fresh concrete and the mechanical and durability properties of hardened concrete were examined. Early age evaluations aimed to determine the reactivity of metakaolin (heat of hydration) and its effect on mixture workability (slump, setting time, unit weight). In addition, three types of shrinkage were monitored in metakaolin-cement systems: chemical, autogenous, and free. Compressive, tensile, and flexural strength and elastic modulus were measured at various concrete ages. The influence of metakaolin addition on durability was assessed through accelerated testing for sulfate resistance, expansion due to alkali-silica reaction, and through rapid chloride permeability measurements. To further quantify the underlying mechanisms of metakaolin's action, the microstructure of pastes was examined. Calcium hydroxide (CH) content was determined using thermogravimetric analysis and verified using differential thermal analysis. Surface area and pore size distribution were evaluated via nitrogen adsorption. These analyses yielded information about the pozzolanic reactivity of metakaolin, associated CH consumption and pore structure refinement, and resulting improvements in mechanical performance and durability of metakaolin-concretes.

Although Glass Fiber Reinforced Polymer (GFRP) has many potential advantages as reinforcement in concrete structures, the loss in tensile strength of the GFRP reinforcing bar can be significant when exposed to the high alkali environments. Much effort was made to estimate the durability performance of GFRP in concrete; however, it is widely believed the data from accelerated aging tests is not appropriate to predict the longer-term performance of GFRP reinforcing bars. The lack of validated long-term data is the major obstacle for broad application of GFRP reinforcement in civil engineering practices. The main purpose of this study is to evaluate the longer-term deterioration rate of GFRP bars embedded in concrete, and to develop an accurate model that can provide better information to predict the longer-term performance of GFRP bars. In previous studies performed by Trejo, three GFRP bar types (V1, V2, and P type) with two different diameters (16 and 19 mm [0.625, and 0.7 in. referred as #5 and #6, respectively]) provided by different manufacturers were embedded in concrete beams. After pre-cracking by bending tests, specimens were stored outdoors at the Riverside Campus of Texas A&M University in College Station, Texas. After 7 years of outdoor exposure, the GFRP bars were extracted from the concrete beams and tension tests were performed to estimate the residual tensile strength. Several physical tests were also performed to assess the potential changes in the material. It was found that the tensile capacity of the GFRP bars embedded in concrete decreased; however, no significant changes in modulus of elasticity (MOE) were observed. Using this data and limited data from the literature, a probabilistic capacity model was developed using Bayesian updating. The developed probabilistic capacity model appropriately accounts for statistical uncertainties, considering the influence of the missing variables and remaining error due to the inexact model form. In this study, the reduction in tensile strength of GFRP reinforcement embedded in concrete is a function of the diffusion rate of the resin matrix, bar diameter, and time. The probabilistic model predicts that smaller GFRP bars exhibit faster degradation in the tensile capacity than the larger GFRP bars. For the GFRP bars, the model indicates that the probability that the environmental reduction factor required by The American Concrete Institute (ACI) and the American Association of State Highway Transportation Officials (AASHTO) for the design of concrete structures containing GFRP reinforcement is below the required value is 0.4, 0.25, and 0.2 after 100 years for #3, #5, and #6, respectively. The ACI 440 and AASHTO design strength for smaller bars is likely not safe.

Black Sea coast line is a hazardous region especially in winter due to the dominant wave action. Therefore, rubble mound breakwaters used as ship shelters are vital structures especially for the fishermen. Construction of the breakwater requires good quality durable armourstones. Due to the nature of the rubble mound breakwaters, armourstones having various sizes and types are used in the construction of these structures. The deterioration of these armourstones with time in the form of abrasion and disintegration may result in the failure of the breakwater. Therefore, it is important to investigate the durability and quality of the armourstones to be used in these structures. In this thesis, the properties of the armourstones taken from five rock quarries and used in the Hisar&ouml / n&uuml / (Bartin), the Tarlaagzi (Bartin) and the Alapli (Zonguldak) rubble mound breakwaters were studied both in field and laboratory in order to assess their qualities and long term durabilities. Based on the in-situ observations and laboratory tests, the Kavakdere, Kavukkavlagi and the Tarlaagzi limestones are good (durable) rocks. However, the &Ccedil / &ouml / mlek&ccedil / ikuyu andesite is found to be generally marginal rock, and the Kiran sandstone is poor rock. CIRIA/CUR, RDId, RERS and Wet-Dry strength ratio classifications are in good agreement with the in-situ observations and the results of the laboratory tests. However RDIs, Average Pore Diameter and Saturation Coefficient classifications do not fully reflect the reality.

Fuel cells are the tools which convert chemical energy into electricity directly by the effective utilization of hydrogen and oxygen (or air). One of the most important barriers for the fuel cell commercialization is the durability of the fuel cell components in the long term operations. In this study, the durability of the PEM fuel cell electrocatalysts were investigated via cyclic voltammetry (CV) and rotating disk electrode (RDE) experiments in order to determine the hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) which corresponds to the half cell reactions in the fuel cell. PEM fuel cell electrodes mainly composed of carbon supported Pt catalysts. In long term operations due to Pt dissolution and carbon corrosion some properties of the electrocatalysts can be changed. Performance losses in catalysts mainly depend on / i) decrease in the total metal surface area (SA) and the electrochemically active surface area (ESA) due to the increase in the particle size ii) decrease in the tafel slope potential in ORR and iii) increase in carbon corrosion. In this study, these properties were examined via accelerated degradation tests performed in CV and RDE. The catalysts having different Pt loadings, synthesized with different ink compositions, pH values and microwave durations were investigated. The commercial catalysts having Pt loadings of 20, 50 and 70 (wt %) were tried and best results were obtained for Pt/V (50 wt %) catalyst. Different carbon to Nafion&reg / ratios of 4, 8, 12 in the ink composition were tried. C/N ratio of 8 gave the best result in Pt dissolution and carbon corrosion degradation tests. The catalysts prepared at different pH values of 1.4, 6.25 and 10 were tried and the catalyst prepared at pH of 10 was less degraded in Pt dissolution test and the catalyst prepared at pH of 6.25 showed better resistance to carbon corrosion. Catalysts prepared under different microwave durations of 50, 60 and 120 s were tried and the catalyst prepared at 60 s gave the best performances.

Studies to determine the location of antique quarries, from where building stones were obtained, are done by comparison of the properties of antique stones and the possible quarry sources around them. In the case when no stonemason marks exists, geologic formations that may be used as building stone should be investigated and properties of antique building stones and geologic formations should be correlated. The aim of this study was the investigation of tuff quarries that could be the source of tuffs used in the construction of Apollon Smintheus Temple. For this purpose, the studies were carried out about the geology of the region, and possible three quarries selected around Smintheion. Durability properties of stones in Temple and quarries were determined with the analyses of physical, physico-mechanical properties and artificial weathering tests of wetting-drying, salt crystallization / Effective porosity, bulk density, water absorption capacity, dry and saturated unit weight, salt content, ultrasonic pulse velocity, modulus of elasticity, uniaxial compressive strength, pore size distribution, capillary absorption and moisture absorption capacities were determined for Temple tuffs and possible quarry tuffs in fresh and artificial weathering cycles. Microstructural investigations were done by mineralogical, petrographical and chemical analyses which were optical microscopy, stereomicroscopy, XRD, SEM, FTIR, MBA and XRF. The results indicated that Temple tuffs and two of the three quarries (Fatma Gerdan and Kizilke&ccedil / ili) had similar engineering geological and micrstructural properties. Therefore, they could be used as building stone during the construction of Temple.

Controlled Low Strength Materials (CLSM) are cementitious self-compacting materials, comprised of low cement content, supplementary cementing materials, fine aggregates, and water. CLSM is typically used as an alternative to conventional compacted granular backfill in applications, such as pavement bases, erosion control, bridge abutments, retaining walls, bedding and backfilling of pipelines. This dissertation presents the findings of an extensive study carried out to determine the corrosivity of CLSM on ductile iron and galvanized steel pipelines. The study was performed in two phases and evaluated more than 40 different CLSM mixture proportions for their corrosivity. An extensive literature survey was performed on corrosion of metals in soils and corrosion of reinforcement in concrete environments to determine possible influential factors. These factors were used as explanatory variables with multiple levels to identify the statistically significant factors. Empirical models were developed for percent mass loss of metals embedded in CLSM and exposed to different environments. The first and only service life models for ductile iron and galvanized steel pipes embedded in CLSM mixtures were developed. Models indicated that properly designed CLSM mixtures can provide an equal or longer service life for completely embedded ductile iron pipes. However, the service life of galvanized pipes embedded in CLSM should not be expected to be more than the service life provided by corrosive soils.

Polymers are added to asphalt binders primarily to stiffen the binder at higher temperatures and thus to protect the pavement against rutting at summertime temperatures early in the pavement's life. Also, it has been noted that polymers typically increase the ductility of a binder and that some polymer-asphalt combinations are especially effective. Furthermore, it is hypothesized that enhancing a binder's ductility, and maintaining this enhancement with binder oxidative aging, contributes to enhanced binder durability in pavements. However, polymer-asphalt interactions and how they might contribute to improved binder performance is not well understood. The goal of this work was to probe the relationship of polymer morphology on asphalt binder rheology and mixture durability. Experiments were conducted on asphalt mixtures and binders, and as a function of oxidative aging. PFC mixtures, which are an open mixture designed to allow enhanced water drainage, were of specific interest. These mixtures were tested for Cantabro Loss, an indicator of a mixture's likelihood of failure by raveling. Asphalt binders were tested using dynamic shear rheometry (DSR), which provided the DSR function, (G' /η'/G'), a measure of binder stiffness that includes both the elastic modulus and the flow viscosity), ductility (used to measure the elongation a binder could withstand before failure), gel permeation chromatography (GPC), used to estimate the relative amount of polymer) and fluorescence microscopy (used to image the polymer morphology in the asphalt binder). From these data, relationships were assessed between binder morphology and binder rheology and between binder rheology and mixture durability, all as a function of binder oxidative aging. Polymer morphology related to ductility enhancement. Polymer morphology related to a change in the DSR function, relative to the amount of polymer, as measured by the polymer GPC peak height. Cantabro loss correlated to the DSR function (R2=0.963). The overall conclusion is that polymer morphology, as indicated by fluorescence microscopy, relates to both the rheological properties of the binder and the Cantabro loss of the mixture. These relationships should yield a better understanding of polymer modification, increased mixture durability (decreased raveling) and improved rheological properties (DSR function and ductility).

Today, with increasing global awareness and regulation of air pollution, interest in the smog-abating property of photocatalytic materials is increasing. Titanium dioxide (TiO2) is the most well known photocatalytic semiconductor and is often considered as one way of solving pollution by a passive but an effective way, particularly to reduce atmospheric nitrogen oxides (NOx=NO+NO2). This relatively new technology is already being used in some of the countries as a construction material, commercially sold as photocatalytic cement, photocatalytic pavement, self-cleaning tiles, and self-cleaning glass. Prior research has examined the photocatalytic properties of TiO2 itself, as well as TiO2-containing cement-based materials. The majority of this effort has been on characterizing and enhancing the photocatalytic efficiency. However, relatively little research was performed to assess the potential impact of the photocatalytic reaction on the "parent" or "host" material. In this research, the focus is on the effect of photocatalysis on the composition, structure, and properties of cementitious materials, which contain titania nanoparticles at early and late ages. Fundamental examinations on the addition of these chemically non-reactive nanoparticles to cement-based materials are performed. The high surface area of nanoparticles could alter early age properties of cementitious materials, such as setting time, dimensional stability, and hydration rate. Various experimental techniques as well as mathematical modeling were used to examine and explain the early age hydration of cementitious materials when TiO2 nanoparticles are present. Further, the effects of the TiO2 on the long term durability of cement-based materials are investigated to demonstrate their suitability for long-term use in the field. The photocatalytic NOx oxidation efficiency and NOx binding capability of TiO2 containing cementitious materials are experimentally investigated. The durability of TiO2-cement is examined by various techniques on samples that went through extensive photocatalysis and environmental exposures. These investigations have led to tentative conclusions on the use of TiO2 nanoparticles in cementitious materials, and suggest avenues for future study.

<p>This thesis concerns various aspects of the durability offibre optic sensors embedded in composite. Since repair orreplacement of embedded sensors is not generally possible, thefunctional reliability of embedded sensors is one of the mostimportant prerequisites for successful use. The main researchobjective was to investigate the interaction between the sensorand the composite, and how this is affecting the mechanical andoptical sensor response. Fibre optic sensors embedded incomposite structures induce local stress concentrations whenthe composite is subjected to mechanical loads andenvironmental changes such as temperature and moisture. Acomplex transfer of stresses through the interfaces between theembedded sensor and the composite occurs and can result inlarge local stresses in the composite and a significant changein the response of the embedded sensor. These stressconcentrations make the interfaces susceptible todebonding.</p><p>The sensor performance was studied experimentally andnumerically. Some basic results were generated for the EFPI andBragg grating sensors. The phase-strain response was determinedduring static and fatigue loading. The results showed that thesensors were more reliable in compression than in tensilestatic and fatigue loading. Generally, the sensor reliabilityduring loading was significantly improved for the Bragg gratingsensors over that of the EFPI sensor, as an effect of thesensor geometry. This was also demonstrated in theinvestigations on impacts. Impacts do not necessarily result indamage in the composite, but might cause debonding or otherfailure modes in the sensor area. Large, local stressconcentrations occur at several positions in the EFPI sensor,which pointed out that this sensor type was not suitable forembedded applications.</p><p>The shift in focus from the sensor concept based on the EFPIsensor to that based on the Bragg grating sensor manifesteditself in several studies. The calculated deformation fieldaround an embedded optical fibre was verified in experimentsusing a high-resolution moiré interferometric technique.Furthermore, the improvement in the coating technology wasverified. A significant higher interfacial strength wasobtained with the silane-treated glass surface. The resultsindicated that at least a twofold improvement of the shearstrength was obtained.</p><p>To simultaneously measure the in-plane strain components andthe temperature change, embedded Bragg grating sensors werearranged in a rosette configuration. The relationship betweenthe optical response from each sensor and the strains in thelaminate was numerically and analytically established.</p><p>Damage lead to stress redistribution in the sensor region,which may influence the output from the embedded Bragg gratingsensor. The effect was numerically evaluated for interfacialdamage, and was compared to that of a sensor with undamagedinterface. The results showed that debonding might have asignificant influence, in particular for combined thermal andmechanical loading.</p><p><b>Keywords</b>: composites, fibre optic sensor, embedded, EFPIsensor, Bragg grating sensor, durability, fatigue, impact,strain measurement, interface, stress analysis</p>

Naudojamų hidrotechnikos statinių konstrukcijos veikiamos įvairių apkrovų ir neigiamo aplinkos poveikio nudėvimos, susiformuoja pažaidos. Pavojingiausios pažaidos, mažinančios pagrindinių laikančiųjų konstrukcijų (atraminių sienų) laikančiąją galią. Netekus laikomosios galios kyla grėsmė viso hidrotechnikos statinio patikimumui ir ilgaamžiškumui. Darbo tikslas – įvertinti hidromazgų atraminių sienų betono paviršinio sluoksnio ilgaamžiškumą apibrėžiančius rodiklius. Atlikus tyrimus nustatyta pagrindinė gelžbetoninių atraminių sienų charakteristika – betono gniuždomasis stipris. Pagal stiprio tyrimo rezultatus įvertintas Gailiušių hidromazgo atraminės sienos patikimumas ir nustatyta, kuris betono apsauginio sluoksnio ilgaamžiškumo rodiklis tiksliausiai atspindi atraminių sienų ilgaamžiškumo skaičiavimo rezultatus. Siūloma ilgaamžiškumo vertinimui naudoti 3.11 formulę. / Constructions of hydraulic structures are under the influence of different loads and negative environment impacts. Due to environmental impacts some deteriorations on the walls take place. The most dangerous kind of deteriorations reduces the bearing capacity of main constructions. The loss of the bearing capacity is very dangerous for the reliability and durability of the retaining wall. The purpose of this paper is to evaluate indicies defining the durability of the concrete covering layer of the retaining walls of hydroschemes. After the analysis it was found out the main characteristics of the reinforced concrete retaining walls – the compression strength of the concrete. The reliability of the retaining walls of Gailiušių hydroscheme was evaluated using the compression strength analysis. It was found out which indicator of the concrete covering layer durability gives the most correct counting results. It is suggested to use formula 3.11 for evaluation of durability.