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The effects of lime content and environmental temperature on the mechanical and hydraulic properties of extremely high plastic claysAli., H., Mohamed, Mostafa H.A. 25 April 2018 (has links)
Yes / This paper focuses on monitoring the evolution of lime-clay reactions using geotechnical parameters as a function of lime content and environmental temperature. Lime contents of 5, 7, 9, 11 and 13% by dry weight of expansive clay powder were added to prepare lime-clay specimens. The specimens were prepared at the same dry unit weight of 12.16 kN/m3 and moisture content of 40% except for tests aimed at the determination of dry unit weight as a function of mellowing period. Prepared specimens were mellowed or cured at two different ambient temperatures of 20 °C and 40 °C. Results attained from Unconfined Compressive Strength and permeability tests were employed to assess the impact of lime content on the mechanical and hydraulic properties of lime treated expansive clays. The results revealed that at the beginning, the rate of strength gain is remarkably fast for a particular period of time which is dependent on lime content. Furthermore, the strength gain on specimens cured at 40 °C is 8 times higher than that observed on specimens cured at 20 °C which highlights significant effect for the environmental temperature on accelerating the chemical reactions. Reduced dry unit weight due to increased resistance to compactability is observable with increasing lime content and higher environmental temperature. Accelerated pozzolanic reaction at higher environmental temperature resulted in permeability coefficient of specimens mellowed for 24 h at 40 °C to be higher than those mellowed at 20 °C. The results also highlighted that the permeability coefficient would be relatively stable when expansive clays were treated with small amounts of lime e.g. 5%.
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The Impact of moisture and clay content on the unconfined compressive strength of lime treated highly reactive claysMuhmed, A., Mohamed, Mostafa H.A., Khan, A. 06 September 2022 (has links)
Yes / This study aims to provide a thorough evaluation for the changes in the microstructure and evolution of strength of highly reactive clays that were treated with 7 % lime over a period of curing time as a function of the mixing moisture content. Three series of testing were carried out on specimens with 100 %, 85 % and 75 % of bentonite content and prepared with different moisture content of 10, 20, 30 and 40 % above the corresponding optimum moisture content. Specimens of 100 % bentonite were treated with 7 % of lime, compacted to achieve a predetermined dry unit weight and cured at temperatures of 20 OC and 40 OC for up to 28 days whereas the specimens with 85 % and 75 % of bentonite content were prepared by the addition of sand and were cured at 20 oC for up to 7 days. Unconfined Compressive Strength tests and Scanning Electron Microscopy were conducted to observe the strength and the microstructural changes resulting from increasing mixing moisture content. California Bearing Ratio and Resilient Modulus were correspondingly determined based on correlations with the Unconfined Compressive Strength. The failure pattern was also studied to better understand the ultimate behaviour of lime stabilised clays. The results revealed that the strength of treated bentonite increased with the increase in the moisture content up to 30 % above the corresponding optimum moisture content and with increasing the curing time and temperature. Nevertheless, substituting bentonite with sand on the specimen resulted in a significant reduction on the attained strength. Furthermore, the results of California Bearing Ratio and Resilient Modulus showed that values for both parameters are significantly enhanced with lime treatment. The microstructural analysis provided visual evidence to the improved strength in which the pozzolanic reaction was found to be significantly affected by the amount of moisture in the mixture. The results suggested that compacting lime treated expansive clays with moisture content moderately higher than the optimum moisture content would result in a significant enhancement to the attained strength over the period of curing.
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TRANSFORMING WASTES AND INDUSTRIAL BYPRODUCTS INTO SUSTAINABLE CONSTRUCTION MATERIALS FOR PAVEMENT SUBGRADE LAYERSFayemi, Joshua Ayobami 01 August 2024 (has links) (PDF)
Waste generation is a constant activity of daily life, encompassing a wide variety including municipal, hazardous, industrial, agricultural, medical, radioactive, and mining waste, as well as sewage sludge. The purpose of this study is to concentrate on utilizing industrial waste, which adversely affects our environment, for use in engineering construction projects. This aims to evaluate the enhancement in both the soil’s index and engineering properties. In most civil engineering projects, the underlying soils are often unsuitable for construction purposes. Some of these soils experience significant volume changes due to moisture variations, leading to damage and instability of structures and infrastructure built on them. The complete removal and replacement of such high plastic clay and expansive soils is not always a cost-effective solution. Therefore, there's a pressing need to improve their utility by stabilizing them through eco-friendly and sustainable methods.The present research employs five industrial waste materials to enhance the clayey soil available in Carbondale, Illinois. These waste materials include Lime Sludge (LS), Lime Kiln Dust (LKD), Fly Ash (FA), Ground Granulated Blast Furnace Slag (GGBS), and Cement Kiln Dust (CKD). Lime Sludge and Lime Kiln Dust were mixed with the soil at proportions of 2%, 4%, 6%, and 8%. In contrast, Fly Ash and Cement Kiln Dust were used at higher ratios of 8%, 16%, 24%, and 32%. Lastly, Ground Granulated Blast Furnace Slag was added at levels of 5%, 10%, 15%, and 20%, all based on the soil's dry unit weight. The samples were prepared for Unconfined Compression Strength (UCS) and Resilient Modulus (RM) based on the Optimum Moisture Content (OMC) and Maximum Dry Density (MDD) data obtained from miniature Proctor test. These specimens underwent a 14-day curing period, sealed in plastic film and Ziploc bags, and were stored in a controlled water tub at room temperature. The UCS value for the untreated Carbondale soil was 320 kN/m2. The results indicated that with higher content of Lime Kiln Dust (LKD) and Cement Kiln Dust (CKD), the UCS strength tends to increase with CKD exhibiting the most desirable strength characteristics. The UCS value for 8% LKD was 1377.70 kN/m2 i.e., 330.52% increase. While the UCS improvements for 5% GGBS is 51.32% and 6% Lime Sludge (LS) is 51.65% with no significant enhancements, these waste materials can be more effective as modifiers. Furthermore, the study revealed that the optimal quantity of Class F fly ash for soil stabilization is 8% by dry unit weight with UCS value of 486.46 kN/m2 resulting in 52.01% increase in UCS strength, exceeding this percentage might cause reduction in strength. The highest UCS strength was obtained with 24% CKD at 3263.14 kN/m2 which corresponds to 919.70% increase when compared to the untreated soil. The results of the Resilient Modulus (RM or Mr) test indicate that the incorporation of additives to untreated Carbondale soil significantly improved its stiffness characteristics and resistance to different load cycles on the subgrade. However, the soil treated with GGBS showed a decrease in stiffness. The Resilient Modulus values ranged from 2% to 70% for LS, 47% to 128% for LKD, 4% to 35% for FA, 90% to 243% for CKD, and -16% to 0.3% for GGBS for different confining pressures. The regression analysis, using the Uzan (1985) model, showed R² values of 0.910, 0.838, 0.803, 0.871, 0.773, and 0.809 for Carbondale soil, Carbondale soil mixed with 6% LS, 8% LKD, 8% FA, 5% GGBS, and 24% CKD, respectively. These results confirm the reliability of the test, as all samples except the GGBS-treated one have R² values greater than 0.800. Additionally, consolidation tests were conducted to assess the compressibility characteristics of the additives in the soil. The selected samples were those with the mix proportions that yielded the highest UCS strength for each additive. These samples were meticulously prepared based on the moisture-density relationship obtained from the miniature Proctor test and were subjected to loading and unloading in a specific sequence. The results indicated an increase in the Compression Index (Cc) for mixtures with LS, LKD, FA, and CKD. Conversely, the mix containing GGBS displayed a reduction in the Compression Index (Cc). The Carbondale soil stabilized with 6% LS can be used for subbase stabilization as the UCS strength is greater than 345 kPa. Also, 2 to 8% LKD content can be used for subbase and base course stabilization. 8% FA without any activator can be used for subbase stabilizer. GGBS can be used for subbase soil stabilization and finally CKD can be used for both subbase and base course stabilization.
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Vliv etherů celulózy na vlastnosti hydraulického vápna / Effect of cellulose ethers on properties of hydraulic limeSkoupil, Jakub January 2019 (has links)
This diploma thesis deals with the study of the influence of cellulose ethers on the properties of hydraulic lime mortars. The availability and price of cellulose ethers in the industrial market is very favorable, but we can´t meet with studies using cellulose ethers in building materials, where lime is used as a binder. Cellulose ethers are commonly used as thickening agents in cement-based materials. The purpose of this diploma thesis is to review if cellulose ethers are appropriate for use in hydraulic lime mortars, either as water retention agents that contribute by water retention to better hydration of hydraulic binder components or to affect the properties of mortar in the fresh state. The theoretical part is dedicated to cellulose ethers, especially their production and how they influence the properties of building materials. In the practical part, the thesis deals with the influence of the dose of five different types of cellulose ethers on the properties of hydraulic lime. The properties in the fresh state and the physical-mechanical properties of mortars were monitored over time.
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Evaluation of Laboratory Durability Tests for Stabilized Subgrade SoilsParker, John Wesley 17 May 2008 (has links) (PDF)
The Portland Cement Association commissioned a research project at Brigham Young University to compare selected laboratory durability tests available for assessing stabilized subgrade materials. Improved understanding of these tests is needed to enable more objective selection of durability tests by design engineers and to facilitate more meaningful comparisons of data obtained for different stabilizer treatments using different evaluation procedures. The laboratory research associated with this project involved two subgrade materials, four stabilizers at three concentrations each, and three durability tests in a full-factorial experimental design. The two subgrade soils used were a silty sand and a lean clay, while the four stabilizer types included Class C fly ash, lime-fly ash, lime, and Type I/II portland cement. The three tests used in this comparative study were the freeze-thaw test, the vacuum saturation test, and the tube suction test. On average, to achieve the same 7-day unconfined compressive strength (UCS) values, the sand required 4.4 times more Class C fly ash than cement, 3.6 times more lime-fly ash than cement, and 6.0 times more lime than cement. Likewise, the clay required 10 times more Class C fly ash than cement, 7.5 times more lime-fly ash than cement, and 1.8 times more lime than cement. Analyses of the test results indicated that the UCS and retained UCS were higher for specimens tested by vacuum saturation than the corresponding values associated with freeze-thaw cycling. This observation suggests that the freeze-thaw test is more severe than the vacuum saturation test for these particular fine-grained materials. Testing also suggested that specimens with 7-day UCS values below 200 psi will generally not survive freeze-thaw cycling. After both freeze-thaw and vacuum saturation testing, the sand specimens treated with lime-fly ash had significantly higher UCS and retained UCS than specimens treated with Class C fly ash, lime, or cement. Similarly, the clay specimens treated with Class C fly ash or lime-fly ash had significantly higher UCS values than specimens treated with cement or lime; however, clay specimens treated with Class C fly ash and lime-fly ash were not significantly different. None of the four stabilizer types were significantly different from each other with respect to retained UCS after vacuum saturation testing. Dielectric values measured in tube suction testing were lowest for specimens treated with lime-fly ash and cement with respect to the sand and for specimens treated with Class C fly ash and cement with respect to the clay. The lime-fly ash and cement successfully reduced the dielectric value of sand specimens to a "marginal" rating, while no stabilizer reduced the moisture susceptibility of the clay to a satisfactory level. A strong correlation was identified between UCS after the freeze-thaw test and UCS after the vacuum saturation test, while very weak correlations were observed between the final dielectric value after tube suction testing and all other response variables. Differences in variability between test results were determined to be statistically insignificant in an analysis of the CVs associated with data collected in this research. Although the freeze-thaw test utilized in this research was determined to be more severe than the vacuum saturation test for materials similar to those tested in this study, the vacuum saturation test is recommended over both the freeze-thaw and tube suction tests because of the shorter test duration, usability for specimens with 7-day UCS values even below 200 psi, and lack of a need for daily specimen monitoring.
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Выбор моделей машинного обучения для внедрения системы оценки кредитоспособности клиентов банка : магистерская диссертация / Selection of machine learning models for the implementation of the bank's customer creditworthiness assessment systemЗайцев, А. В., Zaitsev, A. V. January 2024 (has links)
В работе сравниваются алгоритмы машинного обучения для задачи оценки вероятности дефолта заёмщика и применяются методы интерпретации локальных предсказаний. / The paper compares machine learning algorithms for the problem of estimating the probability of borrower default, and applies methods for interpreting local predictions.
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Effect of lime additions and bulk chromium content on chromium deportment in smelter matte-slag systemsDu Preez, Rudolph C. 03 1900 (has links)
Thesis (MScEng) –Stellenbosch University, 2010 / ENGLISH ABSTRACT: More mining houses are turning their attention to the processing of ore mined
from the UG2 reef. This is mainly due to the depletion of the Merensky reef
or the low availability of ore from the Platreef. With the higher UG2 ore
concentration in the process feed, companies experience more problems with
the processing of the ore due to its high chrome content. Although there are
various possible solutions to the problems experienced in the processing of UG2
ore, very little of thise solutions are actually implemented in the industry.
When smelting chrome-bearing ore, the chrome can go to any of three
phases: matte phase, spinel phase or glass phase. If it reports to the furnace
matte phase it can lead to problems in the down stream processing. When
chrome forms part of the spinel phase it forms a solid, refractory-like material
which, to an extent, is an unwanted material inside the furnace. Lastly the
chrome can report to the glass phase (liquid phase) which is the more desireable
phase to which chrome should report to since it will have little or no impact
on downstream processing.
There were four main objectives for this research project namely to conduct
a literature review to understand the problem of chrome in the smelting
process, to do an experimental simulation of a matte and slag phase in one
crucible, to interpret the experimental results and compare the experimental
results to thermodynamic predictions obtained using FactSageTM.
From literature the following aspects were found to be important:
Silica structures
Research has shown that silica incorporates different metal ions into its
structures. When the metal ions are incorporated into the silica structures
they are seen as part of the glass phase. By incorporating cations such as
chromium into the silica structure the structure is able to maintain its neutral
electrical charge.
Basicity of slag
Oxides once melted will either donate or accept oxide ions. The group of
oxides that are in excess will determine whether that specific slag is acidic or
non acidic. This is important to our study since the basicity can determine
the stability of the spinel phase. Partial pressures
The partial pressure of the system is important since it forms part of the
equilibrium constant calculations - meaning that partial pressures determine
the stability of certain species. Currently different arguments exist as to how
the sulphur pressure inside a molten bath is maintained. What is important,
however, is that for the system in this research project a log oxygen partial
pressure of -8 and a log sulphur partial pressure of -3.5 was chosen. These
values were based on previous research done on PGM and copper smelting
processes.
Chrome deportment
Previous research on chrome deportment shows a relationship between temperature
and the amount of chromium dissolving into the glass phase as well as
an increased chromium(II)oxide solubility (when compared to chromium(III)oxide)
in a silicate melt. Regarding slag chemistry and chrome deportment very little
work has been published for the system found in the PGM industry but it is
mentioned that by adjusting certain slag additives (alumina, lime and silica)
the chrome deportment can be manipulated.
The scope of this project was to investigate the effect of chromium, lime
and silica on chrome deportment. More specifically, the effect of lime. The
reason being that lime was originally added as 10%wt of the feed stream in the
processing of Merensky ore to act as a fluxing agent. With the new furnace
design and higher power densities the slag are maintained at 200oC to 350oC
higher than when Merensky ore was smelted. With these higher slag temperatures
fluxing agents will play a smaller role meaning that lime additions
become less important. Literature studies also showed that additional lime in
a slag system can stabilize the spinel structure (which is an unwanted phase).
Removing lime would be advantageous out of a chrome presepective as well as
an economic point of view.
The research was conducted in three sections namely the determination of
the time required for this particular system to reach equilibrium, the investigation
of different additives on chrome deportment using a controlled atmosphere
and synthetic slags and, lastly, a comparison of the experimental results obtained
to thermodynamic predictions.
For the equilibration studies reaction time periods of 4,7,11 and 16 hours
were used. From the results it was found that the alumina crucible dissolved
into the glass phase continually. This indicated that equilibrium was not
reached. However, a reaction time, rather than an equilibrium time, was chosen
where the species and phases had enough time to react. This was based
on literature, on observations of species diffusing between the matte and slag
phase as well as on two-point analysis (diffusion gradients). A reaction time
of nine hours was chosen With the reaction time fixed, the effect of different slag additives on chrome
deportment was investigated. For the addition of chrome it was seen that an
1.5%wt increase in the starting material increased the chrome content of the
slag phase by 0.025%wt. For the same increase in chromium in the starting
materials the chrome content of the spinel phase increased by 2.1% indicating
that chromium has a tendency to report to the spinel phase. The increase
in chromium had a minor effect on the chrome content of the matte phase,
however, since the chrome content only increased from 0.025%wt to 0.028%wt.
Plotting the results showed that increasing the lime in the starting material
decreases the chromium content in the glass phase. For the 39%wt silica system
the chromium content in the glass phase decreased from 0.75%wt to 0.46%wt
for an increase in the lime content from 1.7%wt to 7.3%wt. The same trend was
seen for the 33%wt silica system. For the spinel phase an increase of 1.27%wt
was seen when the lime content of the starting materials was increased from
1.7%wt to 10.1%wt for a 33%wt silica system. The same increase in lime
increased the chrome content of the matte phase from 0.03%wt to 0.06%wt for
a 33%wt silica system.
Silica also proved to affect chrome deportment. Increasing the silica content
of the starting materials from 25%wt to 39%wt increased the amount of
chromium in the glass phase from 0%wt to 0.46%wt for a 10%wt lime system.
The same effect is seen for a lower lime content except that more chromium
were incorporated into the silica structure. A silica increase from 32.4%wt
to 39%wt resulted in a chromium decrease from 5.2%wt to 0% in the spinel
phase for a 10%wt lime system. The same trend was seen for the 1.5%wt lime
system. An increase in the silica levels lead to an increase in the chrome level
of the matte phase. When silica is increased from 32%wt to 39%wt the chrome
content of the matte phase increased from 0.06%wt to 0.07%wt.
The last part of the research project entailed the comparison of the trends
observed with the experimental results to trends obtained from thermodynamic
predictions. FactSageTM is a program that uses model equations to predict
the Gibbs free energies for different phases. The program is therefore also able
to predict the amount of different phases present at equilibrium. This is called
thermodynamic ”optimization”.
In section 6 trends that were observed from FactSageTM results are compared
to the trends found in the experimental results. It is important to note
that it is only trends that are evaluated and not actual values since FactSageTM
calculations are for a system that is at equilibrium and (as explained above)
this system is not at complete equilibrium. The comparison however was good.
Several trends found in the experimental results were confirmed by the results
from FactSageTM. These included the relationships of chromium fed versus
chromium spinel, lime fed versus chromium spinel, lime fed versus chromium
in glass, silica fed versus chromium in glass, silica fed versus chromium in
spinel and silica fed versus chromium in matte. To conclude, slag additions can be used to manipulate chrome deportment
to an extent. Secondly, FactSageTM can be used for thermodynamic predictions
but a proper understanding as well as some form of validation of the
specific system investigated is still needed.
Due to time constraints and the difficulty of experimentally simulating this
multi-phase system in the lab, only a few parameters were investigated. In
order to obtain a more complete understanding of the system the effect of
partial pressures and temperature should also be investigated.
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Mobilaus dirvožemio rūgštumo analizės įrenginio darbo tyrimai / In Situ Mobile Sampling Equipment for Soil pH AnalysisBartkus, Tadas 16 June 2014 (has links)
Taikant tiksliojo ūkininkavimo sistemą atliekami dirvos, augalų būklės, tręšimo poreikio ir derlingumo matavimai. Naudojantis gautais duomenimis, darbo metu, koreguojami žemės ūkio mašinų technologiniai parametrai. Tokiu būdu optimizuojamos trąšų, kalkių, pesticidų, degalų ir laiko sąnaudos auginant ne tik žemės ūkio augalus maistui bei pašarams, bet ir energetinius augalus – biomasei. Eksperimentiniai tyrimai atlikti mobiliu Veris MSP įrenginiu su Soil pH Manager sistema. Įvertinus sudarytų dirvožemio pH žemėlapių tikslumą, galima teigti, kad įrenginio Veris MSP racionalus darbinis greitis yra 9 km/h. Greitį padidinus, įrenginys matavimo reikšmes fiksuoja didesniais tarpais, todėl lieka neišskirtos mažą plotą užimančios skirtingo pH lauko zonos. Važiuojant įrenginiu 3 km/h greičiu, įrenginio našumas siekė 6,50,5 ha/h, o 12 km/h greičiu – 26,52,2 ha/h. Atliktų dirvožemio rūgštumo tyrimų patikimumą įrodo gautas, dirvožemio pH nustatyto įrenginiu Veris MSP bei nustatyto laboratorijoje tiesinis tarpusavio ryšys (R2 = 0,81). Kalkių normą parinkus, pagal įrenginio duomenis sudarytus kalkinimo žemėlapius, sutaupoma apie 40% kalkių, lyginant su kalkinimu pagal žemėlapius, sudarytus laboratorijoje nustatytų pH reikšmių pagrindu. Kalkinant pagal laboratorijos duomenų vidurkį (vienoda 500 kg/ha norma), atskiri lauko plotai būtų nepakankamai pakalkinti arba perkalkinti. / Applying the system of precision agriculture, soil, plant condition, fertilisation demand, and fertility measures are taken. Using the data obtained, technological parameters of agricultural machines are adjusted in a course of work. In such a way the consumption of fertilisers, lime, pesticides, fuel, and time are optimised growing not only agricultural plants for food and feed, but also raising the materials for biomass. Experimental studies were carried out using a mobile unit Veris MSP with Soil pH Manager System. After the assessment of accuracy of the pH maps formed, it can be stated that the reasonable working speed of the unit Veris MSP is 9 km/h. Increasing the speed, the unit records the measurement values in greater spaces, thus leaving small areas of field with different pH values unmarked. Moving the unit at the speed of 3 km/h, the unit reached work efficiency of 6.5±0.5 ha/h and at 12 km/h – 26.5±2.2 ha/h. The reliability of the soil acidity research conducted is proved by the linear correlation of soil pH identified using the Veris MSP and the soil pH identified in the laboratory (R2 = 0.81). Selecting the lime rates according to the maps created using the data from the unit lime savings are about 40%, compared to the liming based on the maps created on pH values determined in the laboratory. When liming is done according to the average of laboratory data (equal to 500 kg/ha rate), some field areas are under-limed or over-limed.
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Sinterização de vidro soda-cal-sílica comercial assistida por campo elétrico / Commercial soda-lime-silica glass sintering assisted by electrical fieldBacha, Marcelo Gomes 31 May 2017 (has links)
Métodos de produção eficientes que economizam tempo e energia são sempre exigidos e novos processos de sinterização de baixo custo têm sido desenvolvidos para materiais cerâmicos e implementados por empresas e pesquisadores em todo o mundo. Com este objetivo, uma nova abordagem conhecida como Flash Sintering está atraindo grande interesse. Esta nova técnica de sinterização envolve a aplicação de campo elétrico através de uma amostra durante o aquecimento, gerando assim aceleração abrupta da cinética de densificação, diminuindo o tempo de sinterização de horas para segundos e diminuindo o aquecimento do forno em até centenas de graus Celsius. Frequentemente descritas para cerâmicas policristalinas e compósitos de cerâmica e vidro, a sinterização auxiliada por campo elétrico com apenas vidro não foi encontrado na literatura. A sinterização assistida por campo elétrico foi controlada com sucesso, sem que ocorresse o escoamento da amostra, obtendo uma elevada densidade relativa do vidro comercial. Um vidro de janela soda-cal-sílica não estequiométrica foi usado na pesquisa devido à sua importância comercial, por ser um material de partida de baixo custo, por apresentar condução iônica e haver na literatura dados de propriedades físicas e de cinética de sinterização convencional. O campo elétrico também influencia fortemente a cinética de sinterização do vidro soda-cal-sílica. Os resultados experimentais foram comparados com cálculos analíticos realizados a partir do modelo de Clusters não-isotérmico de sinterização de vidro por fluxo viscoso com cristalização concorrente. O aumento de temperatura nos compactos de pó de vidro durante o aquecimento do forno e aplicação de campo elétrico foi estimado usando um modelo de radiação de corpo negro. Preliminarmente, o aumento da temperatura devido ao efeito Joule pode explicar a diminuição da temperatura de amolecimento em comparação com a temperatura do forno e a sinterização rápida do vidro estudado. / Efficient production methods saving time and energy are always demanded and novel reduced-cost sintering processes have being developed for ceramic materials and implemented by companies and researchers of all over the world. With this aim, a new sintering approach generally known as flash sintering is attracting great interest. This new sintering technique involves the application of electric field through a sample while heating, thereby generating abrupt acceleration of the densification kinetics, decreasing the sintering time from hours to seconds and decreasing the oven heating in up to hundreds of degrees Celsius. Well described for polycrystalline ceramics and ceramic-and-glass composites, the sintering of pure glass aided by electric field is still lacking in the literature. The sintering assisted by electric field, was successfully controlled, without sample flow, achieved a high relative density of a commercial glass. A non-stoichiometric soda-lime-silica window glass was used due to its commercial importance, low cost starting material, ionic conduction, and literature on physical properties and conventional sintering kinetics. Electric field was observed to also strongly influence window glass sintering kinetics. The experimental results were compared with analytical calculations obtained from the non-isothermal Clusters model of glass sintering by viscous flow with concurrent crystallization. The temperature increase in the glass powder compacts during oven heating and electric field application was estimated by using a black-body radiation model. Preliminary, the temperature increase due to Joule effect can explain the softening temperature decrease compared with the oven temperature, and the fast sintering of the studied glass.
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Desenvolvimento de um sistema de aplicação localizada de calcário a taxas variáveis. / Development of a variable rate lime application system.Cerri, Domingos Guilherme Pellegrino 06 February 2002 (has links)
As distribuidoras de calcário convencionais existentes no mercado são projetadas para distribuir o calcário em doses constantes, sem levar em consideração a variabilidade espacial existente no terreno. A presente pesquisa teve como objetivo, projetar e construir um sistema de aplicação localizada de calcário a taxas variáveis. Este sistema, possibilita a distribuição diferenciada de calcário no solo. Isto é possível porque as coordenadas geográficas da distribuidora de calcário são obtidas através do Sistema de Posicionamento Global Diferencial - ("Differential Global Positioning System" - DGPS) e, essas coordenadas, juntamente com as informações de velocidade da máquina e um mapa de prescrição da quantidade de calcário para cada ponto da área, são transferidas para um microcomputador que regula automaticamente a máquina, para aplicar a quantidade adequada de calcário que o terreno deve receber. A distribuição deste insumo no solo foi regulada por um dispositivo dosador, controlado por um motor de passo. Este recebe os impulsos elétricos provenientes de uma interface de potência, controlada pelo microcomputador. A confirmação do posicionamento do dispositivo dosador foi feita através de um sensor potenciométrico. Utilizou-se a linguagem de programação C++ para confeccionar o programa de controle do sistema, o qual foi submetido a ensaios para avaliar sua acurácia. No ensaio para determinação do tempo de resposta pode-se observar que transições de maior dosagem para menor, o tempo de resposta foi menor do que para transições de menor dosagem para maior. Nos ensaios de verificação da quantidade de calcário efetivamente aplicada no solo, o erro observado entre quantidade desejada e a realmente aplicada não ultrapassou 3%. Através dos resultados obtidos nos ensaios, pode-se concluir que o sistema está funcionando de acordo com o proposto. / Most of the conventional lime spreaders available in the Brazilian market distribute lime at fixed rates without considering the spatial variability feature of the field. The purpose of this study was to design and build a variable rate lime application system. The developed system calculates the geographic coordinates of the lime spreader position obtained by a Differential Global Positioning System (DGPS). These coordinates, information on the machine speed and a prescription map of the quantity of lime needed for each area within the field are transferred to a computer. The program in the computer automatically adjusts the position of the machine metering device using a step motor driven by electric impulses generated by an electronic interface. The metering device position was checked through potentiometric sensors. The C++ programming language was used to write the control program for the system, which was tested to evaluate its accuracy. The tests demonstrated a shorter response time when changing from larger to smaller application rates than when changing from smaller to larger rates. In the test to verify the amount of lime effectively applied on the soil, the observed error between the desired amount and the real amount applied did not exceed 3%. The results of the tests indicate that the system operates according to the established goals.
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