<div>The link between volatile organic compounds (VOCs) from breath and various diseases and specific conditions has been identified since long by the researchers. Canine studies and breath sample analysis on Gas chromatography/ Mass Spectroscopy has proven that there are VOCs in the breath that can detect and potentially predict hypoglycemia. This project aims at developing a smart nanosensor system to detect hypoglycemia from human breath. The sensor system comprises of 1-Mercapto-(triethylene glycol) methyl ether functionalized goldnanoparticle (EGNPs) sensors coated with polyetherimide (PEI) and poly(vinylidene fluoride -hexafluoropropylene) (PVDF-HFP) and polymer composite sensor made from PVDF-HFP-Carbon Black (PVDF-HFP/CB), an interface circuit that performs signal conditioning and amplification, and a microcontroller with Bluetooth Low Energy (BLE) to control the interface circuit and communicate with an external personal digital assistant. The sensors were fabricated and tested with 5 VOCs in dry air and simulated breath (mixture of air, small portion of acetone, ethanol at high humidity) to investigate sensitivity and selectivity. The name of the VOCs is not disclosed herein but these VOCs have been identified in breath and are identified as potential biomarkers for other diseases as well. </div><div> </div><div> The sensor hydrophobicity has been studied using contact angle measurement. The GNPs size was verified using Ultra-Violent-Visible (UV-VIS) Spectroscopy. Field Emission Scanning Electron Microscope (FESEM) image is used to show GNPs embedded in the polymer film. The sensors sensitivity increases by more than 400% in an environment with relative humidity (RH) of 93% and the sensors show selectivity towards VOCs of interest. The interface circuit was designed on Eagle PCB and was fabricated using a two-layer PCB. The fabricated interface circuit was simulated with variable resistance and was verified with experiments. The system is also tested at different power source voltages and it was found that the system performance is optimum at more than 5 volts. The sensor fabrication, testing methods, and results are presented and discussed along with interface circuit design, fabrication, and characterization.</div>

Before the German reunification, Dresden was a city of motorized traffic and cyclist were rare. But in the 90's began a change of transport policy and cycling became more important. This Master Thesis wants to show the current standing of cycling in Dresden. Thats why the results of the "SrV"-study should be analysed with regard to potential cyclists and their journeys. As methods were used a descriptive analysis and the linear discriminant analysis, both used at a personal and journey-specific level of data. As a result, Dresden have to do much more to become a good "cycling-city", so the bike-level wasn't really high in the year 2013. Instead the car is still the mostly used transport vehicle and the proportion in the Modal-Split is only slowly sinking. But this study shows typical characteritics of cyclists and cycling journays of Dresden, so there is a basis to get more people involved to cycle and become a more eco-friendly city.:Abbildungsverzeichnis i Abkürzungsverzeichnis iii 1. Einleitung 1. 2. Theoretischer Teil 4 2.1 Diskriminanzanalyse 4 2.1.1 Umsetzung im Zweigruppenfall 6 2.1.2 Umsetzung im Mehrgruppenfall 8 2.1.3 Güteprüfung 9 2.2 Datensatz 12 2.3 Literaturrecherche 15 3. Praktischer Teil 23 3.1 Deskriptive Analyse 24 3.1.1 Auswertung auf Personenebene 25 3.1.2 Auswertung auf Wegeebene 33 3.2 Diskriminanzanalyse 40 3.2.1 Anwendung auf Personenebene 40 3.2.2 Anwendung auf Wegeebene 48 4. Fazit 54 5. Kritische Würdigung 58 6. Ausblick 61 Literaturverzeichnis I

This thesis is carried out in collaboration with a private company, DANSiC AB This study is an extension of a research work started by DANSiC AB in 2019 to classify a source. This study is about classifying a source into two classes with the sensitivity of one source higher than the other as one source has greater importance. The data provided for this thesis is based on sensor measurements on different temperature cycles. The data is high-dimensional and is expected to have a drift in measurements. Principal component analysis (PCA) is used for dimensionality reduction. “Differential”, “Relative” and “Fractional” drift compensation techniques are used for compensating the drift in data. A comparative study was performed using three different classification algorithms, which are “Linear Discriminant Analysis (LDA)”, “Naive Bayes classifier (NB)” and “Random forest (RF)”. The highest accuracy achieved is 59%,Random forest is observed to perform better than the other classifiers. / <p>This work is done with DANSiC AB in collaboration with Linkoping University.</p>

Indiana University-Purdue University Indianapolis (IUPUI) / This research performs a comparative study of techniques for combining spatial data and multivariate statistical methods for characterizing water quality conditions in a river basin. The study has been performed on the White River basin in central Indiana, and uses sixteen physical and chemical water quality parameters collected from 44 different monitoring sites, along with various spatial data related to land use – land cover, soil characteristics, terrain characteristics, eco-regions, etc. Various parameters related to the spatial data were analyzed using ArcHydro tools and were included in the multivariate analysis methods for the purpose of creating classification equations that relate spatial and spatio-temporal attributes of the watershed to water quality data at monitoring stations. The study compares the use of various statistical estimates (mean, geometric mean, trimmed mean, and median) of monitored water quality variables to represent annual and seasonal water quality conditions. The relationship between these estimates and the spatial data is then modeled via linear and non-linear multivariate methods. The linear statistical multivariate method uses a combination of principal component analysis, cluster analysis, and discriminant analysis, whereas the non-linear multivariate method uses a combination of Kohonen Self-Organizing Maps, Cluster Analysis, and Support Vector Machines. The final models were tested with recent and independent data collected from stations in the Eagle Creek watershed, within the White River basin. In 6 out of 20 models the Support Vector Machine more accurately classified the Eagle Creek stations, and in 2 out of 20 models the Linear Discriminant Analysis model achieved better results. Neither the linear or non-linear models had an apparent advantage for the remaining 12 models. This research provides an insight into the variability and uncertainty in the interpretation of the various statistical estimates and statistical models, when water quality monitoring data is combined with spatial data for characterizing general spatial and spatio-temporal trends.

Smokeless powders are a set of energetic materials, known as low explosives, which are typically utilized for reloading ammunition. There are three types which differ in their primary energetic materials; where single base powders contain nitrocellulose as their primary energetic material, double and triple base powders contain nitroglycerin in addition to nitrocellulose, and triple base powders also contain nitroguanidine. Additional organic compounds, while not proprietary to specific manufacturers, are added to the powders in varied ratios during the manufacturing process to optimize the ballistic performance of the powders. The additional compounds function as stabilizers, plasticizers, flash suppressants, deterrents, and opacifiers. Of the three smokeless powder types, single and double base powders are commercially available, and have been heavily utilized in the manufacture of improvised explosive devices. Forensic smokeless powder samples are currently analyzed using multiple analytical techniques. Combined microscopic, macroscopic, and instrumental techniques are used to evaluate the sample, and the information obtained is used to generate a list of potential distributors. Gas chromatography – mass spectrometry (GC-MS) is arguably the most useful of the instrumental techniques since it distinguishes single and double base powders, and provides additional information about the relative ratios of all the analytes present in the sample. However, forensic smokeless powder samples are still limited to being classified as either single or double base powders, based on the absence or presence of nitroglycerin, respectively. In this work, the goal was to develop statistically valid classes, beyond the single and double base designations, based on multiple organic compounds which are commonly encountered in commercial smokeless powders. Several chemometric techniques were applied to smokeless powder GC-MS data for determination of the classes, and for assignment of test samples to these novel classes. The total ion spectrum (TIS), which is calculated from the GC-MS data for each sample, is obtained by summing the intensities for each mass-to-charge (m/z) ratio across the entire chromatographic profile. A TIS matrix comprising data for 726 smokeless powder samples was subject to agglomerative hierarchical cluster (AHC) analysis, and six distinct classes were identified. Within each class, a single m/z ratio had the highest intensity for the majority of samples, though the m/z ratio was not always unique to the specific class. Based on these observations, a new classification method known as the Intense Ion Rule (IIR) was developed and used for the assignment of test samples to the AHC designated classes. Discriminant models were developed for assignment of test samples to the AHC designated classes using k-Nearest Neighbors (kNN) and linear and quadratic discriminant analyses (LDA and QDA, respectively). Each of the models were optimized using leave-one-out (LOO) and leave-group-out (LGO) cross-validation, and the performance of the models was evaluated by calculating correct classification rates for assignment of the cross-validation (CV) samples to the AHC designated classes. The optimized models were utilized to assign test samples to the AHC designated classes. Overall, the QDA LGO model achieved the highest correct classification rates for assignment of both the CV samples and the test samples to the AHC designated classes. In forensic application, the goal of an explosives analyst is to ascertain the manufacturer of a smokeless powder sample. In addition, knowledge about the probability of a forensic sample being produced by a specific manufacturer could potentially decrease the time invested by an analyst during investigation by providing a shorter list of potential manufacturers. In this work, Bayes* Theorem and Bayesian Networks were investigated as an additional tool to be utilized in forensic casework. Bayesian Networks were generated and used to calculate posterior probabilities of a test sample belonging to specific manufacturers. The networks were designed to include manufacturer controlled powder characteristics such as shape, color, and dimension; as well as, the relative intensities of the class associated ions determined from cluster analysis. Samples were predicted to belong to a manufacturer based on the highest posterior probability. Overall percent correct rates were determined by calculating the percentage of correct predictions; that is, where the known and predicted manufacturer were the same. The initial overall percent correct rate was 66%. The dimensions of the smokeless powders were added to the network as average diameter and average length nodes. Addition of average diameter and length resulted in an overall prediction rate of 70%.

This thesis focuses on statistical and machine learning methods designed for sequential and repeated measurement data. We start off by considering the classic general linear model (MANOVA) followed by its generalization, the growth curve model (GMANOVA), designed for analysis of repeated measurement data. By considering a binary classification problem of normal data together with the corresponding maximum likelihood estimators for the growth curve model, we demonstrate how a classification rule based on linear discriminant analysis can be derived which can be used for repeated measurement data in a meaningful way. We proceed to the topics of neural networks which serve as our second method of classification. The reader is introduced to classic neural networks and relevant subtopics are discussed. We present a generalization of the classic neural network model to the recurrent neural network model and the LSTM model which are designed for sequential data. Lastly, we present three types of data sets with an total of eight cases where the discussed classification methods are tested. / Den här uppsatsen introducerar klassificeringsmetoder skapade för data av typen upprepade mätningar och sekventiell data. Den klassiska MANOVA modellen introduceras först som en grund för den mer allmäna tillväxtkurvemodellen(GMANOVA), som i sin tur används för att modellera upprepade mätningar på ett meningsfullt sätt. Under antagandet av normalfördelad data så härleds en binär klassificeringsmetod baserad på linjär diskriminantanalys, som tillsammans med maximum likelihood-skattningar från tillväxtkurvemodellen ger en binär klassificeringsregel för data av typen upprepade mätningarn. Vi fortsätter med att introducera läsaren för klassiska neurala nätverk och relevanta ämnen diskuteras. Vi generaliserar teorin kring neurala nätverk till typen "recurrent" neurala nätverk och LSTM som är designade för sekventiell data. Avslutningsvis så testas klassificeringsmetoderna på tre typer av data i totalt åtta olika fall.

O uso de dados biométricos da face para verificação automática de identidade é um dos maiores desafios em sistemas de controle de acesso seguro. O processo é extremamente complexo e influenciado por muitos fatores relacionados à forma, posição, iluminação, rotação, translação, disfarce e oclusão de características faciais. Hoje existem muitas técnicas para se reconhecer uma face. Esse trabalho apresenta uma investigação buscando identificar uma face no banco de dados ORL com diferentes grupos de treinamento. É proposto um algoritmo para o reconhecimento de faces baseado na técnica de subespaço LDA (PCA + LDA) utilizando uma rede neural SOM para representar cada classe (face) na etapa de classificação/identificação. Aplicando o método do subespaço LDA busca-se extrair as características mais importantes na identificação das faces previamente conhecidas e presentes no banco de dados, criando um espaço dimensional menor e discriminante com relação ao espaço original. As redes SOM são responsáveis pela memorização das características de cada classe. O algoritmo oferece maior desempenho (taxas de reconhecimento entre 97% e 98%) com relação às adversidades e fontes de erros que prejudicam os métodos de reconhecimento de faces tradicionais. / The use of biometric technique for automatic personal identification is one of the biggest challenges in the security field. The process is complex because it is influenced by many factors related to the form, position, illumination, rotation, translation, disguise and occlusion of face characteristics. Now a days, there are many face recognition techniques. This work presents a methodology for searching a face in the ORL database with some different training sets. The algorithm for face recognition was based on sub-space LDA (PCA + LDA) technique using a SOM neural net to represent each class (face) in the stage of classification/identification. By applying the sub-space LDA method, we extract the most important characteristics in the identification of previously known faces that belong to the database, creating a reduced and more discriminated dimensional space than the original space. The SOM nets are responsible for the memorization of each class characteristic. The algorithm offers great performance (recognition rates between 97% and 98%) considering the adversities and sources of errors inherent to the traditional methods of face recognition.

In this thesis, the expression variation problem in two-dimensional (2D) and three-dimensional (3D) face recognition is tackled. While discriminant analysis (DA) methods are effective solutions for recognizing expression-variant 2D face images, they are not directly applicable when only a single sample image per subject is available. This problem is addressed in this thesis by introducing expression subspaces which can be used for synthesizing new expression images from subjects with only one sample image. It is proposed that by augmenting a generic training set with the gallery and their synthesized new expression images, and then training DA methods using this new set, the face recognition performance can be significantly improved. An important advantage of the proposed method is its simplicity; the expression of an image is transformed simply by projecting it into another subspace. The above proposed solution can also be used in general pattern recognition applications. The above method can also be used in 3D face recognition where expression variation is a more serious issue. However, DA methods cannot be readily applied to 3D faces because of the lack of a proper alignment method for 3D faces. To solve this issue, a method is proposed for sampling the points of the face that correspond to the same facial features across all faces, denoted as the closest-normal points (CNPs). It is shown that the performance of the linear discriminant analysis (LDA) method, applied to such an aligned representation of 3D faces, is significantly better than the performance of the state-of-the-art methods which, rely on one-by-one registration of the probe faces to every gallery face. Furthermore, as an important finding, it is shown that the surface normal vectors of the face provide a higher level of discriminatory information rather than the coordinates of the points. In addition, the expression subspace approach is used for the recognition of 3D faces from single sample. By constructing expression subspaces from the surface normal vectors at the CNPs, the surface normal vectors of a 3D face with single sample can be synthesized under other expressions. As a result, by improving the estimation of the within-class scatter matrix using the synthesized samples, a significant improvement in the recognition performance is achieved.

In this thesis, the expression variation problem in two-dimensional (2D) and three-dimensional (3D) face recognition is tackled. While discriminant analysis (DA) methods are effective solutions for recognizing expression-variant 2D face images, they are not directly applicable when only a single sample image per subject is available. This problem is addressed in this thesis by introducing expression subspaces which can be used for synthesizing new expression images from subjects with only one sample image. It is proposed that by augmenting a generic training set with the gallery and their synthesized new expression images, and then training DA methods using this new set, the face recognition performance can be significantly improved. An important advantage of the proposed method is its simplicity; the expression of an image is transformed simply by projecting it into another subspace. The above proposed solution can also be used in general pattern recognition applications. The above method can also be used in 3D face recognition where expression variation is a more serious issue. However, DA methods cannot be readily applied to 3D faces because of the lack of a proper alignment method for 3D faces. To solve this issue, a method is proposed for sampling the points of the face that correspond to the same facial features across all faces, denoted as the closest-normal points (CNPs). It is shown that the performance of the linear discriminant analysis (LDA) method, applied to such an aligned representation of 3D faces, is significantly better than the performance of the state-of-the-art methods which, rely on one-by-one registration of the probe faces to every gallery face. Furthermore, as an important finding, it is shown that the surface normal vectors of the face provide a higher level of discriminatory information rather than the coordinates of the points. In addition, the expression subspace approach is used for the recognition of 3D faces from single sample. By constructing expression subspaces from the surface normal vectors at the CNPs, the surface normal vectors of a 3D face with single sample can be synthesized under other expressions. As a result, by improving the estimation of the within-class scatter matrix using the synthesized samples, a significant improvement in the recognition performance is achieved.

O uso de dados biométricos da face para verificação automática de identidade é um dos maiores desafios em sistemas de controle de acesso seguro. O processo é extremamente complexo e influenciado por muitos fatores relacionados à forma, posição, iluminação, rotação, translação, disfarce e oclusão de características faciais. Hoje existem muitas técnicas para se reconhecer uma face. Esse trabalho apresenta uma investigação buscando identificar uma face no banco de dados ORL com diferentes grupos de treinamento. É proposto um algoritmo para o reconhecimento de faces baseado na técnica de subespaço LDA (PCA + LDA) utilizando uma rede neural SOM para representar cada classe (face) na etapa de classificação/identificação. Aplicando o método do subespaço LDA busca-se extrair as características mais importantes na identificação das faces previamente conhecidas e presentes no banco de dados, criando um espaço dimensional menor e discriminante com relação ao espaço original. As redes SOM são responsáveis pela memorização das características de cada classe. O algoritmo oferece maior desempenho (taxas de reconhecimento entre 97% e 98%) com relação às adversidades e fontes de erros que prejudicam os métodos de reconhecimento de faces tradicionais. / The use of biometric technique for automatic personal identification is one of the biggest challenges in the security field. The process is complex because it is influenced by many factors related to the form, position, illumination, rotation, translation, disguise and occlusion of face characteristics. Now a days, there are many face recognition techniques. This work presents a methodology for searching a face in the ORL database with some different training sets. The algorithm for face recognition was based on sub-space LDA (PCA + LDA) technique using a SOM neural net to represent each class (face) in the stage of classification/identification. By applying the sub-space LDA method, we extract the most important characteristics in the identification of previously known faces that belong to the database, creating a reduced and more discriminated dimensional space than the original space. The SOM nets are responsible for the memorization of each class characteristic. The algorithm offers great performance (recognition rates between 97% and 98%) considering the adversities and sources of errors inherent to the traditional methods of face recognition.