MESMEG / Department of Mining and Environmental Geology / Many recent studies have shown that some of the greatest water needs occur in areas underlain by crystalline rocks with complex hydrogeology. Crystalline basement rocks underlie over 60% of the South African surface, and the Limpopo Province of South Africa is no exception. Previous attempts to develop the lithologies of Limpopo for groundwater abstraction without the use of sound scientific methodologies resulted in low yielding boreholes and a higher rate of borehole failure. The complexity of the lithologies in the region necessitates the use of sound scientific methodologies for the delineation of promising groundwater potential zones. Therefore, the principal objective of the present study was to delineate groundwater potential zones through an integrated approach of remote sensing, geophysics, as well as the use of ancillary datasets. The area of focus is located in the northeastern section of Limpopo province, covering an area of about 16 800km2. Geologically, it is underlain by three Lithostratigraphic domains comprised of Archean-aged basement rocks, Soutpansberg volcano-sedimentary succession and subsidiary basins of the main Karoo young sedimentary cover. In general, the groundwater potential of a region is a function of factors such as lithology, lineaments, slope, climate and land use/ land cover. Thus, the present study used parameters such as lineaments, lithologies, slope, and land use/ land cover to produce a groundwater potential zone map. The thematic layers were prepared from raw datasets, which include; LANDSAT 8 OLI, ASTER-DEM, aeromagnetic data, geological maps, and land use/land cover data, which were overlaid in a GIS environment. The resultant groundwater map revealed the presence of five distinct classes of groundwater potential zones, which were categorised into excellent, good, moderate, low and very low. Interpretation of the results shows that the study area is dominated by areas that may be regarded as moderate water potential zones, covering about 52% of the total area. On the other hand, low and good groundwater potential zones occur in almost equal proportions of 19.52 % and 24 % respectively. The results obtained were validated using GRIP borehole dataset, and a number of follow-up geophysical surveys. iii Overlaying of the boreholes dataset on the map showed positive correlation between borehole yields groundwater potential zones. On the other hand, follow-up Vertical Electrical Sounding surveys revealed the presence of conductive layers in some selected target areas. The groundwater potential zone map and validation results provided a meaningful regional assessment of groundwater distribution in the study area. Thus, the results of this study can be used as a guideline for future groundwater exploration projects. / NRF

MESHWR / Department of Hydrology and Water Resources / Lebalelo area of Sekhukhune district is one of many areas in South Africa experiencing portable water scarcity, especially during prolonged dry season. Due to the dominance of low yielding aquifers in South Africa, it is essential to manage groundwater resources in these low yielding aquifers. However, the management of low yielding aquifer is difficult in areas like Labelelo where the hydrogeological characteristics of the aquifers are understudied. This study investigated the hydrogeological characteristics of the aquifers in the area using combined geophysical method and analytical groundwater models. Four newly drilled borehole and five existing boreholes were used for this study. Geophysical survey was carried out using magnetic and electromagnetic methods. The magnetic survey was used to locate the position of magnetic bodies such as dolerite dykes and different lithologies with different magnetic properties. The electromagnetic survey however, was used to determine zones of high permeability associated with the intrusive bodies as well as high permeability zones in fault planes. Step test, constant discharge test and recovery tests were conducted on all the boreholes to stress the borehole. This was used to determine a suitable and sustainable pumping rate of the aquifer. Pumping test data from the pumping period and recovery was evaluated and interpreted using AQTESOLVE. Aquifer transmissivity, storativity, internal and external hydraulic boundaries were determined from the data. The transmissivity in the area ranges from 0.08 to 124.7 m2/day. The aquifer types in the area are double porosity aquifer, radial flow aquifer with single porosity. Inductive Coupled Plasma (ICP-MS) was used to measure heavy metals, trace metals and cations while Ion Chromatography (IC) was used to determine anions in groundwater of the study area. The groundwater in the area is dominated by calcium carbonate as a result of long residence time with dolomite. The hydrochemistry of the water indicates that the chemistry of the groundwater in the area is mainly controlled by rock-water interaction. / NRF

MENVSC / Department of Ecology and Resource Management / Some boreholes in South Africa which serve as a source of drinking water for rural communities are reported to have high fluoride concentration, much above the WHO guideline of 1.5 mg/L. This study aimed at activating aluminosilicate clay soil mechanochemically, modifying aluminosilicate clay soil with Al-oxide and fabricating porous ceramic granules using Al-oxide modified mechanochemically activated aluminosilicate clay soil/ mechanochemically activated clay soil/ corn starch and evaluating their performances in defluoridation of groundwater. The raw clay materials were mechanochemically activated for 5, 10, 15 and 30 minutes for physicochemical transformation of the solid aggregate. The morphology of the samples showed the honeycomb structure. The surface area analyses of samples using Brunauer–Emmett–Teller (BET) gave the highest surface area of 50.5228 m2/g at 30 min activation time. Hence, the optimum activation time was 30 min. The Fourier Transform Infrared (FT-IR) analysis showed increase in the absorbance of FT-IR by Si-O-H groups at 510 cm-1 with increasing milling time. This is evidence that more surface Si-O-H groups were available at higher particle surface area that would be necessary to interact with fluoride. X-ray diffraction (XRD) analyses revealed that, at 30 minutes milling time, the peak broadening is intensified whereas the reflection peak intensities decreased. The X-ray fluorescence spectrometry (XRF) results for 30 minutes milling time showed that silica and alumina were the highest components in the clay soil. Using the activated clay in batch defluoridation of fluoride-spiked water, a maximum fluoride removal of 41% was achieved at a pHe of 2.41. The initial fluoride concentration was 9 mg/L while the sorbent dosage was 0.6 g/100 mL and the contact time being 30 minutes. The adsorption data fitted to both Langmuir and Freundlich isotherms. The adsorption data fitted only the pseudo-second-order kinetic, showing chemisorption. Optimization of Al3+ concentration for modification was carried out by modifying the mechanochemical activated aluminosilicate clay soil with different concentrations of Al3+ from which the optimum modification was achieved with 1.5 M. Characterisation studies on the Al-oxide modified mechanochemically activated aluminosilicate clay soil by SEM, BET, FT-IR, XRD and XRF, analyses were carried out to determine the resultant changes in physicochemical properties of the adsorbent owing to modification. The SEM image of Al-oxide modified mechanochemically activated clay soil showed many small pores and honey-comb structure on the surface of different images. The BET surface area and the BDH adsorption cumulative area of the Al-oxide modified mechanochemically activated v aluminosilicate clay soil were more than double those for the raw clay soil. There was also an increase in pore volume of the Al-oxide modified mechanochemically activated aluminosilicate clay soil. The FT-IR spectra showed that there was increase in the absorbance by the Si-OH, H-O-H, Al-O-H and Si-O-Al. The equilibrium pH of solution was higher than the point-of-zero charge (pHpzc) implying that fluoride removal occurred at solution pH > pHpzc where the net surface charge of the mechanochemically activated clay aluminosilicate soil was negative.The efficiency of 1.5 M Al-oxide modified aluminosilicate clay soil to remove fluoride from water was studied and found to be 96.5 % at pHe 6.86, contact time of 30 minutes and dosage of 0.3 g/100 mL for 10 mg/L fluoride solution at 200 rpm shaking speed. The result shows that Al-oxide modified mechanochemically activated aluminosilicate clay soil is effective for defluoridation. The adsorption data fitted to both Langmuir and Freundlich isotherms. The adsorption data fitted only the pseudo-second-order kinetic, showing chemisorption. Al-oxide modified mechanochemically activated aluminosilicate clay soil was tested for fluoride removal on field water and the percentage fluoride removal was 96.5 % at the dosage of 0.6 g/100 mL with the pHe of 6.48. The optimum Al-oxide modified mechanochemically activated aluminosilicate clay soil/ mechanochemically activated clay soil/ corn starch mixing ratio for fabrication of porous ceramic granules was determined by varying ratios and temperature. The optimum ratio found was 20:5:1.The porous ceramic granules were characterised using SEM, BET, FT-IR, XRD and XRF. SEM analysis showed that the porous ceramic granules have the porous structure of the organic foam template. The porous ceramic granule showed an increase in pore surface area and volume as compared to mechanochemically activated aluminosilicate clay soil. The FT-IR showed the presence of a strong broad bending and stretching vibrations band at about 993 cm-1 which shows the presence of Si–O–Si bonds. Mineralogical characterisation showed the presence of quartz, albite, horneblende and microcline as the main minerals of the calcined porous ceramic granules. The major oxides of the porous ceramic granules as shown by XRF analysis were SiO2, Al2O3, MnO and Na2O. The porous ceramic granules reduced the concentrations of fluoride in the water from 10 to 3.31 mg/L. The optimum adsorption capacity was 0.6648 mg/g at a pHe of 6.32 and the percentage fluoride removal was 66.9 % at an adsorbent dosage of 1.0063 g/100 mL and a temperature of 600 ⁰C. The porous ceramic granules were tested for fluoride removal on field water and the percentage fluoride removal was 45.4 % at the dosage of 1.0009 g/100 mL with the pHe of 7.87. Mechanochemically activated aluminosilicate clay soil showed higher adsorption capacity at acidic pH, therefore it is recommended that future work should focus on improving their adsorption capacity at wider range of pH. The porous ceramic granules can also be evaluated in column dynamic flow experiments.