The prevalence of female adults and adolescents living with diagnosed HIV infection continues to rise. Latina women in the United States (US) are not only disproportionately affected by human immunodeficiency virus (HIV) infection, but also underutilize HIV prevention services, such as HIV testing. Data are limited on the differences in HIV risk among Latinas by country of birth, and opportunities still exist to prevent transmission of HIV and reduce HIV-related disparities. This dissertation describes the risk behaviors, testing behaviors, and test results among women tested for HIV at public sites in Florida. Additionally, it compares these characteristics by HIV testing site type among pregnant women. Multivariable logistic regression was used to estimate the adjusted odds ratios (AOR) and associated 95% confidence intervals for the outcome variables of risk behaviors, previous testing, and positive HIV test results. Of the total 209,954 records, 184,037 were from women not currently pregnant, of which 87,569 (45.6%) were among non-Hispanic Blacks (NHBs), 47,926 (26.0%) non-Hispanic Whites (NHWs), and 41,117 (22.3%) Latinas. Women who reported previous HIV testing had decreased odds of being Latina compared to NHW women (AOR 0.90; 95% confidence interval [CI] 0.87, 0.94), and testing event results indicate that foreign-born Latina women were significantly less likely to report partner risk (AOR 0.42; 95% CI: 0.40-0.54) than US-born Latina women. Of the 24,863 records of pregnant women, 10,199 (41.1%) were among Latinas, 6,796 (27.4%) were among NHB, and 6,631 (26.7%) were among NHW. The testing records indicated that Latina and NHB women had decreased odds of reporting partner risk than NHW women (Latina: AOR 0.20; 95% CI: 0.14-0.28; and NHB: AOR 0.14; 95% CI: 0.10-0.21), and records of women tested in prisons/jails had higher odds of reporting previous HIV testing compared to prenatal care sites (AOR 1.86; 95% CI: 1.03-3.39). Reported risk behaviors varied by race/ethnicity and Latina country of origin. Knowledge of these differences can enhance current testing and prevention strategies for women, and aid in targeting HIV prevention messaging, program decision-making, and allocation of resources, corresponding to the central approach of High Impact Prevention and the National HIV/AIDS Strategy.

O empreendedorismo é um fenômeno de abrangência global que tem direcionado a atenção de diversas instituições de ensino, entidades representativas de classe, do terceiro setor e órgãos governamentais, que buscam um melhor entendimento dos fatores que contribuem para o crescimento e desenvolvimento econômico. A ação empreendedora é a mola propulsora responsável pela dinamização da economia, que por meio da introdução de novos produtos e serviços, promove a geração de empregos e a distribuição de renda. Por trás da criação das organizações está a figura do empreendedor, um indivíduo que, partindo de suas ideias e percepções, com criatividade, trabalho árduo e perseverança, administra e assume o risco do resultado de seu empreendimento. No Brasil, das 4,5 milhões de empresas existentes, aproximadamente 1,5%, são responsáveis pela geração de 70% dos postos de trabalho, segundo dados do IBGE. Estas empresas são categorizadas como empresas de alto crescimento ou alto impacto (scale ups), pois apresentam taxas de crescimento acima de 20%. Este estudo objetiva descrever as características de empreendedores que criaram e conduzem empresas de alto impacto, segundo suas próprias percepções. Partindo de uma revisão bibliográfica sobre a importância do empreendedorismo, conceitos e definições, seu impacto no Brasil e no mundo e utilizando-se também de relatórios de órgãos governamentais e instituições apoiadoras e monitoradores da atividade empreendedora, desenvolveu-se uma pesquisa de campo, utilizando-se de entrevistas semiestruturadas, aplicadas por meio de videoconferências. Dessa maneira, entrevistou-se um grupo de indivíduos associados a uma organização não governamental, que atua no fomento da atividade empreendedora no Brasil e em diversos países, e que se enquadram nesse perfil empresarial. Os dados obtidos foram tratados mediante o uso da técnica de análise de conteúdo que identificou 18 categorias que envolvem aspectos pessoais e da criação e do desenvolvimento dos negócios. Pode-se inferir que empreendedorismo de alto impacto é o resultado de uma ideia inovadora, desenvolvida e trabalhada com comprometimento de seu idealizador, ofertando um produto ou serviço diferenciado que agrega um valor singular para os seus clientes. / Entrepreneurship is a global phenomenon that coverage has focused the attention of several educational institutions, professional representative bodies, third sector and government agencies that seek a better understanding of the factors that contribute to the economic growth and development. The entrepreneurial action is the driving force responsible for stimulating the economy, through the introduction of new products and services, promotes job creation and income distribution. Behind the creation of organizations is the figure of the entrepreneur, an individual who, from their ideas and perceptions, with creativity, hard work and perseverance, manages and assumes the risk of the outcome of your venture. In Brazil, the 4.5 million existing businesses, approximately 1.5%, are responsible for generating 70% of jobs, according to IBGE data. These companies are categorized as high-growth or high-impact companies (scale ups), because their growth rates above 20%. This study aims to describe the characteristics of entrepreneurs who created and lead high-impact companies, according to their own perceptions. From a literature review on the importance of entrepreneurship, concepts and definitions, its impact on Brazil and the world and also using government agencies reports and supporting institutions and Listeners of entrepreneurial activity, we developed a field research using If semi-structured interviews, applied through videoconferences. Thus, we interviewed a group of individuals associated with a non-governmental organization that acts in fostering entrepreneurial activity in Brazil and in several countries, and that fit this corporate profile. The data were processed by using the content analysis technique identified 18 categories involving personal aspects and the creation and business development. It can be inferred that high-impact entrepreneurship is the result of an innovative idea, developed and worked with commitment of its creator, offering a product or special service that adds a unique value for its customers.

The financial sector stands for an important part of society’s fundamental infrastructure andnational economy. Previous financial crises indicate the importance of having a well-regulatedfinancial market. Former directives of regulating the insurance industry had insufficient solvencyregulations and were lacking in risk management. Therefore, the regulatory framework SolvencyII, the successor to Solvency I, has been established on the European market. The objective ofSolvency II is to ensure consumer protection by ensuring insurance companies properly reflectthe risks their businesses are vulnerable to.The regulatory framework Solvency II came into force in the turn of 2015/2016. However, it hasbeen on every insurers’ agenda for years and preparations have been done. It is therefore ofinterest to investigate how Swedish insurance companies have adjusted to Solvency II at an earlystage after the transition.This has been investigated by conducting interviews with mainly Chief Risk Officers and RiskManagers at Swedish insurance companies. As a complement, a questionnaire was distributed toasset and capital managers, having insurers as customers, regarding their perception of insurers’changes in investment behaviors.The findings of this study imply that insurance companies have had a compliance focus to adoptthe regulation rather than a business focus. No indications of adjustments to corporate businessstrategy has yet been noticed. However, some companies have developed a risk culture withinthe organizations. The extensive reporting and calculations of capital that Solvency II entails, haslead to implementations of new systems and processes for companies. It is further noticed thatSwedish insurance companies use the standard model for calculating the capital requirements.Solvency II has lead to increased understanding of the trade-off between capital, risk, and returnby holding a risk-adjusted capital. Also, an increased engagement of employees in the riskmanagement process has been noticed. The companies are aligned with the ORSA process, sinceit is one of the requirements, and are aware of the potential benefits the ORSA process cancontribute to. Lastly, this study indicates an improved risk awareness and culture within theinsurance companies by educating existing employees and employing new competentemployees.

This was a mixed-method user-centered study regarding the University of North Texas's student-owned learner record and credentialing system. Through methods of quantitative and qualitative inquiry, student perceptions were unearthed and recommendations to improve the system were provided.

Polymers are subjected to physical and chemical changes during their processing, service life, and further recovery, and they may also interact with impurities that can alter their composition. These changes substantially modify the stabilisation mechanisms and mechanical properties of recycled polymers. Detailed knowledge about how the different stages of their life cycle affect the degree of degradation of polymeric materials is important when discussing their further waste recovery possibilities and the performance of recycled plastics. A dual-pronged experimental approach employing multiple processing and thermo-oxidation has been proposed to model the life cycle of recycled high-impact polystyrene (HIPS). Both reprocessing and thermo-oxidative degradation are responsible for coexistent physical and chemical effects (chain scission, crosslinking, apparition of oxidative moieties, polymeric chain rearrangements, and physical ageing) on the microstructure and morphology of polybutadiene (PB) and polystyrene (PS) phases; these effects ultimately influence the long-term stability, and the rheological and mechanical behaviour of HIPS. The PB phase has proved to be the initiation point of HIPS degradation throughout the life cycle. Thermo-oxidation seems to have more severe effects on HIPS properties; therefore, it can be concluded that previous service life may be the part of the life cycle with the greatest influence on the recycling possibilities and performance of HIPS recyclates in second-market applications. The results from the life cycle degradation simulation were compared with those obtained from real samples from a large-scale mechanical recycling plant. A combination of different analytical strategies (thermal analysis, vibrational spectroscopy, and chromatographic analysis) is necessary to obtain a detailed understanding of the quality of recycled HIPS as defined by three key properties: degree of mixing, degree of degradation, and presence of low molecular weight compounds. / QC 20101119

Polymers are subjected to physical and chemical changes during their processing, service life, and further recovery, and they may also interact with impurities that can alter their composition. These changes substantially modify the stabilisation mechanisms and mechanical properties of recycled polymers. The assessment of the quality properties of recycled polymers is therefore crucial to guarantee the performance of recyclates in further applications. Three key quality properties have been defined for this quality analysis: degree of mixing (composition), degree of degradation, and presence of low molecular weight compounds (degradation products, contaminants, additives). Furthermore, detailed knowledge about how the different stages of their life cycle affect the degree of degradation of polymeric materials is important when discussing their further waste recovery possibilities and the performance of recycled plastics. A dual-pronged experimental approach employing multiple processing and thermo-oxidation has been proposed to model the life cycle of recycled high-impact polystyrene (HIPS used in packaging applications, and electrical and electronic equipment (E&E). Both reprocessing and thermo-oxidative degradation are responsible for coexistent physical and chemical effects (chain scission, crosslinking, apparition of oxidative moieties, polymeric chain rearrangements, and physical ageing) on the microstructure and morphology of polybutadiene (PB) and polystyrene (PS) phases; these effects ultimately influence the long-term stability, and the rheological and mechanical behaviour of HIPS. The PB phase has proved to be the initiation point of HIPS degradation throughout the life cycle. Thermo-oxidation seems to have more severe effects on HIPS properties; therefore, it can be concluded that previous service life may be the part of the life cycle with the greatest influence on the recycling possibilities and performance of HIPS recyclates in second-market applicat / Vilaplana Domingo, FJ. (2008). Analytical strategies for the quality assessment of recycled high-impact polystyrene (HIPS) [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/2186

In an increasingly interconnected, and electricity-reliant world, households are asked to build up their resilience to crises. Local, distributed electricity production within a microgrid with capability to operate disconnected from the larger grid has been shown to be an effective tool for increasing power system resilience in the past. The energy production of local renewable sources is, however, not sufficient in meeting normal household energy demand. This thesis explores whether the forming of communities can be utilised to reduce energy demand and as a result, increase the resiliency of both the community and urban environments. The analysis of household energy use and the subsequently developed toolbox provide insights into energy use both under normal societal function and during a crisis. Through living and cooking together as a community, significant energy-efficiency gains were possible, exceeding those reasonably achieved within each individual household. Community was further determined to be important in the planning and development of more resilient combinations of renewable energy, going beyond solar power. When implemented in theoretical scenarios, energy communities at a building and block level could provide sufficient energy for the households’ most immediate needs without major sacrifices of wellness. The scheme proposed is argued to require not only monetary investments, but also larger societal shifts. Producing sufficient quantities of electricity within urban environments will mean a large change in how cities are experienced. Public understanding and acceptance for such a change is likely to be necessary. Through the implementation, the role of the municipality would go from action-taking to mostly laying the groundwork for the formation of communities, as well as advising these as they achieve higher household resilience. Most critically, however, there is a need for the broader population to embrace working together in communities.

O crescimento na geração de rejeitos de equipamentos elétricos e eletrônicos (REEE), legislações mais rigorosas e o valor agregado destes materiais incentivam o desenvolvimento de tecnologias de reciclagem. Contudo, a reciclagem dos componentes poliméricos dos REEE (CP-REEE) precisa superar desafios como a degradação durante o uso e reprocessamento, a presença de diferentes aditivos nos rejeitos e a depreciação de propriedades causada pela mistura não controlada de polímeros. Assim, o objetivo deste trabalho foi desenvolver um estudo sobre a reciclagem mecânica na forma de blendas poliméricas de rejeitos do copolímero acrilonitrila-butadieno-estireno (ABS) e do poliestireno de alto impacto (HIPS), empregando agentes compatibilizantes. No desenvolvimento do trabalho foram realizadas a caracterização dos CP-REEE, análise das propriedades mecânicas, químicas, térmicas e morfológicas dos polímeros e das blendas de ABS/HIPS nas proporções de 1:3, 1:1 e 3:1 com variações na composição dos polímeros reciclados e virgens e por fim, realizado um estudo do envelhecimento foto-oxidativo acelerado de uma blenda ABS/HIPS. Os resultados mostraram que os polímeros ABS e HIPS reciclados ainda apresentam boas propriedades mecânicas e que a presença de agentes compatibilizantes provoca o aumento da tenacidade nas blendas ABS/HIPS. A incorporação de polímeros virgens nos materiais reciclados não promove ganho significativo nas propriedades mecânicas das blendas. Blendas com até 50% de ABS demonstraram ter propriedades próximas às do HIPS, enquanto as blendas com altos teores de ABS não alcançaram valores de propriedades mecânicas similares aos do ABS virgem. O comportamento das propriedades das blendas virgens e recicladas frente ao envelhecimento fotoquímico foi similar, indicando que o material reciclado apresenta grande potencial para aplicações. O estudo de blendas ABS/HIPS de CP-REEE demonstra que o controle da composição das blendas definem a sua aplicação. / The growth in waste electrical and electronic equipment (WEEE) generation, directives more stringent and the aggregate value presents in these waste are encouraging the development of recycling technologies. However, recycling of polymeric components from WEEE (PC-WEEE) must overcome challenges such as degradation during use and reprocessing, the presence of various additives in the waste and the depreciation of properties caused by uncontrolled polymers mixture. The aim of this work was to develop a study of the mechanical recycling in the form blends with of polymeric waste of acrylonitrile-butadiene-styrene copolymer blends (ABS) and high impact polystyrene (HIPS) using compatibilizers. During the study was carried out the characterization of the PCWEEE and mechanical, chemical, thermal and morphological analysis of the polymers and the ABS / HIPS blends in proportions of 1:3, 1:1 and 3:1 with recycled and virgin polymers, as well as a study of the accelerated photo-oxidative aging of the ABS/HIPS blends. The results showed that ABS and HIPS recycled polymers still have good mechanical properties and the presence of compatibilization agents leads to increased toughness in ABS/HIPS blends. The incorporation of virgin polymers in recycled materials does not promote significant gain in the mechanical properties of the blends. Blends with up to 50% ABS have demonstrated to be closer to the HIPS, while blends with high content of ABS did not reach values of mechanical properties similar to the virgin ABS. The mechanical properties of virgin and recycled blends during the photochemical aging were similar, indicating that the recycled material has great potential for applications. The study of ABS/HIPS blends from PC-WEEE demonstrated that control of the blend composition establish their applications.

O crescimento na geração de rejeitos de equipamentos elétricos e eletrônicos (REEE), legislações mais rigorosas e o valor agregado destes materiais incentivam o desenvolvimento de tecnologias de reciclagem. Contudo, a reciclagem dos componentes poliméricos dos REEE (CP-REEE) precisa superar desafios como a degradação durante o uso e reprocessamento, a presença de diferentes aditivos nos rejeitos e a depreciação de propriedades causada pela mistura não controlada de polímeros. Assim, o objetivo deste trabalho foi desenvolver um estudo sobre a reciclagem mecânica na forma de blendas poliméricas de rejeitos do copolímero acrilonitrila-butadieno-estireno (ABS) e do poliestireno de alto impacto (HIPS), empregando agentes compatibilizantes. No desenvolvimento do trabalho foram realizadas a caracterização dos CP-REEE, análise das propriedades mecânicas, químicas, térmicas e morfológicas dos polímeros e das blendas de ABS/HIPS nas proporções de 1:3, 1:1 e 3:1 com variações na composição dos polímeros reciclados e virgens e por fim, realizado um estudo do envelhecimento foto-oxidativo acelerado de uma blenda ABS/HIPS. Os resultados mostraram que os polímeros ABS e HIPS reciclados ainda apresentam boas propriedades mecânicas e que a presença de agentes compatibilizantes provoca o aumento da tenacidade nas blendas ABS/HIPS. A incorporação de polímeros virgens nos materiais reciclados não promove ganho significativo nas propriedades mecânicas das blendas. Blendas com até 50% de ABS demonstraram ter propriedades próximas às do HIPS, enquanto as blendas com altos teores de ABS não alcançaram valores de propriedades mecânicas similares aos do ABS virgem. O comportamento das propriedades das blendas virgens e recicladas frente ao envelhecimento fotoquímico foi similar, indicando que o material reciclado apresenta grande potencial para aplicações. O estudo de blendas ABS/HIPS de CP-REEE demonstra que o controle da composição das blendas definem a sua aplicação. / The growth in waste electrical and electronic equipment (WEEE) generation, directives more stringent and the aggregate value presents in these waste are encouraging the development of recycling technologies. However, recycling of polymeric components from WEEE (PC-WEEE) must overcome challenges such as degradation during use and reprocessing, the presence of various additives in the waste and the depreciation of properties caused by uncontrolled polymers mixture. The aim of this work was to develop a study of the mechanical recycling in the form blends with of polymeric waste of acrylonitrile-butadiene-styrene copolymer blends (ABS) and high impact polystyrene (HIPS) using compatibilizers. During the study was carried out the characterization of the PCWEEE and mechanical, chemical, thermal and morphological analysis of the polymers and the ABS / HIPS blends in proportions of 1:3, 1:1 and 3:1 with recycled and virgin polymers, as well as a study of the accelerated photo-oxidative aging of the ABS/HIPS blends. The results showed that ABS and HIPS recycled polymers still have good mechanical properties and the presence of compatibilization agents leads to increased toughness in ABS/HIPS blends. The incorporation of virgin polymers in recycled materials does not promote significant gain in the mechanical properties of the blends. Blends with up to 50% ABS have demonstrated to be closer to the HIPS, while blends with high content of ABS did not reach values of mechanical properties similar to the virgin ABS. The mechanical properties of virgin and recycled blends during the photochemical aging were similar, indicating that the recycled material has great potential for applications. The study of ABS/HIPS blends from PC-WEEE demonstrated that control of the blend composition establish their applications.

Les homopolymères à base de polypropylène isotactique (iPP en anglais) ont une rigidité plus élevée que le polyéthylène (PE), mais aussi une dureté limitée, en particulier à températures plus basses. Ceci peut être surmonté en incorporant un élastomère copolymère d'éthylène et de propylène directement dans la matrice semi-cristalline de iPP. De tels mélanges obtenus in situ dans des réacteurs successifs sont bien connus, et leur production nécessite un procédé multi-étapes. De façon succincte, un procédé industriel pour la synthèse de PP choc (hiPP, high impact PP en anglais) implique 2 zones de réaction (chaque zone peut être composée d'un ou plusieurs réacteurs). L’iPP est fabriqué dans la première zone. Les poudres encore actives sont ensuite dégazées et envoyées dans une seconde zone dans laquelle est incorporé un élastomère (généralement un copolymère de propylène et d'éthylène appelé caoutchouc éthylène-propylène (ethylene-propylene rubber (EPR) en anglais). L'homopolymère iPP peut être produit en phase gaz ou en suspension (slurry en anglais) dans un hydrocarbure, alors que l'EPR doit être fabriqué dans un réacteur en phase gaz. Dans la thèse actuelle, nous nous sommes concentrés sur les procédés intégralement en phase gaz. Par conséquent, la morphologie du polypropylène choc (hiPP) dépendra fortement de celle de l'iPP intermédiaire, qui, à son tour, dépendra de la morphologie du précatalyseur. Cependant, le même précatalyseur peut conduire à différentes morphologies d’iPP, selon le protocole d'injection suivi. L'injection de catalyseur est donc un aspect critique de la production du hiPP. Cet aspect a été étudié grâce à la réalisation d'un plan d'expériences de polymérisation du propylène. On a utilisé des catalyseurs supportés Ziegler-Natta (ZN), disponibles commercialement, dans un réacteur à cuve agitée et un réacteur phase gaz à flux stoppé. On a mis en évidence pourquoi la prépolymérisation et le mouillage du catalyseur par un hydrocarbure avant d'être introduits dans le réacteur assurent de hautes activités et un contrôle de la morphologie des particules de polymère tout en produisant l'iPP. Au cours de la production de l’hiPP, la thermodynamique de sorption de la phase gaz a un impact important sur la cinétique d'homopolymérisation et de copolymérisation du propylène. Par exemple, les hydrocarbures supérieurs améliorent la solubilité du propylène dans le polymère (phénomène de «co-solubilité») ce qui conduit à une augmentation de l'activité. De plus, la solubilité et la diffusivité des différents monomères (et de leurs mélanges) utilisés pour produire l’hiPP (propylène, éthylène et mélange éthylène / propylène) dans les poudres dépendent des températures et des pressions auxquelles le procédé est conduit. Les données expérimentales de ces quantités ont été obtenues et des modèles semi-empiriques généralement utilisés dans l'industrie des polyoléfines ont été utilisés pour comprendre leur dépendance à l'égard des conditions du procédé. Finalement, plusieurs poudres d’hiPP ont été obtenues dans le réacteur à cuve agitée avec un catalyseur ZN supporté, en suivant la voie intégrale phase gaz. La morphologie de la matrice iPP et les conditions de la copolymérisation telles que la quantité de copolymère, la température, la pression, la quantité relative d'éthylène par rapport au propylène et la présence d'hydrogène ont été systématiquement variées pour comprendre leur impact sur la répartition du caoutchouc dans la matrice PP. Ce facteur est, à son tour, crucial pour (1) un fonctionnement du procédé industriel optimal, et (2) les propriétés mécaniques recherchées de l'hiPP / Isotactic Polypropylene (iPP) homopolymers have higher stiffness than polyethylene (PE), but also limited toughness, especially at lower temperatures. This can be overcome by incorporating an elastomeric copolymer of ethylene and propylene directly in the semi crystalline iPP matrix. Such in situ reactor blends are well-known, and their production requires of multi-step reaction process. Very briefly, an industrial process for high impact polypropylene (hiPP) products involves 2 reaction zones (each zone can be composed of one or more reactors). iPP is made in the first zone, the still active powders are then degassed and sent to a second zone in which an elastomer (usually a copolymer of propylene and ethylene referred to as Ethylene-Propylene Rubber (EPR)) is made. The iPP homopolymer can be produced in the gas phase or slurry phase, whereas the EPR must be made in a gas phase reactor. In the current thesis, our focus was on an “all gas phase”process.Therefore, the morphology of hiPP will be greatly dependent on that of the intermediate iPP, which in turn, will depend on the precatalyst morphology. However, the same precatalyst can lead to different iPP morphologies, depending on the injection protocol followed. Therefore, catalyst injection is a critical aspect while producing hiPP. Such aspect has been studied by performance of a designed set of propylene polymerization reaction experiments. Commercially available supported Ziegler-Natta (ZN) catalysts along with a lab-scale stirred-bed reactor and a gas phase stopped flow reactor have been used. It is understood why prepolymerization and wetting the catalyst with hydrocarbon before being charged to the reactor ensure high activity and quality morphology while producing iPP. During the production of hiPP, sorption thermodynamics of the gas phase have a big impact on propylene homopolymerization and copolymerization kinetics. For instance, higher hydrocarbons enhance the propylene solubility in polymer (which is known as “cosolubility” phenomenon) which leads to an activity increase. In addition, the solubility and diffusivity of the different monomers used to produce hiPP (propylene, ethylene and ethylene/propylene mixtures) in the powders depend on the temperatures and pressures which the process is conducted at. Experimental data of these quantities was obtained and semi-empirical models generally used in the polyolefin industry were used to understand their dependence on the process conditions. Finally, several hiPP powders were made in the lab-scale stirred-bed reactor with a supported ZN catalyst, following the “all gas phase” route. The morphology of the iPP matrix and conditions during copolymerization such as amount of copolymer, temperature, pressure, relative amount of ethylene to propylene and the presence of hydrogen have been systematically varied to comprehend their impact on the rubber distribution among the PP matrix. The aforementioned factor is, in turn, crucial for (1) a correct industrial process operation, and (2) the mechanical properties sought-after in hiPP