The geomorphological impact of small fossorial mammals (adapted to digging and living underground), such as rodents can be significant, and both their direct and indirect effects may contribute to landscape formation. This thesis is based on empirical field studies of two burrowing rodent species in sub-polar environments, namely invasive House mice (Mus musculus) on sub-Antarctic Marion Island and Norwegian lemmings (Lemmus lemmus) in sub-Arctic Abisko. The spatial distribution, sediment displacements, impact on vegetation and microclimatic effects of the rodents are documented. Invasive mice and rats, introduced on sub-Antarctic Islands during the 19th century, lack natural enemies and are shown to have a significant direct and indirect geomorphic impact by direct sediment displacement, vegetation removal by burrowing, grazing and trampling and thereby exposing the sediments for rain, wind and frost processes.  The geomorphic impacts of lemmings are comparatively more limited as they rely on natural hollows and snow cover for protection and do not burrow to the same extent as other fossorial rodents in cold regions. Lemmings are thus suggested to have little impact on landform integrity, but can affect vegetation composition. A comparison of the findings from this study with published data on seven other rodent species and other physical mass transfer mechanisms in sub-polar and alpine environments suggests that fossorial rodents are a significant and sometimes dominant geomorphic force in sub-polar and alpine environments. The geomorphic work by ground squirrels, ice rats, plateau pikas and zokors is shown to be in the same order of magnitude as solifluction and rock falls. In alpine and periglacial environments these rodents are considered to act as key-stone species and ecosystem engineers through the creation of landforms by  dislocation and of soil and other impacts on soil properties, vegetation and ecosystem function

Title: Phosphinoferrocene ligands with polar amide substituents Author: Hana Charvátová Department: Department of Inorganic Chemistry Supervisor: prof. RNDr. Petr Štěpnička, Ph.D. Abstract: This thesis is focused on phosphino-urea ferrocene ligands that are still rather neglected in the literature. It describes the synthesis of novel polar amides and hydrazides of 1'-(diphenylphosphino)ferrocene-1-carboxylic acid (Hdpf) with or without ethylene linker bearing various urea and guanidine terminal functional groups. Urea and guanidine derivatives with ethylene bridge can be prepared from Hdpf and appropriate amine with amidation agents. Phosphine ureas without the linker are accessible from reactions of primary amide of Hdpf with suitable acylation agents while analogical guanidine is obtained from guanylation of amide-amine generated from Hdpf acylbenzotriazole and ethylenediamine. Reaction of the acylbenzotriazole with free guanidine leads to [1-(diphenylphosphino)ferrocenecarbonyl]guanidine hydrochloride. These ferrocene ligands were used to prepare four types of palladium(II) complexes, viz. where L denotes the newly synthesized ligands and LNC is 2- [(dimethylamino)methyl]phenyl-C,N auxiliary chelating ligand. Catalytic efficiency of complexes with ethylene bridge was tested on reactions of aromatic...

La mer de Barents possède un écosystème particulièrement riche. Elle est affectée par le changement climatique actuel, comme le reste de l'Arctique. L'effet le plus visible et le plus connu est la réduction spectaculaire de la banquise. On examine dans cette thèse les répercussions de ces changements sur l'hydrologie et le phytoplancton en mer de Barents. Pour cela, on s'appuie sur la création d'une base de données historiques comprenant les paramètres hydrologiques et bio-géochimiques. Un modèle 3D bio-géochimique spécifique à l'écosystème arctique est aussi utilisé quand les observations sont manquantes. Enfin, les données satellites fournissent des séries temporelles de concentration de glace, de Chlorophyle-a...La mer de Barents est caractérisée par un front polaire séparant les eaux atlantiques issues des mers Nordiques des eaux arctiques dont la position est connue à l'ouest de 35°E. Nous avons pu montrer que ce front se sépare en deux branches dans l'Est du bassin: le front du Nord et le front du Sud. Ces fronts enferment les eaux de la mer de Barents qui se forment en hiver. Un doublement du volume des eaux atlantiques (une " Atlantification " de la mer de Barents), a aussi été mise en évidence. Elle accompagne un déplacement des fronts Nord et Sud vers le Nord-est. Le volume des eaux de la mer de Barents reste inchangé.Ces changements, affectant l'hydrologie et la glace de Mer, ont un impact significatif sur le phytoplancton. Les deux efflorescences qui le caractérisent ont lieu plus au Nord et à l'Est. La biomasse totale annuelle a augmenté de 40% lors des deux dernières décennies. Ce travail montre que les conditions de glace de mer et la structure frontale sont les paramètres clefs dirigeant la variabilitéinter-annuelle du phytoplancton. / The Barents Sea has a particularly rich ecosystem. This is an Arctic region subject to intense climate changes. The drastic decrease in sea ice cover is the most visible effect. What are the impacts of these climatic changes on the hydrology and phytoplankton? In order to answer these questions, this thesis relies on the creation of an extensive historical database of physical and bio-geochemical parameters. A 3D bio-geochemical model with an Arctic specific ecosystem is used when observations are lacking. At least, remote sensing data provides valuable time series of Ice concentration, Chlorophyll-a... The Polar Front, separating the Atlantic Water coming from the Nordic Sea from the Arctic Water, is the principal feature of the Barents Sea region. Its position is known west of 35°E, but we showed that the polar front splits into two branches in the East part of the Barents Sea: the "Southern Front" and the "Northern Front". They enclose the winter locally formed Barents Sea Water. An “Atlantification”, illustrating a doubling of the Atlantic Water volume, has been evidenced and goes along with a North-eastward shift of the fronts. These hydrological and sea ice changes have a significant impact on the phytoplankton development. The two blooms of the Barents Sea occur further North and East with a 40% total anual biomass increase for the last two decades. This study suggests that the winter sea ice conditions and the frontal structure are the key mechanisms driving the inter-annual phytoplankton variability.

This thesis focuses on the long-term rotational stability of the Earth and terrestrial planets. One important class of perturbation is a reorientation of the solid planet with respect to a rotation pole that remains fixed in an inertial frame. These motions are driven by mass redistribution within or on the surface of the planet (e.g. glaciation, mantle convective flow). Long-term changes in the orientation of the rotation pole are called True Polar Wander (TPW). / Earth and Planetary Sciences

Since the sandwich structure of ferrocene was elucidated in 1952, metallocenes have generated a vast amount of interest. Transition metal metallocenes have previously been shown to be suitable precursors in the syntheses of novel organometallic and metallo-organic complexes, although the use of metal halide starting materials for organometallic synthesis is much more common due to their being readily commercially available and generally easier to handle than the extremely air- and moisture-sensitive metallocene alternatives. In this project, the polar transition metal metallocenes Cp2V, Cp2Cr, Cp2Mn and Cp2Ni were employed as precursors in the synthesis of fourteen novel metal containing complexes, in several cases generating products which could not have been obtained using metal halide starting materials.

This thesis focuses on video watermarking robust against geometric attacks and video compressions. In addition to the requirements for an image watermarking algorithm, a digital video watermarking algorithm has to be robust against advanced video compressions, frame loss, frame swapping, aspect ratio change, frame rate change, intra- and inter-frame filtering, etc. Video compression, especially, the most efficient compression standard, H.264, and geometric attacks, such as rotation and cropping, frame aspect ratio change, and translation, are considered the most challenging attacks for video watermarking algorithms. In this thesis, we first review typical watermarking algorithms robust against geometric attacks and video compressions, and point out their advantages and disadvantages. Then, we propose our robust video watermarking algorithms against Rotation, Scaling and Translation (RST) attacks and MPEG-2 compression based on the logpolar mapping and the phase-only filtering method. Rotation or scaling transformation in the spatial domain results in vertical or horizontal shift in the log-polar mapping (LPM) of the magnitude of the Fourier spectrum of the target frame. Translation has no effect in this domain. This method is very robust to RST attacks and MPEG-2 compression. We also demonstrate that this method can be used as a RST parameters detector to work with other watermarking algorithms to improve their robustness to RST attacks. Furthermore, we propose a new video watermarking algorithm based on the 1D DFT (one-dimensional Discrete Fourier Transform) and 1D projection. This algorithm enhances the robustness to video compression and is able to resist the most advanced video compression, H.264. The 1D DFT for a video sequence along the temporal domain generates an ideal domain, in which the spatial information is still kept and the temporal information is obtained. With detailed analysis and calculation, we choose the frames with highest temporal frequencies to embed the fence-shaped watermark pattern in the Radon transform domain of the selected frames. The performance of the proposed algorithm is evaluated by video compression standards MPEG-2 and H.264; geometric attacks such as rotation, translation, and aspect-ratio changes; and other video processing. The most important advantages of this video watermarking algorithm are its simplicity, practicality and robustness.

Thesis (M. Sc. (Animal Production)) -- University of Limpopo / The objectives of this study were: 1) To determine the effect of oocyte retrieval techniques (slicing and aspiration) on the quality and quantity of cattle oocytes, 2) To evaluate the effect of different concentrations of hormones on the maturational rate of cattle oocytes selected by brilliant cresyl blue staining, 3) To evaluate fertilization rate and cleavage/embryonic development of oocytes with or without cumulus cells, and 4) To compare the effect of fresh and frozen thawed semen on the fertilization rate of cattle oocytes. In Experiment 1: oocytes were recovered from abattoir derived ovaries using slicing and aspiration. The recovered oocytes were exposed for 90 minutes to 26μM of brilliant cresyl blue (BCB) stain and classified according to the colour of their cytoplasm: BCB+ (oocytes with blue cytoplasm) and BCB- (unstained oocytes). There was no difference (P>0.05) in the quality of oocytes recovered using slicing (60.7 %) or aspiration (53.7 %) techniques. In experiment 2: The BCB selected and the non-selected immature oocytes were randomly allocated into medium 199 + 10 % fetal bovine serum (FBS) maturation media. The media was supplemented with three different concentrations of hormones as treatments (T). The T1 (0.5 μg/ml of follicle stimulating hormone (FSH), 5mg/ml of luteinizing hormone (LH) and 2 μg/ml of estradiol (E2) as the control group. Then, T2 (1 μg/ml of FSH, 6 mg/ml of LH and 2.5 μg/ml of E2) and T3 (1.5 μg/ml of FSH, 7 mg/ml of LH and 4.5 μg/ml of E2). Maturation rate of oocytes was determined by the protrusion of the first polar bodies 24 hours following in vitro maturation. Treatment 2 yielded higher (P<0.05) maturation rate for both BCB+ (65.6 %) and without BCB (60.3 %) oocytes with T1 giving lower (P<0.05) maturation rate for BCB+ (22 %) and without BCB (16 %) oocytes. However, BCB- oocytes had lower (P<0.05) polar body extrusion (3.03 %, 8.1 % and 2.2 %) for T1, T2 and T3, respectively. In Experiment 3: one group of the presumptive zygotes was denuded of cumulus cells and the other group was cultured with cumulus cells. The presumptive zygotes were in vitro cultured in SOF-BSA and changed to SOF-FBS after 48 hours. High fertilization/cleavage rate was observed in oocytes cultured with cumulus cells (29.0 %) compared to the denuded oocytes (20.0 %) for 2-4 cells stage. Day 7 blastocysts were more (P<0.05) on oocytes cultured with cumulus cells (32 %) compared to denuded oocytes (13 %). In experiment 4: The matured oocytes were fertilized using fresh and frozen thawed semen. The oocytes fertilized with frozen thawed semen obtained a better number of 2-4 cell cleavage (23 %) when compared to fresh semen (19 %). Oocytes that were fertilized with frozen thawed semen also obtained higher morula (13 %) and blastocyst (8 %) compared to fresh semen with morula (3.4 %) and blastocyst (2 %). In conclusion, immature oocytes that were exposed to BCB+ and cultured in M199 supplemented with 10 % FBS, 0.5 μg/ml of FSH, 5 mg/ml of LH and 2 μg/ml of E2 had a higher (P<0.05) number of matured oocytes (extrusion of first polar body) compared to those that were not exposed to BCB (no BCB). Oocytes that were cultured with cumulus cells yielded a higher (P<0.05) number of cleaved embryos compared to the denuded oocytes. Slicing yielded a higher (P<0.05) number of oocytes, however the quality of oocytes recovered was similar compared to those recovered by the aspiration technique (P>0.05). Oocytes fertilized with frozen thawed semen yielded higher (P<0.05) number of 2-4 cell, morula and blastocyst when compared with oocytes that were fertilized using fresh semen. Keywords: ovaries, oocytes, slicing, aspiration, COCs, BCB, polar body and cattle

Thesis (M. Sc. (Animal Production)) -- University of Limpopo, 2015 / The objectives of this study were: 1) To determine the effect of oocyte retrieval techniques (slicing and aspiration) on the quality and quantity of cattle oocytes, 2) To evaluate the effect of different concentrations of hormones on the maturational rate of cattle oocytes selected by brilliant cresyl blue staining, 3) To evaluate fertilization rate and cleavage/embryonic development of oocytes with or without cumulus cells, and 4) To compare the effect of fresh and frozen thawed semen on the fertilization rate of cattle oocytes. In Experiment 1: oocytes were recovered from abattoir derived ovaries using slicing and aspiration. The recovered oocytes were exposed for 90 minutes to 26μM of brilliant cresyl blue (BCB) stain and classified according to the colour of their cytoplasm: BCB+ (oocytes with blue cytoplasm) and BCB- (unstained oocytes). There was no difference (P>0.05) in the quality of oocytes recovered using slicing (60.7 %) or aspiration (53.7 %) techniques. In experiment 2: The BCB selected and the non-selected immature oocytes were randomly allocated into medium 199 + 10 % fetal bovine serum (FBS) maturation media. The media was supplemented with three different concentrations of hormones as treatments (T). The T1 (0.5 μg/ml of follicle stimulating hormone (FSH), 5mg/ml of luteinizing hormone (LH) and 2 μg/ml of estradiol (E2) as the control group. Then, T2 (1 μg/ml of FSH, 6 mg/ml of LH and 2.5 μg/ml of E2) and T3 (1.5 μg/ml of FSH, 7 mg/ml of LH and 4.5 μg/ml of E2). Maturation rate of oocytes was determined by the protrusion of the first polar bodies 24 hours following in vitro maturation. Treatment 2 yielded higher (P<0.05) maturation rate for both BCB+ (65.6 %) and without BCB (60.3 %) oocytes with T1 giving lower (P<0.05) maturation rate for BCB+ (22 %) and without BCB (16 %) oocytes. However, BCB- oocytes had lower (P<0.05) polar body extrusion (3.03 %, 8.1 % and 2.2 %) for T1, T2 and T3, respectively. In Experiment 3: one group of the presumptive zygotes was denuded of cumulus cells and the other group was cultured with cumulus cells. The presumptive zygotes were in vitro cultured in SOF-BSA and changed to SOF-FBS after 48 hours. High fertilization/cleavage rate was observed in oocytes cultured with cumulus cells (29.0 %) compared to the denuded oocytes (20.0 %) for 2-4 cells stage. Day 7 blastocysts were more (P<0.05) on oocytes cultured with cumulus cells (32 %) compared to denuded oocytes (13 %). In experiment 4: The matured oocytes were fertilized using fresh and frozen thawed semen. The oocytes fertilized with frozen thawed semen obtained a better number of 2-4 cell cleavage (23 %) when compared to fresh semen (19 %). Oocytes that were fertilized with frozen thawed semen also obtained higher morula (13 %) and blastocyst (8 %) compared to fresh semen with morula (3.4 %) and blastocyst (2 %). In conclusion, immature oocytes that were exposed to BCB+ and cultured in M199 supplemented with 10 % FBS, 0.5 μg/ml of FSH, 5 mg/ml of LH and 2 μg/ml of E2 had a higher (P<0.05) number of matured oocytes (extrusion of first polar body) compared to those that were not exposed to BCB (no BCB). Oocytes that were cultured with cumulus cells yielded a higher (P<0.05) number of cleaved embryos compared to the denuded oocytes. Slicing yielded a higher (P<0.05) number of oocytes, however the quality of oocytes recovered was similar compared to those recovered by the aspiration technique (P>0.05). Oocytes fertilized with frozen thawed semen yielded higher (P<0.05) number of 2-4 cell, morula and blastocyst when compared with oocytes that were fertilized using fresh semen. Keywords: ovaries, oocytes, slicing, aspiration, COCs, BCB, polar body and cattle

The Antarctic sea ice region is relatively stable in extent from year to year and sees little long-term variability, the primary driver for its seasonal advance and retreat being the seasonal changes in advection of heat through the atmosphere. However, observations show a slight positive trend in its extent over recent decades. Recent work has built on the hypothesis that anomalous poleward moisture fluxes could be seen in concert with anomalous decreases in sea ice variability by providing evidence of this correlation in the Arctic sea ice region. In order to test this hypothesis and to investigate the atmospheric circulation patterns during states of low sea ice concentration in the Antarctic, records of de-seasonalized sea ice concentration anomalies are made for five regions of the Antarctic polar region, and composite distributions of variables of atmospheric circulation for the lowest 10th percentile of months with low mean sea ice concentration are compiled. Meridional moisture fluxes from these composites are tested against the entire population of meridional moisture fluxes using the Student's t-test with a confidence level of 95%, and the differences from the overall mean fields for atmospheric conditions during these cases are calculated. Of the five regions, the Ross Sea, Weddell Sea, and Pacific Ocean sections exhibit significant local moisture flux anomalies in the direction of the pole during months with low sea ice concentration, supporting the hypothesis that moisture transport into the polar region is important for the variability of sea ice in the Antarctic. The Bellingshausen - Amundsen Seas and Indian Ocean sectors show weak local signals of poleward moisture fluxes, indicating that there are other varying factors affecting the sea ice more heavily in these regions. Mean geopotential height anomalies during months with anomalously low sea ice concentration indicate that the Weddell Sea and Pacific Ocean regions are coupled with the positive phase of the Southern Annular Mode, while low sea ice concentration in the Indian Ocean as well as the Bellingshausen and Amundsen Seas regions show concurrence with the negative phase. With general circulation models predicting a persistence of the positive phase of the Southern Annular Mode in a warming climate, it is important to understand how the Antarctic sea ice region responds to the phase of this oscillation.

Title: Comparison of functions of sports testers designed for control and monitoring of parameters of movement in water Objectives: Comparison and evaluation of individual functions of selected sport-testers in different types of swimming training. Methods: The research group consisted of one probande, a student of Charles University FTVS. In the research, we chose a controlled observation method to detect and compare the individual functions of selected sports testers over three types of swimming training. Results: Based on an analysis of the accuracy of the recording of observed quantities for individual sporttesters, we found that the sporttesters Polar and Garmin can be used both to manage and guide and control swimming training. However, the final record needs to be supplemented by the exact sum of the swimming metres, which in turn refines the results of the average swimming speed. The Swimmo sports tester was rated the worst, based on inaccurate measurements of individual quantities and instrument control. In an overall assessment of all devices and their parameters, the Sporttester Polar was the best. Keywords: heart rate, swimming training, Garmin, Polar, Swimmo