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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
11

MAGNETIC AND ORBITAL ORDERS COUPLED TO NEGATIVE THERMAL EXPANSION IN MOTT INSULATORS, CA2RU1-XMXO4 (M = 3D TRANSITION METAL ION)

Qi, Tongfei 01 January 2012 (has links)
Ca2RuO4 is a structurally-driven Mott insulator with a metal-insulator (MI) transition at TMI = 357K, followed by a well-separated antiferromagnetic order at TN = 110 K. Slightly substituting Ru with a 3d transition metal ion M effectively shifts TMI and induces exotic magnetic behavior below TN. Moreover, M doping for Ru produces negative thermal expansion in Ca2Ru1-xMxO4 (M = Cr, Mn, Fe or Cu); the lattice volume expands on cooling with a total volume expansion ratio reaching as high as 1%. The onset of the negative thermal expansion closely tracks TMI and TN, sharply contrasting classic negative thermal expansion that shows no relevance to electronic properties. In addition, the observed negative thermal expansion occurs near room temperature and extends over a wide temperature interval. These findings underscores new physics driven by a complex interplay between orbital, spin and lattice degrees of freedom. These materials constitute a new class of Negative Thermal Expansion (NTE) materials with novel electronic and magnetic functions.
12

Multipoles in Correlated Electron Materials

Cricchio, Francesco January 2010 (has links)
Electronic structure calculations constitute a valuable tool to predict the properties of materials. In this study we propose an efficient scheme to study correlated electron systems with essentially only one free parameter, the screening length of the Coulomb potential. A general reformulation of the exchange energy of the correlated electron shell is combined with this method in order to analyze the calculations. The results are interpreted in terms of different polarization channels, due to different multipoles. The method is applied to various actinide compounds, in order to increase the understanding of the complicate behaviour of 5f electrons in these systems. We studied the non-magnetic phase of δ-Pu, where the spin polarization is taken over by a spin-orbit-like term that does not break the time reversal symmetry. We also find that a non-trivial high multipole of the magnetization density, the triakontadipole, constitutes the ordering parameter in the mysterious hidden order phase of the heavy-fermion superconductor URu2Si2. This type of multipolar ordering is also found to play an essential role in the hexagonal-based superconductors UPd2Al3,  UNi2Al3 and UPt3 and in the dioxide insulators UO2, NpO2 and PuO2. The triakontadipole moments are also present in all magnetic actinides we considered, except for Cm. These results led us to formulate a new set of rules for the ground state of a system, that are valid in presence of strong spin-orbit coupling interaction instead of those of Hund; the Katt's rules. Finally, we applied our method to a new class of high-Tc superconductors, the Fe-pnictides, where the Fe 3d electrons are moderately correlated. In these materials we obtain the stabilization of a low spin moment solution, in agreement with experiment, over a large moment solution, due to the gain in exchange energy in the formation of large multipoles of the spin magnetization density. / Felaktigt tryckt som Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 705
13

Theoretical study of magnetic odering of defects in diamond

Benecha, Evans Moseti 11 1900 (has links)
Magnetic ordering of dopants in diamond holds the prospect of exploiting diamond’s unique properties in the emerging field of spintronics. Several transition metal defects have been reported to order ferromagnetically in various semiconductors, however, low Curie temperatures and lack of other fundamental material properties have hindered practical implementation in room temperature spintronic applications. In this Thesis, we consider the energetic stability of 3d transition metal doped-diamond and its magnetic ordering properties at various lattice sites and charge states using ab initio Density Functional Theory methods. We find the majority of 3d transition metal impurities in diamond at any charge state to be energetically most stable at the divacancy site compared to substitutional or interstitial lattice sites, with the interstitial site being highly unstable (by ~8 - 10 eV compared to the divacancy site). At each lattice site and charge state, we find the formation energies of transition metals in the middle of the 3d series (Cr, Mn, Fe, Co, Ni) to be considerably lower compared to those early or late in the series. The energetic stability of transition metal impurities across the 3d series is shown to be strongly dependent on the position of the Fermi level in the diamond band gap, with the formation energies at any lattice site being lower in p-type or ntype diamond compared to intrinsic diamond. Further, we show that incorporation of isolated transition metal impurities into diamond introduces spin polarised impurity bands into the diamond band gap, while maintaining its semiconducting nature, with band gaps in both the spin-up and spin-down channels. These impurity bands are shown to originate mainly from s, p-d hybridization between carbon sp 3 orbitals with the 3d orbitals of the transition metal. In addition, the 4p orbitals contribute significantly to hybridization for transition metal atoms at the substitutional site, but not at the divacancy site. In both cases, the spin polarisation and magnetic stabilization energies are critically dependent on the lattice site and charge state of the transition metal impurity. By allowing magnetic interactions between transition metal atoms, we find that ferromagnetic ordering is likely to be achieved in divacancy Cr+2, Mn+2, Mn+1 and Co0 as well as in substitutional Fe+2 and Fe+1, indicating that transition metal-doped diamond is likely to form a diluted magnetic semiconductor which may successfully be considered for room temperature spintronic applications. In addition, these charge states correspond to p-type diamond, except for divacancy Co0, suggesting that co-doping with shallow acceptors such as B ( will result in an increase of charge concentration, which is likely to enhance mediation of ferromagnetic spin coupling. The highest magnetic stabilization energy occurs in substitutional Fe+1 (33.3 meV), which, also exhibits half metallic ferromagnetic ordering at the Fermi level, with an induced magnetic moment of 1.0 μB per ion, thus suggesting that 100 % spin polarisation may be achieved in Fe-doped diamond. / Physics / D. Litt. et Phil. (Physics)
14

Magnetic properties and proton spin-lattice relaxation in molecular clusters

Allalen, Mohammed 06 June 2006 (has links)
In this work we studied magnetic properties of molecular magnets of the new heteropolyanion {Cu20}, dodecanuclear cluster {Ni12}, and the heterometallic {Cr7M} wheels, in which one of the CrIII ions of Cr8 has been replaced by a Fe, Cu, Zn, Ni, ion with this extra-spin acts as local probe for the spin dynamics.Such systems have been synthesized recently and they are well described using the Heisenberg spin Hamiltonian with a Zeeman term of an applied magnetic field along the z-axis. Using the numerical exact diagonalization method, we have calculated the energy spectrum and the eigenstates for different compounds,and we have used them for reexamining the available experimental susceptibility data to determine the values of exchange parameters.We have studied the thermodynamic properties such magnetization, susceptibility, heat-capacity. At low temperature regions molecular magnets act as individual quantum nanomagnets and can display super-paramagnetic phenomena like macroscopic quantum tunneling, ground state degeneracy, level-crossing. A crucial issue for understanding these phenomena is the coupling between magnetic molecular levels and the environment such as nuclear spins. We have modeled the behavior of the proton spin lattice relaxation rate as a function of applied magnetic field for low temperatures as it is measured in Nuclear Magnetic Resonance (NMR) experiments.
15

Exploring the Frustrated Spin-Chain Compound Linarite by NMR and Thermodynamic Investigations

Schäpers, Markus 28 October 2014 (has links) (PDF)
Within the last decades low-dimensional frustrated quantum spin systems have attracted great interest in the field of modern research. In these systems a competition of various magnetic interactions takes place, leading to an energetically degenerated magnetic ground state, and thus to the occurrence of exotic, unconventional physical properties at low temperatures. This thesis focuses on the quasi one-dimensional frustrated spin chain system linarite, PbCuSO4(OH)2. In this compound the basic building blocks are CuO4 plaquettes which are connected to each other along one crystallographic direction, analogue to a chain. The frustration in linarite is established due to the competition between the magnetic interactions. The nearest-neighbor magnetic spins are coupled ferromagnetically along the chain via a coupling constant J1, while the next-nearest neighbors are coupled antiferromagnetically via a coupling constant J2. For this configuration it is not possible to satisfy all magnetic couplings simultaneously, hence the system is magnetically frustrated. In this work, comprehensive thermodynamic and nuclear magnetic resonance (NMR) studies demonstrate that linarite is one of the richest and most fascinating compounds in the class of low-dimensional frustrated magnets. By means of susceptibility, magnetization, specific heat, magnetocaloric effect, magnetostriction, and thermal-expansion measurements a rich magnetic phase diagram could be mapped out below a temperature of 2.8 K. The phase diagram contains five different magnetic regions/phases for an external magnetic field pointing along the chain direction. Based on the thermodynamic studies it was possible to calculate the exchange integrals within the frustrated J1-J2 model and extensions of it by using various theoretical approaches. The magnetic microscopic nature of the different long-range magnetic phases present in linarite were investigated by NMR measurements and by collaborative neutron scattering experiments. The ground state (phase I) is identified as an incommensurate elliptical helical structure. Via a theoretical modelling the 1H-NMR spectrum of the ground state could be explained, revealing a rearrangement of the zero-field structure in an external magnetic field of 2.0 T used for the NMR studies. By further increasing the external field the system undergoes a complex spin flop transition in two steps (phase I - phase III - phase IV). In phase III a phase separation takes place where one part of the spins form a circular spiral structure while the remaining fraction form a simple antiferromagnetic structure. In phase IV the remaining circular spiral structure vanishes, so that all spins collectively form the antiferromagnetic collinear phase. The most peculiar physical properties studied in this thesis take place in region V at high fields, showing only tiny features in the thermodynamic properties. The magnetic spins in region V form a sine-wave modulated spin-density structure as identified via NMR and neutron investigations. It is discussed whether region V is related to a multipolar phase or if the spin-density wave structure could possibly coexist with such a phase.
16

Exploring the Frustrated Spin-Chain Compound Linarite by NMR and Thermodynamic Investigations

Schäpers, Markus 07 October 2014 (has links)
Within the last decades low-dimensional frustrated quantum spin systems have attracted great interest in the field of modern research. In these systems a competition of various magnetic interactions takes place, leading to an energetically degenerated magnetic ground state, and thus to the occurrence of exotic, unconventional physical properties at low temperatures. This thesis focuses on the quasi one-dimensional frustrated spin chain system linarite, PbCuSO4(OH)2. In this compound the basic building blocks are CuO4 plaquettes which are connected to each other along one crystallographic direction, analogue to a chain. The frustration in linarite is established due to the competition between the magnetic interactions. The nearest-neighbor magnetic spins are coupled ferromagnetically along the chain via a coupling constant J1, while the next-nearest neighbors are coupled antiferromagnetically via a coupling constant J2. For this configuration it is not possible to satisfy all magnetic couplings simultaneously, hence the system is magnetically frustrated. In this work, comprehensive thermodynamic and nuclear magnetic resonance (NMR) studies demonstrate that linarite is one of the richest and most fascinating compounds in the class of low-dimensional frustrated magnets. By means of susceptibility, magnetization, specific heat, magnetocaloric effect, magnetostriction, and thermal-expansion measurements a rich magnetic phase diagram could be mapped out below a temperature of 2.8 K. The phase diagram contains five different magnetic regions/phases for an external magnetic field pointing along the chain direction. Based on the thermodynamic studies it was possible to calculate the exchange integrals within the frustrated J1-J2 model and extensions of it by using various theoretical approaches. The magnetic microscopic nature of the different long-range magnetic phases present in linarite were investigated by NMR measurements and by collaborative neutron scattering experiments. The ground state (phase I) is identified as an incommensurate elliptical helical structure. Via a theoretical modelling the 1H-NMR spectrum of the ground state could be explained, revealing a rearrangement of the zero-field structure in an external magnetic field of 2.0 T used for the NMR studies. By further increasing the external field the system undergoes a complex spin flop transition in two steps (phase I - phase III - phase IV). In phase III a phase separation takes place where one part of the spins form a circular spiral structure while the remaining fraction form a simple antiferromagnetic structure. In phase IV the remaining circular spiral structure vanishes, so that all spins collectively form the antiferromagnetic collinear phase. The most peculiar physical properties studied in this thesis take place in region V at high fields, showing only tiny features in the thermodynamic properties. The magnetic spins in region V form a sine-wave modulated spin-density structure as identified via NMR and neutron investigations. It is discussed whether region V is related to a multipolar phase or if the spin-density wave structure could possibly coexist with such a phase.

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