Effective coastal adaptation to sea-level rise requires an understanding of how much and how fast glaciers and ice sheets will melt in the coming decades, together with an understanding of the provenance of that ice melt. When land ice is lost to the oceans, sea-levels do not rise uniformly across the globe, but exhibit a “sea-level fingerprint” specific to the source of ice melt, posing an important question motivating this thesis: Which ice mass(es) will contribute the first 1m/3 feet of sea-level rise? The glacial-geologic record archives the vulnerability of ice sheets and their sub-sectors to past warming. To analyze this record of past glacial change, I develop and apply cosmogenic-nuclide techniques for investigating the climate sensitivity of four key ice sheets. The novel geochemical techniques described here also allow me to investigate processes of landscape evolution, including subglacial and subaerial erosion. Subglacial erosion dictates landscape development in glaciated and formerly glaciated settings, which in turn influences ice-flow dynamics and the climate sensitivity of ice masses, making it an important input in ice-sheet models. In Chapter 1, I use 10Be measurements in surficial bedrock and a 4-m-long bedrock near Jakobshavn Isbræ, to constrain the erosion rate beneath the Greenland Ice Sheet (GrIS) on historical and orbital timescales. 10Be concentrations measured below ~2 m depth in a 4-m-long bedrock core are greater than what is predicted by an idealized production-rate depth profile and I develop a model to utilize this excess 10Be at depth to constrain orbital-scale erosion rates. I find that erosion rates beneath GrIS were 0.4–0.8 mm yr-1 during historical times and 0.1–0.3 mm yr-1 on Pleistocene timescales. The broad similarity between centennial- and orbital-scale erosion rates suggests that subglacial erosion rates adjacent to Jakobshavn Isbræ have remained relatively uniform throughout the Pleistocene. In Chapter 2, I present cosmogenic 10Be and 3He data from Ferrar dolerite pyroxenes in surficial rock samples and a bedrock core from the McMurdo Dry Valleys, Antarctica, opening new opportunities for exposure dating in mafic rocks. I describe scalable laboratory methods for isolating beryllium from pyroxene, estimate a spallation production rate for 10Be in this mineral phase, referenced to 3He, of 3.6 ± 0.2 atoms g-1 yr-1, and present initial estimates for parameters associated with 10Be and 3He production by negative muon capture. I also demonstrate that the 10Be-3He pair in pyroxene can be used to simultaneously resolve exposure ages and subaerial erosion rates, and that the precision of my 10Be measurements in pyroxene enable exposure dating on Last Glacial Maximum to Late Holocene surfaces, including moraines, on a global scale. In Chapter 3, I apply exposure dating locally to investigate the Last Glacial Maximum (LGM) and initial deglaciation of the Laurentide Ice Sheet (LIS), the most dynamic continental ice sheet, in southern New England and New York City. I synthesize new and existing exposure age chronologies from moraines and other glacial deposits that span ~26 to 20.5 ka, and quantify retreat rates for the southeastern LIS margin. Initial retreat at <5 to 30 m yr-1 started within the canonical LGM period, representing the slowest LIS retreat rates of the entire New England deglacial record, which I relate to a slow rise in modeled local summer temperatures through the LGM. Employing similar exposure dating techniques in Chapter 4, I describe the first 10Be ages from nunataks of the Juneau Icefield (JIF), Alaska, that I collected through the Juneau Icefield Research Program (JIRP) in order to evaluate icefield thinning during the Late Glacial and Holocene. I find that the JIF was smaller-than-present under warm climate conditions during the early-to-mid Holocene, elucidating the sensitivity of the icefield to warming. Tackling the climate crisis more broadly and in turn, addressing pressing Earth science questions like those posed in this dissertation, requires diverse perspectives. Yet, the Earth sciences have historically been among the least diverse of the STEM disciplines. As one contribution to a comprehensive effort through JIRP to increase diversity in the geosciences pipeline, Chapter 5 details the curriculum for a two-week course titled ‘A Virtual Expedition to the Juneau Icefield’ that I co-designed and co-taught in 2021 to bring accessible polar science experiences to high school students.

The waters of the Indian Ocean southeast of Africa are a crucial junction for surface and deep ocean processes that serve as vital controls on Earth’s climate system. At the surface, the Agulhas Current, its retroflection, and Agulhas Leakage transfer water from the Indian and South Atlantic. The addition of this heat and salt to the Atlantic Basin helps drive the Meridional Overturning Circulation and the formation of deep water in the North Atlantic Ocean. On the timescales of centuries, the Meridional Overturning Circulation ultimately returns this water back to the Indian Ocean in the form of North Atlantic Deep Water. Proxy reconstructions show that the vigor of ocean overturning is immensely important to the global climate system, driving changes in atmospheric CO₂ concentrations and temperature and precipitation patterns across the planet. I use x-ray fluorescence core scanning, sediment provenance techniques, and core images from International Ocean Discovery Program Site U1474, located in the Natal Valley of the southwest Indian Ocean, to investigate past changes in the Agulhas Current and North Atlantic Deep Water. 40K/40Ar provenance ages measured on the clay fraction of sediment from Site U1474 indicate that, despite its great distance from the core site, the Zambezi is the most important factor influencing the deposition of terrigenous sediment in the Natal Valley. We present these results in a quantitative way, reinforcing the conclusions of previous studies. However, a comparison to newly available proxy records influenced by current speed and hydroclimate suggests that the strength of the Agulhas does not have a major influence on terrigenous sediment sources, at least at the headwaters of the Agulhas Current. Instead, I suggest that low-latitude hydrologic processes driven by zonal and meridional temperature gradients in conjunction with sea level are responsible for sediment source variability. In core photos, I found evidence for deep water variability in the Natal Valley in the form of millimeter-to-centimeter scale layers of olive-green sediment. To an overwhelming extent, these layers are formed during glacial periods, especially at their termination. I complement observations at Site U1474 with published proxy data for oxygen concentrations and measurements of total organic carbon percent in the Natal Valley and by extending our search for these green layers to core sites around the world. With these data, it is possible to confidently connect these layers to organic carbon concentrations in the sediment, reduction-oxidation processes in sediments following burial, and the local concentration of dissolved oxygen in the deep water. There are comparable fluctuations in the abundances of green layers in core sites in the path of North Atlantic Deep Water during glacial cycles, where more frequent and more intense green layer formation is driven by higher bottom water oxygen concentrations. Peaks in the abundance of green layers approximately 250 ka and 900 thousand years ago coincide with global scale excursions toward isotopically light benthic carbon isotopes. Connecting the green layers to the release of isotopically light organic carbon from sediments leads me to propose that long-observed fluctuations in the carbon cycle may be attributable to deep ocean oxygenation.

No description available.

Seafloor sedimentary depositional and erosional processes create a record of near and far-field climatic and tectonic signals adjacent to continental margins and within oceanic basins worldwide. In this dissertation I study both modern and paleo-seafloor surface processes at three separate and distinct study sites; Cascadia offshore Oregon, U.S.A., the Eastern North American Margin from south Georgia in the south to Massachusetts in the north, and the Deep Galicia Margin offshore Spain. I have the advantage of using modern geophysical methods and high power computing resources, however the study of seafloor processes at Columbia University's Lamont-Doherty Earth Observatory (LDEO) stretches back over ~80 yrs. Specifically I use data collected during a variety of geophysical research cruises spanning the past ~50 yrs.-the majority of which can be directly attributed to seagoing programs managed by LDEO. The modern seafloor is the integrated result of all previous near and far field processes. As such, I look below the seafloor using multi-channel seismic reflection data, which is the result of innumerable soundings stacked together to create an image of the sub-seafloor (paleo) horizons. I map, analyze and interpret the sub-seafloor sedimentary horizons using a variety of both novel and established methods. In turn, I use multi-beam sonar data, which is also the result of innumerable soundings to map, analyze, and interpret the modern seafloor topography (bathymetry). Additionally, I look to the results from academic ocean drilling programs, which can provide information on both the composition and physical properties of sediments. The sediment composition alone can provide important information about both near and far-field processes, however when supplemented with physical properties (e.g., density/porosity) the results become invaluable. In my second chapter, I use a compilation of multi-beam sonar bathymetry data to identify and evaluate 86 seafloor morphological features interpreted to represent large-scale erosional scours not previously recognized on the Astoria Fan offshore Oregon, U.S.A. The Astoria Fan is primarily composed of sediments transported from the margin to the deep ocean during Late Pleistocene interglacial periods. A significant portion of the sediments have been found to be associated with Late Pleistocene outburst flood events attributed to glacial lakes Bonneville and Missoula. The erosional scours provide a record of the flow path of the scouring event(s), which if well understood can provide important information for the study of past earthquakes as the sedimentary record remains intact outside of the erosional force created by the massive flood events. I design and implement a Monte Carlo inversion to calculate the event(s) flow path at each individual scour location, which results in a comprehensive map of Late Pleistocene erosion on the Astoria Fan. The results indicate that at least 4 outburst flood events are recorded by the scour marks. In my third chapter, I build a stratigraphic framework of the Eastern North American margin using a compilation of multi-channel seismic data. Horizon Au is a primary horizon within the stratigraphic framework and is thought to represent a significant margin wide bottom-water erosional event associated with subsidence of the Greenland-Scotland Ridge and opening of Fram Strait in the late Eocene/early Oligocene. A recent study found that the bottom-water was enriched in fossil carbon, leading us to hypothesize that the bottom-water erosion recorded by horizon Au may have been facilitated by chemical weathering of the carbonate sediments. I use sediment isopach(s) to build a margin-wide model of the late Eocene/early Oligocene continental margin in order to estimate the volume of sediments eroded/dissolved during the event marked by horizon Au. The results indicate that ~170,000 km3 of sediments were removed with a carbonate fraction of 42,500 km³, resulting in 1.15e18 mol CaCO₃ going into solution. An influx of this magnitude likely played a role in significant climatic changes identified at the Eocene-Oligocene transition (EOT). In my fourth chapter, I use a combination of 3D multi-channel seismic and multi-beam sonar bathymetry data collected during the Galicia 3D Seismic Experiment in 2013. The Galicia Bank is the largest of many crustal blocks and is located 120 km west of the coast on the Iberian Margin. The crustal blocks have been attributed to the opening of the North Atlantic Ocean in the Late Triassic/Middle Jurassic. The Galicia Bank is the source for the majority of sediments delivered to the Deep Galicia Margin, the focus of this study. I map the seafloor and 5 paleo-seafloor surfaces in order to study controls on sediment delivery provided by the crustal blocks. The results show that the crustal blocks begin as a barrier to and remain a primary control on sediment delivery pathways to the Deep Galicia basin. Additionally, the paleo-seafloor surfaces record morphological structures that can inform us on both near and far field past climatic and tectonic events e.g., the Alpine Orogeny and Pleistocene inter-glacial periods.

Rockfall from rock slopes adjacent to roadways is a major hazard and poses a problem for transportation agencies across the country. The state of Tennessee has implemented the Tennessee Rockfall Management System (RMS) as a means of reducing the liabilities associated with rockfall hazard. It utilizes digital data acquisition via PDAs coupled with distribution via an expandable web-based GIS database. The Tennessee Rockfall Hazard Rating System (RHRS) is part of the Tennessee RMS and assigns a numeric hazard rating according relative hazard for all slopes identified as having a high potential for delivering rock blocks onto Tennessee Department of Transportation maintained roadways. The Tennessee RHRS uses standard rock slope failure mechanisms (planar failure, wedge failure, topple failure, differential weathering, and raveling) along with the site and roadway geometry to assess the rockfall hazard of an individual slope. This study suggests methods that will expedite fieldwork, including an informational guide on how to properly identify individual failure mechanisms in the field. Also, the study examines the current method of scoring abundance and suggests an alternative, multiplicative approach. The alternative of using a multiplicative abundance is considered and its results summarized. / Master of Science

Indiana University-Purdue University Indianapolis (IUPUI) / Deep injection of waste CO2 and fluids from regional energy plants into the St. Peter Formation of the Illinois Basin, could effectively provide long term deep geologic storage. This research aims to explore the viability of this proposed injection. There are some basic criteria that must be met to effectively store waste in a geologic reservoir. First, the reservoir must have sufficient porosity and permeability for both injectivity and for migration of the injected fluid through the reservoir. Second, the reservoir must be overlain by some form of impermeable seal or cap layer(s). Third, the reservoir should be sufficiently isolated from interaction with surface and near surface water. Finally, the formation must contain enough storage volume to handle significant amounts of injected material. Massive sandstone formations that host large saline aquifers have the potential to serve as high capacity storage sites. Much of the research targeting the potential suitability and storage capacity attributes of these formations has been promising, but reproducibility of the results has been less than ideal. Some of this variability has been attributed to petrological differences in the sandstone reservoirs that are not readily evident when studying the target formation over a geographically significant area. Based on the criteria, a promising candidate for injection and storage is the St. Peter Sandstone of the Illinois Basin. This study investigates the viability of liquefied CO2 storage within the St. Peter Sandstone on a micro scale. Initial porosity and permeability of the formation plug samples ranged from 16% to 19% and 26 to 981 millidarcies (mD), respectively. The wide difference in permeability is attributed to variations in strength of the cement, in this case quartz overgrowth in the sandstone. This preliminary evidence indicates that the storage capacity of the formation will remain constant or increase depending on injection location, suggesting that the St. Peter Formation will lend itself well to future storage.

[pt] Estudos econômicos de áreas com indícios de hidrocarbonetos estão imersos em incertezas de diferentes naturezas (geológicas, de engenharia e econômicas). No início do estudo, aspectos da geologia, dos fluidos, das rochas e do reservatório só são conhecidos por métodos indiretos que fornecem informações imprecisas. A redução dessas incertezas é limitada pelos elevados custos de perfuração de poços que permitam testes diretos. Conseqüentemente, decisões de investimentos de exploração têm que ser tomadas sob risco motivando, assim, o desenvolvimento de métodos para a avaliação econômica probabilística de propriedades. O foco desta dissertação é a avaliação econômica probabilística de recursos petrolíferos, antes da perfuração do poço pioneiro. O cálculo do valor econômico de uma propriedade depende das estimativas dos perfis temporais de receitas e custos associados ao seu desenvolvimento e produção (D e P). A obtenção de tais elementos requer um projeto de D e P para a propriedade que, em função dos dados disponíveis, é menos detalhado do que um projeto de simulação multicelular. Nesta dissertação, uma metodologia de avaliação baseada em simulação de Monte Carlo é apresentada juntamente com uma implementação- protótipo. A realização das numerosas replicações, necessárias para se obter uma avaliação probabilística, se torna viável graças a um programa capaz de gerar o projeto de D e P automaticamente. Esse programa foi desenvolvido pela Petrobras com base em regras fornecidas por um especialista. Além da justificativa para a abordagem adotada, da descrição e implementação do método, são feitas considerações sobre distribuições de probabilidade para codificar incertezas e sobre os resultados dos testes iniciais do sistema protótipo. / [en] Economics studies of areas with indications of hydrocarbons are submerged in uncertainties of assorted natures (geological, of engineering and economical). At the start of the study, aspects concerning the geology, the fluids, the rocks and the reservoir are only known through indirect methods that yield imprecise information. The reduction of these uncertainties is limited by high costs of drilling wells that allow direct tests. Consequently, decisions on exploration investments have to be made under risk. This motivates the development of methods for probabilistic economic evaluation of properties. This dissertation addresses the probabilistic economic evaluation of petroleum resources, prior wildcat well drilling. Assessing the economic value of a property depends on estimates of incomes and costs time profiles associated to its development and production (D and P). Obtaining such elements requires a D and P project for the property that, due to the limited data available, is less detailed than a multi- cellular simulation project. In this thesis, a probabilistic evaluation methodology based on Monte Carlo simulation is presented along with a prototype implementation. Performing the numerous replications necessary to obtain a probabilistic evaluation becomes feasible thanks to a procedure capable of automatically generating the D and P project. That procedure was developed by Petrobras based on heuristic rules supplied by an expert. In addition to a justification for the proposed approach, the description of the method and its implementation, comments are made on probability density functions used for encoding uncertainties, and on the results of the initial tests with the prototype system.

Made available in DSpace on 2017-07-21T18:15:26Z (GMT). No. of bitstreams: 1 Tatiane Ferrari do Vale.pdf: 5883642 bytes, checksum: c0523633b1b2c9b55472d5152adbcb24 (MD5) Previous issue date: 2017-04-10 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / This dissertation deals with the management of the territory, the regional sustainable economy, information and educational environment, and geoconservation, whereas a greater understanding of these issues may assist in the application process of aspiring geoparks. It aims to contribute to the preparation of the candidature file of the project Fernando de Noronha Geopark to UNESCO, analyzing the actions performed in the Geopark Azores (Portugal) in order to propose good practices. The theoretical basis includes topics such as geodiversity, geological heritage, geosites,geoconservation, Geotourism and sustainable tourism. The methodology of this study was conducted by a bibliographic and documentary study, with field research in Fernando de Noronha (PE) and the Azores (Portugal). Considerations are made concerning the management of the territory in geoparks and benefits and problems identified in the Geopark are presented. Finally, some actions are proposed in a plan of actions. It is concluded that Fernando de Noronha has the potential to integrate the Global Network of Geoparks, since it develops some guidelines and criteria of UNESCO. However, some actions should be carried out before the submission of the candidature file to the organization. Such actions include the creation of a management structure, development of educational programs focusing on the geology of the archipelago, a strategy of geoconservation and incentive to the development of new products based on local features. / Esta dissertação trata da gestão do território, da economia regional sustentável, da informação e ambiente educacional e da geoconservação, visto que um maior entendimento destas questões pode auxiliar no processo de candidatura de geoparks aspirantes. Tem como objetivo contribuir com a proposta de elaboração do Dossiê de Candidatura do Projeto Geopark Fernando de Noronha à UNESCO, analisando as ações realizadas no Geopark Açores (Portugal) a fim de propor boas práticas. O embasamento teórico engloba temas como geodiversidade, patrimônio geológico, geossítios, geoconservação, geoturismo e turismo sustentável. A metodologia deste trabalho foi realizada mediante um estudo bibliográfico e documental, com pesquisa de campo em Fernando de Noronha (PE) e nos Açores (Portugal). São feitas considerações a respeito da gestão do território em geoparks e apresentados os benefícios e problemas identificados no Geopark Açores. Por fim, algumas ações são propostas em um Plano de Ações. Conclui-se que Fernando de Noronha tem potencial para integrar a Rede Global de Geoparks, pois já desenvolve algumas diretrizes e critérios da UNESCO, no entanto, algumas ações devem ser realizadas antes da submissão do dossiê de candidatura à organização. Tais ações incluem a criação de uma estrutura de gestão, desenvolvimento de programas educativos com enfoque na geologia do arquipélago, uma estratégia de geoconservação e fomento a novos produtos baseados nas características locais.

Nuclear power generation is being regarded as a solution to ever increasing demand for electricity, and concerns over global warming and climate change due to the use of fossil fuels. Although nuclear power generation is considered to be reliable, economical, clean, and safe, the wastes produced from the nuclear fuel cycle are not, and can remain hazardous for hundreds of thousands of years. An international consensus has developed over the past several decades that deep geologic disposal of low, intermediate, and high level radioactive wastes is the best option to protect the biosphere. In this thesis, both regional scale and sub-regional scale models are created to simulate groundwater flow and transport for a representative Canadian Shield setting, honouring site-specific topography and surface water features. Sub-surface characteristics and properties are derived from numerous geoscience studies. In addition, a regional scale model is developed, centred on the Bruce Nuclear Power Development (BNPD) site near Tiverton, Ontario, and located within the Michigan Basin. Ontario Power Generation (OPG) has proposed a Deep Geologic Repository (DGR) for low & intermediate level waste (L&ILW) at the BNPD site. Paleoclimate simulations using various combinations of parameters are performed for both the Canadian Shield Sub-Regional model, and the Michigan Basin Regional model. Fracture zone permeability is a very important parameter when modelling crystalline rock settings. Migration of a unit tracer representing glacial recharge water can occur to depth in fractures of high permeability. Representative rock compressibility values are necessary as compressibilities are used to calculate storage coefficients, and the one-dimensional loading efficiency; these affect the subsurface propagation of elevated pore pressures due to glacial loading at surface. Coupled density-dependent flow and transport in paleoclimate simulations affects deep flow systems and provides a measure of flow stability, as well as increasing the mean life expectancy at depth. Finally, hydromechanical coupling is a very important mechanism for reducing vertical hydraulic gradients during a glaciation event when a hydraulic boundary condition equal to the pressure at the base of an ice-sheet is applied at ground surface. Pore water velocities are reduced, thereby retarding migration of surface waters into the subsurface environment.

Nuclear power generation is being regarded as a solution to ever increasing demand for electricity, and concerns over global warming and climate change due to the use of fossil fuels. Although nuclear power generation is considered to be reliable, economical, clean, and safe, the wastes produced from the nuclear fuel cycle are not, and can remain hazardous for hundreds of thousands of years. An international consensus has developed over the past several decades that deep geologic disposal of low, intermediate, and high level radioactive wastes is the best option to protect the biosphere. In this thesis, both regional scale and sub-regional scale models are created to simulate groundwater flow and transport for a representative Canadian Shield setting, honouring site-specific topography and surface water features. Sub-surface characteristics and properties are derived from numerous geoscience studies. In addition, a regional scale model is developed, centred on the Bruce Nuclear Power Development (BNPD) site near Tiverton, Ontario, and located within the Michigan Basin. Ontario Power Generation (OPG) has proposed a Deep Geologic Repository (DGR) for low & intermediate level waste (L&ILW) at the BNPD site. Paleoclimate simulations using various combinations of parameters are performed for both the Canadian Shield Sub-Regional model, and the Michigan Basin Regional model. Fracture zone permeability is a very important parameter when modelling crystalline rock settings. Migration of a unit tracer representing glacial recharge water can occur to depth in fractures of high permeability. Representative rock compressibility values are necessary as compressibilities are used to calculate storage coefficients, and the one-dimensional loading efficiency; these affect the subsurface propagation of elevated pore pressures due to glacial loading at surface. Coupled density-dependent flow and transport in paleoclimate simulations affects deep flow systems and provides a measure of flow stability, as well as increasing the mean life expectancy at depth. Finally, hydromechanical coupling is a very important mechanism for reducing vertical hydraulic gradients during a glaciation event when a hydraulic boundary condition equal to the pressure at the base of an ice-sheet is applied at ground surface. Pore water velocities are reduced, thereby retarding migration of surface waters into the subsurface environment.