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This thesis presents 1.3 mm and 3.1 mm continuum maps of seven star forming regions within the Large Magellanic Cloud (LMC) as observed with the Atacama Large Millimeter/Submillimeter Array (ALMA). The data were taken as part of six projects retrieved from the ALMA public archive plus one project observed specifically for this work. We developed a technique to combine Band 3 and Band 6 maps to estimate dust-only emission corrected for free-free emission contamination. We also present an automated \texttt{clean} masking script, with a listing of the code, which we adapted and used for all of the imaging in this thesis. From these observations we identify 32 molecular clumps in the LMC and estimate their total mass from their dust emission. We derive a cumulative clump mass function ($N(\geq M) \propto M^{\alpha+1}$) and fit it with a double power law to find $\alpha_{\mathrm{low}} = -1.76^{+0.07}_{-0.1}$, $\alpha_{\mathrm{high}} = -3.3^{+0.3}_{-0.6}$, and a break mass of $2500^{+700}_{-300}$ M$_{\odot}$. Comparing to the clump mass function derived by Indebetouw et al. (2013) from carbon monoxide spectral line emission for 30 Doradus-10 shows a consistent mass range of clumps between 205 $\mathrm{M}_{\odot}$ and 5740 $\mathrm{M}_{\odot}$ as well as consistency between their single power law fit and our low mass power law index. Also comparing to core and clump mass functions from several star forming regions in the Milky Way we find consistency between most of their high mass indices and our low mass index, which is where the clump mass ranges overlap. / Thesis / Master of Science (MSc)

Gas phase molecular clusters present an ideal medium for observing factors that drive chemical reactions without outside interferences from excessive solvent molecules. Introducing an ion into the cluster promotes ion-molecule interactions that may manifest in a variety of non-covalent or even covalent binding motifs and are of significant importance in many fields including atmospheric and astronomical sciences. For instance, in outer space, molecules are subject to ionizing radiation where ion-molecule reactions become increasingly competitive to molecule-molecule interactions. To elucidate individual ion-molecule interaction information, mass spectrometry was used in conjunction with appropriate theoretical calculations. Three main categories of experiment were conducted in this dissertation. The first of which were thermochemical equilibrium measurements where an ion was introduced to an ion mobility drift cell wherein thermalizing collisions occur with helium buffer gas facilitating a reversible reaction with a neutral molecule allowing the standard changes in enthalpy and entropy to be determined. The second type of experiment was an ion mobility experiment where an ionized homo- or hetero-cluster was injected into the drift cell at specific conditions allowing the reduced mobility and collisional cross-section to be evaluated. Thirdly, kinetics measurements were taken following injection of an ion into the drift cell were an irreversible reaction ensued with the neutral species hindering equilibrium, but prompting rate constant assessment. Previous research has laid the groundwork for this dissertation as the results and discussion contained herein will build upon existing data while maintaining originality. For example, past work has given support for ion-molecule reactions involving precursor species such as acetylene and hydrogen cyanide to form more complex organics, perhaps leading to biologically relevant species. The chemical systems studied for this research are either ionized substituted benzenes like phenylacetylene and benzonitrile or polycyclic aromatic nitrogen-containing hydrocarbons like quinoline and quinoxaline interacting with a variety of neutral species. Hydrogen bonding and its many sub-sections are of the utmost importance to the kinds of reactions studied here. Past work has shown the tendency of organic radical cations to form conventional and unconventional ionic hydrogen bonds with gas phase solvents. Other non-covalent modes of interaction have also been detected in addition to the formation of covalently bound species. Gas phase reactions studied here will explore, via mass-selected ion mobility, reversible and irreversible reactions leading to binding enthalpy and entropy and rate constant determination, respectively, in addition to collisional cross-section determination.

Hard Science-fiction shares a close relationship with the element of spectacle. This is especially apparent in Christopher Nolan’s Interstellar (2014), a film based in realistic science and emotional appeal. Nolan makes use of creating a team comprised of creative minds with different backgrounds. This includes theoretical physicist Kip Thorne, co-writer Jonathan Nolan, and composer Hans Zimmer. Together, the four develop a film that focuses on three main facets of science: time dilation, black holes, and dimensions. Incorporating these elements based in the historical world gives Interstellar its classification as hard science-fiction, a genre based more solidly in realistic science than classical science-fiction. Thorne serves as an executive producer and advisor to all matters scientific, Zimmer composes the score to accompany and intensify the moments of spectacle, and the Nolan brothers serve to create the plot behind Interstellar. The film’s spectacle can be seen throughout, notably in the “Miller’s Planet” and “Gargantua” scenes. Nolan also incorporates Welsh Poet Dylan Thomas’s “Do not go gentle into that good night” to exemplify the film’s theme of perseverance against increasing odds. It is through these elements that Interstellar serves itself as an exemplary film for showcasing the relationship between the nature of hard science-fiction and spectacle.

<p>In this thesis, we present theoretical and statistical techniques broadly related to systems of dynamically-interacting particles. We apply these techniques to observations of dense star clusters in order to study gravitational interactions between stars. These include both long- and short-range interactions, as well as encounters leading to direct collisions and mergers. The latter have long been suspected to be an important formation channel for several curious types of stars whose origins are unknown. The former drive the structural evolution of star clusters and, by leading to their eventual dissolution and the subsequent dispersal of their stars throughout the Milky Way Galaxy, have played an important role in shaping its history. Within the last few decades, theoretical work has painted a comprehensive picture for the evolution of star clusters. And yet, we are still lacking direct observational confirmation that many of the processes thought to be driving this evolution are actually occuring. The results presented in this thesis have connected several of these processes to real observations of star clusters, in many cases for the first time. This has allowed us to directly link the observed properties of several stellar populations to the physical processes responsible for their origins.</p> <p>We present a new method of quantifying the frequency of encounters involving single, binary and triple stars using an adaptation of the classical mean free path approximation. With this technique, we have shown that dynamical encounters involving triple stars occur commonly in star clusters, and that they are likely to be an important dynamical channel for stellar mergers to occur. This is a new result that has important implications for the origins of several peculiar types of stars (and binary stars), in particular blue stragglers. We further present several new statistical techniques that are broadly applicable to systems of dynamically-interacting particles composed of several different types of populations. These are applied to observations of star clusters in order to obtain quantitative constraints for the degree to which dynamical interactions affect the relative sizes and spatial distributions of their different stellar populations. To this end, we perform an extensive analysis of a large sample of colour-magnitude diagrams taken from the ACS Survey for Globular Clusters. The results of this analysis can be summarized as follows: (1) We have compiled a homogeneous catalogue of stellar populations, including main-sequence, main-sequence turn-off, red giant branch, horizontal branch and blue straggler stars. (2) With this catalogue, we have quantified the effects of the cluster dynamics in determining the relative sizes and spatial distributions of these stellar populations. (3) These results are particularly interesting for blue stragglers since they provide compelling evidence that they are descended from binary stars. (4) Our analysis of the main-sequence populations is consistent with a remarkably universal initial stellar mass function in old massive star clusters in the Milky Way. This is a new result with important implications for our understanding of star formation in the early Universe and, more generally, the history of our Galaxy. Finally, we describe how the techniques presented in this thesis are ideally suited for application to a number of other outstanding puzzles of modern astrophysics, including chemical reactions in the interstellar medium and mergers between galaxies in galaxy clusters and groups.</p> / Doctor of Philosophy (PhD)

<p>We present an observational protocol to observe and interpret asymmetries in stellar explosions using scattered light echoes. Spectroscopy of multiple light echoes are used to observe single astronomical sources from multiple viewing angles, allowing for direct observations of explosion asymmetries, when they exist. We present asymmetry detections for two famous historical supernovae: the ~25-year-old SN 1987A and the ~330-year-old Cassiopeia A. In both supernovae we find asymmetries in the first few hundred days of the explosion that appear to be correlated with the geometry of Fe-rich material in the remnant states.</p> <p>Spectroscopy of SN 1987A light echoes reveals a variation in the Hα line profile as a function of echo azimuth, with maximum asymmetry at position angles 16◦ and 186◦, in agreement with the major-axis of the elongated remnant ejecta. We interpret our asymmetry detection as evidence for a two-sided distribution of high-velocity 56Ni in the first few hundred days of SN 1987A, with the most dominant asymmetry redshifted in the south. For Cassiopeia A, we find evidence for a ~4000 km/s velocity excess in the first hundred days of the explosion, roughly aligned with an Fe-rich outflow in the supernova remnant and approximately opposite in direction to the motion of the compact object.</p> <p>Core-collapse supernovae have not yet been successfully modelled despite decades of progress in input physics and computing capability. Despite the significance of thermonuclear Type Ia supernovae to cosmology, the progenitor systems and explosion details also remain unclear. Both observational and theoretical work suggest that non-spherical effects are not only common in supernovae, but may in fact aid in generating successful explosions. In addition to offering a new technique for observing supernova asymmetries, spectroscopy of scattered light echoes allows a direct causal connection to be made between stellar explosions and their observed remnant states.</p> / Doctor of Philosophy (PhD)

<p>The formation of star clusters occurs in a complex environment and involve a large number of physical processes. One of the most important processes to consider is radiative feedback. The radiation released by forming stars heats the surrounding gas and suppresses the fragmentation of low mass objects. Ionizing radiation can also drive large scale outflows and disperse the surrounding gas. Owing to all this complexity, the use of numerical simulations to study cluster formation in molecular clouds has become commonplace. In order to study the effects of radiative feedback on cluster formation over larger spatial scales than previous studies, we present hydrodynamical simulations using the AMR code FLASH which make use of cluster particles. Unlike previous studies, these particles represent an entire star cluster rather than individual stars. We present a subgrid model for representing the radiative output of a star cluster which involves randomly sampling an IMF over time to populate the cluster. We show that our model is capable of reproducing the properties of observed clusters. The model was then incorporated into FLASH to examine the effects of radiative feedback on cluster formation in full hydrodynamical simulations. We find that the inclusion of radiative transfer can drive large scale outflows and decreases the overall star formation efficiency by a factor of 2. The inclusion of radiative feedback also increases the degree of subclustering. The use of cluster particles in hydrodynamical simulations represents a promising method for future studies of cluster formation and the large scale effects of radiative feedback.</p> / Master of Science (MSc)

Le travail que je présente dans cette thèse est un travail principalement expérimental effectué au sein du laboratoire LAMAp de l'Université de Cergy-Pontoise, à l'aide du dispositif expérimental appelé FORMOLISM. Les principaux composants de ce dispositif sont: l'ultravide (10-10 mbar), l'ultra-froid (~5 K), des jets atomiques, la spectrométrie de masse TPD (Thermally Programmed Desorption) et la spectroscopie laser dans l'UV mettant en oeuvre des longueurs d'onde autour de ~200 nm. Grâce à la technique REMPI-TOF (Resonantly Enhanced Multi-Photon Ionization – Time Of Flight), nous avons étudié d'une part, la conversion de spin nucléaire de la molécule d'hydrogène H2 sur une surface de glace d'eau amorphe poreuse et d'autre part les processus de formation de cette molécule, qui est la plus abondante dans le milieu interstellaire, sur des surfaces simulant des grains de poussière interstellaire. Les résultats de cette étude présentent un intérêt capital en astrophysique. En effet cette formation ne peut se produire en phase gaz mais peut être expliquée par la rencontre de deux atomes d'hydrogène sur un grain de poussière du milieu interstellaire qui joue le rôle de catalyseur. Différents processus sont impliqués dans la formation de H2 qu'il s'agit d'identifier. Dans ce but, je présente des résultats entièrement nouveaux sur la formation de H2 moléculaire sur une surface de silicate amorphe. Je montre que la molécule peut se former dans un état rovibrationnellement excité de son niveau fondamental jusqu'à une température d'environ 70K et qu'elle est relâchée dans la phase gaz immédiatement après sa formation. Ces résultats démontrent la compétition entre deux mécanismes de formation à très basses température (<18 K) tandis qu'un autre mécanisme prend le relais jusqu'à 70K. / The work that I present in this thesis is primarily an experimental work carried out in the LAMAp laboratory at the University of Cergy-Pontoise, using the experimental device called FORMOLISM. The main components of this device are: ultra-high vacuum (10-10 mbar), ultra-low temperature (~5 K), atomic jets, TPD mass spectrometry (Thermally Programmed Desorption) and laser spectroscopy using ultraviolet wavelengths around ~200 nm. Thanks to the REMPI-TOF (Resonantly Enhanced Multi-Photon Ionization – Time Of Flight) technique, we have studied i) the nuclear spin conversion of the hydrogen molecule H2 on a porous amorphous water ice surface and ii) the processes of formation of this molecule, which is the most abundant in the interstellar medium, on surfaces simulating interstellar dust grains. The results of this study are of capital interest in astrophysics. Actually, this formation cannot occur in the gas phase but can only be explained by the encounter of two hydrogen atoms on a dust grain in the interstellar medium, the latter playing the role of a catalyst. Different processes are involved in the formation of H2 which require to be identified. With this aim, I present entirely new results on molecular H2 formation on an amorphous silicate surface. I show that the molecule can form in a rovibrationnally excited state of its ground state up to a temperature of about 70 K and that the molecule is released into the gas phase immediately after its formation. These results demonstrate the competition between two mechanisms of formation at very low temperature (<18 K) while another mechanism takes over up to 70 K.