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<p>The traditional semiconductor device scaling based on Moore’s law is reaching its physical limits. New materials hosting rich physical phenomena such as correlated electronic behavior may be essential to identify novel approaches for information processing. The tunable band structures in such systems enables the design of hardware for neuromorphic computing. Strongly correlated perovskite nickelates (ReNiO3) represent a class of quantum materials that possess exotic electronic properties such as metal-to-insulator transitions. In this thesis, detailed studies of NdNiO3 thin films from wafer-scale synthesis to structure characterization and to electronic device demonstration will be discussed.</p> <p>Atomic layer deposition (ALD) of correlated oxide thin films is essential for emerging electronic technologies and industry. We reported the scalable ALD growth of neodymium nickelate (NdNiO3) with high crystal quality using Nd(iPrCp)3, Ni(tBu2-amd)2 and ozone (O3) as precursors. By controlling various growth parameters such as precursor dose time and reactor temperature, we have optimized ALD condition for perovskite phase of NdNiO3­. We studied the structure and electrical properties of ALD NdNiO3 films epitaxially grown on LaAlO3 and confirmed their properties were comparable to those synthesized by physical vapor deposition methods. </p> <p>ReNiO3 undergoes a dramatic phase transition by hydrogen doping with catalytic electrodes independent of temperature. The electrons from hydrogen occupy Ni 3<em>d</em> orbitals and create strongly correlated insulating state with resistance changes up to eight orders of magnitudes. At room temperature, protons remain in the lattice locally near catalytic electrodes and can move by electrical fields due to its charge. The effect of high-speed voltage pulses on the migration of protons in NdNiO3 devices is discussed. After voltage pulses were applied with changing the voltage magnitude in nanosecond time scale, the resistance changes of the nickelate device were investigated. </p> <p>Reconfigurable perovskite nickelate devices were demonstrated and a single device can switch between multiple electronic functions such as neuron, synapse, resistor, and capacitor controlled by a single electrical pulse. Raman spectroscopy showed that differences in local proton distributions near the Pd electrode leads to different functions. This body of results motivates the search for novel materials where subtle compositional or structural differences can enable different gaps that can host neuromorphic functions.</p>

The strength and behavior of composite slabs are governed by the shear interaction between the concrete and the steel deck. The interaction property depends on several factors and it is not possible to express the relationship from a purely analytical basis. As such, analysis and design methods available today use the interaction property derived from full scale performance tests. In numerical modeling, the interaction property is obtained from a variety of elemental push off tests which, for the most part, do not represent actual slab bending. This research comprises experimental, analytical and numerical investigations of composite slabs. The central objective of the experimental work is to develop a new small scale test method for evaluating the performance and behavior of composite slabs and also for determining the shear interaction property for use in numerical analysis. The characteristics of the new test specimen are simple, easy and economical to conduct, as well as comparable in performance and behavior with the more common full slab test. The analytical study was conducted to determine whether data from small scale tests can be used in the present analytical methods to predict the strength of the actual slabs, to use the same test data for input in the numerical analysis, and to improve the present Partial Shear Connection (PSC) design procedure. A model that relates the shear bond stress to slab slenderness, which can be used to estimate the shear interaction property for slabs with any slenderness, was developed. Finally, a finite element study was conducted to develop a simple modeling method that is suitable for analyzing composite slabs with variable slenderness. Parametric analyses to determine the effect of slenderness on the performance and behavior of composite slabs, and on the accuracy of the present design methods were also conducted. The results of this investigation demonstrate that the small scale test is feasible as a replacement for the full scale test. Data from the small scale test can be used not only in the analytical methods but also in the numerical analysis, thus eliminating the need for separate push off type tests. / Ph. D.