This work has been devoted to the study of phase transformations involving chemical ordering and magnetic properties evolution in bulk Fe-Pt alloys composed of nanometer-sized grains. A comprehensive study of phase transformations and ordering in Fe-Pt alloys is performed by a combination of in-situ neutron powder diffraction and thermal analysis. The dependence of ordering processes on the alloy composition and initial microstructure (homogeneous A1 phase or multilayer-type) is established. Through the use of mechanical alloying and subsequent heat treatment it has been possible to achieve the formation of chemically highly ordered L10 FePt and, in the case of the Fe-rich and Pt-rich compositions, L12 Fe3Pt and FePt3 phases, respectively. Whereas in Pt-rich alloys the decoupling effect of the FePt3 phase leads to coercivity improvement, in Fe-rich nanocomposites a peculiar nanometer scale multilayer structure gives rise to remanence enhancement due to large effects of exchange interactions between the crystallites of the phases. The structure, magnetic properties and magnetisation reversal processes of these alloys are investigated. Experimentally observed phenomena are understood on the basis of a simple two-particle interaction model. Neutron diffraction has also been used for the investigation of the magnetic structure of ordered and partially ordered nanocrystalline Fe-Pt alloys. It has been shown that the magnetic moment of Fe atoms in L10-type Fe Pt alloys is sensitive to the compositional order. The results are compared to density functional calculations.

Nutzbare Energie ist ein knappes Gut. Aus ökonomischen und ökologischen Gründen wird die effiziente und nachhaltige Nutzung der verfügbaren Energie angestrebt. Wird Energie in elektrischer Form bereitgestellt oder transportiert, kommt der Minimierung der Verluste an elektrotechnischen Anlagen oder Bauelementen eine grundlegende Bedeutung zu. So werden beispielsweise Transformatorenkomponenten und Verstärkerelemente aus weichmagnetischen Werkstoffen mit geringem Ummagnetisierungsverlust gefertigt. In dieser Arbeit wird der Zusammenhang zwischen der magnetischen Mikrostruktur und dem magnetischen Ummagnetisierungsverlust nanokristalliner Ringbandkerne untersucht. Der Einfluss von Stärke und Lage einer induzierten Anisotropie wird anhand induktiver Hysteresemessung und simultaner Beobachtung magnetischer Domänen mit stroboskopischer Kerrmikroskopie charakterisiert.

The thesis is based on articles describing the fundamental research of carbon based nanomaterials for their possible utilization in biomedicine. The aim of this thesis was to describe the way how human osteoblasts (SAOS-2 cell line) and primary human mesenchymal stem cells (hMSC) adhere, grow and behave on surfaces made of several carbon allotropes - nanocrystalline diamond (NCD), single walled carbon nanotubes (SWCNTs) films and graphene. The utilization of carbon as the basic material promised good biocompatibility and possibility of useful surface modifications. The NCD had modified surface nanotopography (nanoroughness and nanostructuring prepared by dry ion etching). All the materials had modified surface atomic termination with oxygen and hydrogen which changes the surface electrical conductivity, surface charge and wettability. It was hypothesized that the surface termination can also influence the cell adhesion and growth. It turned out that all the studied materials were suitable as substrates for cultivation of mentioned cell types. Various nanoroughnesses of NCD surface had different effect on the cell adhesion and cell metabolic activity. Nanostructuring of the NCD influenced the formation of focal adhesions. The surface terminations of NCD and the other studied nanomaterials in...

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Le transport et la distribution de l'énergie électrique sont traditionnellement réalisés en alternatif (50 Hz ou 60 Hz), un des éléments-clés de ces infrastructures est le transformateur de puissance. Ce dernier est utilisé depuis plus d'un siècle et donc sa conception est maîtrisée (avec des rendements très élevés, supérieurs à 99 %). Depuis quelques années, la part des énergies renouvelables est en constante augmentation. Bien souvent, la production des énergies renouvelables est éloignée des centres de consommation. Or, le transport en courant continu sous haute tension (HVDC) sur de grandes distances est plus rentable. Dans ce cas, nous avons besoin de convertisseurs de puissance fonctionnant pour certains avec des Transformateurs Moyennes Fréquences (TMF) entre 1 kHz et quelques dizaines de kilohertz. Dans ces applications, la recherche du rendement maximal est primordiale. L'augmentation de la fréquence de fonctionnement a pour effet bénéfique de diminuer l'encombrement d'un transformateur. Cependant un certain nombre de problèmes vont apparaître avec cette augmentation. Nous pouvons citer : les pertes dans les conducteurs et dans le circuit magnétique sont liées à la fréquence ; le type de bobinages (fil de Litz et feuillard) et les matériaux magnétiques (ferrites et nanocristallins) en moyennes fréquences sont différents de ceux utilisés en 50 Hz ; le refroidissement est plus complexe car la densité de puissance volumique est plus élevée... Ainsi dans cette thèse, nous avons mis en place une méthodologie de conception afin de maîtriser au mieux le dimensionnement d'un TMF avec un compromis précision et coût de calculs. Nous avons identifié les modèles (analytiques et numériques) susceptibles d'être utilisés pour estimer les performances d'un TMF. Deux TMF d'une puissance de 180 kVA et de 1 kVA ont été dimensionnés, fabriqués et testés afin de mettre en évidence le domaine de validité et d'ajuster les différents modèles. Ce travail nous a permis de mettre en place une méthodologie de conception allant des spécifications du convertisseur jusqu'à la simulation de celui-ci avec le modèle du transformateur dimensionné. Nous avons mis en évidence : l'influence de paramètres technologiques sur l'élévation de la résistance pour des bobinages de type feuillard et l'influence de paramètres technologiques sur les propriétés magnétiques des matériaux nanocristallins. Ce travail de thèse a été réalisé avec le groupe « Matériaux du Génie Electrique » du laboratoire Ampère et financé par l'institut pour la transition énergétique SuperGrid Institute / The transmission and distribution of electric power is normally made by ac networks (50 Hz or 60 Hz), where one of the key elements of this infrastructure is the power transformer; used for more than a century, its design is very well understood, with a level of operating efficiency normally greater than 99%. In recent years, the share of renewable energy has been increasing. Often times the energy generated from renewable sources is produced far from consumption centers, and so transportation in the form of high voltage direct current (HVDC) over long distances is more profitable, due to the lower losses seen than with HVAC after a certain length of transmission line. In this case, we need power converters operating with Medium Frequency Transformers (MFT) from 1 kHz to tens of kilohertz. For these applications, the research of their maximum efficiency in operation is paramount. Increasing the transformer operating frequency has the beneficial effect of reducing its size. However, a number of problems will appear with this frequency increase, such as: the increase in the losses in the conductors and the magnetic circuit that are related to the frequency; the less well understood winding type (Litz wire and foil) and magnetic materials (ferrites and nanocrystalline) in the MF that are different from those used at 50 Hz; the cooling is more complex because the power density is higher, etc. In this thesis, a design methodology was developed in order to optimise the design of MFTs with respect to the compromise between accuracy and the length of calculations. In addition, analytical and numerical models were identified that can be used to accurately estimate the performance of an MFT. Furthermore, two MFTs (apparent power: 180 kVA and 1 kVA, respectively) were sized, manufactured and tested in order to demonstrate the domain of validity of the models, and also for optimisation of the different models. This work has enabled the development of a design methodology using the converter specifications and build a simulation with complete model of the transformer, which can then be used to validate an MFT design. We have highlighted: the influence of the technological parameters on the rise of resistance in the foil coils and the influence of the technological parameters on the magnetic properties of nanocrystalline materials. This work was performed with the group "Materials for Electrical Engineering" Ampère laboratory and funded by the Institute for Energy Transition SuperGrid Institute.

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Exploring new technologies that can meet the world’s energy demands in an efficient and clean manner is critically important due to the depletion of natural resources and environmental concerns. Dye-sensitized solar cells (DSSCs) are low-cost and clean technology options that use solar energy efficiently and are being intensively studied. How to further reduce the cost of this technology while enhancing device performance is one of the demanding issues for large scale application and commercialization of DSSCs. In this research dissertation, four main contributions are made in this regard with the motivation to reduce further cost of DSSC technology. Firstly, ~10% efficiencies were achieved after developing understanding of key concepts and procedures involved in DSSCs fabrication. These efficiencies were achieved after step-by-step modifications in the DSSC design. Secondly, carbon nanotubes (CNTs) were successfully employed as an alternative to Pt in the counter electrodes of DSSCs. DSSCs fabricated with CNTs were ~86% as efficient as Pt-based cells. Non-aligned CNTs were successfully grown using four different CVD methods and finally, multi-walled vertically aligned CNTs (MW-VACNTs) were synthesized using water-assisted chemical vapor deposition (WA-CVD). Thirdly, carbon derived from pyrolysis of nanocrystalline cellulose (NCC) was successfully employed in counter electrodes of DSSCs instead of Pt. DSSCs with NCC were ~58% as efficient as Pt-based DSSCs. Fourthly, novel organic metal-free dyes were designed and employed instead of commonly used Ru-based dyes. DSSCs with these novel sensitizers were ~62% as efficient as those using the conventional Ru-based dyes. Characterization techniques including current-voltage measurements, scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), cyclic voltammetery (CV), thermogravimetric analysis (TGA), small angle x-ray scattering (SAXS), atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS) were used.

Dye-sensitized solar cells (DSC) have attracted considerable scientific and industrial interest during the past decade as an economically feasible alternative to conventional photovoltaic devices. DSCs have the potential to be as efficient as silicon solar cells, but at a fraction of the cost of silicon solar cells. The unique advantage of DSC compared to conventional solar cells is that the light absorption, electron transport and hole transport are handled by different components which reduces the chance of recombination. In the present work, to facilitate DSC with good energy conversion efficiency, its performance have been evaluated as a function of titania layer morphology, redox couple concentration and the catalytic layer on the counter electrode. The results that are obtained in the present investigations have been organized as follows Chapter 1 gives a brief exposure to DSC technology. Special emphasize has been on the structure and individual components of the DSC. Chapter 2 describes various experimental techniques that are employed to fabricate and characterize DSCs under study. Chapter 3 presents a systematic study of the characteristics of DSC made of three different types of electrodes namely: TiO2 nanotubes (TNT) which have excellent electron transport properties, TiO2 microspheres (TMS) which possess high surface area and light scattering ability and TiO2 nano particles (TNP) possessing high surface area. The electronic, morphological, optical and surface properties of individual electrodes are studied. The highest efficiency of 8.03% is obtained for DSCs prepared with TMS electrodes. A higher value of effective diffusion coefficient (Deff) and diffusion length (Ln) of electrons as obtained by electrochemical impedance spectroscopy (EIS) analysis confirms a high charge collection efficiency in microsphere based cell. Chapter 4 gives a detailed study of DSCs fabricated with a tri-layer photo anode with TNTs as light scattering layer. The tri-layer structure has given an enhanced efficiency of 7.15% which is 16% higher than TNP based cell and 40% higher than TNT based cells. Chapter 5 deals with the investigations on the effect of concentration of redox couple on the photovoltaic properties of DSC for different ratios of [I2] to [LiI] (1:2, 1:5 and 1:10) with five viii concentrations of I2 namely 0.01 M, 0.03 M, 0.05 M, 0.08 M and 0.1M in acetonitrile. It is found that the open circuit potential (Voc) decreases with increase in the ratio of redox couple whereas short circuit current density (Jsc) and fill factor (FF) increase. The reason for the decline in Voc is the higher recombination between electrons in the conduction band of TiO2 and the I3- ions present in the electrolyte, induced by the absorptive Li+ ions. In addition using EIS it is found that the τ improves with the increase in [LiI] at a particular [I2], whereas at a fixed [I2]/ [LiI] ratio the increase in [I2] is found to reduce the τ and Deff due to the enhanced recombination. Chapter 6 describes the application of carbon based counter electrode (CE) materials for DSCs. Two counter electrode materials have been investigated namely (1) Multiwalled carbon nanotubes (MWCNT) synthesized by pyrolysis method and (2) Platinum decorated multiwalled carbon nanotubes (Pt/MWCNT) prepared by chemical reduction of platinum precursors. Using Pt/MWCNT composite electrode the DSC achieved an energy conversion efficiency of 6.5 %. From the analysis on symmetric cells, it is found that electro catalytic activity of Pt/MWCNT CE is similar to that of platinum CE, though the platinum loading is very less for the former. This is attributed to the effective utilization of catalyst owing to high surface area arising from the increased surface roughness. Chapter 7 discusses the application of titanium foil in place of glass substrate for the photo anode. The titanium foil offers fabrication of flexible DSC. The performance of DSC with TMS layers and aligned titania nanotube arrays (TNA) prepared by anodization method is studied. Compared to TMS based cell, TNA has given a better efficiency at a lower thickness. Chapter 8 presents the scheme used to seal DSCs and its stability analysis. We have employed the usual hot melt sealing for edge whereas hole sealing is carried out with tooth pick and a UV curable adhesive. The degradation in efficiency is found to be 20% for low efficiency cells whereas, for high efficiency cells it is found to be 45% after 45 days. The leakage of highly volatile acetonitrile through the edge and hole is found to be responsible for the reduction in the performance of the device. Hence a high temperature sealing method is proposed to fabricate stable cells. Chapter 9 gives summary and conclusions of the present work

Magister Scientiae - MSc (Physics) / An increasing energy demand and growing environmental concerns regarding the use of fossil fuels in South Africa has led to the challenge to explore cheap, alternative sources of energy. The generation of electricity from Photovoltaic (PV) devices such as solar cells is currently seen as a viable alternative source of clean energy. As such, crystalline, amorphous and nanocrystalline silicon thin films are expected to play increasingly important roles as economically viable materials for PV development. Despite the growing interest shown in these materials, challenges such as the partial understanding of standardized measurement protocols, and the relationship between the structure and optoelectronic properties still need to be overcome.